共查询到20条相似文献,搜索用时 93 毫秒
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研究了使用硫化废渣和废锰渣在酸性介质下反应,浸取提锰工艺,工艺简单,可达到两渣同时治理的目的,碳酸锰的生产还可产生高的经济效益。 相似文献
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复合净水剂的制备及应用研究 总被引:12,自引:0,他引:12
研究了用硫铁矿浇渣(红泥)和废硫酸为原料制备复合净水剂的方法,并应用于造纸工业废水的处理。实验结果表明其净水效果优于聚合铝,处理的水质各项指标均符合排放标准,且工艺简单,处理成本低,是中小型造纸企业废水处理的行之有效的方法之一。 相似文献
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《环境污染与防治》2004,(6)
利用高岭土制备 PAS的研究尹荔松 周克省 周良玉 孔德明(中南大学物理科学与技术学院 ,湖南长沙 4 10 0 83 )研究了以高岭土为原料 ,制备净水剂聚合硫酸铝 ( PAS)的方法和工艺。结果表明 ,高岭土经过 70 0℃高温煅烧 1h,再酸浸 ,氧化铝的析出率达到 92 .1%。在高岭土制备聚合硫酸铝的工艺中 ,用氨水调整聚合硫酸铝的盐基度 ,得到盐基度的上升与氨水的添加量成正比。关键词 :高岭土 ,聚合硫酸铝 ,净水剂绿化带对公路交通噪声衰减的效果研究丁亚超 周敬宣 李 恒(华中科技大学环境科学与工程学院 ,湖北武汉 4 3 0 0 74 )通过对 8处林… 相似文献
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传统湿法制备活性白土工艺中存在水耗、酸耗大等清洁水平较低的问题,本研究提出了在生产工艺流程中循环使用硫酸酸性废液、并从循环3次的硫酸废液中回收铝盐制备无铁硫酸铝的一种改良型湿法制备活性白土工艺,对末端治理采用电石渣替代石灰作为中和剂进行了探索性实验研究。实验结果表明,改良型湿法制备活性白土工艺对活性白土产品的理化性质无明显影响,产品质量符合行业标准,且酸的利用率从20%提高到约90%,水耗减少量为原工艺的1/3,无铁硫酸铝主要参数符合相关产品技术标准(HG/T2225-2001)。用电石渣作为中和剂处理酸性废液能够实现出水水质稳定达标,处理成本从255万元降低至210万元。本研究的实施使得活性白土的生产工艺清洁生产水平有较大提高。 相似文献
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为了克服有机絮凝剂的二次投加及有毒性的缺点,以硅酸钠、硫酸钛、硫酸铝为原料,制备了聚合硅酸钛铝(PTAS)无机高分子复合絮凝剂处理模拟江水。结果表明,在n(Ti+Al)∶n(Si)=1∶3,n(Ti)∶n(Al)=1∶5,模拟江水pH值为5~9.3,絮凝剂投加量为0.3 mmol/L(以金属离子计)时,PTAS对模拟江水的混凝效果最好,除浊率达到92.5%以上。此外,通过X-射线衍射说明聚硅酸与硫酸铝、硫酸钛不是单纯的原料复合;红外吸收光谱显示钛、铝离子及其水解聚合产物可与共存的聚硅酸生成Si—O—Al键和Ti—O—Si键;激光粒度分析表明PTAS在聚合过程中粒度并没有明显变化,但均比聚硅酸粒径大。 相似文献
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以硫酸铝(AS)和二甲基二烯丙基氯化铵聚合物(PDMDAAC)为原料制备了无机-有机复合混凝剂(PASPDMDAAC),并利用其对页岩气钻井废水中TOC的去除率为响应值,采用响应面法中Box-Behnken实验设计,优化了制备工艺条件。结果表明:复合混凝剂制备工艺条件对页岩气钻井废水中TOC的去除率影响显著性依次为反应温度反应时间Al/PDMDAAC质量比;在响应曲面法模拟优化条件下,PAS-PDMDAAC复合混凝剂对页岩气钻井废水中TOC的去除率为74.35%;当反应温度为70℃,反应时间为70 min,AS/PDMDAAC质量比为6时,制备的复合混凝剂对页岩气钻井废水中TOC的去除率偏差为0.72%,符合实验精度要求。通过微观结构表征发现:PAS-PDMDAAC复合混凝剂中存在聚合羟基铝; AS水解形成羟基铝后,通过静电作用与PDMDAAC复合成规则的纳米微孔链状空间结构,并通过混凝实验溶液中Zeta电位变化,进一步验证了复合混凝剂中因静电作用使其电中和能力减弱的结论,此时复合混凝剂的最佳pH为6,弱酸性条件可避免铝盐类复合混凝剂的沉淀,以上研究结果为提高无机-有机复合混凝剂的混凝效果提供了参考。 相似文献
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为了探讨碱式硫酸铝对二氧化硫的吸收效果,对所需试剂硫酸铝和碳酸钙的适宜比例(碱度),以及碱式硫酸铝能稳定存在的铝量范围等进行了研究,测定了不同铝量和碱度的碱式硫酸铝对二氧化硫的吸收量以及pH值,并分析每种吸收液的饱和吸收量,最后将其与乙二胺/磷酸溶液的吸收情况进行对比。结果表明,碱度为40%时,铝量要保持在70 g/L以下才能在加热时不产生沉淀,吸收过程pH由4.5左右一直下降到2.0左右保持稳定,饱和吸收时间控制在140~160 min为宜,较为理想的方案是铝量32 g/L,碱度35%。 相似文献
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Ming-Yen Wey Ben-Horng Liou Shu-Yii Wu Ching-Hong Zhang 《Journal of the Air & Waste Management Association (1995)》2013,63(11):855-863
Abstract The growing amount of rubber waste, such as that from tires and cables, has resulted in serious environmental problems. Since rubber waste is not easily biodegradable even after a long period of landfill treatment, material and energy recovery is the preferable alternative to disposal. The potential offered by waste tire pyrolysis for solving both energy and waste treatment problems is widely recognized. Pyrolysis is one method of inducing thermal decomposition without using any oxidizing agent, or using such a limited supply of the agent that oxidization does not proceed to an appreciable extent. The latter may be described as autothermal pyrolysis and will be studied in the present work. The main objective of this research was to study the operating parameters of autothermal pyrolysis of scrap tires in a laboratory-scale fluidized bed reactor with a 100-cm bed height (10 cm I.D.) and a 100-cm freeboard (25 cm I.D.). Scrap tires were pyrolyzed in a limited oxygen supply, so that the heat for pyrolysis of the scrap tires was provided by combustion of some portion of the scrap tires. The operating parameters evaluated included the effect on the pyrolysis oil products and their relative proportions of (1) the air factor (O.O7–O35); (2) the pyrolysis temperature (370–570 °C); and (3) the catalyst added (zeolite and calcium carbonate). The results show that: (1) the composition of the liquid hydrocarbon obtained is affected significantly by the air factor; (2) the higher operating temperature caused a higher yield of gasoline and diesel; (3) the yield of gasoline increased due to the catalyst zeolite added, and the yield of diesel increased due to the addition of the catalyst calcium carbonate; (4) the principal constituents of gasoline included dipentene and diprene. 相似文献
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John E. Hatch 《Journal of the Air & Waste Management Association (1995)》2013,63(2):145-147
The history of the metallurgy of aluminum and its alloys has been closely associated with chlorine and fluorine. Fluorine is important in smelting operations. This paper deals with melting operations and discusses the use of chlorine to remove aluminum and magnesium oxides, dissolved hydrogen, and minor elements such as sodium and magnesium to obtain aluminum alloys of a quality satisfactory for modern use in transportation, aircraft, building, and other industries. A development period of ten years has resulted in a series of graded processes that accomplish this chlorine use effectively enough that atmospheric contamination is no longer a problem. The use of these processes which operate between the melting and casting units is discussed in some detail. The use of a new process to remove magnesium from recycled scrap aluminum is also considered. 相似文献