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1.
Gd2O3: Eu^3 phosphors were prepared by urea homogeneous precipitation with different surfactant and sol-gel method. XRD patterns show that all the obtained samples are in cubic Gd2O3, and the results of FTIR and fluorescent spectra conformed that OP is a good surfactant for preparing the Gd2O3:Eu^3 phosphors. The SEM photographs show that the particles prepared by urea homogeneous precipitation method are all spherical and well-dispersed, and grain morphology can be controlled by different surfactant. XRD and SEM indicate that the particle sizes prepared by sol-gel method are in the range of 5-30 nm, and the grain sizes increase with increasing of heated temperatures. Luminescence spectra indicat that the main emission peaks of all samples are at 610 nm, the intensities are different from samples prepared with different surfactant and the luminescence intensities increase with increasing of annealed temperatures.  相似文献   

2.
The (60 - x)Bi2O3 - xGeO2-30B2O3-10ZnO (x = 5, 10, 20, 30 molar percent) glasses doped with Er^3+ and Er^3+/Yb^3+ were fabricated using the melting method. The thermal stability of the glasses was studied with their DTA curves. The results show that the difference between the glass transition temperature and the crystallization onset temperature increases with the increase of GeO2 content, indicating that the thermal stability of the glass has become better. The absorption spectra were recorded and the stimulated emission cross sections were calculated using the McCumber theory. The Ω2, O4, and Ω6 parameters,the transition probability, the radiative lifetime, and the fluorescence branch ratio of Er^3+ for optical transition were calculated from their absorption spectra in terms of reduced matrix U^(t)(λ = 2, 4, 6) character for optical transitions. The infrared emission of Er^3+ was measured upon excitation with 970 nm light and the full width at half-maximum (FWHM) was estimated from the emission spectra. The pumping efficiency and the intensity of the emission at the 1.54 μm band of Er^3+ were enhanced considerably by co-doping Yb^3+ .  相似文献   

3.
The hardystonite phosphors of Eu2+ activated M2ZnSi2O7(M=Sr,Ba) were synthesized by combustion-assisted method.They were systematically characterized by photoluminescence excitation and emission spectra.The emission spectra of these two phosphors showed that the main emission peaks are at 475 and 503 nm due to 4f65d1→4f7 transition of Eu2+.Both phosphors could be efficiently excited in the wavelength range of 250-425 nm where the near ultraviolet light-emitting diode was well matched.The(x,y) color coordinates were determined with the emission values(x,y)=(0.41,0.21) and(0.16,0.45) for the M2ZnSi2O7:Eu2+(M=Sr,Ba) phosphors.  相似文献   

4.
The new phosphor calcium magnesium chlorosilicate, codoped with Eu^2+ and Dy^3+, was synthesized with the help of the high temperature solid state reaction in reducing atmosphere. The excitation and emission spectra were very similar to that of Ca8Mg(SiO4)4Cl2 :Eu^2+, and the Dy^3+ concentration influenced the emission intensity of this phosphor. The intensity of Eu^2+ and Dy^3+ codoped CMSC was stronger than that of Eu^2+ singly doped CMSC. The emission spectrum of the Dy^3+ ion overlapped the absorption band of the Eu^2+ ion, indicating that an energy transfer from Dy^3+ to Eu^2+ took place in CMSC:Eu^2+, Dy^3+ phosphor. The mechanism of the energy transfer from Dy^3+ tO Eu^2+, in this phosphor, might be resonant energy transfer.  相似文献   

5.
Sr2Al2SiO7:Ce^3+, Tb^3+ white emitting phosphors were fabricated using the sol-gel method. X-Ray Powder Diffraction (XRD) analysis confirmed the formation of Sr2Al2SiO7:Ce^3+, Tb^3+. Scanning Electron Microscopy (SEM) observation indicated that the microstructure of the phosphor consisted of regular fine grains with an average size of about 0.5-1 μm. Luminescence properties were analyzed by measuring the photoluminescence spectra. The Ce^3+, Tb^3+-codoped Sr2Al2SiO7 phosphors showed four main emission peaks: one at 414 nm for Ce^3+ and three at 482, 543, and 588 nm for Tb^3+. The emission spectra of the samples with different doping concentrations showed that the Tb^3+ emission was dominant because of the persistent energy transfer from Ce^3+. The decay characteristic was better than that prepared by the solid-state process in the comparable condition. The codoped phosphor displayed long persistent white phosphorescence.  相似文献   

6.
M0.2Ca0.8TiO3 : Pr^3 (M = Mg^2 , Sr^2 , Ba^2 , Zn^2 ) long persistence red phosphors were prepared by solid state reaction. The influence of the partially replacing Ca^2 in CaTiO3 with Mg^2 , Sr^2 , Ba^2 , Zn^2 on the excitation spectra, the emission spectra and the long persistence properties were studied. The results suggest that certain quantity of Mg^2 , Sr^2 , Ba^2 , Zn^2 which partially replace Ca^2 can enhance the luminescent intensity and prolong the afterglow persistence of the samples. The intensity of Mg0.2Ca0.8TiO3: Pr^3 is above all of the samples. Take Mg0.2Ca0.8TiO3:Pr^3 as the basic sample, the influence of Pr^3 concentrations (C (Pr^3 )) on the long afterglow properties were also studied.The results suggest that when the C (Pr^3 ) is 0.10% (tool fraction) the intensity of the sample is the highest. The excitation spectra of all these samples show broad band spectra ranging from 300 - 500 nm peaking at about 342 nm. The emission spectra also exhibit a broad band peaking at 613 nm (CaTiO3: Pr^3 is 612 nm). XRD research indicates that the crystalline phases change due to the replacement of divalent metal ions. The research on the thermoluminescence spectra of Mg0.2Ca0.8TiO3:Pr^3 indicates that the peak is at 107.35℃ and the depth of the trap energy is about 0.852 eV.  相似文献   

7.
Long-Lasting Properties of Rare Earth-Doped Y2O2S Phosphors   总被引:1,自引:0,他引:1  
The aim of this presentation is to report a new result of afterglow materials. The Y2O2S:Ln^3 (Ln = Sm, Tm)phosphors show bright reddish orange and orange-yellow colors when excited by UV or visible light. The main spectroscopic characterizations of Sm^3 and Tm^3 in yttrium oxysulfide and their long-lasting phosphorescence were measured and discussed in this presentation. Their long-lasting phosphorescence can be seen by the naked eyes clearly for about one hour in the dark room after the irradiation light sources were removed. XRD and photoluminescence (PL) spectra as well as the luminance decay were used to characterize these long-lasting phosphorescence phosphors. The results of XRD indicate that the products synthesized through the flux fusion method under 1050℃ for 6 h have a good crystallization without any detectable amount of impurity phase. Both the PL spectra and luminance decay results reveal that these phosphors have efficient luminescent and good long-lasting properties. We believe that the experimental data gathered in our present work will be useful in finding some new long-lasting phosphors with different colors.  相似文献   

8.
The (Ba1- x, Srx ) 2 SiO4 : EU^2+ green-emitting phosphors were synthesized by conventional solid-state reaction in a CO-reductive atmosphere, and their luminescent properties were investigated. The XRD data show that the Ba/Sr ratio not only affects the lattice parameters, but also influences the emission peak. The excitation spectra indicate that this phosphor can be effectively excited by UV light from 370 to 470 nm. The emission band is due to the 4f^65d^1→4f^7 transition of the Eu^2+ ion. With an increase in x, the emission band shifts to longer wavelength and the reason was discussed. The emission spectra exhibit a satisfactory green performance under different excitation wavelength(380,398,412,420,460 nm). (Ba1- x, Srx ) 2 SiO4 : EU^2+ is a promising phosphor for green white-lighting-emission diode by ultraviolet chip.  相似文献   

9.
The long afterglow phosphor CaAl2Si2O8:Eu^2+ , Dy^3+ was prepared by a sol-gel method. The sol-gel process and the structure of the phosphor were investigated by means of X-ray diffraction analysis (XRD). It is found that the single anorthite phase formed at about 1000 %, which is 300 % lower than that required for the conventional solid state reaction. The obtained phosphor powders are easier to grind than those of solid state method and the partical size of phosphor has a relative narrow distribution of 200 to 500 nm. The photoluminescence and afterglow properties of the phosphor were also characterized. An obvious blue shift occurs in the excitation and emission spectra of phosphors obtained by sol-gel and solid state reaction methods. The change of the fluorescence spectra can be attributed to the sharp decrease of the crystalline grain size of the phosphor resulted from the sol-gel technique.  相似文献   

10.
Long afterglow phosphors MAl2O4:Eu^2+ , Dy^3+ (M = Ca, Sr, Ba) were synthesized by microemulsion method, and their crystal structure and luminescent properties were compared and investigated. XRD patterns of samples indicate that phosphors CaAl2O4:Eu^2+, Dy^3+ and SrAl2O4 : Eu^2+, Dy^3+ are with monoelinie crystal structure and phosphor BaAl2O4:Eu^2+ , Dy^3+ is with hexagonal crystal structure. The wide range of excitation spectrum of phosphors MAl2O4: Eu^2 + , Dy^3+ (M = Ca,Sr, Ba) indicates that the luminescent materials can he excited by light from ultraviolet ray to visible light and the maximum emission wavelength of phosphors MAl2O4:Eu^2+ , Dy^3+ (M = Ca, Sr, Ba) is found mainly at λem of 440 nm (M = Ca), 520 nm (M = Sr) and 496 nm (M = Ba) respectively, the corresponding colors of emission light are blue, green and eyna-green respectively. The afterglow decay tendency of phosphors can he summarized as three processes: initial rapid decay, intermediate transitional decay and very long slow decay. Afterglow decay curves coincide with formula I = At^ - n, and the sequence of afterglow intensity and time is Sr 〉 Ca 〉 Ba.  相似文献   

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