共查询到17条相似文献,搜索用时 93 毫秒
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采用EBSD研究了不同线宽和退火前后Cu互连线的织构和晶界特征分布.Cu互连线均具有多重织构,其中(111)织构强度最高.沉积态样品在室温下发生了自退火现象,并出现了一些异常长大的晶粒.随高宽比降低和退火处理,Cu互连线晶粒尺寸变大,(111)织构得到加强,而具有较低应变程度的织构与(111)织构强度的比例下降.沉积态样品出现了(111)<112>和(111)<231>织构组分.退火后,出现了(111)<110>组分,而且(111)<112>和(111)<231>组分得到增强.Cu互连线以大角度晶界为主,其中具有55°~60°错配角的晶界和∑3晶界比例最高,35°~40°的错配角和∑9晶界次之.随高宽比增加和退火处理,∑3晶界比例逐渐升高,∑9晶界比例下降. 相似文献
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观察了ULSI中大马士革结构的Cu互连线的晶粒生长和晶体学取向.分析了线宽及退火对Cu互连线显微结构及电徙动的影响.Cu互连线的晶粒尺寸随着线宽的变窄而减小.与平坦Cu膜相比,Cu互连线形成微小的晶粒和较弱的 (111) 织构.300℃、30min退火促使Cu互连线的晶粒长大、(111) 织构发展,从而提高了Cu互连线抗电徙动的能力.结果表明,Cu的扩散涉及晶界扩散与界面扩散,而对于较窄线宽的Cu互连线,界面扩散成为Cu互连线电徙动失效的主要扩散途径. 相似文献
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利用背散射电子衍射(EBSD)技术和X射线衍射(XRD)对SPCD冷轧钢板缓慢升温退火工艺下的再结晶取向特征、织构的形成规律及与形变织构的关系进行研究,并与快速加热退火工艺下的IF钢再结晶取向特点进行对比。结果表明:宏观织构显示冷轧态下{111}〈112〉形变织构稳定存在,随后的再结晶过程中γ线上存在{111}〈112〉与{111}〈110〉织构的竞争,其中再结晶初期{111}〈112〉织构占主导,后期{111}〈110〉吞食{112}〈110〉和{001}〈110〉织构进而取代{111}〈112〉作为γ线织构的主导取向;不同取向新晶粒具有不同的再结晶形核地点:{111}〈110〉新晶粒主要在{112}〈110〉和{111}〈112〉形变晶粒的晶界处形核;{111}〈112〉新晶粒主要在相同取向的形变晶粒内形核;而{110}〈001〉新晶粒主要在{111}〈112〉形变晶粒的形变带内形核。 相似文献
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Cu互连线显微结构和应力的AFM及SNAM分析 总被引:1,自引:0,他引:1
在ULSI中采用Cu互连线代替Al以增加电子器件的传输速度和提高器件的可靠性,Cu的激活能约为1.2eV,而Al的激活能约为0.7eV,Cu互连线寿命约为Al的3-5倍。Cu大马士革互连线的制备工艺为:在硅衬底上热氧化生成的SiO2上开出凹槽,在凹槽中先后沉积阻挡层Ta和晶种层Cu,然后由电镀的Cu层将凹槽填满,最后采用化学机械抛光将凹槽外多余的Cu研磨掉,Cu互连线的尺寸为:200um长,0.5μm厚,宽度分别为0.35,0.5,1至3μm不等,部分样品分别在200℃,300℃和450℃下经过30min退火。利用原子力显微镜(AFM)和扫描近场声学显微镜(SNAM),同时获得形貌像和声像,分别了Cu大马士革凹槽构造引起的机械应力和沉积引起的热应力对Cu互连线显微结构及可靠性的影响,SNAM是在Topometrix公司AFM基础上建造的实验装置,实验采用的机械振动频率在600Hz-100kHz之间。分析测试结果如下:1.AFM和SNAM可以实现对微米和亚微米特征尺寸的Cu互连线的局域应力分布和显微结构的原位分析。2.采用AFM,TEM、XRD观察和测试了Cu互连线的晶体结构,分析了大马士革凹槽工艺 对Cu晶粒尺寸及取向的影响。平坦的沉积态Cu膜的晶粒尺寸约为100nm;而由大马士革工艺制备的凹槽中的Cu互连线的晶粒尺寸约为70-80nm,凹槽结构抑制了晶粒生长,平坦的沉积态Cu膜有较强的(111)织构;而凹槽中的Cu互连线的(111)织构减弱,(200)和其它的晶体取向分量增强。3.SNAM声阻尼信号对材料局域应力的变化敏感,SNAM声图衬底可显示出局域应力的分布,在沉积态的Cu互连线声图中,金属和SiO2介电层的界面处像衬度强,表明该处为应力较高的区域,而在退火后的Cu互连线的声图中,金属和SiO2介电层的界面处像衬度弱,表明退火后该处应力减小,我们对Cu膜进行了宏观应力的测试,退火后应力值从沉积态的661MPa减少至359Mpa,这与SNAM声成像的结果相符合。 相似文献
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采用二维面探测器X射线衍射(XRD)测量1μm和0.5μm厚Al互连线退火前后的残余应力.沉积态Al线均为拉应力,且随膜厚的增加而减小.沿长度方向的应力明显高于宽度方向的应力,表面法线方向应力最小.250℃退火2.5h后,互连线在各方向上的应力都减弱,其中1μm Al线应力减弱幅度高于0.5μm互连线.采用电子背散射衍射(EBSD)方法,测量退火前后Al互连线(111),(100),(110)取向晶粒的IQ值.退火后平均IQ值提高,互连线残余内应力随之减小.EBSD分析结果与XRD应力测试结果相符合. 相似文献
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采用二维面探测器X射线衍射(XRD)测量1μm和0.5μm厚Al互连线退火前后的残余应力.沉积态Al线均为拉应力,且随膜厚的增加而减小.沿长度方向的应力明显高于宽度方向的应力,表面法线方向应力最小.250℃退火2.5h后,互连线在各方向上的应力都减弱,其中1μm Al线应力减弱幅度高于0.5μm互连线.采用电子背散射衍射(EBSD)方法,测量退火前后Al互连线(111),(100),(110)取向晶粒的IQ值.退火后平均IQ值提高,互连线残余内应力随之减小.EBSD分析结果与XRD应力测试结果相符合. 相似文献
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Microstructure and reliability of copper interconnects 总被引:7,自引:0,他引:7
Changsup Ryu Kee-Won Kwon Loke A.L.S. Haebum Lee Nogami T. Dubin V.M. Kavari R.A. Ray G.W. Wong S.S. 《Electron Devices, IEEE Transactions on》1999,46(6):1113-1120
The effects of texture and grain structure on the electromigration lifetime of Cu interconnects are reported. Using different seed layers, (111)- and (200)-textured CVD Cu films with similar grain size distributions are obtained. The electromigration lifetime of (111) CVD Cu is about four times longer than that of (200) CVD Cu. For Damascene CVD Cu interconnects, the electromigration lifetime degrades for linewidths in the deep submicron range because the grains are confined as a result of conformal deposition in narrow trenches. In contrast, electroplated Cu has relatively larger grains in Damascene structure, resulting in longer electromigration lifetime than CVD Cu and no degradation for linewidths in the deep submicron range 相似文献
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Change in the in-plane orientation of (111) grains in the copper film was studied in situ by electron backscatter diffraction
(EBSD) during its thermal treatment inside the scanning electron microscope (SEM). Two separate investigations were carried
out each at different locations of the film. Both of the investigations showed the presence of (111) fiber texture with increased
strengths of {111}〈112〉 and {111}〈110〉 orientations. During the first investigation, the {111}〈110〉 component became sharper
relative to {111}〈112〉, while in the second investigation the sharpness decreased relative to {111} 〈112〉 with increasing
temperature. No such changes in the in-plane orientation of the (111) grains were observed during the similar experiment carried
out on the Cu film in freestanding condition. The role of silicon subtrate on influencing these changes has been proposed
based on dislocation activity within the grains. The increase in the inclination of (111) planes to the specimen surface in
{111}〈110〉 and {111}〈112〉 grains as a function of temperature was linked to the stress relaxation. The inclination of the
(111) planes to the specimen surface leads to decrease in the sharpness of the (111) texture components. Finally, similar
transformation in the texture of (111) grains in Cu damascene interconnects was investigated. 相似文献
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Tomoyuki Yoshida Shoji Hashimoto Yasuichi Mitsushima Takeshi Ohwaki Yasunori Taga 《Microelectronics Reliability》1999,39(3):347
The effect of residual gas constituents and substrate temperature during Ti sputtering on the texture of TiN/Ti films deposited on SiO2/Si substrates has been investigated. The Ti(002) and TiN(111) preferred texture of the films deposited at 350°C was found to be improved drastically by increasing the H2O partial pressure from 1×10−9 to 3×10−8 Torr. Both of the Ti(002) and TiN(111) textures showed a similar H2O partial pressure and substrate temperature dependence because of the epitaxial transfer between these planes. The improved Ti(002) texture was attributed to the self-assembly of Ti atoms on the SiO2 surface, which had a low surface free energy due to the formation of surface OH groups. Two kinds of layered Al-alloy interconnects, AlSiCu/Ti/TiN/Ti and AlCu/TiN/Ti, were fabricated with the highly textured TiN/Ti film, and their Al(111) texture and electromigration lifetime were then evaluated. It was confirmed that both of the interconnects have strong Al(111) texture and longer EM lifetimes. 相似文献
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Electromigration-Induced Plasticity: Texture Correlation and Implications for Reliability Assessment
A.S. Budiman P.R. Besser C.S. Hau-Riege A. Marathe Y.-C. Joo N. Tamura J.R. Patel W.D. Nix 《Journal of Electronic Materials》2009,38(3):379-391
Plastic behavior has previously been observed in metallic interconnects undergoing high-current-density electromigration (EM)
loading. In this study of Cu interconnects, using the synchrotron technique of white-beam x-ray microdiffraction, we have
further found preliminary evidence of a texture correlation. In lines with strong (111) textures, the extent of plastic deformation
is found to be relatively large compared with that of weaker textures. We suggest that this strong (111) texture may lead
to an extra path of mass transport in addition to the dominant interface diffusion in Cu EM. When this extra mass transport
begins to affect the overall transport process, the effective diffusivity, D
eff, of the EM process is expected to deviate from that of interface diffusion only. This would have fundamental implications.
We have some preliminary observations that this might be the case, and report its implications for EM lifetime assessment
herein. 相似文献
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T. G. Koetter H. Wendrock H. Schuehrer C. Wenzel K. Wetzig 《Microelectronics Reliability》2000,40(8-10)
The microstructure of unpassivated PVD copper interconnects has been determined by electron backscatter diffraction technique (EBSD) inside a scanning electron microscope (SEM), and the appearance and growth of voids and hillocks during the electromigration testing has been observed in situ inside the SEM. The EBSD measurement indicates a strong <111 > texture for the tested line and a high angle boundary fraction of more than 70%. The comparison of the EBSD maps and the SEM images of the defect formation due to electromigration shows that the voids are formed mainly at the sidewall and after blocking grains. These images indicate that the diffusion paths are both the interface and the grain boundaries. 相似文献
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Paul R. Besser Ehrenfried Zschech Werner Blum Delrose Winter Richard Ortega Stewart Rose Matt Herrick Martin Gall Stacye Thrasher Mike Tiner Brett Baker Greg Braeckelmann Larry Zhao Cindy Simpson Cristiano Capasso Hisao Kawasaki Elizabeth Weitzman 《Journal of Electronic Materials》2001,30(4):320-330
The microstructure of inlaid Cu lines has been quantified as a function of annealing conditions, post-plating, and post-CMP.
The grain size distribution was measured using the median intercept method, crystallographic texture was characterized by
pole figure analysis, and mechanical stress was determined using x-ray diffraction. The median grain size and mechanical stress
level increase with increasing anneal temperature. The crystallographic texture is independent of the anneal temperature and
is predominantly (111) with a small fraction of sidewall-nucleated (111) grains. The (111) grains nucleated from the trench
bottom have a preferred in-plane orientation. The grain growth in the trench is independent of that in the overburden. 相似文献
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J. -Y. Cho K. Mirpuri D. N. Lee J. -K. An J. A. Szpunar 《Journal of Electronic Materials》2005,34(1):53-61
To understand the effect of line width on textural and microstructural evolution of Cu damascene interconnect, three Cu interconnects
samples with different line widths are investigated. According to x-ray diffraction (XRD) results, the (111) texture is developed
in all investigated lines. Scattered {111}〈112〉 and {111}〈110〉 texture components are present in 0.18-μm-width interconnect
lines, and the {111}〈110〉 texture was developed in 2-μm-width interconnect lines. The directional changes of the (111) plane
orientation with increased line width were investigated by XRD. In addition, microstructure and grain-boundary character distribution
(GBCD) of Cu interconnect were measured using electron backscattered diffraction (EBSD) techniques. This measurement demonstrated
that a bamboo-like microstructure is developed in the narrow line, and a polygranular structure is developed in the wider
line. The fraction of ∑3 boundaries is increased as the line width increases but is decreased in the blanket film. A new interpretation
of textural evolution in damascene interconnect lines after annealing is suggested, based on the state of stress and growth
mechanisms of Cu deposits. 相似文献