半干旱区湿地地下水埋深对芦苇SPAC系统水分运移耗散的影响

准确把握土壤-植被-大气系统（简称"SPAC"）中水分的运输和耗散规律是区域水资源可持续管理的重要前提。以白洋淀湿地为研究区,结合现场实测和模型模拟方法,探讨台田地下水埋深变化对芦苇SPAC系统中的水分运移耗散影响。结果表明:1）随着地下水埋深的增加,芦苇蒸散发（ET_a）开始下降,ET_a下降的地下水埋深阈值在100 cm左右;随着地下水埋深的降低,生长季0~120 cm土壤剖面由水分亏损转为盈余,亏盈转换的地下水埋深阈值在60 cm左右,并且亏损量与地下水埋深呈正相关。2）相同的地下水埋深变化对不同月的土壤水分储量、蒸散发的影响程度均存在差异,其中6月影响程度最高。在对白洋淀进行生态补水时,应避免在汛期前的春季进行大量的生态补水,可以优先考虑在生长末期的秋冬季来进行生态补水。3）综合考虑植被生长需求和生态节水,白洋淀芦苇最优的地下水埋深区间在110~150 cm,此时生长季内芦苇蒸散发具有10%~20%的节水潜力。     

地下水浅埋区作物对地下水利用与田间水分管理

禹城地区位于黄河下游冲积平原上，受引黄水影响，区内地下水埋深较浅。对冬小麦生长季节农田水分平衡的分析发现，在地下水浅埋区地下水对土壤水的补给为农田腾发的重要的水分来源，而现行的灌溉制度未考虑这一特点，造成了灌溉水的深层渗漏和动力能源的损耗。文中针对冬小麦提出了地下水对土壤水补给量与冬小麦腾发量之间的估算公式，并从农田灌溉和地下水位调控两个方面提出了田间水分管理措施，以提高作物的水分利用效率。     

安徽淮北平原地下水动态变化研究

论文对安徽淮北地区69个地下水位站的1980-2006年平均地下水埋深资料进行分析,得出淮北地区多年平均地下水埋深2.33m,1980-1990年各地下水年均埋深较浅、变幅较小,1990年以后地下水埋深变幅加大,且埋深有明显的加深趋势。研究认为淮北平原地下水动态虽然受降水量、蒸发量和人类活动等多种因素影响,但近些年来地下水的动态变化主要是人类活动影响的结果。这些人类活动包括地下水资源开发利用、土地利用、水利工程、农业节水灌溉措施等。其中过度开发利用地下水是导致安徽淮北平原地下水埋深下降,地下水资源减少的主要原因。适度开发利用地下水有利于淮北地区地下水的循环更新,但过度的开发利用,已造成平原北部开始出现严重的环境地质问题,应限制开采。     

浅埋薄基岩煤层开采对潜水含水层的影响及定量评价

为研究干旱矿区浅埋薄基岩煤层开采对潜水含水层的影响程度,选择凉水井煤矿为研究对象,在资料收集、野外调查、室内测试的基础上,采用数值模拟的手段分析潜水含水层对煤层开采的响应规律。研究结果表明:研究区风积沙降水入渗系数高达0.53,降水是地下水补给的主要来源(约95%),地下水总量受大气降水控制明显;开采前地下水向河流的排泄约占78%,蒸发排泄约占22%;受采掘矿井水排泄量(34.09%)影响,河流与蒸发排泄量占比分别减少至53.07%和12.84%;利用潜水含水层地下水漏失量Ql与开采前地下水排泄总量Qd的比值来表征地下水量的扰动程度Eq(Eq=Ql/Qd),扰动程度高达27%。     

塔里木河下游输水间歇地下水埋深及化学组分的变化

基于适时监测资料,对塔里木河下游2006年11月第11次输水停止后地下水埋深和地下水化学特征时空变化进行分析总结,结果发现,塔里木河下游上段地下水埋深自2007年3月～2009年9月呈增加变化,地下水主要离子含量以增加变化为主;中段地下水埋深呈增加变化,但主要离子的含量以下降变化为主要特征;下段地下水埋深从2008年8月起呈减小变化趋势,地下水中主要离子含量随地下水位的上升而增加.在各断面距离输水河道远处,地下水埋深变化首先与断面距离水源地大西海子水库的远近有关,距离大西海子水库较近的英苏断面在输水间歇地下水埋深呈增加变化,但变化幅度不大;喀尔达伊断面地下水埋深在输水间歇以增加变化为主;阿拉干和考干断面地下水埋深在2008年8月以后才开始受到输水的影响,地下水化学特征的变化则表现出较复杂的变化.     

利用δ18O信息分析冬小麦对浅埋深地下水的利用

黄河下游引黄灌区地下水埋深通常较浅,冬小麦生长季存在对地下水的利用,论文应用稳定同位素方法研究冬小麦对地下水的利用特征。在中国科学院禹城综合试验站开展实验,通过分析不同灌溉处理条件下土壤水和植物茎水δ¹⁸O值之间的关系,应用同位素线性混合模型估算了冬小麦不同生育期对地下水的利用比例。研究结果表明,水的¹⁸O信息能很好地揭示冬小麦对不同层次土壤水的利用特征,雨养处理,40%田间持水量处理和现行灌溉制度处理下冬小麦在返青后对地下水的利用分别占其总耗水量的28%,22%和4%左右。研究结果显示适度的灌溉有利于促进作物对不同层次土壤水分的稳定利用,而现行的大田灌溉方式则抑制了作物对地下水资源的利用。     

河套灌区土壤水和地下水动态变化及水平衡研究

为探究田间土壤水及地下水在不同作物种植区、不同灌期等情况下的动态变化规律与水平衡特征,以春小麦、玉米、向日葵为典型作物,在河套灌区选取4块2亩的试验田,于2009年4-11月采集田间土壤及地下水样品进行研究.结果表明,不同作物地块间土壤含水率的变化差别主要集中在5-9月的作物生长期.夏灌灌水量不足,土壤含水率呈下降趋势,田间土壤水分变化属于“蒸腾蒸发消耗型”;秋浇期内水量充足,各地块各土层含水率均明显增加,田间土壤水分呈“入渗补给型”.各地块地下水埋深月均变化趋势基本一致,由于优先流的存在,地下水对灌溉降水响应快.本文定量研究了区域土壤水和地下水的变化规律,揭示了灌区水平衡要素间的相互转换关系,可为灌区科学合理的水资源管理提供理论依据.     

毛乌素沙地气候变化及其对植被覆盖的影响

利用1961—2007年毛乌素沙地气温、降水资料,对研究区近50 a来气温和水分资源各分量的时空变化进行了研究,并结合TM影像和中巴资源卫星影像,从气候变化和群落水分收支平衡的角度,对毛乌素沙地近20 a的植被覆盖变化及其原因进行了分析。结果表明:近50 a,沙地增温趋势显著,变化率为0.33℃/10 a。全区域年均温变化趋势的范围为0.16~0.5℃/10 a,且增温的程度存在西北部最强、东南部最弱的趋势。水分资源各分量时空分布极不均匀:东南部降水量P和可利用降水Δw多、陆面蒸散E强,西北部相反。P、E、Δw均呈现出逐年减少的趋势,并且大致经历了3个变化阶段。近20 a毛乌素沙地植被覆盖变化与气候变化密切相关。为适应不断变化的气候需要,在进行沙地治理与生态建设中,必须考虑人工植被建设的可持续性问题。     

极端干旱气候下盐化草甸植被净初级生产力对全球变化的响应

利用作者建立的塔里木盆地北部盐化草甸植被净初级生产力模型 ,模拟了极端干旱气候下盐化草甸植被净初级生产力对全球变化的响应。结果表明 ,在一定土壤质地条件下 ,盐化草甸植被净初级生产力随地下水埋深的增加而逐渐下降。地下水埋深越大 ,盐化草甸植被净初级生产力对地下水埋深变化的响应越敏感。全球变化造成的温度升高对盐化草甸植被净初级生产力的影响 ,也是依地下水埋深的不同而有所差异。地下水埋深较小时,盐化草甸植被净初级生产力对温度升高的反应较小 ;随着地下水埋深的加大,其响应程度明显增加。因而 ,地下水埋深越大 ,盐化草甸植被净初级生产力对全球变化的响应就越明显。     

滨海平原含水层顶板埋深对水质的影响研究——以盐城第Ⅲ承压含水层为例

基于盐城滨海平原水文地质分区内部水文地质钻孔数据及2005~2014年水质因子监测数据,综合运用GIS及ANOVA等方法,研究了实验样区第Ⅲ承压含水层孔隙地下水的水质在时空维度上对含水层顶板埋深变化的响应特征,分析了地下水质动态演变规律,并对研究区地下水管理与保护提出了建议.研究结果表明:该区第Ⅲ承压含水层顶板埋深大多位于-118.9m~-85.45m之间;由于不同埋深的地下水所处的水文地质条件及开采利用状态差异,地下水典型水质因子含量与含水层顶板埋深因素之间呈现出一定相关性:矿化度、总碱度和细菌总数3种因子与埋深的关联强度最高(相关度分别为69.67%、75.76%和58.09%),总硬度因子的关联强度处于中等水平(49.18%);高锰酸钾指数受埋深影响较小(35.27%);同时还发现,在不同埋深分级区间各因子与埋深的关联强度差异明显,表现出不同的动态演变特征.     

Effects of two sludge application on fractionation and phytotoxicity of zinc and copper in the soil

The potential harm of heavy metals is a primary concern in application of sludge to the agricultural land. A pot experiment was conducted to evaluate the effect of two sludges on fractionation of Zn and Cu in soil and their phytotoxicity to pakchoi. The loamy soil was mixed with 0%, 20%, 40%, 60% and 80% (by weight) of digested sewage sludge (SS) and composted sludge (SC). The additions of both sludges caused a significant raise in all fractions, resulting in that exchangeable (EXCH) and organic bound (OM) became predominance of Zn and organic bound Cu occupied the largest portion. There was more available amount of Zn and Cu in SS treatments than SC treatments. During the pot experiment, the concentration of Zn in EXCH, carbonate (CAR) and OM and Cu in EXCH and OM fractions decreased in all treatments, so their bioavailability reduced. Germination rate and plant biomass decreased when the addition rate was high and the best yield appeared in 20% mixtures at the harvest of pakchoi. The two sludges increased tissue contents of Zn and Cu especially in the SS treatments. Zn in pakchoi was not only in relationship to ΔEXCH and ΔCAR forms but also in ΔOM forms in the sludge-soil mixtures. Tissue content of Cu in pakchoi grown on SC-soils could not be predicted by ΔEXCH. These correlation rates between Zn and Cu accumulation in pakchoi and variation of different fractions increased with time, which might indicate that sludges represented stronger impacts on the plant in long-term land application.     

Intraspecific differences in effects of co-contamination of cadmium and

A hydroponic experiment was carried out to study intraspecific differences in the effects of different concentrations of cadmium (Cd)(0-10 mg/L) and arsenate (As(V)) (0-8 mg/L) on the growth parameters and accumulation of Cd and As in six wheat varieties Jing-9428, Duokang-1, Jingdong-11, Jing-411, Jingdong-8 and Zhongmai-8. The endpoints of wheat seedlings, including seed germination,biomass, root length and shoot height, decreased with increasing the Cd and As concentrations. Significant differences in seed germination, biomass, root length, shoot height and the accumulation of Cd and As were observed between the treatments and among the varieties (p ＜ 0.05). The lethal dosage 50% were about 20, 80, 60, 60, 80 and 20 mg As/L for Jing-9428, Duokang-1, Jingdong-11,Jing-411, Jingdong-8 and Zhongmai-8, respectively, and the corresponding values for Cd were about 30, 80, 20, 40, 60 and 10 mg Cd/L, respectively. Among the six varieties, Duokang-1 was found to be the most resistant to Cd and As toxicity, and Zhongmai-8 was the most sensitive to Cd and As co-contamination. The resistance of the six varieties was found dependant on the seedling uptake of Cd and As. Duokang-1 was the most suitable for cultivation in Cd and As co-contaminated soils.     

Toxic effects of acetochlor, methamidophos and their combination on nifH gene in soil

Toxic effects of two agrochemicals on nifH gene in agricultural black soil were investigated using denaturing gradient gel electrophoresis （DGGE） and sequencing approaches in a microcosm experiment. Changes of soil nifH gene diversity and composition were examined following the application of acetochlor, methamidophos and their combination. Acetochlor reduced the nifH gene diversity （both in gene richness and diversity index values） and caused changes in the nifH gene composition. The effects of acetochlor on nifH gene were strengthened as the concentration of acetochlor increased. Cluster analysis of DGGE banding patterns showed that nifH gene composition which had been affected by low concentration of acetochlor （50 mg/kg） recovered firstly. Methamidophos reduced nifH gene richness that except at 4 weeks. The medium concentration of methamidophos （150 mg/kg） caused the most apparent changes in nifH gene diversity at the first week while the high concentration of methamidophos （250 mg/kg） produced prominent effects on nifH gene diversity in the following weeks. Cluster analysis showed that minimal changes of nifH gene composition were found at 1 week and maximal changes at 4 weeks. Toxic effects of acetochlor and methamidophos combination on nifH gene were also apparent. Different nifH genes （bands） responded differently to the impact of agrochemicals： four individual bands were eliminated by the application of the agrochemicals, five bands became predominant by the stimulation of the agrochemicals, and four bands showed strong resistance to the influence of the agrochemicals. Fifteen prominent bands were partially sequenced, yielding 15 different nifH sequences, which were used for phylogenetic reconstructions. All sequences were affiliated with the alpha- and beta-proteobacteria, showing higher similarity to eight different diazotrophic genera.     

EDTA-enhanced phytoremediation of lead contaminated soil by Bidens maximowicziana

Phytoremediation is a potential cleanup technology for the removal of heavy metals from contaminated soils.Bidens maximowicziana is a new Pb hyperaccumulator,which not only has remarkable tolerance to Pb but also extraordinary accumulation capacity for Pb.The maximum Pb concentration was 1509.3 mg/kg in roots and 2164.7 mg/kg in overground tissues.The Pb distribution order in the B. maximowicziana was:leaf>stem>root.The effect of amendments on phytoremediation was also studied.The mobility of soil Pb and the Pb concentrations in plants were both increased by EDTA application.Compared with CK(control check),EDTA application promoted translocation of Pb to overground parts of the plant.The Pb concentrations in overground parts of plants was increased from 24.23-680.56 mg/kg to 29.07-1905.57 mg/kg.This research demonstrated that B.maximowicziana appeared to be suitable for phytoremediation of Pb contaminated soil,especially,combination with EDTA.     

Distribution and ecological effect of mercury in Laogang landfill, Shanghai, China

Laogang landfill near Shanghai is the largest landfill in China, and receives about 10000 t of daily garbage per day, Samples of topsoil and plants were analyzed to evaluate mercury pollution from the landfill. For topsoil samples, there were significant correlations among total mercury （HgT）, combinative mercury （Hgc） and gaseous mercury （HgG）, and content of total organic carbon （TOC）, but, no significantly relationship was found between Hg content and filling time. Hg content changes in vertical profiles with time showed that the average Hgv of profiles 1992, 1996, and 2000 was similar, but their average HgG was quite different. HgT was significantly correlated with Hgc in profile 1992 and 2000, and Hgv was significantly correlated with Hg6 in profile 1996. HgG/Hgv ratio in profile samples decreased in the order of （HgG,/HgT）1992〉（HgG/HgT）1996〉〉（HgG/HgT）2000. A simple outline of Hg release in landfill could be drawn： with increasing of filling time, degradation undergoes different biodegradation, accordingly, gaseous mercury goes through small, more, and small proportion to total mercury. Distribution of Hg in plants was inhomogeneous, following the order of leaf〉root〉stem. The highest value of leaf may be associated with higher atmospheric Hg from landfill. Ligneous plants （e.g. Phyllostachys glanca, Prunus salicina and Ligustrum lucidum） are capable of enriching more Hg than herbaceous plants.     

Arsenic uptake by arbuscular mycorrhizal maize （Zea mays L.） grown in an arsenic-contaminated soil with added phosphorus

The effects of arbuscular mycorrhizal (AM) fungus (Glomus mosseae) and phosphorus (P) addition (100 mg/kg soil) on arsenic (As) uptake by maize plants (Zea mays L.) from an As-contaminated soil were examined in a glasshouse experiment.Non-mycorrhizal and zero-P addition controls were included.Plant biomass and concentrations and uptake of As,P,and other nutrients,AM colonization,root lengths,and hyphal length densities were determined.The results indicated that addition of P significantly inhibited root colonization and development of extraradical mycelium.Root length and dry weight both increased markedly with mycorrhizal colonization under the zero-P treatments,but shoot and root biomass of AM plants was depressed by P application.AM fungal inoculation decreased shoot As concentrations when no P was added,and shoot and root As concentrations of AM plants increased 2.6 and 1.4 times with P addition,respectively.Shoot and root uptake of P,Mn,Cu,and Zn increased,but shoot Fe uptake decreased by 44.6%,with inoculation, when P was added.P addition reduced shoot P,Fe,Mn,Cu,and Zn uptake of AM plants,but increased root Fe and Mn uptake of the nonmycorrhizal ones.AM colonization therefore appeared to enhance plant tolerance to As in low P soil,and have some potential for the phytostabilization of As-contaminated soil,however,P application may introduce additional environmental risk by increasing soil As mobility.     

Enzymatic oxidation of aqueous pentachlorophenol

The influence of the nonionic surfactant Tween 80 on pentachlorophenol （PCP） oxidation catalyzed by horseradish peroxidase was studied. The surfactant was tested at concentrations below and above its critical micelle concentration （CMC）. Enhancement of PCP removal was observed at sub-CMCs. The presence of Tween 80 in the reaction mixture reduced enzyme inactivation which occurred through a combination of free radical attack and sorption by precipitated products. A simple first-order model was able to simulate time profiles for enzyme inactivation in the presence or absence of Tween 80. At supra-CMCs, the surfactant caused noticeable reductions in PCP removal, presumably through micelle partitioning of PCP which precluded the hydrophobic PCP molecule from interacting with the enzyme.     

Decomposition of alachlor by ozonation and its mechanism

Decomposition and corresponding mechanism of alachlor, an endocrine disruptor in water by ozonation were investigated. Results showed that alachlor could not be completely mineralized by ozone alone. Many intermediates and final products were formed during the process, including aromatic compounds, aliphatic carboxylic acids, and inorganic ions. In evoluting these products, some of them with weak polarity were qualitatively identified by GC-MS. The information of inorganic ions suggested that the dechlorination was the first and the fastest step in the ozonation of alachlor.     

基于综合水质标识指数和对应分析法的校园河道水质评价

以三峡大学的校园河道求索溪为研究对象,利用综合水质标识指数法确定求索溪水质类别,分析其水质时空变化规律,并利用对应分析法得出求索溪中不同监测点的主要污染因子.研究结果表明:求索溪整体的综合水质标识指数为7.423,整体水质为劣V类(地表水环境质量标准GB 3838-2002)且黑臭.从时间变化来看,求索溪4月份的水质最差,5月份次之,4、5月份所有监测点的水质都劣于V类且黑臭;8月份水质最好,水质为Ⅳ类;从空间分布来看,8个监测点综合水质标识指数均超过6.0,水质为劣V类,其中6号监测点的水质相对最好,监测点3号的水质相对最差;对应分析法得出求索溪的整体水体污染程度受总氮因子的影响最大,其次为总磷.该研究拟为求索溪及类似校园河道的水环境治理研究提供基础依据和参考.     

Potential of plant polyphenol oxidases in the decolorization and removal of textile and non-textile dyes

In this study an effort has been made to use plant polyphenol oxidases; potato （Solanum tuberosum） and brinjal （Solanum melongena）, for the treatment of various important dyes used in textile and other industries. The ammonium sulphate fractionated enzyme preparations were used to treat a number of dyes under various experimental conditions. Majority of the treated dyes were maximally decolorized at pH 3.0. Some of the dyes were quickly decolorized whereas others were marginally decolorized. The initial first hour was sufficient for the maximum decolorization of dyes. The rate of decolorization was quite slow on long treatment of dyes. Enhancement in the dye decolorization was noticed on increasing the concentration of enzymes. The complex mixtures of dyes were treated with both preparations of polyphenol oxidases in the buffers of varying pH values. Potato polyphenol oxidase was significantly more effective in decolorizing the dyes to higher extent as compared to the enzyme obtained from brinjal polyphenol oxidase. Decolorization of dyes and their mixtures, followed by the formation of an insoluble precipitate, which could be easily removed simply by centrifugation.