Impact toughness and fractography of Al–Si–Cu–Mg base alloys

Critical automotive applications using heat-treatable alloys are designed for high impact toughness which can be improved using a specified heat treatment. The alloy toughness and fracture behavior are influenced by the alloy composition and the solidification conditions applied. The mechanical properties of alloys containing Cu and Mg can also be enhanced through heat treatment. The present study was undertaken to investigate the effects of Mg content, aging and cooling rate on the impact toughness and fractography of both non-modified and Sr-modified Al–Si–Cu–Mg base alloys. Castings were prepared from both experimental and industrial 319 alloy melts containing 0–0.6wt% Mg. Test bars were cast in two different cooling rate molds, a star-like permanent mold and an L-shaped permanent mold, with dendrite arm spacing (DAS) values of 24 and 50 μm, respectively. Test bars were aged at 180 °C and 220 °C for 2–48 h. Charpy Impact test was used to provide the impact energy. It was observed that high cooling rates improve the impact toughness whereas the presence of Cu significantly lowers the impact properties which are determined mainly by the Al₂Cu phase and not by the eutectic Si particles. The addition of Mg and Sr were also seen to decrease the impact toughness. The crack initiation energy in these alloys is greater than the crack propagation energy, reflecting the high ductility of Al–Si–Cu–Mg base alloys.     

Characterization of fracture behavior of a Ti alloyed supermartensitic 12%Cr stainless steel using Charpy instrumented impact tests

In this work, the toughness of a Ti-alloyed supermartensitic stainless steel with 12%Cr was evaluated by instrumented Charpy impact tests at − 46 °C. The material was heat treated by quenching and tempering at 500 °C or 650 °C. The temper embrittlement phenomena was detected in the specimen tempered at 500 °C, while the specimens as quenched and quenched and tempered at 650 °C presented a ductile fracture with high impact energy values. The predominance of cleavage fracture instead of intergranular cracks suggests that the temper embrittlement was caused by fine and disperse precipitation observed in the specimen tempered at 500 °C. The dynamic initiation fracture toughness (J_Id) was calculated from the force versus deflection curves using three different methods suggested in the literature to obtain the initiation energy.     

Crack Tip Opening Displacement in atomistic modeling of fracture of silicon

We analyze the fracture of single crystal silicon simulated by atomistic modeling with ReaxFF first principles based reactive force field. The simulations are performed at three temperatures: 500 K, 800 K and 1200 K, capturing both brittle and ductile behavior for the selected crystallographic orientation with (1 0 0) as the fracture plane. Three failure mechanisms are observed: bond breaking, amorphization and emission of dislocations. We demonstrate that the Crack Tip Opening Displacement (CTOD) gives a realistic estimate of the fracture toughness of brittle fracture, linking continuum mechanics fracture theory with the direct crack tip atomistic approach. We discuss the physics based mechanisms of failure in silicon in view of the CTOD measurements.     

Fracture toughness analysis of laser-beam-welded superalloys Inconel 718 and 625

In this study, two 3.2‐mm thick Ni‐base superalloys, Inconel 718 and 625, have been laser‐beam‐welded by a 6‐kW CO₂ laser and their room temperature fracture toughness properties have been investigated. Fracture toughness behaviour of the base metal (BM), fusion zone (FZ) and heat affected zone (HAZ) regions was determined in terms of crack tip opening displacement (CTOD) using compact tension‐type (C(T)) specimens. Laser‐beam‐weld regions showed no significant strength overmatching in both alloys. Ductile crack growth analysis (R‐curve) also showed that both materials exhibited similar behaviour. Compared to the BM there is a slight decrease in fracture toughness of the fusion and the HAZ.     

Toughening of denture base resin with short deformable fibers

Fracture resistance of polymer reinforced with short fibers consists of a sum of contributions from matrix and fiber fracture, fiber debonding and pull-out. The existing models for predicting dependence of fracture toughness on structural variables were derived for the commercially important fiber volume fractions, i.e., for v_f ? 0.1. In this contribution, modification of the existing model for the dependence of the critical strain energy release rate, G_IC, on the fiber type, length and aspect ratio, interfacial adhesion and volume fraction has been attempted to allow predictions at low v_f < 0.10. The predictions based on the modified model were compared with experimental data on fracture toughness of lightly x-linked PMMA used to manufacture base of removable dentures toughened with short randomly oriented deformable fibers. The composite toughness was measured under impact loading to simulate typical mode of fracture of removable dentures. The G_IC for composites containing short Kevlar 29, S2-glass and poly(vinyl alcohol) (PVOH) fibers were obtained using instrumented Charpy impact tests at room temperature and impact speed of 1.0 m/s. Theoretical prediction based on the proposed model and experimental results agreed reasonably well.     

Investigation of impact toughness of a Ni-based superalloy at elevated temperature

The impact toughness of M951 alloy is investigated in temperature range between 20 °C and 800 °C. The results show that the impact toughness of samples impacted at 600 °C shows highest impact toughness value, the impact toughness value drops sharply when the samples impacted at 760 °C. In addition samples impacted at 800 °C show the higher impact toughness than that of samples impact at 760 °C. The scanning electron microscope observations show that cracks initiate at carbides particles due to high stress concentration, which leads to low impact toughness value at 20 °C. The dimples which can absorb more energy are formed during the impact at 600 °C. The samples impacted at 760 °C show lowest impact toughness. Additionally, the dimples nucleation, growth and coalescence are the major fracture mechanism at elevated temperature.     

Microstructure and mechanical properties of high-carbon Si–Al-rich steel by low-temperature austempering

The microstructure and mechanical properties of a high-carbon Si–Al-rich steel austempered at 220–260 °C were studied by optical microscopy, X-ray diffraction, transmission electron microscopy and tension and impact tests. Results show that the nanostructured bainite microstructure composed of 38–57 nm-thickness laths of bainitic ferrite and retained austenite is produced and the excellent combination of mechanical properties is achieved. The high yield strength 1534–1955 MPa and high ultimate tensile strength 2080–2375 MPa are obtained and accompanied by the elongation 6.7–7.8% and the Charpy impact energy 7.8–22.2 J. Fracture surface observations by scanning electron microscopy indicate that both the impact and tension fracture are in a mixed mode of the brittle quasi-cleavage fracture and the ductile dimple fracture, while the ductile dimple fracture is predominant in the tension crack propagation.     

Cure path dependency of mode I fracture toughness in thermoplastic particle interleaf toughened prepreg laminates

The effect of cure cycle on fracture behaviour of a commercial thermoplastic particle interleaved prepreg system was investigated. Laminates were manufactured at 700 kPa in an autoclave using eight different thermal cycles that included both raising the cure temperature above the standard 180 °C cure cycle and incorporating an intermediate dwell stage between 150 and 170 °C prior to reaching the 180 °C cure temperature. Double cantilever beam tests were conducted on specimens from the cured laminates. The stick–slip crack behaviour, observed in samples manufactured using the standard cure cycle, changed to stable crack growth when processing deviated by 10 °C. The mode I fracture toughness values were reduced by 11–22% when incorporating an intermediate dwell stage before the final cure temperature. Scanning electron microscopy inspection of the fracture surfaces showed differences between samples made by standard cure cycles and those made using process deviations.     

Information relevant for the design of structure: Ferritic – Heat resistant high chromium steel X10CrAlSi25

In order to determine the behavior of the X10CrAlSi25 steel at room and elevated temperatures, a number of uniaxial tests were performed using a modern computer controlled material testing machine. Based on these tests, two types of their responses were considered. The first type of responses refers to the material properties presented in the form of engineering stress–strain diagrams. From these diagrams it is possible to derive and consequently to determine tensile strength, yield strength and a Modulus of elasticity. The second type of responses refers to creep behavior presented in the form of creep curves. Based on these curves, creep resistance of the considered material can be derived. Besides, the Charpy impact tests were performed with a Charpy impact machine to define Charpy impact energy as the basis for calculating fracture toughness. Considering tensile strength (584 MPa/20 °C) and yield strength (487 MPa/20 °C), it is visible that both of them are decreased when temperature is increased and fairly low strength levels at high temperature (tensile strength: 29 MPa/800 °C; yield strength: 26 MPa/800 °C) are measured. According to performed creep tests it is visible that this material does not belong to the materials resistant to creep.     

Design and processing of a ceramic laminate with high toughness and strong interfaces

An alumina–aluminium titanate laminate designed to combine high crack deflection capability with strong interfaces is proposed. It is constituted by relatively stiff and brittle external layers with microcracked internal layers to produce multiple crack deflection at the microstructural scale. The most important difference of the laminated structure proposed here and that of other laminates with high capability for crack deflection is that the crack deflection process occurs at local level, thus, delamination lengths are limited and delamination does not lead to the lost of structural integrity.A symmetric structure formed by five layers has been design to minimise residual stresses taking into account the strain on cooling and the Young’s modulus of monolithic materials of the same compositions as those of the layers and fabricated using the same processing procedure as that of the laminate.Special care was given to adjust the processing variables that permitted the fabrication of the designed laminated by sequential slip casting and sintering.Mechanical characterisation has been done in terms of strength (4-points bending), dynamic Young’s modulus, work of fracture and apparent toughness. The two latter parameters have been determined by 3-points bending of Single-Edge-V-Notch-Beams (SEVNB) and fractographic analysis has been performed on the tested samples. The apparent toughness value at the point of failure (12 MPa m^1/2) was comparable to values reported for the stationary state of transformation-toughened ceramics. Work of fracture (62 ± 3 Jm^?2) was significantly higher (≈26%) than that obtained by calculation from the values corresponding to monolithic materials of the same composition as that of the layers, revealing the synergic effect of the laminated structure on the mechanical behaviour of the material.     

Impact behavior of entangled steel wire material

Entangled steel wire (Q195F) with total porosity of 36.3 ± 1.3 to 61.8 ± 2.4% and pore sizes of 15–825 µm have been investigated in terms of the porous morphologies, impact deformation and failure behavior. The results reveal that the impact toughness increases with the decrease of the porosity. The sintered entangled steel wire materials with 61.8 ± 2.4% porosity exhibit an average of 11.8 J/cm² impact toughness. With 36.3 ± 1.3% porosity, the sintered materials have an average of 45.5 J/cm² impact toughness. Impact absorbing energy and impact toughness have been obtained by Charpy impact testing. Essential impact deformation and failure mechanisms such as pore edges (i.e. fibers) bending, bulking, rotating, yielding, densification and fracture, as well as break (or avulsion) of sintering points in the steel wire framework contribute to the excellent energy-absorbing characteristics under impact loading condition.     

The effects of texture and grain morphology on the fracture toughness and fatigue crack growth resistance of nanocrystalline platinum films

The fracture toughness and fatigue crack growth resistance of nanocrystalline materials are significantly affected by the thickness of the specimen. In this work we relate the mechanical properties of nanocrystalline platinum films to their texture and grain morphology. Tensile, creep and fatigue testing of annealed, ∼1 μm films resulted in mechanical properties similar to the as-received films (yield strength of ∼1.2 GPa, fracture toughness ∼17.8 MPa √m, and a fatigue crack growth power law exponent of ∼4.2). However, the breakdown of the initially columnar grain morphology had a marked effect on the transition point from an intergranular to transgranular fatigue cracking mode. Finite element modeling suggests that cyclic (fatigue) grain coarsening and the transition from inter- to transgranular cracking modes are a result of the relative importance of dislocation slip accommodation on in-plane and through-thickness oriented slip directions.     

Evaluation of toughness deterioration by an electrochemical method in an isothermally-aged N-containing austenitic stainless steel

This work presents the results of an evaluation of the deterioration of cryogenic toughness by means of an electrochemical method in a N-containing austenitic stainless steel (JK2) aged at temperatures of 700, 800 and 900 °C for times from 10 to 1000 min. The aging process at 700 and 800 °C caused the decrease in the Charpy V-Notch impact energy at ? 196 °C because of the intergranular precipitation of carbides. Scanning electron micrographs of the Charpy V-Notch test specimens showed the presence of intergranular brittle fracture. The degree of sensitization was determined by the ratio of the maximum current density generated by the reactivation scan to that of the anodic scan, I_r/I_a, using the double-loop electrochemical potentiokinetic reactivation test. The Charpy V-Notch impact energy decreased with increase in the I_r/I_a ratio. This relation permits an estimate of the deterioration of cryogenic toughness due to thermal aging in this type of steel.     

Simultaneously enhanced cryogenic tensile strength and fracture toughness of epoxy resins by carboxylic nitrile-butadiene nano-rubber

Epoxy resins are important matrices for composites. Carboxylic nitrile-butadiene nano-rubber (NR) particles are employed to improve the tensile strength and fracture toughness at 77 K of diglycidyl ether of bisphenol-F epoxy using diethyl toluene diamine as curing agent. It is shown that the cryogenic tensile strength and fracture toughness are simultaneously enhanced by the addition of NR. Also, the fracture toughness at room temperature (RT) is enhanced by the addition of NR. On the other hand, the tensile strength at RT first increases and then decreases with further increasing the NR content up to 5 phr. 5 phr NR is the proper content, which corresponds to the simultaneous enhancements in the tensile strength and fracture toughness at RT. Moreover, the comparison of mechanical properties between 77 K and room temperature indicates that the tensile strength, Young’s modulus and fracture toughness at 77 K are higher than those at RT but the failure strain shows the opposite results. The results are properly explained by the SEM observation.     

Effect of silicon on the fracture toughness and oxidation behavior of hot pressed NbCr2 alloys

NbCr₂ Laves phase alloyed with 0–7 wt.% Si was fabricated by mechanical alloying followed by hot pressing. The influence of silicon on the mechanical properties and oxidation behavior of NbCr₂ were investigated. It was revealed that Si addition has a beneficial effect on the oxidation resistance and fracture toughness of NbCr₂ alloy. The addition of Si partially occupies the Cr site in the Laves phase and partially forms the hard Nb₅Si₃ phase, which can yield an increase in the hardness of as-HPed NbCr₂ alloys. When alloying with 5 wt.% silicon, the fracture toughness value of NbCr₂ reaches the highest (6.45 MPa √m) which is about 13% more than that of unalloyed NbCr₂ and is 4 times higher than that of cast materials (1.2 MPa √m). Addition of silicon also resulted in a substantial improvement in the oxidation resistance of the NbCr₂ alloys exposed in air at 1373 K and 1473 K.     

Influence of the microstructure evolution of ZrO2 fiber on the fracture toughness of ZrB2–SiC nanocomposite ceramics

ZrB₂–SiC nanocomposite ceramics toughened by ZrO₂ fiber were fabricated by spark plasma sintering (SPS) at 1700 °C. The content of ZrO₂ fiber incorporated into the ZrB₂–SiC nanocomposites ranged from 5 mass% to 20 mass%. The content, microstructure, and phase transformation of ZrO₂ fiber exhibited remarkable effects on the fracture toughness of the ZrO_2(f)/ZrB₂–SiC composites. Fracture toughness of the composites greatly improved to a maximum value of 6.56 MPa m^1/2 ± 0.3 MPa m^1/2 by the addition of 15 mass% of ZrO₂ fiber. The microstructure of the ZrO₂ fiber exhibited certain alterations after the SPS process, which enhanced crack deflection and crack bridging and affected fracture toughness. Some microcracks were induced by the phase transformation from t-ZrO₂ to m-ZrO₂, which was also an important reason behind the improvement in toughness.     

Microalloying effects on microstructure and mechanical properties of 18Cr–2Mo ferritic stainless steel heavy plates

The microstructure, including grain size and precipitation, tensile strength and Charpy impact toughness of (Nb + V) 18Cr–2Mo ferritic stainless steel heavy plates with/without Ti were investigated by means of optical microscopy, scanning electron microscopy, transmission electron microscopy, X-ray diffraction and standard tensile strength and Charpy impact toughness testing. It was found that for 18Cr–2Mo heavy plate, a good combination of Nb–V stabilized method without Ti induces refinement of grain sizes due to the precipitation of amounts of fine Nb carbonitrides and V nitrides. Meanwhile, the mechanical testing results indicate that optimal transformation of grain size, precipitation that Nb–V composition system brings to 18Cr–2Mo heavy plate is beneficial to improvement of strength and impact toughness.     

Calcium silicate ceramic scaffolds toughened with hydroxyapatite whiskers for bone tissue engineering

Calcium silicate possessed excellent biocompatibility, bioactivity and degradability, while the high brittleness limited its application in load-bearing sites. Hydroxyapatite whiskers ranging from 0 to 30 wt.% were incorporated into the calcium silicate matrix to improve the strength and fracture resistance. Porous scaffolds were fabricated by selective laser sintering. The effects of hydroxyapatite whiskers on the mechanical properties and toughening mechanisms were investigated. The results showed that the scaffolds had a uniform and continuous inner network with the pore size ranging between 0.5 mm and 0.8 mm. The mechanical properties were enhanced with increasing hydroxyapatite whiskers, reached a maximum at 20 wt.% (compressive strength: 27.28 MPa, compressive Young's modulus: 156.2 MPa, flexural strength: 15.64 MPa and fracture toughness: 1.43 MPa·m^1/2) and then decreased by addition of more hydroxyapatite whiskers. The improvement of mechanical properties was due to whisker pull-out, crack deflection and crack bridging. Moreover, the degradation rate decreased with the increase of hydroxyapatite whisker content. A layer of bone-like apatite was formed on the scaffold surfaces after being soaked in simulated body fluid. Human osteoblast-like MG-63 cells spread well on the scaffolds and proliferated with increasing culture time. These findings suggested that the calcium silicate scaffolds reinforced with hydroxyapatite whiskers showed great potential for bone regeneration and tissue engineering applications.     

Influence of dynamic strain ageing on mixed mode I/III fracture toughness of Armco iron

Fracture toughness tests under mode I and mixed mode I/III loading were carried out at different test temperatures ranging from ambient to 673 K. The dynamic strain ageing (DSA) range in Armco iron was identified to be between 383 and 573 K. A marked increase in fracture toughness was observed in the DSA regime and this correlated with the increase in the strain hardening exponent. The magnitude of fracture toughness, however, decreased with increasing loading angle. The extent of decrease was high at temperatures below the DSA regime (≤383 K) which can be understood in terms of the nature of the stress field ahead of a mixed mode I/III as well as the operative fracture mechanism. However, at higher temperatures, the effect of mode III in this respect diminished in the DSA regime (383–573 K) due to DSA causing the opposite effect, that is fracture toughness to increase.     

Mode I fracture toughness of an adhesively bonded composite–composite joint in a cryogenic environment

To determine the effect of cryogenic temperature on the adhesive fracture toughness of an adhesively bonded joint with composite adherends, monotonic mode I adhesive fracture toughness tests were performed at liquid nitrogen temperature (−196 °C) and at room temperature (27 °C). From these experimental tests, the critical strain energy release rate for both test temperatures was evaluated for the selected bonded joint system constructed of carbon-BMI adherends bonded with AF-191M film adhesive. Experimental results exhibit reduced adhesive fracture toughness at the cryogenic temperature and a profound difference in fracture mode.