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1.
SolidStatePhysics ,SolidStateChemistryandNewMaterials4 4 5 Emissionfromdivalentdysprosium (Dy2 +)incrys tallinestrontiumtetraborate ,XuWuetal.,Chi neseJournalofLuminescence ,2 0 0 1 ,2 2 (4 ) ,3 67.4 4 6 RelationshipbetweenspectralpropertiesandlocalstructureofEu3+inAlF3 basedfluorideglasses ,WuChongfengetal.,ChineseJournalofLumines cence ,2 0 0 1 ,2 2 (4 ) ,3 93 .4 4 7 Propertiesofstuctureandup conversionlumines cenceinTm3+andEr3+co dopedfluoride oxidevitroceramics,QinGuanshietal.…  相似文献   

2.
In order to elucidate the action of La3+ on bone metabolism,effects of La3+ on the osteogenic and adipogenic differentiation of pri-mary mouse bone marrow stromal cells(BMSCs) were studied by 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyl tetrazolium bromide(MTT) test,alkaline phosphatase(ALP) activity measurement,mineralized function,oil red O stain and measurement.The results showed that La3+ pro-moted the proliferation of BMSCs except at 1×10-10 and 1×10-6 mol/L.The effect of La3+ on the osteogenic differentiation depended on con-centrations at the 7th day,but the osteogenic differentiation was inhibited at any concentration at the 14th day.La3+ promoted the formation of mineralized matrix nodules except at 1×10-8 and 1×10-5 mol/L.La3+ inhibited adipogenic differentiation except at 1×10-10 and 1×10-7 mol/L at the 10th day,and inhibited adipogenic differentiation except at 1×10-9 mol/L at the 16th day.These findings suggested that La3+ might have protective effect on bone at appropriate dose and time.This would be valuable for better understanding the mechanism of the effect of La3+ on bone metabolism.  相似文献   

3.
In:Ho:LiNbO3 crystals doped with various concentrations of In3+(0, 1 mol.%, 3 mol.%, 5 mol.%), fixed concentrations of Ho3+ (1 mol.%) were grown by Czochralski method. The X-ray powder diffraction, infrared and UV-visible absorption spectra were measured and modified. Judd-Ofelt approach was employed to study the effect of In doping on spectroscopic properties of Ho:LiNbO3 crystals. In concentrations in crystals were analyzed by an inductively coupled plasma optical emission spectrometry (ICP-OE/MS). For In (3 mol.%):Ho (1 mol.%):LiNbO3 crystal, the obtained intensity parameters were: Ω2=9.6563, Ω4=4.2195, Ω6=14.1526. The results showed that the Ω2 and Ω6 parameters increased with the increase of In3+ concentration. When the In doping concentration was up to 5 mol.%, Ω2 and Ω6 suddenly decreased. In2O3 incorporation had a strong effect on the radiative lifetime, but had less influence on fluorescence branching ratios. The effective distribution coefficient of In3+ in In:Ho:LiNbO3 crystals was less than 1 and increased with increasing concentration of In3+ in the melt.  相似文献   

4.
The Agrobacterium sp.HN1 was isolated from the soil and used to adsorb rare earth ions La3+ and Ce3+.The results showed that the pretreatments of Agrobacterium sp.HN1 did not enhance the adsorption of La3+ and Ce3+.The pH,temperature,time and bacterial age affected the dynamics of adsorption of La3+ and Ce3+.The optimum adsorption conditions for Agrobacterium sp.HN1 were as follows:15 mg/L La3+ of initial concentration,10 mg/L Ce3+,300 mg/L(dry wt.cell) biomass for sorption,6.8 pH,30 oC temperature,150 r/min rotational speed,2 h adsorption time and 28 h bacterial age.The adsorption kinetics of La3+ and Ce3+ for Agrobacterium sp.HN1 followed the pseudo-second order equation.  相似文献   

5.
Organicelectroluminescence (OEL)hasbeenex tensivelystudiedbecauseoftheirpotentialapplicationinflatpaneldisplayssincethefirsttwo layerOELde vicewithhighefficiencyandluminancewasfabricatedin 1987[1~ 3] .Rareearth (RE)metalcomplexeshavesomegoodcharacteristics ,suchasextremelynarrowe missionbandsandhighinternalquantumefficiencies ,whicharesuitableforuseastheemissionmaterialsinOEL[4 ] .Tb3+complexwasfirstintroducedintoOELdevices ,andsharpgreenemissionfromTb3+ionhasbeenobserved[5] .Sincethen …  相似文献   

6.
Ceriumoxideisusedwidelyinthree waycatalystduetoitsoxygenstoragecapabilitywhichenablesthecatalysttooperatemoreefficientlybymakingitlesssensitivetothevariationofoxygenconcentrationinex haustgasstream[1~ 3] .TheoxygenstoragecapabilityofceriastemsfromthevalencechangebetweenCe3+andCe4 +[1,2 ] .Thereareafewotherelementswithvariableoxidationstatewithinthewholeseriesofrareearth .Praseodymiumisoneoftheelementswhichcanformaspectrumofoxygen deficientornonstoi chiometricPrOx.Ontheotherhand ,theproperti…  相似文献   

7.
TheNd3+ dopedgadoliniumvanadateisanewtypeofcrystalwithsuperiorlaserproperties .ItwasfirstpreparedsuccessfullybyscientistsinRussiaandGermany[1] ,thereafter ,inJapan[2 ] ,China[3] ,etc .Alloutgrewcrystalshavebeenverifiedtohaveopticqualityandexcellentlaserproperties .Recently ,BeijingUniversityofTechnologyhasstudiedthecrystaldislocationbythechemicaletchingmethod[4 ] .TheGd VO4 crystalbelongstothetetragonalsystemandhasazirconstructurewith 4 /mmmofpointgroup ,D194h =I4 1/amd (14 1)ofspacegrou…  相似文献   

8.
9.
N31-type phosphate laser glasses doped with different concentrations of Cu were prepared. Their optical loss coefficient at 1053 nm wavelength and nonradiative transition rate from the Nd3+ 4F3/2 state were determined and analyzed in detail. The optical loss coefficient per unit of Cu2+ (cm-1/ppmw) and the fluorescence decay rate (Hz/ppmw) caused by Cu2+ and Nd3+ interaction were 0.0024 and 7.9, respectively. Cu impurity affected both optical loss at 1053 nm and fluorescent emission of Nd3+ 4F3/2 state seriously in N31 laser glass.  相似文献   

10.
In order to improve the luminescence properties of CaTiO3:Pr3+, a series of CaTiO3:Pr3+, such as CaTi0.97Nb0.03O3:Pr3+, Ca0.8Zn0.2TiO3: Pr3+, Ca0.8Zn0.2Ti0.97Nb0.03O3:Pr3+ and B3+-doped Ca0.8Zn0.2Ti0.97Nb0.03O3: Pr3+ were prepared through conventional solid state reaction method. The results of the photoluminescence excitation and emission spectra showed that all the samples emitted red phosphorescence at 612 nm originating from 1D2 to 3H4 emission of Pr3+ under the 337 nm excitation. When examined by the X-ray diffraction (XRD), all the samples presented a predominant phase of CaTiO3 (JCPDS# 42-423) except Zn2+-doped samples which also revealed another phase of Zn2Ti3O8 (JCPDS# 73-579). The results of the afterglow decay curves showed that co-doping Zn2+ ions, Nb5+ ions or adding a small amount of B3+ into Ca0.8Zn0.2Ti0.97Nb0.03O3:Pr3+ were effective in improving the photoluminescence properties of CaTiO3:Pr3+ phosphor. Thermoluminescence results showed that the trap existing in all the samples was the same as in CaTiO3:Pr3+ and doping singly Nb5+ or Zn2+ hardly changed the trap depth but co-doping Nb5+ and Zn2+ could modify the trapping level from 0.63 to 1.26 eV distinctively. In addition, adding a certain amount of B3+ into CTO-PZN could also deepen the trap depth.  相似文献   

11.
Mechanism of Effect of Lanthanum Nitrate on Vigor of Aged Rice Seeds   总被引:2,自引:0,他引:2  
Seedsearlydegeneratedoragedbyun suitablecultivationorunstoragetechniquesmayresultindecreasingofseedvigorandofthecropsoutput,especiallyforrice.Rareearthsacceleratethegerminationandgrowthofthecrops ,suchasrice ,wheat,barley ,veg etablesandoilplants[1~ 3] .Thest…  相似文献   

12.
稀土对水稻种子活力及抗重金属污染的影响   总被引:14,自引:0,他引:14  
邢勇  贾稝  周亚俊 《稀土》2004,25(3):46-48
水稻种子经稀土元素La或Ce处理后,发芽势、发芽率、发芽指数、幼苗生长速度、活力指数都明显增加,田间的生长速度、产量甚至品质也显著提高,收获的籽粒中重金属Hg、Cd、Cr、Pb含量大幅降低,从而全面提高了种子活力。  相似文献   

13.
The purpose of this study is to determine the effect of La3+ solution on seed germination and seedling growth of Salvia miltiorrhiza. Different concentrations of La3+ were used on seed by soaking treated to determine which concentration is the most suitable for the growth of S. miltiorrhiza. Results show that the low concentration of La3+ displays the promotion effect on S. miltiorrhiza seed germination rate and germination potential, and the promotion effect reaches the highest level when the concentration of La3+ solution is 30 mg/L, the germination index and vigor index are the highest in 20 mg/L, and it can also increase the contents of soluble sugar, soluble protein and chlorophyll. Meanwhile, the activity of antioxidant enzyme system (CAT and SOD) are improved, thus the photosynthesis and resistance of plant are enhanced. On the contrary, when the La3+ concentration is high, La3+ can inhibit plant growth. Thus La3+ displays the "homesis effect" on S. miltiorrhiza growth.  相似文献   

14.
A novel type of cysteine synthase (CSase, EC 4.2.99.8) isozyme, designated as CSase 1', was purified to homogeneity from hydrated spinach seeds. The enzyme had a molecular weight of 68,000 and consisted of two identical subunits of M(r), 34,000. The apparent K(m) for O-acetyl-L-serine was 8.33 mM and that for sulfide was 0.66 mM. The activity of CSase 1' was maintained when it was treated at 60 degrees C for 1 min. This novel enzyme was similar to CSases 1, 2, and 3 already purified from spinach leaves, in results of double immunodiffusion, molecular weight, subunit composition, K(m) values for O-acetyl-L-serine and sulfide, and heat stability. On the other hand, N-terminal amino acid sequence, effects of immunotitration, pH optimum, and effects of hydroxylamine on purified CSase 1' were different from those of the other CSases. Furthermore, it was found that CSases 2S and 3S isolated from hydrated spinach seeds were identical with the CSases 2 and 3 reported previously. It was also disclosed that CSases 1, 2, and 3 were localized in chloroplasts, cytosol, and mitochondria, respectively.  相似文献   

15.
Arabidopsis thaliana seeds imbibed for a short duration show phytochrome B (PhyB)-specific photo-induction of germination. Using this system, the relationship was determined between the amount of PhyB in seeds and photon energy required for PhyB-specific germination in two transgenic Arabidopsis lines transformed with either the Arabidopsis PhyB cDNA (ABO) or the rice PhyB cDNA (RBO). Immunochemical detection of PhyB apoprotein (PHYB) showed that the expression level of PHYB in ABO seeds was at least two times higher than that in the wild-type seeds, but in RBO seeds the PHYB level was indistinguishable from that in wild-type seeds. The photon fluence required for induction and photoreversible inhibition of germination was examined using the Okazaki large spectrograph. At the wavelengths of 400-710 nm, the ABO seeds required significantly less photon fluence than wild-type seeds for induction of germination, whereas the RBO seeds required similar fluence to wild-type seeds. A critical threshold wavelength for either induction or inhibition of germination of ABO seeds shifted towards the longer wavelengths relative to wild-type seeds. By assuming that PhyA and PhyB are similar in their photochemical parameters, amounts of Pfr at each wavelength were calculated. The photon fluence required for 50% germination was equivalent to the fluence generating a Pfr/Ptot ratio of 0.21-0.43 in wild-type seeds, and of 0.035-0.056 in ABO seeds. These results indicate that PhyB-specific seed germination is not strictly a function of the Pfr/Ptot ratio, but is probably a function of the absolute Pfr concentration.  相似文献   

16.
The efficacy of a 20,000 ppm calcium hypochlorite treatment of alfalfa seeds artificially contaminated with Salmonella was studied. Salmonella populations reached >7.0 log on sprouts grown from seeds artificially contaminated with Salmonella and then treated with 20,000 ppm Ca(OCl)(2). The efficacy of spray application of chlorine (100 ppm) to eliminate Salmonella during germination and growth of alfalfa was assessed. Alfalfa seed artificially contaminated with Salmonella was treated at germination, on day 2 or day 4, or for the duration of the growth period. Spray application of 100 ppm chlorine at germination, day 2, or day 4 of growth was minimally effective resulting in approximately a 0.5-log decrease in population of Salmonella. Treatment on each of the 4 days of growth reduced populations of Salmonella by only 1.5 log. Combined treatment of seeds with 20,000 ppm Ca(OCl)(2) and followed by 100 ppm chlorine or calcinated calcium during germination and sprout growth did not eliminate Salmonella.  相似文献   

17.
稀土浸种对油菜种子萌发及种苗生长的生物效应   总被引:10,自引:2,他引:8  
浓度低于(800μg/mL)稀土可促进油菜种子萌发的启动。使用浓度为100μg/mL,12小时计数其发芽率为25%,对照为12%。但浓度高于1000μg/mL时,会明显抑制萌发。处理浓度低于800μg/mL时,稀土浸种对油菜种苗根系的生长有明显促进作用。表现为根长、根鲜重增加,根系活力和幼根内源激素—GAs、IAA含量都得到提高。幼苗子叶中叶绿素含量提高。高浓度(>1000μg/mL)对幼苗生长会有抑制作用,正常苗的百分比下降。  相似文献   

18.
Effect of Nd^3+ on Photosynthesis of Spinach   总被引:5,自引:0,他引:5  
The effect of Nd^3 on the photosynthesis and the growth of spinach was studied. The results show that Nd^3 improves the growth of spinach and increases chlorophyll content and photosynthetic rate. UV-Vis spectrum indicates that the Soret band of chl-a in spinach with NdCl3 treatment is blue shifted by 2 nm, and the Q band is red shifted by 1 nm, and the ratio of Soret band intensity and Q band intensity increases. FT-IR spectra show that the peak of porphyrin ring in chl-a of spinach with NdCl3 treatment is widened, suggesting that the formation of Nd^3 -chl-a. Treated by NdCl3, the fluorescence emission peak of PSⅡ in spinach leaves is blue shifted by 12 nm and the intensity declines obviously, indicating that Nd^3 is bound to the PSⅡ protein-pigment complex and the electron transfer rate increases.  相似文献   

19.
We have mapped the expression of the tonoplast intrinsic protein (TIP) gene family members in Arabidopsis seeds by fluorescent protein tagging of their genomic sequences and confocal microscopy. Three isoforms (TIP1;1, TIP2;1,and TIP2;2) have distinct patterns of expression in maternal tissues (outer integument and placento-chalazal region). Two isoforms, TIP3;1 and the previously uncharacterized TIP3;2, are the only detectable TIPS in embryos during seed maturation and the early stages of seed germination. Throughout these developmental stages, both isoforms co-locate to the tonoplast of the protein storage vacuoles, but also appear to label the plasma membrane. Plasma membrane labeling is specific to TIP3;1 and TIP3;2, is independent of the position of the fluorescent protein tag, and appears to be specific to early seed maturation and early germination stages. We discuss these results in the context of the predicted distribution of aquaporins in Arabidopsis seeds.  相似文献   

20.
The effects of exogenous growth factors (indolacetic acid, gibberellic acid and kinetin and steroidal hormones (estrone, estradiol and testosterone on the germination pattern of Pinus pinea seeds were studied. Nucleic acids metabolism during the stages before germination, has also been investigated. Seeds sown in the presence of all these substances, showed a higher growth rate and a higher germination degree than their respective controls; kinetin and estradiol were the most active factors. The level of total nucleic acids was studied in seeds after one day soaking and on the 1rst, 3rd, 5th, and 7th day after sowing. Megagametophytes contained a higher amount of acids when growth factors and steroidal hormones were present, specially after one day soaking. In embryos; after the 3rd day, a similar result was obtained. The RNA fraction increased the most.  相似文献   

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