The scaled performance of Si/Si1-xGexresonant tunneling diodes

Small area resonant tunneling diodes (RTDs) with strained Si_0.4Ge_0.6 potential barriers and a strained Si quantum well grown on a relaxed Si_0.8Ge_0.2 virtual substrate were fabricated and characterized. A room temperature peak current density (J_P) of 282 kA/cm² with a peak to valley current ratio (PVCR) of 2.43 were recorded for a 5×5 μm ² sample, the highest values reported to date for Si/Si_1-xGe_x RTDs. Scaling of the device size demonstrated a decrease in J_P proportional to an increase in the lateral area of the tunnel junctions, whereas the PVCR remained approximately constant. This observation suggests that the dc behavior of such Si/Si_1-xGe_x RTD design is presently limited by thermal effects     

Formation of 0.05-μm p+-n and n+-pjunctions by very low (<500 eV) ion implantation

The current-voltage (I-V) characteristics of ultrashallow p⁺ -n and n⁺-p diodes, obtained using very-low-energy (<500-eV) implantation of B and As, are presented. the p⁺-n junctions were formed by implanting B⁺ ions into n-type Si (100) at 200 eV and at a dose of 6×10¹⁴ cm^-2, and n⁺-p junctions were obtained by implanting As⁺ ions into p-type (100) Si at 500 eV and at a dose 4×10¹² cm^-2. A rapid thermal annealing (RTA) of 800°C/10 s was performed before I-V measurements. Using secondary ion mass spectrometry (SIMS) on samples in-situ capped with a 20-nm ²⁸Si isotopic layer grown by a low-energy (40 eV) ion-beam deposition (IBD) technique, the depth profiles of these junctions were estimated to be 40 and 20 nm for p⁺-n and n⁺-p junctions, respectively. These are the shallowest junctions reported in the literature. The results show that these diodes exhibit excellent I-V characteristics, with ideality factor of 1.1 and a reverse bias leakage current at -6 V of 8×10^-12 and 2×10^-11 A for p⁺-n and n⁺-p diodes, respectively, using a junction area of 1.96×10^-3 cm²     

Electrical characterization of ultra-shallow junctions formed bydiffusion from a CoSi2 layer

Ultra-shallow p⁺/n and n⁺/p junctions were fabricated using a Silicide-As-Diffusion-Source (SADS) process and a low thermal budget (800-900°C). A thin layer (50 nm) of CoSi₂ was implanted with As or with BF₂ and subsequently annealed at different temperatures and times to form two ultra-shallow junctions with a distance between the silicide/silicon interface and the junction of 14 and 20 nm, respectively. These diodes were investigated by I-V and C-V measurements in the range of temperature between 80 and 500 K. The reverse leakage currents for the SADS diodes were as low as 9×10 ^-10 A/cm² for p⁺/n and 2.7×10^-9 A/cm² for n⁺/p, respectively. The temperature dependence of the reverse current in the p ⁺/n diode is characterized by a unique activation energy (1.1 eV) over all the investigated range, while in the n⁺/p diode an activation energy of about 0.42 eV is obtained at 330 K. The analysis of the forward characteristic of the diodes indicate that the p⁺ /n junctions have an ideal behavior, while the n⁺/p junctions have an ideality factor greater than one for all the temperature range of the measurements. TEM delineation results confirm that, in the case of As diffusion from CoSi₂, the junction depth is not uniform and in some regions a Schottky diode is observed in parallel to the n⁺/p junction. Finally, from the C-V measurements, an increase of the diodes area of about a factor two is measured, and it is associated with the silicide/silicon interface roughness     

Si/Si1-xGex heterojunction bipolartransistors produced by limited reaction processing

Si/Si_1-xGe_x heterojunction transistors (HBTs) fabricated by a chemical vapor deposition (CVD) technique are reported. A rapid thermal CVD limited-reaction processing (LRP) technique was used for the in situ growth of all three device layers, including a 20-mm Si_1-xGe_x layer in the base. The highest current gains observed (β=400) were for a Si/Si_1-x Ge_x HBT with a base doping of 7×10¹⁸ cm^-3 near the junction and a shallow arsenic implant to form ohmic contacts and increase current gain. Ideal base currents were observed for over six decades of current and the collector current remained ideal for nearly nine current decades starting at 1 pA. The bandgap difference between a p-type Si layer doped to 5×10¹⁷ cm^-3 and the Si_1-xGe_x(x=0.31) base measured 0.27 eV. This value was deduced from the measurements of the temperature dependence of the base current and is in good agreement with published calculations for strained Si_1-xGe_x layers on Si     

Nickel ohmic contacts to p and n-type 4H-SiC

The first demonstration of Ni ohmic contacts to both p⁺ and n⁺ 4H-SiC formed by ion implantation is reported. Sample preparation conditions are described and experimental results presented. Specific contact resistances in the range of 10^-4 Ω cm ² and 10^-6 Ω cm² for p⁺ and n⁺ 4H-SiC, respectively, have been determined by the transfer length method     

Experimental determination of electron drift velocity in 4H-SiC p+-n-n+ avalanche diodes

4H-SiC p⁺-n-n⁺ diodes of low series resistivity (<1×10^-4 Ω·cm²) were fabricated and packaged. The diodes exhibited homogeneous avalanche breakdown at voltages U_b=250-270 V according to the doping level of the n layer. The temperature coefficient of the breakdown voltage was measured to be 2.6×10^-4 k^-1 in the temperature range 300 to 573 K. These diodes were capable of dissipating a pulsed power density of 3.7 MW/cm² under avalanche current conditions. The transient thermal resistance of the diode was measured to be 0.6 K/W for a 100-ns pulse width, An experimental determination of the electron saturated drift velocity along the c-axis in 4H-SIC was performed for the first time, It was estimated to be 0.8×10⁷ cm/s at room temperature and 0.75×10⁷ cm/s at approximately 360 K     

Si/Si1-x-yGexCy/Si heterojunctionbipolar transistors

We report the first Si/Si_1-x-yGe_xC_y /Si n-p-n heterojunction bipolar transistors and the first electrical bandgap measurements of strained Si_1-x-yGe_x C_y on Si (100) substrates. The carbon compositions were measured by the shift between the Si_1-x-yGe_xC_y and Si_1-xGe_x X-ray diffraction peaks. The temperature dependence of the HBT collector current demonstrates that carbon causes a shift in bandgap of +26 meV/%C for germanium fractions of x=0.2 and x=0.25. These results show that carbon reduces the strain in Si_1-x Ge_x at a faster rate than it increases the bandgap (compared to reducing x in Si_1-xGe_x), so that a Si _1-x-yGe_xC_y film will have less strain than a Si_1-xGe_x film with the same bandgap     

Emission cross sections and spectroscopy of Ho3+ laserchannels in KGd(WO4)2 single crystal

The spectroscopic properties of Ho³⁺ laser channels in KGd(WO₄)₂ crystals have been investigated using optical absorption, photoluminescence, and lifetime measurements. The radiative lifetimes of Ho³⁺ have been calculated through a Judd-Ofelt (JO) formalism using 300-K optical absorption results. The JO parameters obtained were Ω₂=15.35×10^-20 cm², Ω ₄=3.79×10^-20 cm², Ω₆ =1.69×10^-20 cm². The 7-300-K lifetimes obtained in diluted (8·10¹⁸ cm^-3) KGW:0.1% Ho samples are: τ(⁵F₃)≈0.9 μs, τ( ⁵S₂)=19-3.6 μs, and τ(⁵F₅ )≈1.1 μs. For Ho concentrations below 1.5×10²⁰ cm^-3, multiphonon emission is the main source of non radiative losses, and the temperature independent multiphonon probability in KGW is found to follow the energy gap law τ_ph ^-1(0)=βexp(-αΔE), where β=1.4×10^-7 s^-1, and α=1.4×10³ cm. Above this holmium concentration, energy transfer between Ho impurities also contributes to the losses. The spectral distributions of the Ho³⁺ emission cross section σ_EM for several laser channels are calculated in σ- and π-polarized configurations. The peak a σ_EM values achieved for transitions to the ⁵I₈ level are ≈2×10^-20 cm² in the σ-polarized configuration, and three main lasing peaks at 2.02, 2.05, and 2.07 μm are envisaged inside the ⁵I₇→⁵I₈ channel     

Low- and high-field electron-transport parameters for unstrainedand strained Si1-xGex

Ohmic minority and majority drift mobilities as well as saturation velocities are reported for unstrained and strained Si_1-xGe _x alloys up to z=0.31. The electron-transport model is verified by measurements of the in-plane majority drift mobility in strained Si_1-xGe_x samples for various dopant and Ge concentrations. Saturation velocities are determined by full-band Monte Carlo simulations. There is no substantial decrease in the mobility perpendicular to the Si/SiGe interface for doping concentrations above 10¹⁹ cm^-3 and growing x. In contrast, the saturation-drift velocity is strongly reduced with x     

Electrical properties of heavily doped polycrystallinesilicon-germanium films

The electrical properties of polycrystalline silicon-germanium (poly-Si_1-xGe_x) films with germanium mole fractions up to 0.56 doped by high-dose ion implantation are presented. The resistivity of heavily doped p-type (P⁺) poly-Si_1-x Ge_x is much lower than that of comparably doped poly-Si, because higher levels of boron activation and higher hole mobilities are achieved in poly-Si_1-xGe_x. The resistivity of heavily doped n-type (N⁺) poly-S_1-xGe_x is similar to that of comparably doped poly-Si for x<0.45; however, it is considerably higher for larger Ge mole fractions due to significant reductions in phosphorus activation. Lower temperatures (~500°C), as well as lower implant doses, are sufficient to achieve low resistivities in boron-implanted poly-Si_1-xGe_x films, compared to poly-Si films. The work function of P⁺ poly-Si_1-xGe_x decreases significantly (by up to ~0.4 Volts), whereas the work function of N⁺ poly-Si_1-xGe_x decreases only slightly, as Ge content is increased. Estimates of the energy bandgap of poly-Si_1-xGe_x show a reduction (relative to the bandgap of poly-Si) similar to that observed for unstrained single-crystalline Si_1-xGe_x for a 26% Ge film, and a reduction closer to that observed for strained single-crystalline Si _1-xGe_x for a 56% Ge film. The electrical properties of poly-Si_1-xGe_x make it a potentially favorable alternative to poly-Si for P⁺ gate-material applications in metal-oxide-semiconductor technologies and also for p-channel thin-film transistor applications     

DC characteristics of high-breakdown-voltage p-i-n diodes made by20-MeV Si implantation in InP:Fe

A vertical p-i-n diode is made for the first time in InP:Fe using megaelectronvolt energy ion implantation, A 20-MeV Si implantation and kiloelectronvolt energy Be/P coimplantation are used to obtain a buried n⁺ layer and a shallow p⁺ layer, respectively. The junction area of the device is 2.3×10^-5 cm² and the intrinsic region thickness is ≈3 μm. The device has a high breakdown voltage of 110 V, reverse leakage current of 0.1 mA/cm² at -80 V, off-state capacitance of 2.2 nF/cm² at -20 V, and a DC incremental forward resistance of 4 Ω at 40 mA     

Electrical and material quality ofSi1-xGex/Si p-N heterojunctions produced bylimited reaction processing

Si_1-xGe_x/Si p-N heterojunctions prepared by a chemical vapor deposition technique, limited reaction processing (LRP) were characterized using DC electrical measurements, transmission electron microscopy (TEM), and X-ray topography. Heterojunctions with Si _1-xGe_x layer thickness ranging from 52 to 295 nm and a constant Ge fraction of 23% were fabricated to study the effect of increasing the number of misfit dislocations on the device characteristics. Devices with the thinnest layers (⩽120 nm) display forward characteristics with ideality factors of 1.01 and reverse leakage current densities of less than 4 nA/cm for a 5-V reverse bias. These thin-layer devices have dislocation spacings greater than 10 μm. Devices utilizing Si_1-xGe_x layers thicker than 200 nm have forward characteristics which clearly display the presence of recombination currents, and reverse leakage current densities greater than 290 nA/cm² at -5 V. The dislocation spacing in these devices is less than 1 μm. Ideal characteristics were found at room temperature in devices known to contain dislocations     

High-speed performance of Si/Si1-xGexheterojunction bipolar transistors

A theoretical investigation of Si/Si_1-xGe_x heterojunction bipolar transistors (HBTs) undertaken in an attempt to determine their speed potential is discussed. The analysis is based on a compact transistor model, and devices with self-aligned geometry, including both extrinsic and intrinsic parameters, are considered. For an emitter area of 1×5 μm², an f_t of over 75 GHz and f_max of over 35 GHz were computed at a collector current density of 1×10 ⁵ A/cm² and V_CB of 5 V     

High temperature formed SiGe p-MOSFETs with good devicecharacteristics

We have used a simple process to fabricate Si_0.3Ge_0.7/Si p-MOSFETs. The Si_0.3Ge _0.7 is formed using deposited Ge followed by 950°C rapid thermal annealing and solid phase epitaxy that is process compatible with existing VLSI. A hole mobility of 250 cm²/Vs is obtained from the Si_0.3Ge_0.7 p-MOSFET that is ~two times higher than Si control devices and results in a consequent substantially higher current drive. The 228 Å Si_0.3Ge_0.7 thermal oxide grown at 1000°C has a high breakdown field of 15 MV/cm, low interface trap density (D_it) of 1.5×10¹¹ eV^-1 cm^-2, and low oxide charge of 7.2×10¹⁰ cm^-2. The source-drain junction leakage after implantation and 950°C RTA is also comparable with the Si counterpart     

High performance Si/Si1-xGex resonanttunneling diodes

Resonant tunneling diodes (RTDs) with strained i-Si_0.4Ge_0.6 potential barriers and a strained i-Si quantum well, all on a relaxed Si_0.8Ge_0.2 virtual substrate were successfully grown by ultra high vacuum compatible chemical vapor deposition and fabricated using standard Si processing methods. A large peak to valley current ratio of 2.9 and a peak current density of 4.3 kA/cm² at room temperature were recorded from pulsed and continuous dc current-voltage measurements, the highest reported values to date for Si/Si_1-xGe_x RTDs. These dc figures of merit and material system render such structures suitable and highly compatible with present high speed and low power Si/Si_1-xGe_x heterojunction field effect transistor based integrated circuits     

InP/InGaAs HBTs with n+-InP contacting layers grown byMOMBE using SiBr4

InP/InGaAs heterojunction bipolar transistors (HBTs) with low resistance, nonalloyed TiPtAu contacts on n⁺-InP emitter and collector contacting layers have been demonstrated with excellent DC characteristics. A specific contact resistance of 5.42×10^-8 Ω·cm², which, to the best of our knowledge, is the lowest reported for TiPtAu on n-InP, has been measured on InP doped n=6.0×10¹⁹ cm^-3 using SiBr₄. This low contact resistance makes TiPtAu contacts on n-InP viable for InP/InGaAs HBTs     

Optical absorption and stimulated emission of neodymium in yttriumorthosilicate

A spectroscopic investigation of the biaxial crystal yttrium orthosilicate doped with Nd³⁺(Nd³⁺:Y₂SiO₅) has been performed. Spectrally and orientationally resolved emission cross sections necessary for the evaluation of laser performance on the Nd^{3+ 4}F_3/2-⁴I _9/2 and ⁴F_3/2-⁴I_11/2 transitions have been determined. The Judd-Ofelt theory has been applied to measured values of optical absorption line strengths to obtain the orientation averaged intensity parameters: Ω₂-3.34×10^-20 cm², Ω ₄=4.35×10^-20 cm², and Ω₆=5.60×10^-20 cm². These Judd-Ofelt intensity parameter values are significantly different from those previously reported by A.M. Tkachuk et al. Using these intensity parameters, the Nd^{3+ 4}F₂ metastable state lifetime is predicted to be 225 μs. Measured low Nd concentration ⁴F_3/2 lifetimes of 214 μs indicate a high radiative quantum efficiency. Because of the Stark level splitting of the Nd^{3+ 4}F_3/2 and ⁴I_9/2 manifolds, laser operation at twice one of the Cs atomic resonance filter acceptance wavelengths is possible     

Suppression of boron penetration in p-channel MOSFETs usingpolycrystalline Si1-x-yGexCy gatelayers

Boron penetration through thin gate oxides in p-channel MOSFETs with heavily boron-doped gates causes undesirable positive threshold voltage shifts. P-channel MOSFETs with polycrystalline Si_1-x-yGe_xC_y gate layers at the gate-oxide interface show substantially reduced boron penetration and increased threshold voltage stability compared to devices with all poly Si gates or with poly Si_1-xGe gate layers. Boron accumulates in the poly Si_1-x-yGe_xC_y layers in the gate, with less boron entering the gate oxide and substrate. The boron in the poly Si_1-x-yGe_xC_y appears to be electrically active, providing similar device performance compared to the poly Si or poly Si_1-xGe_x gated devices     

Silicide/strained Si1-xGex Schottky-barrierinfrared detectors

By employing a thin silicon sacrificial cap layer for silicide formation, the authors successfully demonstrated Pd₂Si/strained Si_1-xGe_x Schottky-barrier infrared detectors with extended cutoff wavelengths. The sacrificial silicon eliminates the segregation effects and Fermi level pinning which occur if the metal reacts directly with Si_1-x Ge_x alloy. The Schottky barrier height of the silicide/strained Si_1-xGe_x detector decreases with increasing Ge fraction, allowing for tuning of the detector's cutoff wavelength. The cutoff wavelength was extended beyond 8 μm in PtSi/Si _0.85Ge_0.15 detectors. It is shown that high quantum efficiency and near-ideal dark current can be obtained from these detectors     

Formation of cobalt silicided shallow junction using implantinto/through silicide technology and low temperature furnace annealing

This work investigates the shallow CoSi₂ contacted junctions formed by BF₂⁺ and As⁺ implantation, respectively, into/through cobalt silicide followed by low temperature furnace annealing. For p⁺n junctions fabricated by 20 keV BF₂⁺ implantation to a dose of 5×10¹⁵ cm^-2, diodes with a leakage current density less than 2 nA/cm² at 5 V reverse bias can be achieved by a 700°C/60 min annealing. This diode has a junction depth less than 0.08 μm measured from the original silicon surface. For n⁺p junctions fabricated by 40 keV As⁺ implantation to a dose of 5×10¹⁵ cm^-2, diodes with a leakage current density less than 5 nA/cm² at 5 V reverse bias can be achieved by a 700°C/90 min annealing; the junction depth is about 0.1 μm measured from the original silicon surface. Since the As⁺ implanted silicide film exhibited degraded characteristics, an additional fluorine implantation was conducted to improve the stability of the thin silicide film. The fluorine implantation can improve the silicide/silicon interface morphology, but it also introduces extra defects. Thus, one should determine a tradeoff between junction characteristics, silicide film resistivity, and annealing temperature