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研究了在pH2.7的H_3PO_4-KH_2PO_4介质中,锰(Ⅱ)催化高碘酸钾氧化罗丹明B的反应,探讨了反应机理及动力学条件,建立了高选择性催化动力学光度法测定痕量锰(Ⅱ)的新方法.线性范围为 0— 0.5μg/25mL,方法检出限为4.8X10~-10g/mL,用于人发和水样中痕量锰(Ⅱ)的测定,结果满意. 相似文献
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本文研究了新显色剂DBF-偶氮氯膦与锶的显色反应。在1.2mol/LHCL介质中试剂与锶反应形成1:2的蓝色配合物,其最大吸收峰在630nm波长处,表现摩尔吸光系数为5.0×10 ̄4L·mol ̄-1·cm ̄-1,锶量在0 ̄14μg/25ml范围内符合比尔定律。方法用于锶硅铁合金中锶的直接光度测定获得了满意结果。 相似文献
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基于HNO2介质中MnO2·xH2O能分离富集锑继而利用Sb(Ⅲ)与KI的铬阴离子[SbI4]^-在1.1 ̄1.8mol/L的H2SO4介质中与偶氮类显色剂5-Br-PADAP形成的离子缔合物,在乳化剂OP存在下,有较高灵敏度与选择性,可不经萃取分离水相光度法测定Cu中锑。线性范围0 ̄40μg/25mL,ε610=4.3×10^4。 相似文献
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在0.025~0.6mol/LH_2SO_4溶液中,Cr(Ⅵ)萃入N-235甲苯有机相后,二苯偕肼直接显色,其最大吸收峰为560nm,表观摩尔吸光系数为2.4×10 ̄4,铬含量在0.5~20μg/5mL范围内符合比尔定律,回收率为98%~102%,该法满意地用于电镀和铬盐工业废水中Cr(Ⅵ)和Cr(Ⅲ)的测定。 相似文献
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采用HNO_3和H_2O_2一溶解试样,在8mol/LHNO_3介质中,以溴酸钾将Ce(Ⅲ)氧化成Ce(Ⅳ),继以P204/CCl_4萃取Ce(Ⅳ),将三价稀土元素与四价体分离,用ICP—AES法测定CeO_2标准物质中La,Pr.Nd,Sm,Gd和Y,分析结果均落在标准值的置信区问内,RSD<6%. 相似文献
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正With the signing of"Letter of intention for Propelling Integration of Shandong Rare Earth Enterprises"between Shandong Province Commission Of Economy and Informatization,China IronSteel Research Institute Group("China Steel Institute"),and China Rare MetalsRare Earth Co.,Ltd("China Rare Earth"),the"Shandong Rare Earth Group"jointly set up by the 3 units thus broke surface.On August 9,reporters of the China Economic Herald learned from Shandong Province 相似文献
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正In the face of the current situation of the lost WTO dispute on rare earth,and cancellation of export tariff for partial rare earth products,efforts of regulation and integration on rare earth by the state government will again be tightened.Reporters of the Economic Information Daily recently learned from authoritative sources that relevant ministries are 相似文献
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正Last month,Chinalco signed framework agreement for strategic cooperation with Harbin Municipal Government in Harbin Xiong Weiping,Chairman of Chinalco,said that based on the strategic deployment to build world top-class mining company with the highest growth potential,Chinalco was now concentrating all efforts on making strategic transition and structural adjustment,strategic cooperation with the local governments where 相似文献
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《Baosteel Technical Research》2014,8(4)
正Baosteel Technical Research,a quarterly journal,which is issued domestically and abroad,is run and sponsored by Baosteel Group Corporation.Baosteel Technical Research mainly reports the achievements in technological innovation,academic research,new product development and industrial equipment improvement by Baosteel.It will continue to follow up on hot topics and serve the company’s technological development and progress.Its readers include experts in 相似文献