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为了更深入地探讨C60衍生物的非线性光学性质,用5-(2-硫甲基-4-甲基)-嘧啶基-戊二炔-1-醇山梨酸酯与富勒烯C60进行加成反应,获得了一种新型的山梨酸酯类C60衍生物,用MALDI-TOF-MS,IR,UV-vis,1H NMR,DEPT和13CNMR进行了结构表征。利用Q倍频ns/ps Nd:YAG激光脉冲以及z扫描技术和光限辐实验研究了该化合物的非线性折射和光限辐特性,并获得了3阶非线性光学系数和非线性吸收系数。结果表明,C60衍生物有很强的非线性吸收和非线性折射,并具有较低的光限幅箝位值,是一种非常有前途的非线性光学材料。 相似文献
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K. McEwan K. Lewis G.‐Y. Yang L.‐L. Chng Y.‐W. Lee W.‐P. Lau K.‐S. Lai 《Advanced functional materials》2003,13(11):863-867
meso‐Tetrakis{4‐[2‐(trimethylsilyl)ethynyl]phenyl}porphyrin [TPP(4‐CCTMS)_H2] and its complexes with ZnII, NiII, GaIII, InIII, and SnIV were synthesized and characterized. Their nonlinear optical transmission characteristics were determined using a 532 nm, 5 ns pulsed laser at a repetition rate of 20 Hz. Stronger nonlinear absorption was obtained with the zinc derivative, ZnII‐meso‐tetrakis{4‐[2‐(trimethylsilyl)ethynyl]phenyl}porphyrin (TPP(4‐CCTMS)_Zn), than with the standard analogues, ZnII‐meso‐tetraphenylporphyrin (TPP_Zn), and ZnII‐meso‐tetratolyl‐porphyrin (TTP_Zn), indicating that the excited‐state absorption can be influenced via fine molecular modification on the para‐position of the meso‐phenyl rings, without changing the ground‐state absorption. The nonlinear optical response can be further enhanced via insertion of closed‐shell metal ions. In particular, InIIICl‐meso‐tetrakis{4‐[2‐(trimethylsilyl)ethynyl]phenyl}porphyrin (TPP(4‐CCTMS)_InCl), exhibited a larger change in transmission with increasing energy than C60 and a comparable change to the state‐of‐the‐art phthalocyanine dye, chloro(tetra(tert‐butyl)phthalocyanato)indium(III) (Pc(t‐Bu)_InCl). 相似文献
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文中介绍了一种新型金属铟酞菁酯化合物的合成方法。为了研究该化合物的非线性光学性质,在532 nm波长下,分别使用皮秒和纳秒脉冲对样品进行了Z扫描测试。实验结果表明该样品在皮秒和纳秒时域都有很强的反饱和吸收以及非线性正折射。对Z扫描实验数据进行数值模拟分别得到样品在皮秒和纳秒脉冲作用下等效的三阶非线性吸收系数和三阶折射率:ps=4.110-11m/W,ps=4.510-19m2/W 以及ps=5.110-9m/W,ps=1.510-16m2/W。分析讨论了激发态能及对该化合物非线性光学性质的影响,并使用纳秒脉冲激光对样品进行了光限幅测试,在T/T0=0.5时,阈值为2.0J/cm2,实验结果表明该样品拥有良好的光限幅性能。 相似文献
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Dou K. Xiaodong Sun Xiaojun Wang Parkhill R. Yin Guo Knobbe E.T. 《Quantum Electronics, IEEE Journal of》1999,35(7):1004-1014
Optical limiting and upconverted luminescence have been studied in different chromophore-doped aluminosilicate gel materials and the effects of the dynamic processes from different central ions are discussed. Chromophores are metalloporphyrins of tetra-4-sulfonatophenylporphyrinato-copper(II) and tetra-4-sulfonatopfienylporphgrinato-zinc(II) (CuTPPS and ZnTPPS, respectively) which are embedded in aluminosilicate gel hosts. Photo-upconverted luminescence was observed and believed to result from the radiative recombination of the second excited singlet state. Saturated behavior of upconverted emission was found as a function of incident excitation intensity. An optical limiting phenomenon associated with reverse saturated absorption was studied. These effects are attributed to higher excited state, absorption. The observation of upconverted luminescence indicates that the upper excited state absorption occurs while nonlinear absorption is being observed. Dynamic analysis of excited state processes indicates that intersystem crossing and triplet-triplet (quartet-quartet) absorption dominates nonlinear processes and suggests that saturation absorption or reverse saturation absorption is dependent on the ratio of the effective absorption cross section for the excited states to that for the ground state. Absorption cross sections for the excited states are estimated by the data fitting to upconverted emission intensity and nonlinear absorption 相似文献
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报导对一组[Ru(bpy)2L]2+络合物的光谱特性和非线性光学性质的研究。其中bpy=2,2-bipirdine,l=imidazo[f]1.10-phenanthroline(IP),or2-pheny-limidazo[f]1,10-phenanthline (PIP)or PIP的衍生物。采用时间分辨的ns激光对这组Ru络合物在含水溶液中和与DNA结合的发光特性进行研究。实验结果表明,当在L上结合不同电子施主或受主基时,对[Ru(bpy)2L]2+的MLCT的发光强度和寿命都有很大的影响,同样DNA的插入也对此有影响。采用四波混频方法对其非线性光学特性进行了测量,由此推算出三阶极化系数和分子的三阶超极化系数。并讨论了不同配体对三阶非线性光学系数的影响。 相似文献
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利用飞秒脉冲通过Z扫描技术和泵浦-探测技术研究了CdS0.2Se0.8纳米晶掺杂的硼酸盐玻璃滤波片RG665的非线性吸收特性。研究结果表明在800 nm波长 130 fs脉冲激光作用下,RG665滤波片表现较强的非线性吸收特性。通过理论分析拟合实验结果证明RG665滤波片在800 nm下的非线性吸收包含双光子吸收及双光子吸收诱导的激发态吸收两部分,得到双光子吸收系数为0.05 cm/GW,激发态吸收截面为e=310-23 m2,以及导带中低能态电子和导带底电子的寿命分别为13 ps和210 ps。研究结果表明CdS0.2Se0.8纳米晶体掺杂的玻璃是一种很好的非线性光学材料。 相似文献
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本文分别对在连续和脉冲激光入射下,对由材料线性和非线性吸收产生在热致光限幅效应进行了研究,给出了产生最大光限幅效应的条件,为热效应光学限幅应用于光学器件的激光防护提供了理论依据。 相似文献
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通过共价键合将二氨基二枯丁苯氧基氯代铟酞菁(Pc)与羧基化氧化石墨烯(GO-COOH)键合在一起,得到二氨基二枯丁苯氧基氯代铟酞菁-氧化石墨烯键合产物(Pc-GO-COOH),并以键合产物为原料反应得到引发剂。以甲基丙烯酸甲酯(MMA)为聚合反应单体,通过原子转移自由基聚合(ATRP)反应得到四种不同分子量的聚合物样品。采用凝胶渗透色谱(GPC)对聚合物分子量分布测试,结果表明,所制备的聚合物的分子量分布范围较窄,聚合反应具有良好的可控性。采用Z-扫描方法对聚合物样品溶液进行的三阶非线性测试结果表明,所制备的聚合物具有优良的三阶非线性光学性质,且当聚合物的分子量分别为9 063和12 196时,三阶非线性极化率值分别为8.1×10-11、2.1×10-11 esu。同时对聚合物样品的光限幅性能测试结果表明,两种样品的有效激发态与基态吸收截面比分别为2.69和2.20,具有较好的光限幅能力,具有较大的应用前景。 相似文献
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《Quantum Electronics, IEEE Journal of》2008,44(9):894-901
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In the nonlinear directional coupler, the optical field and the nonlinear material usually interact in a spatially and temporally local fashion and the device exhibits a nonlinear transmission characteristics, but it is not bistable. In this paper, it is shown theoretically that optical bistability in the input optical power is possible for the nonlinear directional coupler if the local phase change of the optical mode propagating through tile coupler is influenced by the excitation over the whole coupler. This condition can be satisfied in a coupler based on biased-pin-diodes comprising coupled asymmetric quantum wells in the i-region, Calculations show that in this configuration, the nonlinear directional coupler can exhibit sharp switching characteristics, low switching optical powers, optical bistability or bifurcation 相似文献
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Min-Chuan Lin Sien Chi 《Lightwave Technology, Journal of》1993,11(4):542-547
Optimal conditions for transmission of nonlinear optical pulses in single-mode fibers are presented. When an optical pulse propagates in a fiber, it suffers fiber loss, group velocity dispersion, and self-phase modulation. An optimal output pulse can be obtained by choosing a suitable optical carrier wavelength and an initial input pulse. The system under optimal conditions not only has a more stable performance than the dispersion-free system, but also achieves maximum transmission bit rate for a fixed transmission distance. A bit-length product up to 8550 Gb/s-km or more can be achieved by using dispersion-shifted fibers without amplification 相似文献
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《Electron Device Letters, IEEE》1986,7(2):81-82
A large-area surface-emitting SH GaAlAs LED is fabricated with the aim of reducing optical nonlinear distortion. A drastic reduction of the second-harmonic distortion level due to a compensation effect is confirmed at the position of maximum fiber input power. The developed LED exhibits -61-dB second-harmonic and -57-dB third-harmonic distortion levels under a 100-mA bias current and 50-percent modulation depth. 相似文献
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正交频分复用技术具有较高的频谱效率和好的抗频率选择性衰落性能,被广泛应用于无线通信系统中。但是OFDM信号具有较高的峰均比,当系统采用非线性功放时,OFDM系统需要较大的输入功率回退以避免信号失真。为了研究非线性功放条件下的系统性能,分析了恒包络OFDM系统的实现方式,并以误码率为指标,在加性高斯白噪声信道和多径衰落信道场景下对比了恒包络OFDM系统与采用传统迭代限幅滤波PAPR抑制技术的OFDM系统的性能。 相似文献