含氮化合物在东营凹陷南斜坡油气运移中的应用

利用含氮化合物研究东营凹陷南斜坡油气运移方向。对南斜坡油田不同部位油藏原油中含氮化合物的丰度、异构体参数的绝对大小与相对变化进行研究,结果表明,东营凹陷南斜坡原油间运移分馏效应明显,表现为处于同一运移路径上的油藏,随着运移距离的加大,原油中含氮化合物的总量（KC）逐渐减少,1,8-DMC/2,4-DMC值增加,原油中苯并[a]咔唑相对苯并[c]咔唑富集,导致苯并咔唑参数[a]/（[a]＋[c]）值升高。根据上述几项含氮化合物指标的研究,认为：乐安油田油气一部分由博兴洼陷经石村断层充注而来,另一部分由牛庄洼陷充注;纯化油田东部的油气由牛庄洼陷自东北方向注入。     

利用含氮化合物的分布探讨潜北周返断裂构造带的油气注入点

根据含氮化合物的分布特征,对周返断裂构造带各层位原油注入点位置与油气运移特征进行研究。结果表明:含氮化合物总含量在周11井到周13井之间呈现为高值,屏蔽型二甲基咔唑明显富集,1,8-/2,7-DMC等比值参数均有所增加,原油的注入位置位于周11井至周13井之间;以这两口井的区域为中心,洼陷内生成的油气向地层抬升方向上发生明显运移,表现出短距离侧向运移的特征,决定了研究区油气运移聚集模式主要为自生自储的成藏模式。     

东海盆地西湖凹陷平湖地区油气源对比及油气运移特征分析

为了明确东海盆地西湖凹陷平湖地区油气源及油气运移特征,基于对原油和烃源岩生物标志化合物、原油碳同位素、天然气组分、天然气碳同位素,原油物性、含氮化合物等参数的分析,明确了平湖地区的油气来源,揭示了原油和天然气的运移特征。结果表明：西湖凹陷平湖地区A断块花港组原油C₂₇、C₂₈、C₂₉甾烷以V型(C₂₇≈C₂₉>C₂₈)分布或者L型(C₂₇>C₂₉>C₂₈)分布为主;A断块烃源岩C₂₇、C₂₈、C₂₉甾烷以反L型(C₂₇>C₂₈29)分布为主,D块(H11井)平湖组中段烃源岩以L型分布为主,与原油的生标较为相似。油源对比结果和含氮化合物相关参数显示,平湖地区花港组原油具有垂向+短距离侧向运移的特征(断砂搭接);气源对比结果、天然气...     

高邮凹陷原油轻烃地球化学特征及群组划分

 高邮凹陷是苏北盆地油气潜力最大的凹陷,对该凹陷马家嘴、黄珏、富民、永安等9大油田原油样品的C₆~C₇轻烃特征、Mango轻烃参数及轻烃对比、蚀变星图和成熟度参数展开系统对比研究。C₆~C₇轻烃中富含正己烷,苯相对含量低,正庚烷、甲基环己烷和二甲基环戊烷的相对含量相差不大,显示高邮凹陷原油母质类型为腐泥-腐殖型。Mango轻烃参数K₁平均值为0.97,表明高邮凹陷原油具有相似的沉积环境;上含油气系统的K₂较大,平均值为0.31,表明陆源输入较大;中含油气系统的K₂较小,平均值为0.22,表明水源输入较大,下含油气系统介于两者之间,K₂平均值为0.27。由轻烃星图对比、庚烷值和异庚烷指数显示,上含油气系统的成熟度高,保存条件好;中含油气系统原油成熟度低,受次生演化作用明显;下含油气系统原油处于成熟阶段。     

新型杂环化合物1,5-苯并二氮杂卓衍生物的合成

苯并二氮杂卓类化合物具有较强的药物、生物活性,对其的合成研究一直备受关注.文章通过中间体2-甲基-2,4-二芳基-2,3-二氢-1,5-苯并二氮杂卓（2a-2c）合成了一系列新杂环化合物5-甲基-1,3a,5,-三芳基-1,2,4-噁二唑并[4,5-d]1,5-苯并二氮杂卓（3a-3l）,所得产物具有较高的纯度和分离产率.化合物（3）经IR,1HNMR,MS,元素分析和单晶衍射确证.     

2-（11H-苯[a]咔唑）-乙基氯甲酸酯（BCEC-Cl）合成与结构表征

以苯并环己酮和苯肼为原料设计合成了1,2-苯并-3,4-二氢咔唑母体环,经1,4-四氯苯醌脱氢处理后获得11H-苯[a]咔唑,对11H-苯[a]咔唑进行了化学修饰,在咔唑环的N原子位上引入了氯甲酸酯活性基团,制备了一种新型荧光标记材料分子2-(11H-苯[a]咔唑)-乙基氯甲酸酯,实验中对各步中间体进行了相应的结构表征,并对其光谱性质进行了研究.     

分子内酰基化反应合成新型六环稠杂环化合物

以2-氯甲基-3-苯并喹啉甲酸乙酯（1）为底物与α-萘酚、β-萘酚反应经“一锅法”合成了中间体2-（α-萘氧甲基）苯并[ h]喹啉-3-羧酸（2a）、2-（β-萘氧甲基）苯并[ H]喹啉-3-羧酸（2b）。化合物2a,2b在Eaton′s试剂作用下合成两种新型六环稠杂环化合物萘并[2′,1′,6,7]氧杂卓并[3,4-b]苯并喹啉-7（14H）-酮（3a）和萘并[1′,2′,6,7]氧杂卓并[3,4-b]苯并喹啉-15（8H）-酮（3b）。化合物2a,2b发生分子内傅一克酰基化闭环反应,所合成的新化合物2a、2b、3a、3b的结构经红外光谱、核磁共振谱、质谱及元素分析等得以确认。     

准噶尔盆地西北缘红车断裂带油气来源与成藏模式

在远离源岩区的红车断裂带内二叠系及以上地层均有油气显示。依据原油生物标志化合物色谱、色谱-质谱特征及其包含的参数比值信息可将研究区原油分为2类:A类原油源于沙湾凹陷二叠系烃源岩;B类原油为沙湾凹陷二叠系、白垩系与四棵树凹陷侏罗系三者混源。油气主要有2个运移方向:一是沙湾凹陷油气沿红车断裂带向西运移;二是四棵树凹陷油气越过艾卡断裂向北运移。在此基础上,从多元地质条件及其配置关系出发,总结出3种成藏模式:近源侧向砂体-不整合疏导早期成藏模式、远源混向"Z"字型疏导多期成藏模式、远源混向阶梯状疏导晚期成藏模式。     

准噶尔盆地陆梁地区油气运移方向研究

对准噶尔盆地陆梁地区油气运移方向的研究结果表明 ,陆梁油田的油气可能来源于盆 1井西凹陷和玛湖凹陷。进一步对两者油气可能运移路径的构造形态和运移通道条件进行了分析 ,认为盆 1井西凹陷的油气运移路径为一继承性的斜坡 ,深部的逆断裂和不整合面、中部的正断层及浅部的大套砂砾岩体可作为油气运移通道 ,其油气运移条件较玛湖凹陷有利。在此基础上 ,利用生物标志化合物w (甾烷C2 9ααα2 0S) /w (2 0S +2 0R)和w(C2 9ββ) /w(ββ+αα)、烷烃碳同位素δ13 C和原油碳同位素δ13 C、原油物性等指标在油气二次运移过程中发生的运移效应并结合流体势进行分析认为 ,陆梁地区主要的油气运移方向为西南东北向。证实了盆 1井西凹陷是该区主要的生油凹陷。     

准噶尔盆地陆梁地区油气运移方向研究

对准噶尔盆地陆粱地区油气运移方向的研究结果表明，陆粱油田的油气可能来源于盆1井西凹陷和玛湖凹陷。进一步对两者油气可能运移路径的构造形态和运移通道条件进行了分析，认为盆1井西凹陷的油气运移路径为一继承性的斜坡，深部的逆断裂和不整合面、中部的正断层及浅部的大变砂砾岩体可作为油气运移通道，其油气运移条件较玛湖凹陷有利。在此基础上，利用生物标志化合物ω(甾烷C29ααα20S)/ω(20S十20R)和ω(C29ββ)／ω(ββ αα)、烷烃碳同位素δ^13C和原油碳同位素δ^13C、原油物性等指标在油气二次运移过程中发生的运移效应并结合流体势进行分析认为，陆粱地区主要的油气运移方向为西南-东北向。证实了盆1井西凹陷是该区主要的生油凹陷。     

Carbazole-type compounds in crude oils

Carbazole-type compounds were analyzed using GC and GC-MS-MS. A relatively high concentration of carbazole-type compounds was detected in crude oils of different types (marine and non-marine) and different maturities (low mature and mature) in Tarinl. Liaohe and Keilu basins. The results suggest the ratios of 1, 8-dimethyl-/2, 7-dimethylcarbazole and benu, [a] carbazole/benzo [e] carbazole might be taken as petroleum migration parameters.     

Influence of biodegradation on benzocarbazole distributions in reservoired oils

Partition coefficient difference of benzocarba-zole isomers between oil, water and mineral phase makes them auseful indicator to quantify petroleum migration distance. Because of their nitrogen-heteroatom andannelated aromatic cycles they are generally regarded asbeing more resistant and the effects of biodegradation ontheir concentrations and distributions have not previouslybeen investigated. Reservoir extracts from three wells lo-cated in the Leng43 block of the Liaohe Basin were analyzed to investigate their occurrence and the effect of biodegrada-tion. Both hydrocarbon biomarkers and benzocarbazole isomers show systematical changes with the increase extent of biodegradation in study columns. Carbazole compounds may be biodegraded in a similar way to that observed in aliphatic and aromatic hydrocarbons. The distance from oil water contact is a primary control factor for biodegradation. The concentrations of benzocarbazole isomers show a slight increase in the upper part of the columns then a sharp de-crease towards oil water contact (OWC). Among three iso-mers benzo[a]carbazole seems more susceptible to biode-gradation than other two isomers and benzo[b]carbazole has higher ability to res ist bacterial attack. Benzo[b]carba-zole/benzo- [a]carbazole ratios can sensitively indicate the degree of biodegradation and the benzocarbazole index (BCratio) cannot be directly used as a migration indicator inbiodegraded oils.     

Geochemical significance of pyrrolic nitrogen compounds in various kinds of crude oils from the Tarim Basin

This is a report of the differences in abundances of pyrrolic nitrogen compounds and distribution of alkylated carbazoles among various oils from the Tarim Basin. At the same time, their geochemical significance is discussed.     

Constraints on the diversity of crude oil types in the Lunnan Oilfield, Tarim Basin, NW China

Hydrocarbons, include heavy oils, normal oils, waxy oils and light oils, condensate oils and gases were all found in Lunnan Oilfield, the occurrences of hydrocarbons with complicated physical properties indicates a complicated distribution of reservoirs. By the drilling data, the distribution pattern had been found that, in plan view, the density of crude oils in the western part is heavier than that of oils in the eastern part in Lunnan region, namely the crude oils were mainly found in the western part while the natural gases were mainly found in the eastern, which shows that an obvious differentiation in the east and west part was presented in the Lunnan region. Furthermore, in vertical view, the light hydrocarbons were mainly found in the Carboniferous reservoir while the heavier hydrocarbons were mainly found in the Ordovician and Triassic reservoirs. By analysis of the semi-logarithm distribution of n-alkanes, biomarker ratios and stable carbon isotopic compositions of crude oils, we have found that two oil families and discontinuous distribution were presented in hydrocarbons in Lunnan Oilfield. This kind of discontinuous distribution of geochemical parameters was not from continuous fractionation in migration process. The biodegraded heavy oil reservoirs in western part belong to the lower matured oil family, while the light or condensate oils reservoirs belong to higher matured oil family. Thus, a mixed filling of hydrocarbons was occurred in the middle part in Lunnan Oilfield and resulted in the occurrence of waxy oil. The mixed filling model may help to explain the distribution pattern of hydrocarbon reservoirs in Lunnan Oilfield, especially can lead to a relatively consistent explanation for all kinds of geochemical data, such as physical properties, pyrrolic nitrogen compounds, biomarker parameters and stable carbon isotopic compositions.     

烷基咪唑氟硼酸盐离子液体的合成与溶剂性质研究

研究了反应温度、时间和溶剂等对烷基咪唑氟硼酸盐室温离子液体[R1R2Im]BF4产率的影响,考察了该离子液体溶剂的性质。结果表明,[R1R2Im]BF4与油品中的脂肪族烃类组分不能互溶,但对部分含硫含氮组分均有一定的溶解度,同时还能溶解具有Lewis酸性的AlCl3和杂多酸络合物以及具有加氢活性的无机盐,这为开发Lewis酸催化或加氢催化等离子液体油品液/液双相催化体系奠定了基础。运用量子化学计算方法,考察了[R1R2Im]BF4的电导率与离子液体的分子结构的内在联系。结果表明,当阴离子相同时,N 烷基咪唑阳离子的体积越大,对应的离子液体的电导率越小。     

Sedimentary environment indicators: Benzothiazole and its derivatives

Benzothiazoles distributional characteristics of crude oils and non-hydrocarbon fractions of source rocks in Mangya depression of the Qaidam Basin, Lunnan oil field in the Tarim Basin, Kelamayi oil field in the Junggar Basin and the Tulufan Basin oil field were analyzed. It was found that the distributions of benzothiazole are remarkable diversity in different sedimentary environmental oils. The swamp crude oils contain high quantity of benzothiazole and relatively high quantity of alkylthio-benzothiazole and 2(3H)-benzothiazolone. But the quantity of the 2,2′-dithiobis- benzothiazole is relatively low. The abundance of benzothiazole and 2,2′-dithiobis-benzothiazole are relatively high in semi-brackish water lacustrine crude oils, but the quantity of alkylthio-benzothiazole and 2(3H)-benzothiazolone are relatively low. The benzothiazoles belong to weak acid and mild base compound, and their stabilization conditions relate to their environmental medium. The nitrogenous bases are in favor of alkalescence environment, while weak acid nitrogenous compounds are the main stable products under the weak acid environment. Benzothiazoles have great significance in identifying the oil- and gas-formed environment and the geochemistry study of non-hydrocarbon fraction in the future.     

塔北轮南地区油气成因与成藏探讨

通过对塔里木轮南地区不同层位、不同部位原油烃类化学组成的剖析 ,认为该区原油至少可分为两种不同的成因类型 ,可能存在多成藏期次 .三叠系、侏罗系原油化学组成与分布均一 ,其与轮南中西部断垒、桑塔木断垒西部奥陶系原油性质极为接近 ,以低分子量正构烷烃占优势 ,重排补身烷与重排甾烷、三环萜烷及Ts不甚发育 ,C2 3 三环萜烷为主峰 ,相对低值C2 7/C2 9甾烷等为特征 (第I类 ) ,奥陶系原油还具有中性氮化合物含量高的特征 ;以两断垒带东部石炭系、奥陶系为代表的原油以高值饱芳比、正构烷烃主峰碳后移、高含量C15 重排倍半萜与重排甾烷、低含量中性氮化合物、C2 0 三环萜烷为主峰、相对高值C2 7/C2 9甾烷、甾烷 /藿烷、Ts/ (Ts+Tm)、三环萜 /五环萜值等为特征 (第Ⅱ类 ) .轮南地区原油类型不同由主系油源不同所致 .烃类与非烃类运移指标反映奥陶系、石炭系原油具有自西而东的运移趋势 ;三叠系原油具有不太明显的由北而南的运移趋势 .烃类指标反映三叠系、侏罗系与同类型奥陶系原油间的运移分馏效应不太明显 ,其可能来自相同的烃源岩但成烃与成藏期不同     

风车草的化学成分

以体积分数为85%的乙醇回流提取风车草（Clinopodium chinensis O.Kuntze var.grandiflorum (Maxim.) Hara.）茎叶, 得提取物, 再经大
孔吸附树脂吸附、 硅胶和ODS柱色谱法分离各化学成分, 并经理化性质和波谱数据分析鉴定它们的化学结构. 共分离得到10个化合物, 分别鉴定为醉鱼草苷Ⅳb(1),  醉鱼草苷Ⅳ(2), 风轮菜皂苷(Ⅺ)(3), 香峰草苷(4), 3β,16β,23,28-四羟基齐墩果烷-11,13(18)-二烯-3-［β-D-吡喃葡萄糖-(1→2)］ ［β-D-吡喃葡萄糖-(1→3)］基-β-D-吡喃夫糖苷(5), 槲皮素-3-O-β-D-葡萄糖-(1→6)-O-β-D-葡萄糖苷(6), 风轮菜皂苷Ⅴ(7), 风轮菜皂苷Ⅲ(8), 风轮菜皂苷Ⅴb(9), 风轮菜皂苷Ⅲb(10). 除化合物1,2,4,5外, 其余化合物均为首次从该植物中分离得到.