Black shales in Ukraine – A review

As a result of a long-lasting and complex geological history, organic-matter-rich fine-grained rocks (black shales) with widely varying ages can be found on Ukrainian territory. Several of them are proven hydrocarbon source rocks and may hold a significant shale gas potential.Thick Silurian black shales accumulated along the western margin of the East European Craton in a foreland-type basin. By analogy with coeval organic-matter-rich rocks in Poland, high TOC contents and gas window maturity can be expected. However, to date information on organic richness is largely missing and maturity patterns remain to be refined.Visean black shales with TOC contents as high as 8% and a Type III-II kerogen accumulated along the axis of the Dniepr-Donets rift basin (DDB). They are the likely source for conventional oil and gas. Oil-prone Serpukhovian black shales accumulated in the shallow northwestern part of the DDB. Similar black shales probably may be present in the Lviv-Volyn Basin (western Ukraine).Middle Jurassic black shales up to 500 m thick occur beneath the Carpathian Foredeep. They are the likely source for some heavy oil deposits. TOC contents up to 12% (Type II) have been recorded, but additional investigations are needed to study the vertical and lateral variability of organic matter richness and maturity.Lower Cretaceous black shales with a Type III(-II) kerogen (TOC > 2%) are widespread at the base of the Carpathian flysch nappes, but Oligocene black shales (Menilite Fm.) rich in organic matter (4–8% TOC) and containing a Type II kerogen are the main source rock for oil in the Carpathians. Their thermal maturity increases from the external to the internal nappes.Oligocene black shales are also present in Crimea (Maykop Fm.). These rocks typically contain high TOC contents, but data from Ukraine are missing.     

Upper Permian Main Dolomite microbial carbonates as potential source rocks for hydrocarbons (W Poland)

Various microbialite lithofacies were common in the shallow-water environments which flourished under highly saline and arid climate conditions in the Polish part of the Zechstein (Upper Permian) Main Dolomite (Ca2) carbonates. Data came from detailed analysis of 78 cores from wells located at the southern and northern margins of the Main Dolomite basin in west Poland. Microbialite lithofacies are represented by columnar, planar and domal stromatolites, clotted thrombolites and biolaminites developed in high-to-low energy environments within the upper slope, lower parts of oolitic barrier/shoal, restricted lagoon, and tidal flat and tidal channel zones. In barrier environments ooids were predominant whereas in lagoonal settings microbial oncoids and peloids were common. In basinal settings laminated dolomudstones formed which are regarded as hemipelagic and are partly pelagic microbial in origin. Microbial communities coexisted with algae and developed mainly within shallow marine environments. Microbialites are built of cyanobacterial filaments and organo-mineral coccoidal forms possibly of bacterial origin. Organic geochemistry data confirm that organic matter was transformed by cyanobacteria and bacteria which may have played a main role in hydrocarbon generation. This is confirmed by C₂₉ to C₃₅ hopanes, Pr/Ph ratio below 1.0, and the presence of gammacerane as typical for Ca2 profiles. The role and occurrence of algae, as confirmed by C₂₉-steranes, in hydrocarbon generation was possibly minor. Thus it is concluded that the Main Dolomite microbialites could be the likely source rocks for hydrocarbons, with calculated original TOC values from 0.8 to ca 2.0 wt. %. These units also form the reservoir rocks, with porosities reaching 20%.     

Petrology and depositional evolution of the Paleozoic rocks of Iraq

The study integrates petrographical and lithological data from deep exploration wells and outcrops in northern Iraq to better understand the sedimentary environments present in the basin and to evaluate the depositional evolution of the Paleozoic rocks in Iraq. The studied Paleozoic successions are represented by five sedimentary cycles of intracratonic sequences. These are dominated mainly by siliciclastic and mixed sedimentary packages, and are separated by major and minor unconformity surfaces. These cycles are as follow: the Ordovician cycle, represented by the Khabour Formation; the Silurian cycle, represented by the Akkas Formation; the Middle-Late Devonian to Early Carboniferous cycle, represented by the Chalki, Pirispiki, Kaista, Ora and Harur formations; the Permian–Carboniferous cycle, represented by the Ga’ara Formation and late Permian cycle, represented by the Chia Zairi Formation. Generally, the cycles are characterized by siliciclastic and mixed carbonate–clastic facies with abrupt changes during Late Paleozoic reflecting the environmental and tectonic events during this period. The Ordovician Khabour Formation is suggested to be of shallow marine environment of deposition with stacked transgressive and regressive cycles that are eustatically controlled. The shale of Silurian Akkas Formation was deposited in open-marine environment. Depositional regimes in the Late Devonian to Early Carboniferous are considered as a continuation of deposition in the subsiding basin with a wide geographic distribution that reflect the epicontinental or epeiric seas in a homoclinic ramp setting. The Permo-Carboniferous Ga’ara Formation was deposited in continental to paralic environment while the Late Permian Chia Zairi Formation represents the carbonate platform deposition. The study revealed that potential source rocks may include some shale beds of the Khabour Formation, hot shales of Akkas Formation and the shales of Ora Formation. The sandstones of the Khabour, Akkas and Kaista formations have good reservoir potential. The Late Permian carbonates of Chia Zairi Formation may be self-sourcing and contain multiple reservoirs. The occurrence of shale as source rocks and limestone as reservoir rocks and some evaporates as sealing horizons make the formation as a reservoir in its own right.     

持续沉降是墨西哥湾油气区优质烃源岩形成的重要条件

墨西哥湾盆地是一个典型的中生代—新生代裂谷盆地,形成于北美克拉通南部边缘,大部分时间处于持续而稳定的沉降作用过程中。自晚侏罗世以来持续稳定的沉降形成了中生代富有机质的缺氧海相碳酸盐岩、黑色钙质页岩和泥质石灰岩等优质烃源岩,以及新生界以陆源碎屑为主的巨厚沉积物,存在大量的潜在烃源岩,加之良好的生储盖组合,从而形成了墨西哥湾盆地丰富的油气聚集。     

Geochemistry,reservoir characterization and hydrocarbon generation potential of lacustrine shales: A case of YQ-1 well in the Yuqia Coalfield,northern Qaidam Basin,NW China

Ever since a breakthrough of marine shales in China, lacustrine shales have been attracting by the policy makers and scientists. Organic-rich shales of the Middle Jurassic strata are widely distributed in the Yuqia Coalfield of northern Qaidam Basin. In this paper, a total of 42 shale samples with a burial depth ranging from 475.5 m to 658.5 m were collected from the Shimengou Formation in the YQ-1 shale gas borehole of the study area, including 16 samples from the Lower Member and 26 samples from the Upper Member. Geochemistry, reservoir characteristics and hydrocarbon generation potential of the lacustrine shales in YQ-1 well were preliminarily investigated using the experiments of vitrinite reflectance measurement, maceral identification, mineralogical composition, carbon stable isotope, low-temperature nitrogen adsorption, methane isothermal adsorption and rock eval pyrolysis. The results show that the Shimengou shales have rich organic carbon (averaged 3.83%), which belong to a low thermal maturity stage with a mean vitrinite reflectance (R_o) of 0.49% and an average pyrolytic temperature of the generated maximum remaining hydrocarbon (T_max) of 432.8 °C. Relative to marine shales, the lacustrine shales show low brittleness index (averaged 34.9) but high clay contents (averaged 55.1%), high total porosities (averaged 13.71%) and great Langmuir volumes (averaged 4.73 cm⁻³ g). Unlike the marine and marine-transitional shales, the quartz contents and brittleness index (BI) values of the lacustrine shales first decrease then increase with the rising TOC contents. The kerogens from the Upper Member shales are dominant by the oil-prone types, whereas the kerogens from the Lower Member shales by the gas-prone types. The sedimentary environment of the shales influences the TOC contents, thus has a close connection with the hydrocarbon potential, mineralogical composition, kerogen types and pore structure. Additionally, in terms of the hydrocarbon generation potential, the Upper Member shales are regarded as very good and excellent rocks whereas the Lower Member shales mainly as poor and fair rocks. In overall, the shales in the top of the Upper Member can be explored for shale oil due to the higher free hydrocarbon amount (S₁), whereas the shales in the Lower Member and the Upper Member, with the depths greater than 1000 m, can be suggested to explore shale gas.     

Oolitic shoal complexes characterization of the Lower Triassic Feixianguan Formation in the Yuanba Gas Field,Northeast Sichuan Basin,China

The Yuanba Gas Field is the second largest natural gas reservoir in the Sichuan Basin, southwest China. The vast majority of the natural gas reserve is from the Permian Changhsingian reef complexes and Lower Triassic Feixianguan oolitic shoal complexes. To better understand this reservoir system, this study characterizes geological and geophysical properties, spatial and temporal distribution of the oolitic shoal complexes and factors that control the oolitic shoals character for the Lower Triassic Feixianguan Formation in the Yuanba Gas Field. Facies analysis, well-seismic tie, well logs, seismic character, impedance inversion, and root mean square (RMS) seismic attributes distinguish two oolitic shoal complex facies – FA-A and FA-B that occur in the study area. FA-A, located in the middle of oolitic shoal complex, is composed of well-sorted ooids with rounded shape. This facies is interpreted to have been deposited in shallow water with relatively high energy. In contrast, FA-B is located in flanks of the oolitic shoal complex, and consists of poorly sorted grains with various shape (rounded, subrounded and subangular). The oolitic shoal complexes were mainly deposited along the platform margin. From the early Fei 2 Member period to the late Fei 2 Member period, the oolitic shoals complexes on the platform margin gradually migrated from the southwest to the northeast with an extent ranging from less than 100 km²–150 km² in the Yuanba Gas Field. The migration of oolitic shoals coincided with the development of a series of progradational clinoforms, suggesting that progradational clinoforms caused by sea-level fall maybe are the main reason that lead to the migration of oolitic shoals. Finally, this study provide an integrated method for the researchers to characterize oolitic shoal complexes by using well cores, logs, seismic reflections, impedance inversion, and seismic attribute in other basins of the world.     

Enrichment and distribution of shale oil in the Cretaceous Qingshankou Formation,Songliao Basin,Northeast China

The Songliao Basin is a large-scale petroliferous basin in China. With a gradual decline in conventional oil production, the exploration and development of replacement resources in the basin is becoming increasingly important. Previous studies have shown that the Cretaceous Qingshankou Formation (K₂qn) has favorable geological conditions for the formation of shale oil. Thus, shale oil in the Qingshankou Formation represents a promising and practical replacement resource for conventional oil. In this study, geological field surveys, core observation, sample tests, and the analysis of well logs were applied to study the geochemical and reservoir characteristics of shales, identify shale oil beds, build shale oil enrichment models, and classify favorable exploration areas of shale oil from the Cretaceous Qingshankou Formation. The organic matter content is high in shales from the first member of the Cretaceous Qingshankou Formation (K₂qn¹), with average total organic carbon (TOC) content exceeding 2%. The organic matter is mainly derived from lower aquatic organisms in a reducing brackish to fresh water environment, resulting in mostly type I kerogen. The vitrinite reflectance (Ro) and the temperature at which the maximum is release of hydrocarbons from cracking of kerogen occurred during pyrolysis (T_max) respectively range from 0.5% to 1.1% and from 430 °C to 450 °C, indicating that the K₂qn¹ shales are in the low-mature to mature stage (Ro ranges from 0.5% to 1.2%) and currently generating a large amount of oil. The favorable depth for oil generation and expulsion is 1800–2200 m and 1900–2500 m, respectively as determined by basin modeling. The reserving space of the K₂qn¹ shale oil includes micropores and mircofractures. The micropore reservoirs are developed in shales interbedded with siltstones exhibiting high gamma ray (GR), high resistivity (Rt), low density (DEN), and slightly abnormal spontaneous potential (SP) in the well-logging curves. The microfracture reservoirs are mainly thick shales with high Rt, high AC (acoustic transit time), high GR, low DEN, and abnormal SP. Based on the shale distribution, geochemical characteristics, reservoir types, fracture development, and the process of shale oil generation and enrichment, the southern Taikang and northern Da'an are classified as two favorable shale oil exploration areas in the Songliao Basin.     

The importance of shale composition and pore structure upon gas storage potential of shale gas reservoirs

The effect of shale composition and fabric upon pore structure and CH₄ sorption is investigated for potential shale gas reservoirs in the Western Canadian Sedimentary Basin (WCSB). Devonian–Mississippian (D–M) and Jurassic shales have complex, heterogeneous pore volume distributions as identified by low pressure CO₂ and N₂ sorption, and high pressure Hg porosimetry. Thermally mature D–M shales (1.6–2.5% VRo) have Dubinin–Radushkevich (D–R) CO₂ micropore volumes ranging between 0.3 and 1.2 cc/100 g and N₂ BET surface areas of 5–31 m²/g. Jurassic shales, which are invariably of lower thermal maturity ranging from 0.9 to 1.3% VRo, than D–M shales have smaller D–R CO₂ micropore volumes and N₂ BET surface areas, typically in the range of 0.23–0.63 cc/100 g (CO₂) and 1–9 m²/g (N₂).     

Thermal maturation, potential source rocks and hydrocarbon generation in Mesozoic rocks, Lougheed Island area, Central Canadian Arctic archipelago

Significant oil and gas accumulations occur in and around Lougheed Island, Arctic Canada, where hydrocarbon prospectivity is controlled by potential source rock distribution and composition. The Middle to Upper Triassic rocks of the Schei Point Group (e.g. Murray Harbour and Hoyle Bay formations) contain a mixture of Types I and II organic matter (Tasmanales marine algae, amorphous fluorescing bituminite). These source rocks are within the oil generation zone and have HI values up to 600 mg HC/g Corg. The younger source rocks of the Lower Jurassic Jameson Bay and the Upper Jurassic Ringnes formations contain mainly gas-prone Type II/III organic matter and are marginally mature. Vitrinite reflectance profiles suggest an effective geothermal gradient essentially similar to the present-day gradient (20 to 30°C/km). Maturation gradients are low, ranging from 0.125 to 0.185 log%Ro/km. Increases in subsidence rate in the Early Cretaceous suggest that the actual heat flow history was variable and has probably diminished from that time. The high deposition rates of the Christopher Formation shales coincide with the main phase of rifting in Aptian-Albian times. Uplift and increased sediment supply in the Maastrichtian resulted in a new sedimentary and tectonic regime, which culminated in the final phase of the Eurekan Orogeny. Burial history models indicate that hydrocarbon generation in the Schei Point Group took place during rifting in Early Cretaceous, long before any Eurekan deformation.     

Structural and facies architecture of a diapir-related carbonate minibasin (lower and middle Jurassic,High Atlas,Morocco)

We report the structural geometry and facies architecture of a small diapir-related carbonate-dominated basin from the Jurassic rift of the Moroccan High Atlas. The Azag minibasin is a lozenge-shaped depocenter completely enclosed by tectonic boundaries that we interpret as welds after former salt anticlines or salt walls. The exposed ca. 3000 m-thick infill of the Azag minibasin is asymmetric; layers are tilted to the W defining a rollover geometry. Areally-restricted sedimentary discontinuities and wedges of growth strata near the basin margins indicate sedimentation contemporaneous with diapiric rise of a Triassic ductile layer. Facies evolution through the basin reflects local accommodation by salt withdrawal and regional events in the High Atlas rift. The early basin infill in the Sinemurian and Pliensbachian shows thickness variations indicative of low-amplitude halokinetic movements, with reduced exposed thicknesses compared to surrounding areas. The exposed Toarcian and Aalenian deposits are also reduced in thickness compared to areas outside the basin. Subsidence increased dramatically in the Bajocian-early Bathonian (?), the main phase of downbuilding, when over 2600 m of carbonates and shales accumulated at a rate > 0.5 mm/a in the depocentral area of the minibasin governed by W-directed salt expulsion. The stratigraphic units distinguished often show maximum thicknesses and deeper facies in the depocentral area, and rapidly change to shallower facies at the basin margins. The Bajocian carbonate facies assemblage of the minibasin include: reservoir facies as microbialite-coral reefs in the basin margins (formed during periods of strong diapir inflation and bathymetric relief), basin-expansive oolite bars (formed during episodes of subdued relief), and organic-rich, dark lime mudstones and shales that show source-rock characteristics. The Azag basin is a good analog for the exploration of salt-related carbonate plays in rifts and continental margins where source-rock and reservoir can form in a same minibasin.     

Petroleum composition in the Cuu Long Basin (Mekong Basin) offshore southern Vietnam

The Cuu Long Basin (Mekong Basin) is a rift basin off southern Vietnam, and the most important petroleum producing basin in the country. However, information on petroleum type and characteristics has hitherto been largely unavailable to the public. This paper presents petroleum geochemical data on nine oil samples from four different producing fields in the Cuu Long Basin: the Dragon (Rong), Black Lion (Sutu-Den), Sunrise (Rang ?ong) and White Tiger (Bach Ho) Fields. The oils are highly paraffinic with bimodal normal alkane distributions and show moderate pristane to phytane ratios and a conspicuous hyperbolic decrease in abundance with increasing carbon number of hopane homologues from C₃₀ to C₃₅. The TPP-index of Holba et al. (Holba, A.G., Dzou, L.I., Wood, G.D., Ellis, L., Adam, P., Schaeffer, P., Albrecht, P., Greene, T., Hughes, W.B., 2003. Application of tetracyclic polyprenoids as indicators of input from fresh–brackish water environments. Organic Geochemistry 34, 441–469) is equal to 1 in all samples which in combination with tricyclic triperpane T26/T25 ratios >1 and the n-alkane and hopane distributions mentioned above provide a strong indication of an origin from lacustrine source rocks. This is supported by the absence of marine C₃₀ desmethyl steranes (i.e. 24-n-propylcholestanes) and marine diatom-derived norcholestanes. Based on the overall biological marker distributions, the lakes probably belonged to the overfilled or balanced-fill types defined by Bohacs et al. (Bohacs, K.M., Carroll, A.R., Neal, J.E., Mankiewicz, P.J., 2000. Lake-basin type, source potential, and hydrocarbon character. An integrated sequence-stratigraphic–geochemical framework. AAPG Studies in Geology 46, 3–34). The oils were generated from source rocks at early- to mid-oil-window maturity, presumably Oligocene lacustrine shales that are present in the syn-rift succession. Oils from individual fields may, however, be distinguished by a combination of biological marker parameters, such as the oleanane index, the gammacerane index, the relative abundance of tricyclic terpanes, the proportions of diasteranes and 28-norspergulane, complemented by other parameters. The oils of the Cuu Long Basin show an overall similarity to the B-10 oil from the Song Hong Basin off northern Vietnam, but are markedly different from the seepage oils known from Dam Thi Nai on the coast of central Vietnam.     

Source rock characteristics and hydrocarbon generation modelling of Upper Cretaceous Mukalla Formation in the Jiza-Qamar Basin,Eastern Yemen

The Upper Cretaceous Mukalla coals and other organic-rich sediments which are widely exposed in the Jiza-Qamar Basin and believed to be a major source rocks, were analysed using organic geochemistry and petrology. The total organic carbon (TOC) contents of the Mukalla source rocks range from 0.72 to 79.90% with an average TOC value of 21.50%. The coals and coaly shale sediments are relatively higher in organic richness, consistent with source rocks generative potential. The samples analysed have vitrinite reflectance in the range of 0.84–1.10 %Ro and pyrolysis T_max in the range of 432–454 °C indicate that the Mukalla source rocks contain mature to late mature organic matter. Good oil-generating potential is anticipated from the coals and coaly shale sediments with high hydrogen indices (250–449 mg HC/g TOC). This is supported by their significant amounts of oil-liptinite macerals are present in these coals and coaly shale sediments and Py-GC (S₂) pyrograms with n-alkane/alkene doublets extending beyond nC₃₀. The shales are dominated by Type III kerogen (HI < 200 mg HC/g TOC), and are thus considered to be gas-prone.One-dimensional basin modelling was performed to analysis the hydrocarbon generation and expulsion history of the Mukalla source rocks in the Jiza-Qamar Basin based on the reconstruction of the burial/thermal maturity histories in order to improve our understanding of the of hydrocarbon generation potential of the Mukalla source rocks. Calibration of the model with measured vitrinite reflectance (Ro) and borehole temperature data indicates that the present-day heat flow in the Jiza-Qamar Basin varies from 45.0 mW/m² to 70.0 mW/m² and the paleo-heat flow increased from 80 Ma to 25 Ma, reached a peak heat-flow values of approximately 70.0 mW/m² at 25 Ma and then decreased exponentially from 25 Ma to present-day. The peak paleo-heat flow is explained by the Gulf of Aden and Red Sea Tertiary rifting during Oligocene-Middle Miocene, which has a considerable influence on the thermal maturity of the Mukalla source rocks. The source rocks of the Mukalla Formation are presently in a stage of oil and condensate generation with maturity from 0.50% to 1.10% Ro. Oil generation (0.5% Ro) in the Mukalla source rocks began from about 61 Ma to 54 Ma and the peak hydrocarbon generation (1.0% Ro) occurred approximately from 25 Ma to 20 Ma. The modelled hydrocarbon expulsion evolution suggested that the timing of hydrocarbon expulsion from the Mukalla source rocks began from 15 Ma to present-day.     

东海陆架盆地的前新生界

根据东海陆架盆地周边地质、地球物理和钻井资料,应用岩石学、古生物学、同位素年代学、层序地层学等分析方法,研究东海陆架盆地的前新生界.陆架盆地广泛发育中生界,其中盆地南部发育最全,以三叠—白垩系陆相碎屑岩为主,中部隆起带以发育侏罗—白垩系的陆相火山岩为主,以台湾海峡为中心的盆地南部有海相—海陆过渡相的中生界.在盆地南部钻遇的年龄为1680 Ma的黑云角闪斜长片麻岩和在北部钻遇的糜棱片麻岩分别为浙闽东部前震旦纪变质岩和浙北晚元古代变质岩在海中的延伸.陆架地区晚古生代可能属于亚洲大陆东缘优地槽带的冒地槽,在盆地内尤其在东部坳陷带可能有晚古生代浅变质岩.     

Regional structure and tectonic history of the obliquely colliding Columbus foreland basin, offshore Trinidad and Venezuela

Cenozoic eastward migration of the Caribbean plate relative to the South American plate is recorded by an 1100-km-long Venezuela-Trinidad foreland basin which is oldest in western Venezuela (65-55 Ma), of intermediate age in eastern Venezuela (34-20 Ma) and youngest beneath the shelf and slope area of eastern offshore Trinidad (submarine Columbus basin, 15.0 Ma-Recent). In this study of the regional structure, fault families, and chronology of faulting and tectonic events affecting the hydrocarbon-rich Columbus foreland basin of eastern offshore Trinidad, we have integrated approximately 775 km of deep-penetration 2D seismic lines acquired by the 2004 Broadband Ocean-Land Investigations of Venezuela and the Antilles arc Region (BOLIVAR) survey, 325 km of vintage GULFREX seismic data collected by Gulf Oil Company in 1974, and published industry well data that can be tied to some of the seismic reflection lines. Top Cretaceous depth structure maps in the Columbus basin made from integration of all available seismic and well data define for the first time the elongate subsurface geometry of the 11-15 km thick and highly asymmetrical middle Miocene-Recent depocenter of the Columbus basin. The main depocenter located 150-200 km east of Trinidad and now the object of deepwater hydrocarbon exploration is completely filled by shelf and deepwater sediments derived mainly from the Orinoco delta. The submarine Darien ridge exhibits moderate (20-140 m) seafloor relief, forms the steep (12°-24°), northern structural boundary of the Columbus basin, and is known from industry wells to be composed of 0.5-4.5 km thick, folded and thrust-imbricated, hydrocarbon-bearing section of Cretaceous and early Tertiary limestones and clastic rocks. The eastern and southern boundaries of the basin are formed by the gently (1.7°-4.5°), northward-dipping Cretaceous-Paleogene passive margin of South America that is in turn underlain by Precambrian rocks of the Guyana shield.Interpretation of seismic sections tied to wells reveals the following fault chronology: (1) middle Miocene thrusting along the Darien ridge related to highly oblique convergence between the Caribbean plate and the passive margin of northern South America; continuing thrusting and transpression in an oblique foreland basin setting through the early Pleistocene; (2) early Pliocene-recent low-angle normal faults along the top of the Cretaceous passive margin; these faults were triggered by oversteepening related to formation of the downdip, structurally and bathymetrically deeper, and more seaward Columbus basin; large transfer faults with dominantly strike-slip displacements connect gravity-driven normal faults that cluster near the modern shelf-slope break and trend in the downslope direction; to the south no normal faults are present because the top Cretaceous horizon has not been oversteepened as it is adjacent to the foreland basin; (3) early Pliocene-Recent strike-slip faults parallel the trend of the Darien ridge and accommodate present-day plate motions.     

Methane-dominated thermochemical sulphate reduction in the Triassic Feixianguan Formation East Sichuan Basin, China: towards prediction of fatal H2S concentrations

New sour pools have recently found in the Lower Triassic Feixianguan Fm carbonate reservoirs in the East Sichuan Basin in China with H₂S up to 17.4% by volume. A recent blowout from a well drilled into this formation killed hundreds of people as a result of the percentage concentrations of H₂S. In order to assess the origin of fatal H₂S as well as the cause of petroleum alteration, H₂S concentrations and the isotopes, δ³⁴S and δ¹³C have been collected and measured in gas samples from reservoirs. Anhydrite, pyrite and elemental sulphur δ³⁴S values have been measured for comparison. The high concentrations of H₂S gas are found to occur at depths >3000 m (temperature now at 100 °C) in evaporated platform facies oolitic dolomite or limestone that contains anhydrite nodule occurrence within the reservoirs. Where H₂S concentrations are greater than 10% its δ³⁴S values lie between +12.0 and +13.2‰ CDT. This is within the range of anhydrite δ³⁴S values found within the Feixianguan Fm (+11.0 to +21.7‰; average 15.5±3.5‰ CDT). Thus H₂S must have been generated by thermochemical sulphate reduction (TSR) locally within the reservoirs. Burial history analysis and fluid inclusion data reveal that the temperature at which TSR occurred was greater than about 130–140 °C, suggesting that the present depth-temperature minimum is an artifact of post-TSR uplift. Both methane and ethane were actively involved in TSR since the petroleum became almost totally dry (no alkanes except methane) and methane δ¹³C values become significantly heavier as TSR proceeded. Methane δ¹³C difference thus reflects the extent of TSR. While it is tempting to use a present-day depth control (>3000 m) to predict the distribution of H₂S in the Feixianguan Fm, this is an invalid approach since TSR occurred when the formation was buried some 1000–2000 m deeper than it is at present. The likelihood of differential uplift across the basin means that it is important to develop a basinal understanding of the thermal history of the Feixianguan Fm so that it is possible to determine which parts of the basin have been hotter than 130–140 °C.     

Organic geochemistry and source potential of the lacustrine shales of the Upper Triassic - Lower Jurassic Kap Stewart Formation, East Greenland

The Upper Triassic — Lower Jurassic Kap Stewart Formation (Jameson Land, East Greenland) has been studied by a combination of sedimentological and organic geochemical methods (LECO/Rock Eval, sulphur, gas chromatography) in order to assess the hydrocarbon source potential of the abundant and extensive lacustrine shale intervals present in the formation.The organic matter in the shales is a mixture of algal and higher plant remains (type I and III kerogen). An organic assemblage dominated by algal material, having a rich oil potential, occurs in an interval approximately 10–15 m thick in the uppermost part of the formation. This interval has an organic carbon content up to 10% and Hydrogen Index values up to 700. The interval is consistently traceable along the exposed margins and the central part of the basin. The deposition of the uppermost shale interval coincided with the largest expansion of the lake, during a period with a stratified water column and anoxic bottom-water conditions.Locally the rocks exposed are thermally postmature due to the thermal influence of dolerite sills which intruded the Kap Stewart Formation in Tertiary time. However, the organic-rich shale interval is beyond the influence of the sills and indicates a maturity prior to or in the early stages of oil generation.Calculations of the generative potential of the lacustrine source rocks suggest that significant amounts of petroleum may have been generated in those sediments which have undergone sufficient burial in the southern and central part of the basin. Here, the contemporaneously deposited delta front and barrier island sandstones can thus be considered as potential targets for future hydrocarbon exploration. This type of play may also be of importance in other North Atlantic basins with a similar basin history.     

Geochemical overview and undiscovered gas resources generated from Hamitabat petroleum system in the Thrace Basin,Turkey

Since the first drill in 1957, three oil, 19 gas and condensate fields have been discovered in the Thrace Basin. However, any petroleum system with its essential elements and processes has not been assigned yet. This study consists of two parts, (1) geochemical overview of the previous work in order to get a necessary help to construct a petroleum system and (2) calculation of quantitative undiscovered hydrocarbon resources generated from this system. An extensive overview study showed that the primary reservoir and source rocks in the Thrace Basin are the Middle Eocene Hamitabat sandstones and shales, respectively, hence it appears that the most effective petroleum system of the Thrace Basin becomes the Hamitabat (!) petroleum system. Currently, 18.5 billion m³ of in-place gas, 2.0 million m³ (12.7 million bbl) in-place waxy oil as well as minor amount of associated condensate were discovered from this system. This study showed that the regional distribution of the oil and gas fields almost overlapped with the previously constructed pod of active Hamitabat shales implying that short and up-dip vertical migration pathway of hydrocarbons from the source to trapping side was available. Thermal model demonstrated that hydrocarbon generation from the Hamitabat shales commenced in the Early Miocene. The amount of quantitative gas generation based on the mean-original TOC = 0.94 wt%, mean-original HI = 217 HC/g TOC and the volume of the pod of active source rock = 49 km³ is approximately 110 billion m³ of gaseous hydrocarbons that results in a high generation–accumulation efficiency of 17% when 18.5 billion m³ of already discovered hydrocarbons are considered.     

南沙海域礼乐盆地中生界油气资源潜力

位于南沙东部海域的礼乐盆地是一大型的中、新生代叠置盆地,其特有的地质背景及巨厚的中生代地层显示了其与南沙海域其他新生代沉积盆地的差异。盆地内发育的厚度超过4 000 m的中生代海相地层,主要包括了上侏罗统—下白垩统的滨—浅海相含煤碎屑岩或半深海相页岩、上三叠统—下侏罗统三角洲—浅海相砂泥岩和中三叠统深海硅质页岩等3套地层,展示出盆地具有良好的油气生成潜力。而早期位于华南陆缘、现今位于南沙东部海域的礼乐盆地中生界,完全具备了形成油气藏的基本石油地质条件,具有较为良好的油气资源潜力,其中生界油气资源勘探具有非常重要的意义,将成为我国海域油气勘探的一个重要新领域。     

Effect of sedimentary heterogeneities on hydrocarbon accumulations in the Permian Shanxi Formation,Ordos Basin,China: Insight from an integrated stratigraphic forward and petroleum system modelling

Sedimentary heterogeneities are ubiquitous in nature and occur over a range of scales from core, reservoir to basin scales. They may thus exert significant influences on hydrocarbon generation, migration and accumulation. The sedimentary heterogeneities of the Permian Shanxi Formation in the Ordos Basin, China were modelled using Sedsim, a stratigraphic forward modelling program. The simulation results were then used to construct a 3D petroleum system model using PetroMod. The effects of sedimentary heterogeneities on hydrocarbon accumulations were evaluated by comparing the integrated Sedsim-PetroMod model with the classic 3D basin model. The Sedsim simulation shows that considerable sedimentary heterogeneities are present within the Shanxi Formation, as a result of the interplay of the initial topography, tectonic subsidence, base level change and sediment inputs. A variety of lithologies were developed both laterally and vertically within the Shanxi Formation at kilometre and metre scales, respectively, with mudstones mainly developed in the depositional centre, while sandstones developed in the southern and northern margin areas. A typical source-ward retrogradation is well developed within the Lower Shanxi Formation.A base-case classic 3D basin model was constructed to quantify the Permian petroleum system in the Ordos Basin. The geological and thermal models were calibrated using Vr and borehole temperature data. The source rocks of the Upper Paleozoic became mature (R_o > 0.5%) and high mature (R_o > 1.2%) in the late Triassic and late Jurassic, respectively, in the central and southern areas. During the Early Cretaceous, a tectonically induced geothermal event occurred in the southern Ordos Basin. This caused the source rocks to reach over maturity (R_o > 2.0%) quite rapidly in the early Late Cretaceous in the central and southern areas. All the source rock transformation ratios (TR) at present are greater than 70% in the P₁ coal and P₁ mudstone layers with TR values approaching 100% in the central and southern areas. The transformation ratios of the P₁ limestone are close to 100% over the entire interval.In the base-case model, a large amount of hydrocarbons appear to have been expelled and migrated into the Shanxi Formation, but only a minor amount was accumulated to form reservoirs. In the model, the Shanxi Formation sandstone layer was set to be homogeneous vertically and there was no regional seal rocks present at the top of the Shanxi Formation. Therefore hydrocarbons could not be trapped effectively with only minor accumulations in some local structural highs where hydrocarbons are trapped both at the top and in the up-dip direction by the adjacent mudstone facies. In contrast, the integrated Sedsim-PetroMod model takes into account of the internal lithological and sedimentary facies heterogeneities within the Shanxi Formation, forming complex contiguous sandstone-mudstone stacking patterns. Hydrocarbons were found to have accumulated in multiple intervals of lithological traps within the Shanxi Formation. The results indicate that lithological distinctions, controlled by sedimentary heterogeneities in three dimensions can provide effective sealing in both the top and up-dip directions for hydrocarbon accumulations, with gas being mainly accumulated near the depocentre where lithological traps usually formed due to frequent oscillations of the lake level.     

Geochemical characteristics and hydrocarbon generation modeling of the Jurassic source rocks in the Shoushan Basin, north Western Desert, Egypt

The Shoushan Basin is an important hydrocarbon province in the Western Desert, Egypt, but the origin of the hydrocarbons is not fully understood. In this study, organic matter content, type and maturity of the Jurassic source rocks exposed in the Shoushan Basin have been evaluated and integrated with the results of basin modeling to improve our understanding of burial history and timing of hydrocarbon generation. The Jurassic source rock succession comprises the Ras Qattara and Khatatba Formations, which are composed mainly of shales and sandstones with coal seams. The TOC contents are high and reached a maximum up to 50%. The TOC values of the Ras Qattara Formation range from 2 to 54 wt.%, while Khatatba Formation has TOC values in the range 1-47 wt.%. The Ras Qattara and Khatatba Formations have HI values ranging from 90 to 261 mgHC/gTOC, suggesting Types II-III and III kerogen. Vitrinite reflectance values range between 0.79 and 1.12 VRr %. Rock−Eval T_max values in the range 438-458 °C indicate a thermal maturity level sufficient for hydrocarbon generation. Thermal and burial history models indicate that the Jurassic source rocks entered the mature to late mature stage for hydrocarbon generation in the Late Cretaceous to Tertiary. Hydrocarbon generation began in the Late Cretaceous and maximum rates of oil with significant gas have been generated during the early Tertiary (Paleogene). The peak gas generation occurred during the late Tertiary (Neogene).