铝对TiFe0.9Mn0.1合金贮氢性能的影响

研究了Al对TiFe0.9Mn0.1合金贮氢性能的影响.添加铝后,合金的饱和吸氢量降低,当铝添加量为0.3%、0.6%和1.0%(原子分数)时,饱和吸氢量分别达到TiFe0.9Mn0.1合金的97.6%、95.1%和82.9%.同时铝添加后,合金的平台压力升高,平台斜度增加.XRD衍射发现,随着铝的加入,合金晶格常数即晶胞体积下降.SEM扫描及EDAX能谱分析发现合金晶界上存在高钛相.铝的添加造成合金吸氢量的下降与合金晶胞体积的减小有关.     

贮氢合金V3TiNi0.56Crx的充放电性能和吸放氢性能研究

以V2O5、TiO2等原料,用自蔓延高温合成法制备了钒基贮氢合金V3TiNi0.56Crx(x=0.1、0.3),用EDXRF、XRD等方法分析了合金的组织成分,用LK98BⅡ微机电化学分析系统、PCT测试仪分别测试了合金的充放电性能和吸放氢性能.结果表明:随Cr含量的增加,合金放电容量和吸氢量均降低;气态放氢平台的宽度变窄、倾斜度增加;电化学放电平台电压和气态放氢平台压力均增加;循环稳定性提高.     

镀覆处理对LiNiAl合金贮氢性能影响

用化学镀法和酸性镀法在LaNi4.75Al0.25材料颗粒表面镀覆铜膜,然后压制成块。处理后材料的放氢速度、导热性能、抗粉化效果有显著提高,其中酸性镀得到的颗粒与化学镀得以的颗粒在元素分布、成分、吸氢量、抗粉化效果等上有较大差别,因此压块的放氢动力学和抗粉化效果也不同。     

V3TiNi0.56Alx贮氢合金充放电性能和吸放氢性能研究

用自蔓延高温合成法制备了钒基贮氢合金V3TiNi0.56Alx(x=0.1、0.3),用EDXRF、XRD等方法分析了合金的组织成分,并对合金进行了充放电性能和吸放氢性能测试.结果表明:随Al含量增加,合金的最大放电容量和吸氢量均减小,但循环稳定性提高;合金的放氢平台均在0.5MPa附近,随Al含量增加,平台宽度变窄、平台倾斜度增加.     

V3TiNi0．56Alx贮氢合金充放电性能和吸放氢性能研究

用自蔓延高温合成法制备了钒基贮氢合金V3TiNi0．56Alx（x=0．1、0．3），用EDXRF、XRD等方法分析了合金的组织成分，并对合金进行了充放电性能和吸放氢性能测试。结果表明：随Al含量增加，合金的最大放电容量和吸氢量均减小，但循环稳定性提高；合金的放氢平台均在0．5MPa附近，随Al含量增加，平台宽度变窄、平台倾斜度增加。     

稀土系非化学计量比La(NiMMn)5.6合金的储氢性能

借助X-ray及吸放氢性能测试装置研究了不同处理条件及元素替代对非化学计量比La(NiMMn)5.6合金(M=Sn,Al,Cu)的结构、活化性能、吸氢容量和平台压力等性能的影响,测试了不同温度下合金的PCT曲线.结果表明,无论退火处理、快速凝固、以及Sn,Cu,Al元素取代,合金都出现点阵常数a缩短,c伸长,单胞体积增大.与常规熔铸相比,退火处理和快速凝固均提高了合金的活化性能,且都大大提高了合金的贮氢性能和降低平台压,但快速凝固吸氢量有所降低;快速凝固+低温退火合金的吸氢量最大.分别以Sn,Cu,Al取代Ni,元素替代的La(NiMMn)5.6合金都降低了合金的平台压,平台压降低的顺序按Sn＞Al＞Cu而减少,且都大大减小了滞后.     

V基贮氢合金的研究进展

介绍了近几年V基贮氢合金的研究进展，总结出V基合金具有如下特点：室温有效吸氢量可达2.4wt％以上，吸放氢循环性能优良，室温平台压力可达几个大气压，放氢效率不高，成本较高，但有可能通过利用廉价钒铁原料制备合金的方式降低成本。同时，提出了后续研发重点。     

贮氢材料钒基固溶体合金的研究进展

钒基固溶体合金是一类重要的贮氢材料.概述了金属钒的氢化特性,讨论了钒基固溶体合金有效贮氢量低的原因;综述了合金组元及非金属杂质元素对钒基固溶体合金性能的影响,在吸氢主要元素钒基中添加其它元素(Ti、Ni、Cr、Mn、Fe、Hf、Zr、Nb、Co、Al、Si等)有利于提高合金的贮氢性能.     

CO对LaNi4／7AI0.3合金吸氢动力学特性的影响

研究了氢中含有不同浓度ＣＯ杂质对ＬａＮｉ４．７ＡＩ０．３合金的吸氢动力学曲线及循环性能的影响。结果表明，ＬａＮｉ４．７ＡＩ０．３被ＣＯ毒化后动力学性能退化，同一ＣＯ浓度下随着循环次数的增加，吸氢量降低，随着ＣＯ浓度增加，合金的循环性能进一步降低，动力学特性衰退越严重。探讨了被ＣＯ毒化造成合金动力学特性衰退的原因。     

稀土组元对AB5型无钕贮氢合金低温性能的影响

采用均匀设计的方法设计了无钕贮氢合金的A侧组元La、Ce和Pr,用三电极的方法测试不同成分贮氢合金在-30℃和-40℃下的放电性能、合金的交换电流密度、对称因子以及氢在贮氢合金中的扩散系数,用回归分析方法分析了稀土组元对贮氢合金低温性能的影响.研究表明,在-30℃下0.4C放电容量及在-40℃下0.2C放电容量与铈含量的平方正相关;在-30℃下0.2C放电及在-40℃下0.1C放电,合金放电容量与镧和铈乘积及镧含量的平方正相关,与镧的含量负相关;在-30℃下0.1C放电,合金放电容量与镧和铈乘积、镧含量的平方和铈的含量正相关.贮氢合金的低温性能受氢扩散控制.     

分离靶多弧离子Nb—Al／Mo—Al合金薄膜及其腐蚀行业研究

本文采用分离靶多弧离子镀技术,通过改变基片负偏压和分离靶弧电流等参数,在310SS(stainlesssteel)基片上制备了多种成分的Nb     

磁控溅射Cu-Nb和Cu-Mo薄膜结构与性能

采用磁控溅射制备含1.16%～15.8%(原子分数)Nb的Cu-Nb及含2.2%～27.8%Mo的Cu-Mo合金薄膜,井采用EDX、XRD、SEM、显微硬度仪和电阻计对薄膜的成分、结构和性能进行研究。结果表明,Nb和Mo的添加分别使Cu-Nb及Cu-Mo薄膜晶粒显著细化,Cu-Nb和Cu-Mo薄膜呈纳米晶结构,存在Nb在Cu中的fcc Cu(Nb)和Mo在Cu中的fcc Cu(Mo)非平衡亚稳过饱和固溶体,固溶度随Nb或Mo含量增加而上升。添加Nb和Mo显著提高Cu-Nb及Cu-Mo薄膜的显微硬度和电阻率,且随Nb或Mo含量增加而升高。经650℃热处理1h后,Cu-Nb和Cu-Mo薄膜显微硬度和电阻率均下降,且分析表明均发生基体相晶粒长大,并出现微米-亚微米级富Cu第二相,Cu-Nb及Cu-Mo薄膜结构和性能形成及演变的主要原因是添加的Nb、Mo引起的晶粒细化效应以及退火中基体相晶粒度的增大。     

Properties of ZnO thin films co-doped with hydrogen and fluorine

ZnO films co-doped with fluorine and hydrogen were prepared on Corning glass by radio frequency magnetron sputtering of ZnO targets with varying amounts of ZnF2 in H2/Ar gas mixtures of varying H2 content. The ZnO films' electrical, optical, and structural properties in combination with their compositional properties were investigated. A small addition of H2 to the sputtering gas caused a drastic increase of Hall mobility with a marginal increase in carrier concentration, indicating an effective passivation of grain boundaries due to hydrogenation. For further increase of H2 in sputter gas, the Hall mobility remained at a relatively constant level while the carrier concentration increased steadily. Most of the ZnO films co-doped with fluorine and hydrogen showed average transmittance higher than 83% in the 400-800 nm range, while the average absorption coefficients were lower than 600 cm(-1), implying very low absorption loss in these films. It was discovered that the fabrication of ZnO films with a Hall mobility higher than 40 cm2/Vs and a very low absorption loss in the visible range is possible by co-doping hydrogen and fluorine.     

Hydrogen Effects on the Mechanical Properties of Ti-24Al-11Nb-3V-1Mo Alloy

The effects of hydrogen on the mechanical properties at room temperature of a Ti3Al based alloy Ti-24Al-11Nb-3V-1Mo have been investigated. The results show a parabolic rate relationship between the average hydrogen concentration of the alloy at constant temperature and charging time. The mechanical properties (ultimate bending strength and deflection) decrease with increasing hydrogen content in the alloy. The fractographic feature indicates that the decrease of the mechanical properties is due to the crack nucleation and propagation at the hydride Ti3AIH     

真空电弧沉积多元膜复合靶成分离析效应的研究

用Ti/Mo ,Ti/W和Ti/Me(Me为Fe Cr Al合金 )复合靶采用真空电弧技术沉积了多元膜 ,并对成分离析效应及组织和性能进行了研究。结果表明 ,工作弧电流和阴极镶嵌体的弧斑平均电流对成分离析效应影响程度较大 ,Ti/Me复合靶存在一个无成分离析效应的平衡点。多元膜结构主要为组元原子固溶于Ti2 N中的结构形式 ,并具有较高的显微硬度     

Tb-Fe-Co磁光薄膜溅射条件对Kerr转角的影响

在实际磁光盘生产线上大都使用合金溅射靶溅射记录介质膜,而尚示有直接使用合金靶研究这些关系的报道。我们首先研究了用于磁光油射的系列合金靶,并完善了靶材制造工艺参数,且在此基础上进行了成分以及溅射参数对各种磁光性能影响的研究。首先确定了各种溅射和N2－Ar气流量下Al、Si以及Tb-Fe-Co(Mo）的溅射速率,在此基础上通过改变溅射功率和调整气汉量改变SiN的成分和厚度,在各种功率和气流量下溅射了Mo膜,并测定了这些磁光膜的Kerr线以获得Kerr转角等性能,从而探讨了溅射工艺条件对Kerr的影响。     

A study on electrodeposited Co–Mo alloys thin films

Cobalt–Molybdenum (Co–Mo) induced electrodeposition has been studied from a sulphate bath on Ru electrodes at pH 4. The conditions of electrodeposition of Co–Mo alloys were determined using the cyclic voltametry at different ions concentration ratios. The theoretical model of Scharifker-Hills was used to analyse the current transients for studying the first stage of nucleation of Co–Mo alloys. The electrodeposited coatings were analysed by scanning electron microscopy, X-rays diffraction and alternating gradient force magnetometer techniques. The cyclic voltametry shows that the codeposition of Co–Mo alloys was accompanied by concurrent reactions such as the formation of the molybdenum oxides and the hydrogen evolution reaction. For the electrodeposited Co–Mo, the nucleation is in good agreement with the instantaneous nucleation and three-dimensional (3D) diffusion-limited growth. Co–Mo thin films of an hcp structure have been obtained, and the electrodeposition parameters such as the applied potential have a great influence on the structure, morphology and magnetic properties.     

氯盐环境中新型合金耐蚀钢筋Cr10Mo1的钝化行为

应用线性极化、电化学阻抗谱与电容电位法等方法对比研究了合金耐蚀钢筋Cr10Mo1和普通碳素钢筋在预含不同浓度(0mol·L~(-1)、0.1mol·L~(-1)、0.3mol·L~(-1)、0.6mol·L~(-1))氯盐的较低碱度(pH=12.5)模拟混凝土孔溶液中的钝化行为,利用XPS方法分析钢筋钝化膜组成结构,分析了氯盐作用下两种钢筋钝化行为变化存在差异的原因,揭示了合金耐蚀钢筋强易钝化机制。结果表明:在各氯盐浓度下,合金耐蚀钢筋均能良好致钝且钝化效果并无较大差距,而普通碳素钢筋随氯盐浓度增大钝化效果显著减弱,当氯盐超过一定浓度则几乎不钝化,甚至发生明显点蚀。Cr氧化物作为合金耐蚀钢筋钝化膜不同于普通碳素钢筋的关键成分,高浓度氯盐作用下仍可保持稳定并维持钝化膜层完整密实,从而使耐蚀钢筋呈现强易致钝特性。     

THE EFFECT OF HYDROGEN ON FATIGUE AND DISLOCATION BEHAVIOR OF AN α/β TITANIUM ALLOY

Abstract— Fatigue thresholds and crack growth rates were studied in the experimental alloy, Ti—5Al—4Mo, as a function of temperature, grain size and hydrogen concentration. Deformation is confined to planar slip bands along which fracture occurred at low hydrogen concentrations. Hydrogen accelerated crack growth rates at various combinations of temperature, grain size and hydrogen with a corresponding change in fracture from "cleavage' to interface phase fracture. In addition, hydrogen was found to promote interface phase formation. It is proposed that stress-assisted hydrogen accumulation increases the interface phase hydrogen concentration which reduces the interface phase fracture stress. This process depends on the local stress and β -phase hydrogen concentrations, temperature and the time under load. At 340 K, hydrogen had a relatively small effect on crack growth due to a change in slip behavior with increased hydrogen concentration.     

Improvement of Hydrogen Storage Properties of La0.6M0.4Ni4.8Mn0.2 Alloys

Investigation has been carried out to find the effects of Nd substitution and Cu addition on the hydrogen storage properties of AB5-type alloy with a multicomponent La0.6M0.4Ni4.8Mn0.2 (M=Y, Nd) system. La0.6Y0.4Ni4.8Mn0.2,which was used in an air-conditioning system, showed poor hysteresis and sloping characteristics, which led to a decrease concerning the coefficient of performance of the system. By the substitution of Nd for Y, the hydrogenstorage capacity increased, and the plateau pressure decreased a little, but the hydrogen absorption kinetics decreased dramatically. Cu addition can effectively improve the kinetics of hydride formation without changing the hydrogen storage capacity of La0.6Nd0.4Ni4.8Mn0.2. It has been found that La0.6Nd0.4Ni4.8Mn0.2Cu0.1 alloy showed good hydrogen storage characteristics for metal hydride air-conditioning system. The results showed that, for each component of La0.6Mo.4Ni4.8Mn0.2, the effective hydrogen storage capacity increased with decrease of the unit cell parameter c/a and the hydrogen absorption plateau pressure increased with decrease of the parameter a.