河道生态需水量分析及计算方法研究

随着我国河流生态需水研究的不断深入,河流生态需水成为水利工程建设项目中环境影响评价所必须考虑的重要内容。本文从河道内生态环境需水量这一基本概念出发,对河道内生态环境需水量的计算方法进行探讨分析。     

南方季节性河流河道内生态需水研究——以长江荆南三口为例

考虑南方季节性河流年内径流分布严重不均的问题,依据1951—2015年长江荆南三口5站实测原型年径流量序列,采用Mann-Kendall等方法检测其径流序列的突变年份,通过GEV概率密度最大流量、汛期最小输沙量等方法分别计算了荆南三口河道内生态需水量、输沙需水量和水质净化需水量。结果表明:(1)水文序列的突变年份判别为1970年,由此将水文序列划分为变异前(1951—1970年)和变异后(1971—2015年)两段。(2)水文变异前,河道内年生态需水量、输沙需水量和水质净化需水量分别为1239.27×10~8m~3、910.01×10~8m~3、425.70×10~8m~3;水文变异后,河道内年生态需水量、输沙需水量和水质净化需水量分别为563.32×10~8m~3、501.13×10~8m~3、111.54×10~8m~3。(3)在季节上,为保障季节性河流河道内全年均满足生态流量,1、2、3、4、11、12月份应满足的生态需水量为1647.28m~3/s,5—10月份应满足的生态需水量分别为873.87m~3/s、2499.59m~3/s、5812.76m~3/s、4346.89m~3/s、3901.18m~3/s、1721.70m~3/s。(4)从综合角度考虑,水文变异下长江荆南三口季节性河流河道内年生态需水量为752.71×10~8m~3,年输沙需水量为910.01×10~8m~3,年水质净化需水量为425.70×10~8m~3。     

基于生态保护目标的太子河下游河道生态需水量计算

河流生态需水量计算是进行生态水权分配的一项基础性工作,是生态环境保护和水资源配置的依据.随着社会经济的发展,流域水资源短缺和生态环境问题日益突出.针对太子河下游河段水资源开发利用现状及存在的生态环境问题,在确定生态保护目标的基础上,采用月保证率法和生态水力学法计算下游河道不同等级生态需水量,既可以从各月角度反映河道生态需水是一个与自然径流相适应的过程,又注重水生生物的关键期和生境需求.通过Tennant法验证月保证率法和生态水力学法计算结果可靠,最终确定太子河下游河道最小、适宜和理想等级年生态需水量分别为:5.31×108m3、8.52×108m3和12.17×108m3,而且现状流量可以满足最小生态需水量的要求.     

基于分布式水文模型的徒骇河河流生态需水量预测研究

流域的气候、植被和土地利用方式等变化对河流生态需水具有决定性作用.以徒骇河刘桥闸控制区域为例,定量估算了现状河流生态需水量,并以流域分布式水文模型SWAT为工具,预测了各水平年不同保证率下不同生态恢复目标的各月河流生态需水量.结果表明,现状年河流生态需水量为81.09×106m3,其中自净需水是河流生态需水的主要组成部分,因此保证徒骇河生态需水的关键是污染源的治理.拟通过减少点源排放、减少灌溉水量、减少农药化肥施用及增加干流两边的缓冲带等措施,使污染源得到进一步控制,预测2015年、2020年、2030年河流生态需水量不断减少,丰水年份河流天然径流量能满足河流生态需水要求,但枯水年份仍存在较为严重的生态缺水问题,需要对河流进行生态补水.     

干旱区流域生态需水量估算原则分析

运用河流廊道原理 ,提出了生态需水量计算公式。以额济纳地区为例 ,分析研究了该地区不同景观的生态需水量。结果表明 ,河流两岸的乔灌木林和灌丛草甸的生态需水量为 3 .91× 1 0 8m3,占总需水量的 39.388% ,加上河流和湖泊的蒸发耗水量 0 .55×1 0 8m3及河流自身生态用水 ,四者占总需水量的 73 .61 %。可见 ,只要保证了四者的生态需水量 ,即可保证现状河流廊道的基本功能。但从长远来考虑 ,河道的流量要确保抗性最小面积对生态需水量的要求。     

闸坝河流河道内生态需水研究——以淮河为例

提出了一种估算闸坝下游河道内生态需水的方法--改进的生态水力半径法（AdaptedEcologicalHydraulicRadiusApproach,AEHRA）,该法能够同时计算输出相应河段的生态水位,方便对闸坝进行调度。将其应用到淮河,以鱼类作为生态保护目标,估算了上、中、下游共4个典型闸坝下游河段的生态需水和生态水位,结果表明:①鱼类产卵期内需要较大的生态流量,其顺序为:蚌埠>周口>颍上>白龟山,下游大于上游,中游居中,受断面影响显著;非产卵期则为:周口>颍上>蚌埠>白龟山,中游大于上下游,受河流鱼种影响较大。周口闸下河段全年各月生态需水量相同,需加强上游闸坝的联合调度满足冬季12~-月的生态需水;②要维持河道内生态流量,需进行闸坝调度调整下游水位,保证生态水位;③淮河受人类活动影响剧烈,河流的连续性被切断,生态需水变化没有连续性,只有根据最小生态水位通过闸坝调度,维持河道生态系统最小生态需水,才能逐步恢复淮河健康生态。     

天津市生态需水量分析

依据天津市河湖水系和水资源的特点,结合实际生态用水及供水情况,分区对天津市主要的一级河道、湖库湿地以及二级河道的生态需水量进行计算。采用以基础流量、河道蒸发损失量、河道渗漏损失量三者之和作为天津市的生态需水量。计算结果表明,2020年天津市的生态需水量为14.1×108m3,2030年为17.9×108m3。     

黄河流域城市绿地生态需水时空特征分析

界定了城市绿地生态需水和生态灌溉需水的内涵与特征,构建了城市绿地生态需水和生态灌溉需水的计算模型,对黄河流域45个地级以上城市的绿地生态需水与生态灌溉需水进行计算与分析.研究结果表明:①黄河流域城市绿地年生态需水量为44 749.7×104m3,年生态灌溉需水量为22 783.5×104m3.约占2000年黄河流域城市市区供水总量的4.85%.其中90.2%的生态灌溉需水集中在绿地植物的生长期(4～10月份);②植物需水和生态灌溉需水表现出不同的月变化趋势和空间分异规律.月生态灌溉需水的计算结果为黄河流域城市绿地生态用水的合理配置提供了科学依据.     

疏勒河中游绿洲生态环境需水时空变化特征研究

以疏勒河流域中游绿洲为研究区,借助统计分析法、RS和GIS技术方法,选择1970、1980、1990、2000和2013年疏勒河中游绿洲Landsat TM/ETM影像解译成果作为中游绿洲生态演变研究的基础资料,分析得出各种生态系统覆盖状况.根据疏勒河中游绿洲生态环境需水特征,建立了基于天然植被、河流、湿地和防治耕地盐碱化的疏勒河中游绿洲生态环境需水定量化模型,并估算了不同时段不同区域流域中游绿洲生态环境需水量,探讨了疏勒河中游绿洲生态环境需水时空变化特征,从而为区域水资源合理配置和生态环境协调发展提供参考依据.通过计算得出了疏勒河中游绿洲1970、1980、1990、2000和2013年天然植被、河流基本生态、河流输沙、河流渗漏补给、水面蒸发、湿地生态和防治耕地盐碱化生态环境需水量,同时得出总生态环境需水量分别为17.94×108、7.51×108、6.92×108、6.63×108、5.52×108m3.1970—2013年疏勒河中游绿洲总生态环境需水量呈现逐渐减少趋势,减少了12.42×108m3.1970—2013年疏勒河中游绿洲总生态环境需水量空间变化特征呈现瓜州敦煌玉门,同时各区域生态环境需水量均呈现减少趋势.     

河道生态及环境需水理论探讨

针对地表水开发利用过程中存在的主要问题,从理论上对河道生态、环境需水进行探讨,包括:①在分析已有生态及环境需水概念的基础上,界定了生态及环境需水的定义;②对河道生态及环境需水进行了重点分析和论述。首先,回顾了与河道生态及环境需水研究有关的概念;其次,根据河道水量平衡探讨河道生态及环境需水的机理及其组成;第三,根据人类对地表水的影响强度,将水资源开发利用划分为4个阶段,论述了每个阶段河流生态系统的特点,并分析了河流流量减少所造成的对整个河流生态系统的影响;最后,给出了河道生态及环境需水的概念。论文为河道生态及环境需水研究提供了理论基础和依据。     

Distribution and ecological effect of mercury in Laogang landfill, Shanghai, China

Laogang landfill near Shanghai is the largest landfill in China, and receives about 10000 t of daily garbage per day, Samples of topsoil and plants were analyzed to evaluate mercury pollution from the landfill. For topsoil samples, there were significant correlations among total mercury （HgT）, combinative mercury （Hgc） and gaseous mercury （HgG）, and content of total organic carbon （TOC）, but, no significantly relationship was found between Hg content and filling time. Hg content changes in vertical profiles with time showed that the average Hgv of profiles 1992, 1996, and 2000 was similar, but their average HgG was quite different. HgT was significantly correlated with Hgc in profile 1992 and 2000, and Hgv was significantly correlated with Hg6 in profile 1996. HgG/Hgv ratio in profile samples decreased in the order of （HgG,/HgT）1992〉（HgG/HgT）1996〉〉（HgG/HgT）2000. A simple outline of Hg release in landfill could be drawn： with increasing of filling time, degradation undergoes different biodegradation, accordingly, gaseous mercury goes through small, more, and small proportion to total mercury. Distribution of Hg in plants was inhomogeneous, following the order of leaf〉root〉stem. The highest value of leaf may be associated with higher atmospheric Hg from landfill. Ligneous plants （e.g. Phyllostachys glanca, Prunus salicina and Ligustrum lucidum） are capable of enriching more Hg than herbaceous plants.     

EDTA-enhanced phytoremediation of lead contaminated soil by Bidens maximowicziana

Phytoremediation is a potential cleanup technology for the removal of heavy metals from contaminated soils.Bidens maximowicziana is a new Pb hyperaccumulator,which not only has remarkable tolerance to Pb but also extraordinary accumulation capacity for Pb.The maximum Pb concentration was 1509.3 mg/kg in roots and 2164.7 mg/kg in overground tissues.The Pb distribution order in the B. maximowicziana was:leaf>stem>root.The effect of amendments on phytoremediation was also studied.The mobility of soil Pb and the Pb concentrations in plants were both increased by EDTA application.Compared with CK(control check),EDTA application promoted translocation of Pb to overground parts of the plant.The Pb concentrations in overground parts of plants was increased from 24.23-680.56 mg/kg to 29.07-1905.57 mg/kg.This research demonstrated that B.maximowicziana appeared to be suitable for phytoremediation of Pb contaminated soil,especially,combination with EDTA.     

Decomposition of alachlor by ozonation and its mechanism

Decomposition and corresponding mechanism of alachlor, an endocrine disruptor in water by ozonation were investigated. Results showed that alachlor could not be completely mineralized by ozone alone. Many intermediates and final products were formed during the process, including aromatic compounds, aliphatic carboxylic acids, and inorganic ions. In evoluting these products, some of them with weak polarity were qualitatively identified by GC-MS. The information of inorganic ions suggested that the dechlorination was the first and the fastest step in the ozonation of alachlor.     

Enzymatic oxidation of aqueous pentachlorophenol

The influence of the nonionic surfactant Tween 80 on pentachlorophenol （PCP） oxidation catalyzed by horseradish peroxidase was studied. The surfactant was tested at concentrations below and above its critical micelle concentration （CMC）. Enhancement of PCP removal was observed at sub-CMCs. The presence of Tween 80 in the reaction mixture reduced enzyme inactivation which occurred through a combination of free radical attack and sorption by precipitated products. A simple first-order model was able to simulate time profiles for enzyme inactivation in the presence or absence of Tween 80. At supra-CMCs, the surfactant caused noticeable reductions in PCP removal, presumably through micelle partitioning of PCP which precluded the hydrophobic PCP molecule from interacting with the enzyme.     

基于综合水质标识指数和对应分析法的校园河道水质评价

以三峡大学的校园河道求索溪为研究对象,利用综合水质标识指数法确定求索溪水质类别,分析其水质时空变化规律,并利用对应分析法得出求索溪中不同监测点的主要污染因子.研究结果表明:求索溪整体的综合水质标识指数为7.423,整体水质为劣V类(地表水环境质量标准GB 3838-2002)且黑臭.从时间变化来看,求索溪4月份的水质最差,5月份次之,4、5月份所有监测点的水质都劣于V类且黑臭;8月份水质最好,水质为Ⅳ类;从空间分布来看,8个监测点综合水质标识指数均超过6.0,水质为劣V类,其中6号监测点的水质相对最好,监测点3号的水质相对最差;对应分析法得出求索溪的整体水体污染程度受总氮因子的影响最大,其次为总磷.该研究拟为求索溪及类似校园河道的水环境治理研究提供基础依据和参考.     

Effects of chitosan on growth of an aquatic plant (Hydrilla verticillata) in polluted waters with different chemical oxygen demands

Effects of chitosan on a submersed plant, Hydrilla verticillata, were investigated. Results indicated that H. venicillata could prevent ultrastructure phytotoxicities and oxidativereaction from polluted water with high chemical oxygen demand (COD). Superoxide dismutase (SOD) activity and malondialdehyde (MDA) contents in H. verticillata treated with 0.1% chitosan in wastewater increased with high COD (980 mg/L) and decreased with low COD (63 mg/L), respectively. Ultrastructural analysis showed that the stroma and grana of chloroplast basically remained normal. However, plant cells from the control experiment (untreated with chitosan) were vacuolated and the cell interval increased. The relict of protoplast moved to the center, with cells tending to disjoint. Our findings indicate that wastewater with high COD concentration can cause a substantial damage to submersed plant, nevertheless, chitosan probably could alleviate the membrane lipid peroxidization and ultrastructure phytotoxicities, and protect plant cells from stress of high COD concentration polluted water.     

Removal of cadmium using MnO2 loaded D301 resin

MnO2 loaded weak basic anion exchange resin D301 （Anion exchange resin, macroreticular weak basic styrene） as adsorbent has been prepared and applied to the removal of cadmium. The adsorption characteristics have been investigated with respect to effect of pH, equilibrium isotherms, removal kinetic data, and interference of the coexisting ions. The results indicated that the Cd^2＋ could be efficiently removed using MnO2 loaded D301 resin in the pH range of 3-8 from aqueous solutions with the co-existence of high concentration of alkali and alkaline-earth metals ions. The saturate adsorption capacity of the Cd^2＋ was 77.88 mg/g. The adsorption process followed the pseudo first-order kinetics. The equilibrium data obtained in this study accorded excellently with the Langmuir adsorption isotherm.     

Effect of coagulation pretreatment on the fouling of ultrafiltration membrane

The purpose of this study is to understand the effect and mechanism of preventing membrane fouling, by coagulation pretreatment, in terms of fractional component and molecular weight of natural organic matter （NOM）. A relatively higher molecular weight （MW） of hydrophobic compounds was responsible for a rapid decline in the ultrafiltration flux. Coagulation could effectively remove the hydrophobic organics, resulting in the increase of flux. It was found that a lower MW of neutral hydrophilic compounds, which could remove inadequately by coagulation, was responsible for the slow declining flux. The fluxes in the filtration of coagulated water and supernatant water were compared and the results showed that a lower MW of neutral hydrophilic compounds remained in the supernatant water after coagulation could be rejected by a membrane, resulting in fouling. It was also found that the coagulated flocs could absorb neutral hydrophilic compounds effectively. Therefore, with the coagulated flocs formed on the membrane surface, the flux decline could be improved.     

Penetration analysis of elements and bioleaching treatment of spent refractory for recycling

Acidithiobacillus ferrooxidans ATCC23270 and Acidithiobacillus thiooxidans TM-32 were used for bioleaching of spent refractories of aluminium and copper melting furnaces for their recycling.Firstly,penetration of elements into aluminium melting furnace refractory was investigated and it was found that up to 7 cm from surface was contaminated.Comparison on leaching efficiency by the strains ATCC23270 and TM-32 found that the strain ATCC23270 could treat larger amount of the refractories than the strain TM-32 could do.In the experiment of bioleaching of spent refractory aluminium melting furnace by the strain ATCC23270,high leaching efficiency were obtained on Al,Si,and Ca,and extremely low leaching performance was,however,shown on the rest of elements i.e.,Na,Mn,and Zn.Under the strain TM-32 use,relatively high leaching performance was recognized on Al,Si,Ca,Na,Mn,and Zn.In the experiment of bioleaching for spent refractory copper melting furnace,almost the same leaching trends were shown on Cu,Zn,Al,and Si under the strains ACTT23270 and TM-32 uses.     

Simultaneous removal of ammonium and phosphate by zeolite synthesized from coal fly ash as influenced by acid treatment

Zeolite synthesized from fly ash （ZFA） without modification is not efficient for the purification of NH4＋ and phosphate at low concentrations that occur in real effluents, despite the high potential removal capacity. To develop an effective technique to enhance the removal efficiency of ammonium and phosphate at low concentrations, ZFA was modified with acid treatment and the simultaneous removal of ammonium and phosphate in a wide range of concentration was investigated. It was seen that when compared with untreated ZFA, only the treatment by 0.01 mol/L of H2SO4 significantly improved the removal efficiency of ammonium at low initial concentrations. The behavior was well explained by the pH effect. Treatment by more concentrated H2SO4 led to the deterioration of the ZFA structure and a decrease in the cation exchange capacity. Treatment by 0.01 mol/L H2SO4 improved the removal efficiency of phosphate by ZFA at all initial P concentrations, while the treatment by concentrated H2SO4 （≥0.9 mol/L） resulted in a limited maximum phosphate immobilization capacity （PIC）. It was concluded that through a previous mild acid treatment （e.g. 0.01 mol/L of H2SO4）, ZFA can be used in the simultaneous removal of NH4＋ and P at low concentrations simulating real effluent.