Structure and properties of solid state diffusion bonding of 17-4PH stainless steel and titanium

Abstract

Solid state diffusion bonded joint between titanium and 17-4 precipitation hardening stainless steel was carried out in the temperature range of 800–1050°C in steps of 50°C for 30 min and also at 950°C for 30–180 min in steps of 30 min under a uniaxial pressure of 3·5 MPa in vacuum. Bonded samples were characterised using light microscopy, field emission scanning electron microscopy and X-ray diffraction technique. Up to 850°C for 30 min, FeTi phase was formed at the diffusion interface; however, α-Fe+λ, χ, Fe₂Ti and FeTi phases and phase mixtures were formed above 850°C for 30 min and at 950°C for all bonding times. Maximum tensile strength of ～326 MPa, shear strength of ～254 MPa and impact toughness of ～24 J were obtained for the diffusion couple processed at 1000°C for 30 min and 30–180 min time interval at 950°C, and maximum tensile strength ～323 MPa, shear strength ～243 MPa and impact toughness of ～22 J were achieved when bonding was processed for 120 min. The residual stress of the bonded joints increases with the increase in bonding temperatures and times.     

Effect of welding parameters on diffusion bonding of type 304 stainless steel–copper bimetal

Abstract

Stainless steel AISI type 304 and electrolytic cold rolled copper were joined by diffusion bonding at temperatures ranging from 650 to 950°C, for times from 5 to 45 min, and at pressures from 2 to 12 MPa. After bonding the microstructure of the interface was investigated, including the grain size, and shear and tensile strengths of the bonded specimens were determined. From the results, it was seen that the bond shear strength was dependent on interface grain boundary migration and on grain growth during the bonding process. In addition, attempts were made to find a relationship between grain size and shear strength in the bonding area. Taking into account the results of shear testing and microstructural observation, for a sound bond, optimum bonding conditions were obtained at temperatures of 800–850°C for 15–20 min at 4–6.5 MPa. The fracture behaviour of the diffusion bonded joint was investigated by means of shear and tensile testing under different bonding conditions. It was found that both shear and tensile strengths of the bonds were sensitive to the bonding conditions, and the intermetallic phases did not affect these parameters. Furthermore, the value of shear strength of the bond surface determined by shear testing was higher than the shear strength of the fracture surface determined by tensile testing.     

Effects of temperature on interface microstructure and strength properties of titanium–niobium stainless steel diffusion bonded joints

Abstract

The effects of temperature on interface microstructure and strength properties of Ti/stainless diffusion bonded joint using Nb interlayer, processed in the temperature range 800–950°C for 1·5 h in vacuum were investigated. The stainless steel/Nb interface is free from intermetallic phase up to 900°C; however, Fe₂Nb+Fe₇Nb₆ phase mixture has been observed at 950°C processing temperature. The Nb/Ti interface is free from intermetallic for all processing temperatures. The maximum tensile strength of ～287 MPa (～90% of Ti) and shear strength ～222 MPa (～75% of Ti) along with 6·9% ductility have been achieved in the diffusion bonded joints, when processed at 900°C. The bonded samples failure takes place through the stainless steel/Nb interface for all processing temperatures during the loading.     

An Evaluation of Quality of Joints of Two Dissimilar Metals by Diffusion Bonding using Ultrasonic C Scan

Diffusion bonding of commercially available pure aluminum/copper was carried out between the temperatures of 400°C and 500°C for 60 min under the pressure of 5–15 MPa in vacuum. The effects of temperature and pressure on the microstructure of aluminum/copper diffusion bonded joints were analyzed. The interface micrographs of the bonded samples were observed in optical and scanning electron microscope (SEM) images. The soundness of the bond was evaluated by destructive and nondestructive (ultrasonic C scan) testing methods. The quality of the bonded joints was evaluated by the intensity of the echo and its images of ultrasonic testing and was correlated with destructive parameters such as the strength ratio. Chemical compositions of the interface and the fractured surface of the bonded samples were characterized by energy dispersive spectroscopy (EDS). EDS patterns were confirmed by the formation of the different compositions at the interface of the bonded samples. Better bonding characteristics were observed by diffusion bonding optimum parameters at 450°C with an applied pressure of 15 MPa for 60 min.     

Influence of interface microstructure on the mechanical properties of titanium/17-4 PH stainless steel solid state diffusion bonded joints

In the present study, titanium was diffusion bonded to a type 17-4 precipitation hardening stainless steel in vacuum at different temperatures and times. Bonded samples were characterized using light microscopy, scanning electron microscopy (SEM) and X-ray diffraction technique (XRD). The inter-diffusion of the chemical species across the diffusion interface was evaluated by electron probe microanalysis (EPMA). Up to 850 °C for 60 min, FeTi phase was formed at the diffusion interface; however, α-Fe + λ, χ, Fe₂Ti and FeTi phases and their phase mixtures were formed above 850 °C for 60 min and at 900 °C for all bonding times. The maximum tensile strength of ∼342.4 MPa and shear strength of ∼260.3 MPa along with 12.8% elongation were obtained for the diffusion couple processed at 950 °C. The thicknesses of different reaction products at the bond interface play an important role in determining the mechanical properties of the joints. The residual stress of the bonded joints increases with the increases in bonding temperatures and times.     

Experimental study of diffusion welding/bonding of titanium to copper

In the present study, Ti–6Al–4V alloy was bonded to electrolytic copper at various temperatures of 875, 890 and 900 °C and times of 15, 30 and 60 min through diffusion bonding. 3 MPa uniaxial load was applied during the diffusion bonding. Interface quality of the joints was assessed by microhardness and shear testing. Also, the bonding interfaces were analysed by means of optical microscopy, scanning electron microscopy and energy dispersive spectrometer. The bonding of Ti–6Al–4V to Cu was successfully achieved by diffusion bonding method. The maximum shear strength was found to be 2171 N for the specimen bonded at 890 °C for 60 min. The maximum hardness values were obtained from the area next to the interface in titanium side of the joint. The hardness values were found to decrease with increasing distance from the interface in titanium side while it remained constant in copper side. It was seen that the diffusion transition zone near the interface consists of various phases of βCu₄Ti, Cu₂Ti, Cu₃Ti₂, Cu₄Ti₃ and CuTi.     

Liquid phase bonding of aluminium and aluminium/Nicalon composite using copper interlayers

Abstract

The liquid phase bonding, in air, of unreinforced and fibre reinforced aluminium using copper interlayers has been investigated. Bond strengths have been measured and microstructures characterised using electron microscopy and electron probe microanalysis. The diffusion behaviour and interphase reactions, which depend on the bonding conditions, are discussed, and a mechanism for the formation of a liquid phase bond is proposed. For unreinforced aluminium a bonded area of ~100% was achieved at 550°C by applying a pressure of 10 MPa for 30 min to the joint while using a 10 μm thick copper interlayer. With the composite it was necessary to use a higher bonding pressure (20 MPa) in order to limit oxidation of the copper and maximise the bonded area (to ~80%).

MST/1730     

Effect of transient liquid phase diffusion bonding on properties of ODS nickel alloy MA758

Abstract

An oxide dispersion strengthened (ODS) MA758 nickel alloy was bonded in the fine grain and recrystallised conditions using transient liquid phase diffusion bonding at 1100°C for various hold times. A microstructural study was undertaken to investigate the effect of post-bond heat treatments at 1360°C for 1 hand changes in parent metal grain size on developments of bond microstructure. Shear and fatigue tests were carried out to determine the mechanical integrity of the bonded samples. Results showed that shear and fatigue strengths of diffusion bonds made in the recrystallised condition were higher than those of bonds made in the fine grain condition. The results from oxidation tests performed at 1000°C show that the oxidation rate for samples bonded in the fine grain condition is higher than for those bonded in the recrystallised condition. However, localised oxidation of the joint region was not observed and this indicated that compositional homogeneity across the diffusion bonds had been attained.     

Static coarsening behaviour of lamellar microstructure in selective laser melted Ti–6Al–4V

Static coarsening mechanism of selective laser melted (SLMed) Ti–6Al–4V with a lamellar microstructure was established at temperatures from 700 °C to 950 °C. Microstructure evolution revealed that high heat treatment temperature facilitated martensite decomposition and promoted lamellae growth. At each temperature, the growth rate decreased with increasing holding time. The static coarsening behaviour of SLMed Ti–6Al–4V can be interpreted by Lifshitz, Slyozov, and Wagner (LSW) theory. The coarsening coefficient were 0.33, 0.33–0.4, 0.4–0.5 for 700–800 °C, 900 °C and 950 °C, respectively. This indicated the coarsening mechanism was bulk diffusion at 700–800 °C, and a combination of bulk diffusion and interface reaction at 900 °C and 950 °C conditions.     

Conversion of copper and manganese metallic films to spinel coating

Oxidation of copper + manganese metallic thin films on UNS 430 stainless steel was studied at temperatures of 600–950 °C. The Cu–Mn metallic films were converted to Cu–Mn spinel coating in the temperature range of 600–950 °C as confirmed by X-ray diffraction. Conversion mechanisms of metals to the spinel were investigated. Examination by SEM showed that negligible oxidation of the substrate alloy occurred in the coated samples at temperatures up to 750 °C; a transition layer formed between the substrate and spinel coating at higher temperatures. Cu–Mn spinel coating can provide protection to the metallic substrate at temperatures up to 850 °C. Formation of the spinel coating was due to reactions of CuO, which formed through outward diffusion of copper, with manganese oxides, which formed through inward diffusion of oxygen.     

Microstructure and mechanical properties of low alloy steel T11–austenitic stainless steel 347H bimetallic tubes

Abstract

A low alloy steel (T11) has been bonded to an austenitic stainless steel 347H by hot coextrusion under industrial conditions. The final product was a seamless bimetallic tube with 347H cladding the exterior for corrosion resistance in severely corrosive environments at high temperatures. The microstructures of the coextruded bonding have been compared to those obtained in the laboratory, after diffusion bonding experiments, using hot isostatic pressing (hipping). In all cases both the interdiffusion of the different elements across the interface and the microstructure have been analysed by optical microscopy, SEM, and TEM. On the 347H side a profuse precipitation, mainly of NbC, was found in a region near the interface. Only in the hipped specimens, as result of nickel and chromium diffusion from the stainless steel to the T11 steel, a martensite band was observed parallel to the interface. The heat treatment performed on the bimetallic tubes, to obtain the optimum combination of mechanical properties and corrosion resistance, consisted of austenitisation between 1050–1100°C, water quenching, and a stabilisation treat ment at 850–900°C, followed by slow cooling.     

High-strength oxide ceramics joints obtained by diffusion bonding with the use of platinum and palladium gaskets

Alumina and zirconia ceramics joints were made by diffusion bonding through platinum and palladium gaskets in air at temperatures between 1300 and 1550°C. The instrumentation and the procedure for these joints manufacturing are described. The effects of temperature, pressure and exposition time on 3-pt bending strength of resulting joints were established. The maximum bending strength of the samples reached 500 MPa. During thermal resistance testing the samples withstood several hundreds of thermal cycles at temperatures up to 800°C in air.     

Promising effect of copper on the mechanical properties of transformation-induced plasticity steels

To put in a nut shell ‘Alloying with copper was found to results in promising benefits on mechanical properties of transformation-induced plasticity steels’. In this research, the CMnSiAlCu transformation-induced plasticity steels were annealed at two different temperatures. The unique combination of mechanical properties was obtained in new developed copper containing transformation-induced plasticity steels. It was also showed that by adding 2.4%Cu in transformation-induced plasticity steels and in both 770°C and 800°C annealing treated condition, the yield and tensile strengths were increased by more than 35% and 26%. Moreover, a detailed examination of deformation and strain hardening behaviour of the steels studied revealed that the lower annealing temperature leads to the more uniform strain distribution within the copper-added transformation-induced plasticity steel.     

Diffusion bonding of 410 stainless steel to copper using a nickel interlayer

In the present work, plates of stainless steel (grade 410) were joined to copper ones through a diffusion bonding process using a nickel interlayer at a temperature range of 800–950 °C. The bonding was performed through pressing the specimens under a 12-MPa compression load and a vacuum of 10^? 4 torr for 60 min. The results indicated the formation of distinct diffusion zones at both Cu/Ni and Ni/SS interfaces during the diffusion bonding process. The thickness of the reaction layer in both interfaces was increased by raising the processing temperature. The phase constitutions and their related microstructure at the Cu/Ni and Ni/SS diffusion bonding interfaces were studied using optical microscopy, scanning electron microscopy, X-ray diffraction and elemental analyses through energy dispersive spectrometry. The resulted penetration profiles were examined using a calibrated electron probe micro-analyzer. The diffusion transition regions near the Cu/Ni and Ni/SS interfaces consist of a complete solid solution zone and of various phases based on (Fe, Ni), (Fe, Cr, Ni) and (Fe, Cr) chemical systems, respectively. The diffusion-bonded joint processed at 900 °C showed the maximum shear strength of about 145 MPa. The maximum hardness was obtained at the SS–Ni interface with a value of about 432 HV.     

Partial transient liquid phase diffusion bonding of Zircaloy-4 to stabilized austenitic stainless steel 321

An innovative method was applied for bonding Zircaloy-4 to stabilized austenitic stainless steel 321 using an active titanium interlayer. Specimens were joined by a partial transient liquid phase diffusion bonding method in a vacuum furnace at different temperatures under 1 MPa dynamic pressure of contact. The influence of different bonding temperatures on the microstructure, microindentation hardness, joint strength and interlayer thickness has been studied. The diffusion of Fe, Cr, Ni and Zr has been investigated by scanning electron microscopy and energy dispersive spectroscopy elemental analyses. Results showed that control of the heating and cooling rate and 20 min soaking at 1223 K produces a perfect joint. However, solid-state diffusion of the melting point depressant elements into the joint metal causes the solid/liquid interface to advance until the joint is solidified. The tensile strength of all the bonded specimens was found around 480–670 MPa. Energy dispersive spectroscopy studies indicated that the melting occurred along the interface of the bonded specimens as a result of the transfer of atoms between the interlayer and the matrix during bonding. This technique provides a reliable method of bonding zirconium alloy to stainless steel.     

Effects of reaction products on the bond strength of the transition joint formed between titanium and stainless steel

Abstract

Solid state diffusion bonding was carried out between commercially pure titanium and 304 stainless steel in the temperature range 800 - 950°C for 120 min in vacuum under uniaxial load. The transition joints were characterised using optical and scanning electron microscopy. The study shows the presence of different reaction layers in the diffusion zone and their chemical compositions were determined by energy dispersive spectroscopy. The occurrence of different intermetallic phases such as FeTi, λ, χ, and σ has been predicted from the ternary phase diagram of Fe - Cr - Ti and they were confirmed by the X-ray diffraction technique. A maximum bond strength 76% of that of titanium was obtained for the diffusion couple processed at 800 ° C owing to finer size intermetallic compounds and the increment in joining temperature, which results in growth of brittle intermetallics leading to a sharp fall in the strength of the transition joints.     

Investigation on diffusion bonding of functionally graded WC–Co/Ni composite and stainless steel

A functionally graded WC–Co/Ni composite (FGWC) and 410 stainless steel (410ss) were successfully bonded by diffusion bonding. With the bonding temperature or holding time increasing, the tensile strength of the joints increased firstly and then decreased. The maximum tensile strength of the FGWC/410ss joints was 195 MPa bonded at 950 °C for 80 min. A diffusion layer was formed between the Ni layer and the 410ss as a result of the interdiffusion of Ni and Fe. The Ni layer could release the residual stresses of the FGWC/410ss joints. The fracture of the FGWC/410ss joints occurred in the Ni layer by the way of ductile fracture.     

Vacuum hot roll bonding of titanium alloy and stainless steel using nickel interlayer

Abstract

Vacuum hot roll bonding of titanium alloy and stainless steel using a nickel interlayer was investigated. No obvious reaction or diffusion layer occurs at the interface between stainless steel and nickel. The interface between titanium alloy and nickel consists of an occludent layer and diffusion layers, and there are the intermetallic compounds (TiNi₃, TiNi, Ti₂Ni and their mixtures) in the layers. The total thickness of intermetallic layers at the interface between titanium alloy and nickel increases with the bonding temperature, and the tensile strength of roll bonded joints decreases with the bonding temperature. The maximum tensile strength of 440·1 MPa was obtained at the bonding temperature of 760°C, the reduction of 20% and the rolling speed of 38 mm s^–1.     

An experimental investigation of phase transformation superplastic diffusion bonding of titanium alloy to stainless steel

The solid-state direct diffusion bonding of a near α-phase titanium alloy to an austenitic stainless steel by means of the phase transformation superplasticity (PTSP) caused by the cycles of heating and cooling has been carried out. The test results showed that, under the conditions of T_max = 890°C, T_min = 800°C, cyclic number of heating and cooling N = 10 cycles, specific pressure P = 5 MPa, heating rate V_h = 30°C/s and cooling rate V_c = 10°C/s, the ultimate tensile strength of the joint reached its maximum value (307 MPa), and the bonding time was only 120 s. In the phase transformation superplastic state, the deformation of titanium alloy has a character of ratcheting effect and it accumulates with the cycles of heating and cooling. The observations of tensile fracture interface showed that both the brittle intermetallic compound (FeTi) and the solid solution based on β-Ti were formed on the interface, and the more in quantity and the smaller in size the solid solutions are, the higher the ultimate tensile strength is.     

Effect of reduction rate and annealing temperature on texture evolution and magnetic properties of used non-oriented silicon steel

This paper discusses the method of improving the magnetic properties of used silicon steel by cold rolling and annealing process with used non-oriented silicon steel as the object. The texture evolution and magnetic domain structure are also investigated. Experimental results show that the magnetic domain can be transformed vastly compared with the used silicon steel when the specimens are prepared through the same cold rolling and annealing conditions. The length of the magnetic wall and the density of magnetic domain per unit area are boosted, and the magnetic domain refinement is exceedingly apparent. Under the same annealing condition (at 950 °C for 5 min), the γ-fiber is gradually decreased to 6.6 % and the {110} recrystallization texture is gradually enhanced with increased reduction from 28.3 % to 40 %. The intensity of the Goss texture reaches a maximum of 22.2. For the cold rolling reduction of 34.3 %, the γ-fiber gradually decrease to 13.8 % and the {110} recrystallization texture is gradually enhanced with increase in the annealing temperature from 800 °C to 950 °C. Moreover, the intensity of Goss texture reaches 14. The sample prepared through 40 % reduction and annealing at 950 °C for 5 min exhibited the most desirable magnetic properties. The magnetic induction B₅₀ value of the specimen is increased by 0.052 T, and the core loss P_1.5/50 is reduced by 0.478 W/kg compared with the initial specimen.