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超声电镀锡铋合金研究 总被引:5,自引:0,他引:5
研究了超声波对锡铋合金电镀的影响.通过赫尔槽试验优选出最佳镀液配方和工艺条件,用SEM法观测了镀层形貌,并测试了镀层和镀液性能.结果表明:超声波的作用扩大了电流密度范围和温度范围;所得镀层表面光亮、结晶更细致、均匀,镀层结合力、抗氧化性和可焊性改善明显,耐蚀性增强;镀液性能稳定,阴极电流效率和沉积速度得到提高.因此,超声波对电镀工艺条件、镀层质量和镀液性能都有明显的改善作用. 相似文献
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研究了Ni-B合金电沉积的镀液、镀层性能.阴极极化曲线实验结果表明Ni-B合金电沉积是典型的诱导共沉积类型.镀液稳定性高,镀层硬度高,镀态硬度值可达700~800HV,耐磨性好.镀层具有一定的耐酸能力和很强的耐碱液腐蚀能力. 相似文献
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采用霍尔槽法及电化学法研究了添加剂对镀层质量、镀液分散能力的影响.结果表明随着添加剂BSP,H1,PN,PEG加入量增大,镀层光亮区和镀液分散能力均先增大后减小.X型光亮剂酸性镀铜新工艺适宜条件下可在20~40℃下得到光亮平整的镀层,对应电流密度0.5~14.3 A/dm2.施镀15 min,镀液分散能力可达32.8%... 相似文献
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稀土对电沉积Zn-Fe-La三元合金性能影响的研究 总被引:1,自引:0,他引:1
为了获得更加光亮、致密的Zn-Fe-La三元合金镀层,针对电沉积Zn-Fe-La三元合金镀液组成及工艺条件,系统地研究了稀土对镀层成分含量、镀液稳定性、镀液分散能力以及pH值的影响,测定了镀层的极化曲线、稳定电位和极化电阻,比较了不同稀土含量对镀层耐蚀性的影响.结果表明:稀土的加入可提高镀液稳定性、分散能力,增加电沉积过程阴极极化,使阳极钝化前的活性区腐蚀电位正移,自溶解速度下降,有利于提高镀层耐蚀性,其耐蚀性比Zn-Fe合金镀层及纯Zn镀层有很大提高. 相似文献
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1氯化镍的作用 镀镍溶液中的氯化镍作为阳极活化剂,能提高镀液的导电性能.其含量过低时镍阳极容易钝化,镀液中硫酸镍的含量降低,影响溶液的稳定;含量较高虽然可以提高溶液的导电性能和分散能力,但阳极溶解异常快,泥渣增多,进而使镍镀层产生毛刺、粗糙,镀层内应力增加,也是镀层产生脆裂的潜在因素;对于镀珍珠镍而言,镀液的分散能力不能太高,要求氯化镍含量低一些;对于深孔镀镍和滚镀镍而言,氯化镍含量应高一些,以提高镀液的深镀能力和分散能力. 相似文献
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Zhihong Zhong Hun-chea Jung Tatsuya Hinoki Akira Kohyama 《Journal of Materials Processing Technology》2010,210(13):1805-1810
A diffusion bonding process, for joining of tungsten to ferritic steel using nickel as an interlayer, was developed for nuclear component application. The effect of joining temperature on the microstructure and tensile strength of the joint was investigated in this work. Metallographic analysis revealed that a good bonding was obtained at both the tungsten/nickel and nickel/steel interfaces, and the diffusion products were identified in the diffusion zone. Nano-indentation test across the joining interfaces demonstrated the effect of solid solution hardening in the diffusion zone. Tensile test showed that the maximum average tensile strength of ∼200 MPa was obtained for the joint diffusion bonded at 900 °C. The results were discussed in terms of the joining temperature and of the residual stress generated during joining process. 相似文献
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Yongli Wang Liangyin Xiong Shi Liu 《金属学报(英文版)》2014,27(4):615-620
The permeability and diffusivity of hydrogen in directionally solidified polycrystalline and single crystal nickel foils were measured by gas permeation method.The results showed that both hydrogen diffusivity and permeability were higher in directionally solidified nickel specimen than those in single crystal one at the temperature ranging from 300 to480 °C,and confirmed the existence of short-circuit diffusion along the grain boundaries(GBs) in the directionally solidified nickel.The results suggested that the rapid diffusion along GBs was more obviously characterized in terms of higher permeability rather than higher diffusivity.The contribution of grain boundary to hydrogen transportation was represented by the differences of diffusivity(and permeability) in single crystal nickel and directionally solidified nickel.By modifying the Fick's first diffusion law and counting the grain boundary density,the hydrogen diffusivity and permeability of rapid diffusion along GBs were calculated.The results suggested both the diffusivity and permeability fit the Arrhenius relationship well at different temperature. 相似文献
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This study deals with the influence of various mechanical loadings (fatigue, creep, creep-fatigue) on oxygen diffusion in a particular system, oxidizing nickel. A distinction between the behavior of the oxide layer and underlying nickel was noted during the first step of oxidation at 550°C, in PO
2=1 atm. Mechanical loading causes a decrease of the oxygen mobility through the oxide scale (factor of 103). The oxide thicknesses on nickel undergoing mechanical loadings are different than for an unloaded sample, due to distinct contributions of the oxygen and nickel fluxes in the growing oxide. In the substrate, the ingress of oxygen becomes easier with a constant tensile load (creep). The intergranular-oxygen diffusion coefficient, Di, is increased by a factor of 102 with respect to other samples. In creep, oxygen diffusion takes place along grain boundaries of a structure with smaller grains than in unstrained Ni. A short fatigue period during creep-fatigue decreases the sensitivity of nickel to intergranular-oxygen diffusion. 相似文献
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A study has been made of the growth of nickel oxide layers on the (100), (110), and (111) crystal faces of nickel exposed to oxygen for periods up to 100 hr at temperatures in the range 500–800°C, These layers grow at a rate dependent upon the crystallographic orientation of the nickel face even at thicknesses within the scaling range. The (100) face oxidized more rapidly than the (110) and (111) nickel faces while the latter faces oxidized at different relative rates dependent upon temperature. A diffusional model is employed to interpret the oxidation kinetics wherein nickel transport proceeds in nickel oxide both by short-circuit diffusion at grain boundaries and by lattice diffusion.This work forms part of a research program sponsored by the National Research Council of Canada. 相似文献
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N. V. Abraimov 《Protection of Metals and Physical Chemistry of Surfaces》2017,53(7):1222-1226
A method for the preparation of a complex diffusion coating by preliminary saturation of the surface layer of heat-resistant nickel alloys with nickel and by subsequent chrome aluminizing in vacuum using powder mixtures at processing temperatures of 1000 and 1200°C is analyzed. The characteristics of the chemical composition and structure of coatings and comparative data on the heat resistance at temperatures of 1000, 1050, and 1100°C under the conditions of isothermal oxidation are given. It is shown that the complex coating exhibits increased heat resistance owing to an increase in the uniformity of the surface alloy layers obtained by the diffusion nickel plating. 相似文献
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The behaviour of the tin/tin interface for electrical contact application is addressed in this paper. Two coating systems were studied: a bronze-tin coating system and a bronze-nickel-tin coating system. The transition amplitude δt from partial slip (P.S) to gross slip (G.S), defining the domains of infinite and finite lifetime of the contact, was found using the variable-displacement-amplitude methodology (VDA). Constant-displacement-amplitude (CDA) tests were performed in order to determine the influence of the nickel interlayer on the performance of the electrical contact. The conducted analysis concluded that there is no influence of the nickel interlayer on the electrical endurance during G.S. However, the nickel interlayer, which serves as a diffusion barrier, eliminates the diffusion of copper through the tin coating; thus preventing the formation of copper oxides on the top surface. It concludes that the application of the nickel underlayer by maintaining high tin-tin friction coefficient extends the P.S domain and therefore increases the reliability of the electrical contact. 相似文献
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Stacked single layers of tin and nickel usually made by electrodeposition were prepared by a sputtering process in this study and the alloying behaviour through heating in an electric furnace was investigated by SEM-EDX and X-ray analysis. No remarkable chemical compounds between tin and nickel were produced. The substrate atoms diffused into both surface layers, and a compound or a solid solution was formed. The iron diffusion was driven by the strong affinity between tin and iron. The results suggest the following two basic rules: I. When tin is the underlayer in direct contact with the iron substrate, the alloying of stacked tin and nickel layers hardly occurs. 2. When the nickel underlayer was very thin (e g submicron thickness), the substrate iron atoms can penetrate into the top tin layer through the intermediate one, but there is little evidence for the alloying of tin and nickel. 相似文献
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<正> 前言 研究氢在金属中的扩散与渗透,定量的方法主要有阴极过程量气法、电化学测量法、高真空测量法和核物理法。电化学测量法的设备简单,灵敏度高,测量方便、快速、准确,因而被广泛用于氢渗透研究,但到目前为止,一般都只用于温度低于100℃的测量;高真空测量法只适用于氢渗透速率大的体系,不宜用于温度低于200℃的测量。因此,对于100~200℃下氢在金属中扩散行为,目前还缺少合适的测定方法。本工作应用电化学测量法的原理,建立了一套测试装置,研究了100~200℃下氢在碳钢中的扩散行为。 相似文献