共查询到18条相似文献,搜索用时 281 毫秒
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研究IIR/EPDM体系中共混比、硫黄硫化体系对其共混胶性能的影响。结果表明 ,IIR与EPDM共混相容性较好 ,可以达到共硫化 ;IIR/EPDM共混比为 75 /2 5时共混胶性能最好 ;用传统硫化体系 (CV)、有效硫化体系 (EV)和半有效硫化体系 (SEV)都能得到性能较好的共混胶 ,其中以CV体系的硫化胶性能最好。 相似文献
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研究了IIR/EPDM共混体系中的并用比、硫黄硫化体系对共混胶耐热老化性能的影响。研究结果表明 ,IIR与EPDM的相容共混性较好 ,共混胶力学性能较好。用正常硫黄、低硫高促进剂和无硫硫化体系都能得到性能较好的共混胶 ,其中以有效硫化体系硫化胶的耐热老化性能最为突出 相似文献
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研究了IIR/EPDM共混体系中的并用比、硫黄硫化体系对共混胶耐热老化性能的影响。研究结果表明,IIR与EPDM的相容共混性较好,共混胶力学性能较好。用正常硫黄、低硫高促进剂和无硫硫化体系都能得到性能较好的共混胶,其中以有效硫化体系硫化胶的耐热老化性能最为突出。 相似文献
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采用硫黄硫化体系和过氧化物(硫化剂DCP)硫化体系对EPDM/NR并用胶实施复合交联,考察了不同共混比EPDM/NR共混胶的硫化特性、硫化胶的物理机械性能、耐水性及耐溶剂性能。结果表明:复合交联后,胶料的硫化特性、物理机械性能均有所提高;EPDM母炼胶中DCP的用量要高于NR;胶料共混比为80/20(EPDM/NR),其耐水性和耐溶剂性能达到最佳。 相似文献
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三元乙丙橡胶/乙烯-辛烯共聚物/甲基乙烯基硅橡胶共混物的制备与性能 总被引:2,自引:0,他引:2
用动态硫化法制备了乙烯-辛烯共聚物(POE)/甲基乙烯基硅橡胶(MVQ)热塑性弹性体(PMTPV),进而将其与三元乙丙橡胶(EPDM)共混制备EPDM/POE/MVQ三元共混物(EPDM/PMTPV)。对高温开炼机、转矩流变仪、双螺杆挤出机3种工艺制备的PMTPV进行了性能对比,研究了EPDM/PMTPV的共混比对胶料性能的影响。结果表明,双螺杆挤出机制备PMTPV的综合性能最好;随着PMTPV用量的增加,EPDM/PMTPV共混胶的力学性能、绝缘性、耐寒性、耐热性及耐油性得以改善。扫描电镜分析结果也说明在EPDM/PMTPV体系中,EPDM与MVQ的相容性比在EPDM/MVQ直接共混体系中有了较大程度的提高。 相似文献
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以黑液-蒙脱土(BL-MMT)为填充补强剂,制备了丁基橡胶(IIR)和三元乙丙橡胶(EPDM)的复合材料,考察了IIR与EPDM的比例、硫化体系和BL-MMT的量对BL-MMT/IIR/EPDM复合材料性能的影响。研究结果表明,IIR与EPDM比例减小可以改善BL-MMT/IIR/EPDM的加工性能,提高其耐热氧老化性能,IIR与EPDM比例为80/20时BL-MMT/IIR/EPDM复合材料的综合性能较好;普通(CV)硫化体系、半有效(SEV)硫化体系和有效(EV)硫化体系均可以使BL-MMT/IIR/EPDM复合材料共硫化,CV硫化体系得到的硫化胶综合物理性能最好,EV硫化体系得到的硫化胶耐热氧老化性能最好;综合BL-MMT/IIR/EPDM复合材料的力学性能及耐热氧老化性能,BL-MMT的填充量30份为宜。 相似文献
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Sarawut Prasertsri Kanokwan Kurakanok Nattapon Sukkapan 《Journal of Polymer Research》2016,23(11):228
This research aimed to investigate the effect of blend ratios on cure characteristics, mechanical and dynamic properties, morphology and automotive fuel resistance of ethylene-propylene diene rubber (EPDM) and epoxidized natural rubber (ENR) blends containing carbon black and calcium carbonate hybrid filler. The composition of EPDM/ENR blends varied were 100/0, 70/30, 50/50, 30/70 and 0/100 %wt/wt. All ingredients used for preparing each blended compound, except for the curatives, were mixed in a kneader. Thereafter, the compound was further mixed with curatives on a two-roll mill and then were vulcanized together with shaped by compression molding before determining cure characteristics, mechanical properties, morphology and weight swelling ratio in three automotive fuels; gasohol-91, diesel and engine oils. The results indicated that Mooney viscosity and cure time of EPDM/ENR blends tended to decrease with increasing ENR content, while cure rate index and crosslink density increased. Tensile strength of all EPDM/ENR blends is lower than that of the individual EPDM and ENR. This is attributed to the incompatibility between nonpolar and polar nature of EPDM and ENR, respectively, supporting by the glass transition temperature form dynamic mechanical thermal analysis (DMTA) and scanning electron micrographs (SEM). Owing to the differences in polarity of automotive fuels and rubbers, weight swelling of EPDM/ENR vulcanizates decreased in diesel and engine oils, but increased in gasohol-91 with increasing in ENR content. 相似文献
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NBR/EPDM的增容共混研究 总被引:4,自引:1,他引:4
本文采用第三组份增容途径,改善了NBR/EPDM并用胶的相容性、加工性和力学性能。通过对不同增容体系的研究对比,发现不同增容剂的增容效果差异很大,其巾以EVA-14增容效果最为显著,加入该增容剂的并用胶,在适当的工艺条件及硫化体系下,可获得最佳力学性能。本文还研究了不同增容剂对并用炭黑胶各种性能的影响,可以做到在不降低并用胶的力学性能的同时,提高并用胶的耐热空气老化、耐大气老化和耐臭氧老化性能.透射电镜实验和动态力学谱图证明了加与未加增容剂时,NBR/EPDM并用胶均为两相结构,增容剂起表面活性剂的作用,加强了两相界面间的相互作用,使分散相EPDM细微化和均匀化。 相似文献
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Thermoplastic natural rubber based on polyamide‐12 (PA‐12) blend was prepared by melt blending technique. Influence of blending techniques (i.e., simple blend and dynamic vulcanization) and types of natural rubber (i.e., unmodified natural rubber (NR) and epoxidized natural rubber (ENR)) on properties of the blends were investigated. It was found that the simple blends with the proportion of rubber ~ 60 wt % exhibited cocontinuous phase structure while the dynamically cured blends showed dispersed morphology. Furthermore, the blend of ENR exhibited superior mechanical properties, stress relaxation behavior, and fine grain morphology than those of the blend of the unmodified NR. This is attributed to chemical interaction between oxirane groups in ENR molecules and polar functional groups in PA‐12 molecules which caused higher interfacial adhesion. It was also found that the dynamic vulcanization caused enhancement of strength and hardness properties. Temperature scanning stress relaxation measurement revealed improvement of stress relaxation properties and thermal resistance of the dynamically cured ENR/PA‐12 blend. This is attributed to synergistic effects of dynamic vulcanization of ENR and chemical reaction of the ENR and PA‐12 molecules. Furthermore, the dynamically cured ENR/PA‐12 blend exhibited smaller rubber particles dispersed in the PA‐12 matrix. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011 相似文献
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Virgin ethylene propylene diene monomer (EPDM) rubber in a thermoplastic elastomeric blend of polypropylene (PP) and EPDM rubber was substituted by ground EPDM vulcanizate of known composition, after which the mechanical properties of the raw EPDM/waste EPDM/PP blends were determined. The ratio of the rubber content in the waste EPDM (r‐W‐EPDM) to the raw EPDM (R‐EPDM) in the blends was varied from 0 : 100 to 45 : 55. Attempts to replace higher amounts (>45%) of R‐EPDM by W‐EPDM failed because of processing difficulty. Although a drop in mechanical properties of the blends was observed at lower loadings of W‐EPDM, the properties showed improvement at intermediate W‐EPDM loadings. The R‐EPDM/W–EPDM/PP blends were found to be reprocessable. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 82: 3304–3312, 2001 相似文献