Shear Mode Ultrasonic Transducers from Flexible Piezoelectric PLLA Fibers for Structural Health Monitoring

Shear mode guided waves are highly demanded for underwater structural health monitoring (SHM) applications due to their simplified non-dispersive feature and minimal acoustic energy loss in the presence of liquid. Excitation and detection of pure shear wave are challenging using conventional piezoelectric materials used in the current ultrasonic transducers because they have complex piezoelectric responses mixed with multiple longitudinal, transverse, and shear modes. They also suffer from aging issue due to depoling. Here, conformable shear mode ultrasonic transducers are designed and made of flexible piezoelectric poly (L-lactic acid) (PLLA) fibers on both flat and tubular structures. The electromechanical responses over a macroscopic area of the transducers are evaluated in a wide frequency range up to 500 kHz. The PLLA fiber-based shear mode ultrasonic transducers exhibit a consistent sensitivity of detecting defects in liquid and air. In addition, the only shear mode in PLLA fibers originates from crystal structure without requiring electrical poling to render piezoelectricity, thus does not depole due to aging. The theoretical analyses including ab initio calculations and experimental results on both flat and tubular structures show the great potential of PLLA material and significant advantage of PLLA fiber-based shear mode ultrasonic transducers for underwater SHM applications.     

Grain Boundary Diffusion Hardening in Potassium Sodium Niobate-Based Ceramics with Full Gradient Composition and High Piezoelectricity

Reducing mechanical losses and suppressing self-heating are critical characteristics for high-power piezoelectric applications. For environmentally friendly Pb-free piezoelectric ceramics, traditional acceptor doping or annealing treatments have successfully improved the mechanical quality factor (Q_m) based on a ceramic matrix with a poor piezoelectric coefficient (d₃₃<100 pC/N). Nevertheless, a ceramic with high Q_m and d₃₃ values has not been reported owing to the inverse relationship between Q_m and d₃₃. Herein, a novel hardening method called grain boundary diffusion is used to develop Pb-free potassium sodium niobate ceramics, where Q_m increased by more than two-fold (from 51 to 132) and a high d₃₃ value (d₃₃ = 360 pC/N) is maintained. Significantly, d₃₃ retained 98% of its initial value after 180 days, exhibiting improved aging stability. The established properties are associated with the formation of the core-shell microstructure and the full gradient composition distribution using structural characterizations and phase-field simulations, where the core maintains a high d₃₃ and the shell provides a hardening effect. The novel hardening effect in piezoelectric materials, known as grain boundary diffusion hardening, highlights the enhancement of the mechanical quality factor with high piezoelectricity, providing a new paradigm for the design of functional materials.     

2D Layered Dipeptide Crystals for Piezoelectric Applications

2D piezoelectric materials such as transition metal dichalcogenides are attracting significant attention because they offer various benefits over bulk piezoelectrics. In this work, the fabrication of layered biomolecular crystals of diphenylalanine (FF) obtained via a co-assembly of l,l - and d,d - enantiomers of FF monomers is reported. Their crystal structure, thermal and chemical stabilities, and piezoelectric properties are investigated. Single crystal X-ray diffraction results show that FF enantiomers are arranged in the form of bilayers consisting of monomers with alternating chirality packed into a tape-like monoclinic structure belonging to a polar space group P2₁. Each bilayer ( ≈ 1.5 nm thick) demonstrates strong out-of-plane piezoelectricity (d₃₃  ≈  20 pm V⁻¹) that is almost an order of magnitude higher than in the archetypical piezoelectric material quartz. The grown crystals demonstrate better thermal and chemical stabilities than self-assembled hexagonal FF nanotubes studied in the past. Piezoelectric bilayers, being held via weak aromatic interaction in the bulk crystals, can be exfoliated by mechanical or chemical methods, thus resulting in a 2D piezoelectric material, which can find various applications in biocompatible and ecologically friendly electromechanical microdevices, such as sensors, actuators, and energy harvesting elements used in implantable and wearable electronics.     

Domain Engineering of Lead‐Free Li‐Modified (K,Na)NbO3 Polycrystals with Highly Enhanced Piezoelectricity

Aging and re‐poling induced enhancement of piezoelectricity are found in (K,Na)NbO₃ (KNN)‐based lead‐free piezoelectric ceramics. For a compositionally optimized Li‐doped composition, its piezoelectric coefficient d₃₃ can be increased up to 324 pC N^?1 even from a considerably high value (190 pC N^?1) by means of a re‐poling treatment after room‐temperature aging. Such a high d₃₃ value is only reachable in KNN ceramics with complicated modifications using Ta and Sb dopants. High‐angle X‐ray diffraction analysis reveals apparent changes in the crystallographic orientations related to a 90° domain switching before and after the aging and re‐poling process. A possible mechanism considering both defect migration and rotation of spontaneous polarization explains the experimental results. The present study provides a general approach towards piezoelectric response enhancement in KNN‐based piezoelectric ceramics.     

Recent Progress on Structure Manipulation of Poly(vinylidene fluoride)-Based Ferroelectric Polymers for Enhanced Piezoelectricity and Applications

Poly(vinylidene fluoride) (PVDF)-based polymers demonstrate great potential for applications in flexible and wearable electronics but show low piezoelectric coefficients (e.g., −d₃₃ < 30 pC N⁻¹). The effective improvement for the piezoelectricity of PVDF is achieved by manipulating its semicrystalline structures. However, there is still a debate about which component is the primary contributor to piezoelectricity. Therefore, current methods to improve the piezoelectricity of PVDF can be classified into modulations of the amorphous phase, the crystalline region, and the crystalline–amorphous interface. Here, the basic principles and measurements of piezoelectric coefficients for soft polymers are first discussed. Then, three different categories of structural modulations are reviewed. In each category, the physical understanding and strategies to improve the piezoelectric performance of PVDF are discussed. In particular, the crucial role of the oriented amorphous fraction at the crystalline–amorphous interface in determining the piezoelectricity of PVDF is emphasized. At last, the future development of high performance piezoelectric polymers is outlooked.     

Field-Induced Multiscale Polarization Configuration Transitions of Mesentropic Lead-Free Piezoceramics Achieving Giant Energy Harvesting Performance

The development of high-performance (K,Na)NbO₃ (KNN)-based lead-free piezoceramics for next-generation electronic devices is crucial for achieving environmentally sustainable society. However, despite recent improvements in piezoelectric coefficients, correlating their properties to underlying multiscale structures remains a key issue for high-performance KNN-based ceramics with complex phase boundaries. Here, this study proposes a medium-entropy strategy to design “local polymorphic distortion” in conjunction with the construction of uniformly oversize grains in the newly developed KNN solid-solution, resulting in a novel large-size hierarchical domain architecture (≈0.7 µm wide). Such a structure not only facilitates polarization rotation but also ensures a large residual polarization, which significantly improves the piezoelectricity (≈3.2 times) and obtains a giant energy harvesting performance (W_out = 2.44 mW, P_D = 35.32 µW mm⁻³, outperforming most lead-free piezoceramics). This study confirms the coexistence of multiphase through the atomic-resolution polarization features and analyzes the domain/phase transition mechanisms using in situ electric field structural characterizations, revealing that the electric field induces highly effective multiscale polarization configuration transitions based on T–O–R sequential phase transitions. This study demonstrates a new strategy for designing high-performance piezoceramics and facilitates the development of lead-free piezoceramic materials in energy harvesting applications.     

Structural Origins of Silk Piezoelectricity

Uniaxially oriented, piezoelectric silk films are prepared by a two‐step method that involves first air drying aqueous, regenerated silk fibroin solutions into films, and then drawing the silk films to a desired draw ratio. The utility of two different drawing techniques—zone drawing and water‐immersion drawing—is investigated for processing the silk for piezoelectric studies. Silk films zone drawn to a ratio of λ 5 2.7 display relatively high dynamic shear piezoelectric coefficients of d₁₄ 5 –1.5 pC N²¹, corresponding to an increase in d₁₄ of over two orders of magnitude due to film drawing. A strong correlation is observed between the increase in silk II, β‐sheet content with increasing draw ratio as measured by FTIR spectroscopy (C_b $ \propto $ e^2.5λ), the concomitant increasing degree of orientation of β‐sheet crystals detected via wide‐angle X‐ray diffraction (full width half maximum (FWHM) = 0.22° for λ = 2.7), and the improvement in silk piezoelectricity (d₁₄ $ \propto $ e^2.4λ). Water‐immersion drawing leads to a predominantly silk I structure with a low degree of orientation (FWHM 5 75°) and a much weaker piezoelectric response compared to zone drawing. Similarly, increasing the β‐sheet crystallinity without inducing crystal alignment, e.g., by methanol treatment, does not result in a significant enhancement of silk piezoelectricity. Overall, a combination of a high degree of silk II, β‐sheet crystallinity and crystalline orientation are prerequisites for a strong piezoelectric effect in silk. Further understanding of the structural origins of silk piezoelectricity provides important options for future biotechnological and biomedical applications of this protein.     

Visualizing Piezoelectricity on 2D Crystals Nanobubbles

2D crystals with noncentrosymmetric structures exhibit piezoelectric properties that show great potential for applications in energy conversion and electromechanical devices. Quantitative visualization of piezoelectric field spatial distribution is expected to offer a better understanding of macroscopic piezoelectricity, yet remains to be realized. Here, a technique of mapping piezoelectric potential on 2D materials bubbles based on the measurements of surface potential using kelvin probe force microscope is reported. By using odd number of layers hexagonal boron nitride and MoS₂ nanobubbles, strain-induced piezoelectric potential profiles are quantitatively visualized on the bubbles. The obtained piezoelectric coefficient is 3.4 ± 1.2 × 10⁻¹⁰ C m⁻¹ and 3.3 ± 0.2 × 10⁻¹⁰ C m⁻¹ for hBN and MoS₂, in agreement with the values reported. On the contrary, homogeneous distribution of surface potential is measured on even number of layers crystals bubbles where the crystal's inversion symmetry is restored. Using such technique, in situ visualization of photogenerated charge carrier separation under piezoelectric potential is also achieved, which offers a platform of investigating the coupling between piezoelectricity and photoelectric effect, and an approach of tuning piezoelectric field. The present work should aid the understanding of local piezoelectric potential and its various affecting factors including substrate doping and external stimuli, and give insights for designing piezoelectric nanodevices based on 2D nanobubbles.     

Boosting Piezo-Catalytic Activity of KNN-Based Materials with Phase Boundary and Defect Engineering

Although the piezo-catalysis is promising for the environmental remediation and biomedicine, the piezo-catalytic properties of various piezoelectric materials are limited by low carrier concentrations and mobility, and rapid electron-hole pair recombination, and reported regulating strategies are quite complex and difficult. Herein, a new and simple strategy, integrating phase boundary engineering and defect engineering, to boost the piezo-catalytic activity of potassium sodium niobate ((K, Na)NbO₃, KNN) based materials is innovatively proposed. Tur strategy is validated by exampling 0.96(K_0.48Na_0.52)Nb_0.955Sb_0.045O₃-0.04(Bi_xNa_4-3x)_0.5ZrO₃-0.3%Fe₂O₃ material having phase boundary engineering and conducted the defect engineering via the high-energy sand-grinding. A high reaction rate constant k of 92.49 × 10⁻³ min⁻¹ in the sand-grinding sample is obtained, which is 2.40 times than that of non-sand-grinding one and superior to those of other representative lead-free perovskite piezoelectric materials. Meanwhile, the sand-grinding sample has remarkable bactericidal properties against Escherichia coli and Staphylococcus aureus. Superior piezo-catalytic activities originate from the enhanced electron-hole pair separation and the increased carrier concentration. This study provides a novel method for improving the piezo-catalytic activities of lead-free piezoelectric materials and holds great promise for harnessing natural energy and disease treatment.     

Boosting Piezoelectricity by 3D Printing PVDF-MoS2 Composite as a Conformal and High-Sensitivity Piezoelectric Sensor

Additively manufactured flexible and high-performance piezoelectric devices are highly desirable for sensing and energy harvesting of 3D conformal structures. Herein, the study reports a significantly enhanced piezoelectricity in polyvinylidene fluoride (PVDF) achieved through the in situ dipole alignment of PVDF within PVDF-2D molybdenum disulfide (2D MoS₂) composite by 3D printing. The shear stress-induced dipole poling of PVDF and 2D MoS₂ alignment are harnessed during 3D printing to boost piezoelectricity without requiring a post-poling process. The results show a remarkable, more than the eight-fold increment in the piezoelectric coefficient (d₃₃) for 3D printed PVDF-8wt.% MoS₂ composite over cast neat PVDF. The underlying mechanism of piezoelectric property enhancement is attributed to the increased volume fraction of β phase in PVDF, filler fraction, heterogeneous strain distribution around PVDF-MoS₂ interfaces, and strain transfer to the nanofillers as confirmed by microstructural analysis and finite element simulation. These results provide a promising route to design and fabricate high-performance 3D piezoelectric devices via 3D printing for next-generation sensors and mechanical–electronic conformal devices.     

Strong Piezoelectricity and Improved Rectifier Properties in Mono- and Multilayered CuInP2S6

Most atomically thin piezoelectrics suffer from weak piezoelectric response or current rectification along the thickness direction, which largely hinders their applications in a vertical crossbar architecture. Therefore, exploring new types of ultrathin materials with strong longitudinal piezoelectric coefficient and rectification is highly desired. In this study, the monolayer of van der Waals CuInP2S6 (CIPS) is successfully exfoliated and its strong piezoelectricity in the out-of-plane direction with an effective coefficient d33eff of ≈5.12 pm V⁻¹, which is one or two orders of magnitude higher than that of most existing monolayer materials with intrinsic d33, is confirmed. A prototype vertical device is further constructed and the current rectification is achieved through the flexoelectricity induced by the scanning tip force. The switching between low and high rectification states can be readily controlled by tuning the mechanical loads. These findings manifest that CIPS possesses promising application in vertical nanoscale piezoelectric devices and provides a novel strategy for achieving a good current rectification in ultrathin piezoelectrics.     

Hierarchically Interconnected Piezoceramic Textile with a Balanced Performance in Piezoelectricity,Flexibility, Toughness,and Air Permeability

Softening of piezoelectric materials facilitates the development of flexible wearables and energy harvesting devices. However, as one of the most competitive candidates, piezoelectric ceramic-polymer composites inevitably exhibit reduced power-generation capability and weak mechanical strength due to the mismatch of strength and permittivity between the two phases inside. Herein a flexible, air-permeable, and high-performance piezoceramic textile composite with a mechanically reinforced hierarchical porous structure is introduced. Based on a template-assisted sol-gel method, a three-order hierarchical ceramic textile is constructed by intertwining submillimeter-scale multi-ply ceramic fibers that are further formed by twisting micrometer-scale one-ply ceramic fibrils. Theoretical analysis indicates that large mechanical stress can be easily induced in the multi-order hierarchical structure, which greatly benefits the electrical output. Fabricated samples generate an open-circuit voltage of 128 V, a short-circuit current of 120 µA, and an instantaneous power density of 0.75 mW cm⁻², much higher than the previously reported works. The developed multi-order and 3D-interconnected piezoceramic textile shows satisfactory piezoelectricity (d₃₃ of 190 pm V⁻¹), air permeability (45.1 mm s⁻¹), flexibility (Young's modulus of 0.35 GPa), and toughness (0.125 MJ m⁻³), collectively. The design strategy of obtaining balanced properties promotes the practicality of smart/functional materials in wearables and flexible electronics.     

High-Efficiency Reactive Oxygen Species Generation by Multiphase and TiO6 Distortion-Mediated Superior Piezocatalysis in Perovskite Ferroelectrics

Piezocatalysis, governed by piezo-potential within piezoelectrics, has gained prominence for reactive oxygen species (ROS) generation, which is significant to environmental and biological applications. However, designing piezocatalysts with excellent piezocatalytic performance in a wide temperature and efficient charge carrier separation ability is still challenging. Herein, eco-friendly BaTiO₃ (BT)-based perovskite ferroelectrics with tailored multiphase coexistence in a wide temperature range are constructed to boost higher piezoelectricity and large piezo-potential, which is attributed to decreased polarization anisotropy by flat Gibbs energy profile. Elevated piezo-potential in designed BT-based piezocatalyst guarantees high-efficient generation rate of •OH (200 µmol g⁻¹ h⁻¹) and •O₂⁻ (40 µmol g⁻¹ h⁻¹) by ultrasound stimulation, which is 3.5 times more than that of pure BT. Besides, piezocatalytic capacity to degrade dye wastewater shows a rate constant of 0.0182 min⁻¹ and gives an antibacterial rate of 95% within 30 min for eliminating E. coli. Theoretical simulations validate that the local distortion of TiO₆ octahedra also contributes to piezocatalytic performance by inducing electron–hole pairs separation in real space, and better response to slight structural deformation. This work is important to design high-performance piezocatalysts with high-efficiency ROS generation for sewage treatment and sonodynamic therapy.     

The Contributions of Polar Nanoregions to the Dielectric and Piezoelectric Responses in Domain‐Engineered Relaxor‐PbTiO3 Crystals

The existence of polar nanoregions is the most important characteristic of relaxor‐based ferroelectric materials. Recently, the contributions of polar nanoregions to the shear piezoelectric property of relaxor‐PbTiO₃ (PT) crystals are confirmed in a single domain state, accounting for 50%–80% of room temperature values. For electromechanical applications, however, the outstanding longitudinal piezoelectricity in domain‐engineered relaxor‐PT crystals is of the most significance. In this paper, the contributions of polar nanoregions to the longitudinal properties in [001]‐poled Pb(Mg_1/3Nb_2/3)O₃‐0.30PbTiO₃ and [110]‐poled Pb(Zn_1/3Nb_2/3)O₃‐0.15PbTiO₃ (PZN‐0.15PT) domain‐engineered crystals are studied. Taking the [110]‐poled tetragonal PZN‐0.15PT crystal as an example, phase‐field simulations of the domain structures and the longitudinal dielectric/piezoelectric responses are performed. According to the experimental results and phase‐field simulations, the contributions of polar nanoregions (PNRs) to the longitudinal properties of relaxor‐PT crystals are successfully explained on the mesoscale, where the PNRs behave as “seeds” to facilitate macroscopic polarization rotation and enhance electric‐field‐induced strain. The results reveal the importance of local structures to the macroscopic properties, where a modest structural variation on the nanoscale greatly impacts the macroscopic properties.     

Acoustic Gain in Solids due to Piezoelectricity,Flexoelectricity, and Electrostriction

A quantitative discussion of the combined influence of three electromechanical effects: piezoelectricity, flexoelectricity, and electrostriction in solids is provided for acoustic absorption and gain. While piezoelectricity occurs in non‐centrosymmetric materials only, flexoelectricity and electrostriction exist in all materials. Two important new results are demonstrated: 1) the possibility to realize acoustic gain in all materials (centrosymmetric and non‐centrosymmetric) when the acoustic Cherenkov condition is fulfilled, and 2) realization of acoustic gain in the presence of a strong dc electric field, even when the Cherenkov condition is not fulfilled, in the case of strong cross‐coupling between piezoelectricity, flexoelectricity, and electrostriction. A simple analytical expression for the acoustic dispersion relation is derived for the combined effect of piezoelectricity, flexoelectricity, and electrostriction. At lower frequencies, the piezoelectric effect dominates for inversion‐asymmetric materials. At high frequencies (≈>1 MHz) flexoelectricity becomes increasingly important and eventually provides a major mechanism for gain and absorption in barium titanate (BaTiO₃). In the presence of strong electric fields (≈>1 MV m^?1), electrostriction provides a dominant isolated contribution to absorption/gain in BaTiO₃. Strong coupling between the three electromechanical contributions determines the total absorption/gain coefficient.     

Simultaneous Realization of Good Piezoelectric and Strain Temperature Stability via the Synergic Contribution from Multilayer Design and Rare Earth Doping

Niobate-based lead-free piezoceramics have attracted wide attention due to their excellent piezoelectric properties. Although the temperature sensitivity of piezoelectricity or strain in one sample has been solved to a certain extent, how to simultaneously improve the temperature stability of both in one sample is still an issue. Herein, by constructing multilayer composite ceramics and doping Ho element, both improved piezoelectric and strain temperature stability (the variations are below 3% under 30–100 °C) are achieved, showing great property advantage compared with previous reports. Different from the compositionally graded composite ceramic design, the Ho doping can not only increase orthorhombic-tetragonal phase transition temperature (T_O-T) and then create the condition for the formation of successive phase transition, but also stabilize the oriented domain state. Therefore, the excellent temperature stability of both piezoelectricity and strain can be attributed to the multistep phase transition induced by the multilayer design, the fine regulation of T_O-T interval by the optimization of lamination combination, and the stabilized polarization induced by Ho doping. The new strategy for solving both piezoelectric and strain temperature sensitivity can further promote the commercial application of potassium sodium niobate-based lead-free piezoelectric ceramics.     

Multilevel Structure Engineered Lead-Free Piezoceramics Enabling Breakthrough in Energy Harvesting Performance for Bioelectronics

The prevalence of wearable/implantable medical electronics together with the rapid development of the Internet of Medicine Things call for the advancement of biocompatible, reliable, and high-efficiency energy harvesters. However, most current harvesters are based on toxic lead-based piezoelectric materials, raising biological safety concerns. What hinders the application of lead-free piezoelectric energy harvesters (PEHs) is the low power output, where the key challenge lies in obtaining a high piezoelectric voltage constant (g₃₃) and harvesting figure of merit (d₃₃ × g₃₃). Here, micron pores are introduced into phased boundary engineered high-performance (K, Na)NbO₃-based ceramic matrix, resulting in the state-of-the-art g₃₃ and the highest d₃₃ × g₃₃ values of 57.3 × 10⁻³ Vm N⁻¹ and 20887 × 10⁻¹⁵ m² N⁻¹ in lead-free piezoceramics, respectively. Concomitantly, ultrahigh energy harvesting performances are obtained in porous ceramic PEHs, with output voltage and power density of 200 V and 11.6 mW cm⁻² under instantaneous force impact and an average charging rate of 14.1 µW under high-frequency (1 MHz) ultrasound excitation, far outperforming previously reported PEHs. Porous ceramic PEHs are further developed into wearable and bio-implantable devices for human motion sensing and percutaneous ultrasound power transmission, opening avenues for the design of next-generation eco-friendly WIMEs.     

Multifunctional Barium Titanate Coated Carbon Fibers

Multifunctional materials have received significant research interest due to the potential for performance enhancements over traditional materials through the integration of responsive properties. Composite materials are ideally suited for use as multifunctional materials due to their use of two or more phases and the ease at which their properties can be anisotropically tailored. Here, a methodology for the integration of ferroelectricity into a fiber reinforced polymer composite is presented by synthesizing a barium titanate nanowire film on the surface of carbon fibers using a novel two‐step hydrothermal process. A refined piezoelectric force microscopy method is used to quantify the piezoelectric properties of the core–shell fiber resulting in an average d₃₃ of 31.6 ± 14.5 pm V^?1 and an average d₃₁ of ?5.4 ± 3.2 pm V^?1. The multifunctionality of this piezoelectric coated fiber is demonstrated through excitation of a cantilevered fiber with a 0.5 g sinusoidal base acceleration at the fiber's fundamental resonant frequency, producing a root‐mean‐square voltage of 16.4 mV. This result demonstrates the ferroelectric properties of the multifunctional structural fiber and its application for sensing and energy harvesting.     

Modulation of Mechanical Interactions by Local Piezoelectric Effects

Piezoelectricity is a well‐established property of biological materials, yet its functional role has remained unclear. Here, a mechanical effect of piezoelectric domains resulting from collagen fibril organisation is demonstrated, and its role in tissue function and application to material design is described. Using a combination of scanning probe and nonlinear optical microscopy, a hierarchical structuring of piezoelectric domains in collagen‐rich tissues is observed, and their mechanical effects are explored in silico. Local electrostatic attraction and repulsion due to shear piezoelectricity in these domains modulate fibril interactions from the tens of nanometre (single fibril interactions) to the tens of micron (fibre interactions) level, analogous to modulated friction effects. The manipulation of domain size and organisation thus provides a capacity to tune energy storage, dissipation, stiffness, and damage resistance.     

Multifunctional Artificial Artery from Direct 3D Printing with Built‐In Ferroelectricity and Tissue‐Matching Modulus for Real‐Time Sensing and Occlusion Monitoring

Treating vascular grafts failure requires complex surgery procedures and is associated with high risks. A real‐time monitoring vascular system enables quick and reliable identification of complications and initiates safer treatments early. Here, an electric fieldassisted 3D printing technology is developed to fabricate in situ‐poled ferroelectric artificial arteries that offer battery‐free real‐time blood pressure sensing and occlusion monitoring capability. The functional artery architecture is made possible by the development of a ferroelectric biocomposite which can be quickly polarized during printing and reshaped into devised objects. The synergistic effect from the potassium sodium niobite particles and the polyvinylidene fluoride polymer matrix yields a superb piezoelectric performance (bulk‐scale d₃₃ > 12 pC N^?1). The sinusoidal architecture brings the mechanical modulus close to the level of blood vessels. The desired piezoelectric and mechanical properties of the artificial artery provide an excellent sensitivity to pressure change (0.306 mV mmHg^?1, R² > 0.99) within the range of human blood pressure (11.25–225.00 mmHg). The high pressure sensitivity and the ability to detect subtle vessel motion pattern change enable early detection of partial occlusion (e.g., thrombosis), allowing for preventing grafts failure. This work demonstrates a promising strategy of incorporating multifunctionality to artificial biological systems for smart healthcare systems.