Hydrogeological and isotopic survey of geothermal fields in the Buyuk Menderes graben, Turkey

The main high and low enthalpy geothermal fields in the Buyuk Menderes graben (Western Anatolia) and their reservoir temperatures are as follows: Kizildere (242 °C), Germencik (232 °C), Aydin-Ilicabasi (101 °C), Yılmazkoy (142 °C), Salavatli (171 °C), Soke (26 °C), Denizli -Pamukkale (36 °C), Karahayit (59 °C), Golemezli (101 °C) and Yenice (70 °C). The geothermal systems are controlled by active graben faults. The reservoir rocks in the geothermal fields are the limestone and conglomerate units within Neogene sediments and the marble-quartzite units within Paleozoic metamorphic formations. There are clear δ¹⁸O shifts from the Mediterranean Meteoric Water Line (MMWL) in the Kizildere, Germencik and Aydin fields, where a good relation between high temperatures and δ¹⁸O shift has also been observed, indicating deep circulation and water rock interactions. In the Pamukkale, Karahayit, Golemezli and Yenice fields and in Soke region, low temperatures, small isotope shifts, shallow circulations and mixing with shallow cold water have been noted.     

First solar radiation atlas for the Arab world

In the year 1998, the Arab League Educational, Cultural and Scientific Organization (ALESCO), Directorate of Science and Scientific Research, Tunis, had launched the “Solar Radiation Atlas for the Arab World”. This atlas contains three sets of maps (using Mercator projection) for monthly means, where each stands for one month. These are sunshine duration, global solar radiation and diffuse solar radiation. The atlas contains data for nearly 280 stations from 19 Arab states which cover latitudes from 0° (tropic) to 37°N and longitudes 19°E to nearly 60°E with different elevations from the sea level. It also contains useful tables of the monthly recorded means of the direct, diffuse and global solar radiation as well as the sunshine duration for 16 Arab states including 207 cities.The maximum recorded annual mean (10 years) of the global solar radiation in the Arab world was 6.7 kW h/m²/day in Nouakchott (latitude 20°56′N, longitude 17°02′E), Mauritania, and 6.6 kW h/m²/day in Tamenraset (latitude 36°11′N and longitude 5°31′E), Algeria, while the lowest recorded annual mean global solar radiation was 4.1 kW h/m²/day in Mosul (latitude 43°N and longitude 36°E), Iraq. Furthermore, the maximum recorded annual mean sunshine duration in the Arab world was 10.7 h in Aswan (latitude 23°58′N, longitude 32°47′E), Egypt, and the lowest was 7.5 h in Tunis (latitude 36°50′N, longitude 10°14′E), Tunisia.     

Spectral reflectance properties of black chrome for use as a solar selective coating

The NASA-Lewis Research Center has determined that a widely available, commercially electroplated decorative finish known as black chrome has desirable solar selective properties. Black chrome electroplated coating has high absorbence in the solar spectrum and low emissivity in the 250°F blackbody thermal spectrum.The discovery of the solar selective properties of black chrome adds another high-efficiency coating to the older, previously known coatings. Additionally, the black chrome is significant as a solar selective coating because the current extensive use of black chrome in the electroplating industry as a durable, decorative finish makes black chrome widely available and potentially lower cost as a solar selective coating.The spectral reflectance properties of a commercially prepared black chrome on steel have been measured. Values are presented for reflectance of the black chrome. These are compared with the reflectance of black paint (Nextel) and with two available samples of black nickel which had been prepared for solar selective properties.The reflectance of black chrome, the two black nickels, and black paint integrated over the solar spectrum for air mass 2 were 0·132, 0·123, 0·133 and 0·033, respectively.The reflectance of the black chrome, two black nickels, and black paint integrated over the blackbody spectrum for 250°F from 3 to 15 μm are 0·912, 0·934, 0·891 and 0·033, respectively. These reflectance measurements indicate absorptivity-to-emissivity ( ) values of 9·8, 13·8, 8·0 and 1·00, respectively.     

Compressors driven by thermal solar energy: entropy generated, exergy destroyed and exergetic efficiency

This work is devoted to the study of the entropy generated, the exergy destroyed and the exergetic efficiency of lithium-bromide absorption thermal compressors of single and double effect, driven by the heat supplied by a field of solar thermal collectors. Two different applications have been considered and compared: air-cooled and water-cooled units. Water-cooled compressors work with temperatures and pressures lower than air-cooled compressors considering, in both cases, the same suction temperature, equal to 5°C. While the absorption temperature in water-cooled compressors can reach 40°C, in air-cooled systems it can vary between 30°C and more than 50°C. Under these conditions, the discharge temperature (boiling temperature within the desorber) of a single effect air-cooled unit lies between 65 and 110°C, the maximum discharge pressure being around 0.12 bar. The discharge temperatures (boiling temperature within the high pressure desorber) of the double effect air-cooled thermal compressor lies between 110°C for a final absorption temperature of 30°C, and 180°C for a final absorption temperature of 50°C. Discharge pressures can reach values of 0.3 and 1.5 bar, respectively. The lithium-bromide air-cooled thermal compressors of double-effect can be viable with absorption temperatures around 50°C, when the temperature difference between the lithium-bromide solution and the outside air is about 8°C. The double effect thermal compressor generates less entropy and destroys less exergy than the single effect unit, leading to a higher exergetic efficiency. In both cases, the compression process of the cooling fluid occurs with entropy reduction.     

Comparison of electrochromic amorphous and crystalline tungsten oxide films

A detailed systematic study of the tungsten oxide thin films has been carried out using WO₃ films after they were annealed at progressively increasing temperatures ranging from 350°C to 450°C in oxygen environments. The structural properties of the films were characterized using X-ray diffraction and Raman spectroscopy. The amorphous WO₃ films remain as an amorphous phase up to 385°C and begin to crystallize at 390°C and then are completely crystallized at 450°C. Absorption peaks of the films are found to shift to a higher energy side with increasing annealing temperature up to 385°C and then shift abruptly to a lower energy as the films begin to crystallize at 390°C. Deconvolution of the absorption spectra shows that there are two different polaron transitions in the amorphous WO₃ films.     

A SOLAR EJECTOR COOLING SYSTEM USING REFRIGERANT R141b

A high-performance solar ejector cooling system using R141b as the working fluid was developed. We obtain experimentally a COP of 0.5 for a single-stage ejector cooling system at a generating temperature of 90°C, condensing temperature of 28°C, and an evaporating temperature 8°C. For solar cooling application, an optimum overall COP can be obtained around 0.22 at a generating temperature of 95°C, evaporating temperature of 8°C and solar radiation at 700 W m⁻².     

Reflection at transparent V-grooved surface

Reflection at transparent V-grooved surface was studied on the basis of geometrical analysis and ray tracing using Fresnel's formulas. For normally incident light, the reflectivity at the V-grooved surface of tilt angles between 0° and 30° and between 45° and 54° are approximated by the reflectivities and the squared reflectivities, respectively, at a smooth surface. For obliquely incident light, the V-grooved surface is effective to reduce the reflectivity at large angle of incidence by reducing the actual angle of striking the surface. In addition, the V-grooved surface of large tilt angle reduces the reflectivity at a small angle of incidence due to multiple reflections between adjacent opposite surfaces of the groove. The daily average reflectivity monotonically decreases with increasing tilt angle from 30° to its upper limit (59.1° for n=1.5) in the analysis. When normally incident light enters the layer and a part of it reflects at the rear surface, the escape from the upper surface can be prevented by serial total internal reflections at the upper surface of medium tilt angle (30.9°–41.0° for n=1.5).     

Influence of injection timing on the exhaust emissions of a dual-fuel CI engine

Environmental concerns and limited amount of petroleum fuels have caused interests in the development of alternative fuels for internal combustion (IC) engines. As an alternative, biodegradable, and renewable fuel, ethanol is receiving increasing attention. Therefore, in this study, influence of injection timing on the exhaust emission of a single cylinder, four stroke, direct injection, naturally aspirated diesel engine has been experimentally investigated using ethanol blended diesel fuel from 0% to 15% with an increment of 5%. The engine has an original injection timing 27° CA BTDC. The tests were performed at five different injection timings (21°, 24°, 27°, 30°, and 33° CA BTDC) by changing the thickness of advance shim. The experimental test results showed that NO_x and CO₂ emissions increased as CO and HC emissions decreased with increasing amount of ethanol in the fuel mixture. When compared to the results of original injection timing, at the retarded injection timings (21° and 24° CA BTDC), NO_x and CO₂ emissions increased, and unburned HC and CO emissions decreased for all test conditions. On the other hand, with the advanced injection timings (30° and 33° CA BTDC), HC and CO emissions diminished, and NO_x and CO₂ emissions boosted for all test conditions.     

Evaluation of temperature characteristics of high-efficiency InGaP/InGaAs/Ge triple-junction solar cells under concentration

Temperature characteristics of the open-circuit voltage (V_oc) were investigated in the temperature range from 30°C to 240°C for the InGaP/InGaAs/Ge triple-junction cells. Also, single-junction cells that had the similar structure to the subcells in the triple-junction cells were studied. In the high-temperature range (from 170°C to 240°C), the temperature coefficients of V_oc of the InGaP/InGaAs/Ge triple-junction solar cell (dV_oc/dT) were different from those in the low-temperature range (from 30°C to 100°C). This is because photo-voltage from the Ge subcell becomes almost 0 V in the high-temperature range. It was found that the open-circuit voltage of a Ge single-junction cell reduced to almost 0 V temperatures over 120°C under 1 sun condition.     

High-temperature measurements in well WD-1A and the thermal structure of the kakkonda geothermal system, Japan

The New Energy and Industrial Technology Development Organization (NEDO) drilled well WD-1a between 1994 and 1995 in the Kakkonda geothermal field as part of their Deep Seated Geothermal Resources Survey project. High-temperature measurements were carried out in WD-1a. Logging temperatures above 414°C were confirmed at 3600 m and 3690 m depth after 82 h standing time. Simple Horner extrapolations based on observed temperatures up to 82 h after shut-in suggested a temperature of about 500°C at 3500 m depth. Temperatures between 500°C and 510°C were also confirmed at 3720 m depth after 129–159 h standing time, using calibrated melting .tablets. These are the highest temperatures measured in a geothermal well. These results suggest a thermal structure consisting of three layers. Layer one is a shallow permeable zone of the reservoir, at less than 1500 m depth, at 230°C to 260°C. The second layer is a deep zone of the reservoir, which is less permeable and has a temperature of 350°C to 360°C from 1500 m to about 3100 m depth. The third layer is a zone of heat conduction. The transition between the hydrothermal-convection zone and the deeper heat-conduction zone is at 3100 m depth in well WD-1a.     

An organic PCM storage system with adjustable melting temperature

A proper storage temperature is an important criterion for selecting a phase change material (PCM) for a passive solar heating application. Here we describe a novel procedure to produce a mixture of carboxylic acids with a melting temperature adjustable to the climate specific requirements. The approach is based on the ideal solution model and differential scanning calorimetry (DSC). The applicability of the method is demonstrated and it is also applied to a PCM wall design. The accuracy of the theoretical model is ±2°C in the temperature range of 20°–30°C and even a ±0.5°C accuracy can be obtained by the experimental procedure.     

The use of moderate vacuum environments as a means of increasing the collection efficiencies and operating temperatures of flat-plate solar collectors

It is shown that evacuating a flat-plate solar collector to a pressure 1–25 torr results in elimination of the natural convection heat loss from the absorber for absorber-to-cover spacings up to 15 cm. This mode of heat transfer then reduces to pure conduction through the air space between the absorber and the cover. The effect of this reduction on the total upward heat loss from the collector is considered for a variety of collector operating conditions and is shown to be especially pronounced for collectors employing wavelength-selective surfaces (high absorptance for solar radiation, but low emittance for the energy re-radiated by the absorber). Computer simulations of collector performance for the Dallas, Texas area indicate that the combination of a moderate vacuum and a selective surface (α = 0·90, = 0·15) can increase daily energy collection as much as 278 per cent over that obtained with a non-vacuum collector using a flat-black (α = = 0·95) surface and can make it possible to operate at a temperature of 150°C with a daily energy collection efficiency of more than 40 per cent. The theoretical predictions are supported by the results of twelve experiments with a no-load solar tester. At an absorber-to-cover spacing of 7·5 cm, the steady-state temperature of a moderately selective absorber (α = 0·75, = 0·3) was increased from 115°C at atmospheric pressure to 179°C at a pressure of 25 torr.     

Accelerated aging tests of chromium containing amorphous hydrogenated carbon coatings for solar collectors

Chromium containing amorphous hydrogenated carbon films (a-C : H/Cr) have been prepared by simultaneous rf plasma activated chemical vapour deposition of methane and magnetron sputtering of a chromium target. During deposition the substrates were heated (up to 300°C) and DC biased (−200 and −600 V) in order to obtain films with high chemical stability. Constant temperature tests were performed at 250°C in air with coatings deposited on silicon substrates. The degradation of the coatings was monitored by Raman spectroscopy and reflectance and transmission measurements. The main degradation mechanisms are discussed and the relevant parameters which improve the durability of the coatings are presented. Furthermore, the durability of solar selective, multilayered coatings which were deposited on copper sheets was investigated. Based on accelerated aging tests at different temperature loads in air (at 220°C, 250°C and 300°C) and in a humid environment (80°C sample temperature in humid air with 85°C and 95% relative humidity) the service lifetime in a flat plate collector is predicted to amount to more than 25 years.     

Crystallization as a limit to develop solar air-cooled LiBr–H2O absorption systems using low-grade heat

In the present work the use of low-temperature solar heat is studied to produce cooling at 5°C, using a double-stage LiBr–H₂O air-cooled absorption cycle. A solar plant, consisting of flat plate collectors feeding the generators of the absorption machine, has been modeled. Operating conditions of the double-stage absorption machine, integrated in the solar plant without crystallization problems for condensation temperatures up to 53°C, are obtained. Results show that about 80°C of generation temperature are required in the absorption machine when condensation temperature reach 50°C, obtaining a COP equal to 0.38 in the theoretical cycle.A comparative study respect to single-stage absorption cycles is performed. Efficiency gain of the double-stage solar absorption system, over the single-stage one, will increase with higher condensation temperatures and lower solar radiation values. Single-stage cycles cannot operate for condensation temperatures higher than 40°C using heat from flat plate collectors. For higher condensation temperatures (45°C) the generation temperatures required (105°C) are very high and crystallization occurs. Condensation temperatures able to use in double-stage cycles may be increased until 53°C using heat from flat plate collectors without reaching crystallization.     

Effect of heat treatment on carbon in multicrystalline silicon

Effect of heat treatment on carbon in cast multicrystalline silicon (mc-Si) has been studied by means of Fourier Transmission Infrared Spectroscopy. Carbon is found to be involved in the formation of as-grown precipitates in mc-Si with higher oxygen content. The experimental results reveal that carbon is difficult to precipitate in mc-Si with lower oxygen or higher nitrogen concentration during annealing in the temperature range from 450°C to 1150°C. Carbon can enhance the nucleation of oxygen precipitates at lower temperature (<850°C). Although carbon does not affect the amount of oxygen precipitates at higher temperature (>950°C), it is suggested that carbon diffuses into oxygen precipitates by the enhancement of silicon self-interstitials. The experiments point out that preannealing at 750°C enhances the decrease of substitute carbon concentration during subsequent annealing at 1050°C. Dislocations and grain boundaries in mc-Si do not affect carbon thermal treatment properties.     

Thermal imaging of solid oxide fuel cell anode processes

A Si-charge-coupled device (CCD), camera-based, near-infrared imaging system is demonstrated on Ni/yttria-stabilized zirconia (YSZ) fragments and the anodes of working solid oxide fuel cells (SOFCs). NiO reduction to Ni by H₂ and carbon deposition lead to the fragment cooling by 5 ± 2 °C and 16 ± 1 °C, respectively. When air is flowed over the fragments, the temperature rises 24 ± 1 °C as carbon and Ni are oxidized. In an operational SOFC, the decrease in temperature with carbon deposition is only 4.0 ± 0.1 °C as the process is moderated by the presence of oxides and water. Electrochemical oxidation of carbon deposits results in a ΔT of +2.2 ± 0.2 °C, demonstrating that electrochemical oxidation is less vigorous than atmospheric oxidation. While the high temperatures of SOFCs are challenging in many respects, they facilitate thermal imaging because their emission overlaps the spectral response of inexpensive Si-CCD cameras. Using Si-CCD cameras has advantages in terms of cost, resolution, and convenience compared to mid-infrared thermal cameras. High spatial (0.1 mm) and temperature (0.1 °C) resolutions are achieved in this system. This approach provides a convenient and effective analytical technique for investigating the effects of anode chemistry in operating SOFCs.     

Torque and power characteristics of a helium charged Stirling engine with a lever controlled displacer driving mechanism

This study presents test results of a Stirling engine with a lever controlled displacer driving mechanism. Tests were conducted with helium and the working fluid was charged into the engine block. The engine was loaded by means of a prony type micro dynamometer. The heat was supplied by a liquefied petroleum gas (LPG) burner. The engine started to run at 118 °C hot end temperature and the systematic tests of the engine were conducted at 180 °C, 220 °C and 260 °C hot end external surface temperatures. During the test, cold end temperature was kept at 27 °C by means of water circulation. Variation of the shaft torque and power with respect to the charge pressure and hot end temperature were examined. The maximum torque and power were measured as 3.99 Nm and 183 W at 4 bars charge pressure and 260 °C hot end temperature. Maximum power corresponded to 600 rpm speed.     

Production of biohydrogen from hydrolyzed bagasse with thermally preheated sludge

Production of biohydrogen from dark fermentation is an interesting alternative to producing renewable fuels because of its low cost and various usable substrates. Cellulosic content in plentiful bagasse residue is an economically feasible feedstock for biohydrogen production. A statistical experimental design was applied to identify the optimal condition for biohydrogen production from enzymatically hydrolyzed bagasse with 60-min preheated seed sludge. The bagasse substrate was first heated at 100 °C for 2 h and was then hydrolyzed with cellulase. Culture of the pretreated bagasse at 55 °C provided a higher H₂ production performance than that obtained from cultures at 45 °C, 65 °C, 35 °C and 25 °C. On the other hand, the culture at pH 5 resulted in higher H₂ production than the cultures at pH 6, pH 4 and pH 7. The optimal culture condition for the hydrogen production rate was around 56.5 °C and pH 5.2, which was identified using response surface methodology. Moreover, the pretreatment of bagasse under alkaline conditions gave a thirteen-fold increase in H₂ production yield when compared with that from preheatment under neutral condition.     

Evolution du coefficient d'échange et des pertes de charge dans un faisceau de tubes, en fonction de l'angle d'attaque

This experimental study concerns local and overall measurements of mass transfer coefficients by an electrochemical method, on a cylinder placed inside a bundle. The yaw angle is variable: 0°, 22.5°, 45°, 60°, 90°; the Reynolds number lies between 10⁴ and 10⁵. From the Chilton-Colburn analogy, a heat transfer law is deduced: Nu = f (Pr, Re, A). A correlation is also proposed for friction factors, as a function of α. Finally, the effect of bundle supports over transfer coefficients is characterized.