HOW TO USE FLUIDIZATION TO OBTAIN DRYING KINETICS COUPLED WITH QUALITY EVOLUTION

This paper presents the main activities of the Gas Fluidization and Drying Team of the Chemical Engineering Laboratory at Toulouse. The emphasis has been put on the modeling of a fluidized bed dryer and its derivates such as a flotation fluidized bed, by the analysis of heat and mass transfer together with the physico-chemical transformations of the product during drying. Several studies have been performed on different solids (cereal and chemical products) to illustrate the effect of the operating conditions on dehydration and degradation kinetics The knowledge of heat and mass transfer coefficients in flotation fluidized bed allows to determine intrinsec drying and degradation kinetics. These kinetics can be used in any conductive or convective drier model.     

Measurement of constant drying rate of wet material placed in a fluidized bed of inert particles under reduced pressure

The objective of this study is to estimate the drying characteristics of a relatively large material immersed in a fluidized bed under reduced pressure by measuring the constant drying rate. The constant drying-rate period in a fluidized bed under reduced pressure is difficult to measure because it is extremely short. To maintain the constant drying-rate period, distilled water is directly supplied to the drying material. Through our experiment, the heat transfer coefficient of the material surface was also determined. The results were compared with data on hot air drying. The constant drying rate is higher for fluidized bed drying than for hot air drying. It suggests that the heat transfer coefficient on the surface of the drying material is much larger for fluidized bed drying than for hot air drying. For fluidized bed drying, the effect of pressure in the drying chamber on the heat transfer coefficient is slight at the same normalized mass velocity of dry air (G/G_mf). The temperature difference between the inside of the drying chamber and the drying material is much smaller for fluidized bed drying than for hot air drying. The constant drying rate increases as the pressure in the drying chamber decreases.     

Fundamental Research on Drying Process in Institute of Engineering Thermophysics,CAS

Abstract

Some results of our fundamental research on drying processes are summed up in this article. It consists of three parts: (1) Multistage fluidized bed drying, including particle flowing characteristics, heat and mass transfer between particles and drying medium, drying characteristics of drying materials; (2) Impinging stream drying, the flowing and drying characteristics of a vertical impinging stream dryer, one-stage and multistage semi-circular impinging stream dryer and combined vertical and semi-circular impinging stream dryer are discussed; (3) The effects of rapid transient heat and mass transfer on drying processes, such as time and space scales for nonFourier or nonFickian and influence of extreme heat and mass transfer are also discussed.     

INVESTIGATION ON THE INCIPIENT FLUIDIZATION AND HEAT TRANSFER IN A CENTRIFUGAL FLUIDIZED BED DRYER

Abstract

Based on the continuum theory, a physical model of gas-solid two phase flow in a centrifugal fluidized bed has been proposed. A set of governing equations to describe the fluidization state are obtained and solved numerically after some simplifying. The quantitative experimental study on the characteristics of the incipient fluidization in the centrifugal fluidized bed is performed to examine the proposed model. Gas-solid two phase heat transfer in CFB during a drying process is also conducted. The influences of bed thickness, particle diameter, physical properties of particle, rotating speed of the bed and the gas superficial velocity on heat transfer characteristics are examined. A correlation that can be used to calculate the heat transfer coefficients in the drying process in CFB is obtained.     

Experimental Study of the Heat and Mass Transfer During Drying in a Fluidized Bed Dryer

ABSTRACT

Drying curves obtained in a pilot-scale fluidized bed dryer using biological source solids (sawdust, soya and fish meal) were used to estimate the parameters involved in heat and mass transfer phenomenas: heat transfer coefficient and moisture diffusivity coefficient. Parameters involved in mass transfer were estimated from drying models based on diffusional mechanisms and others that in addition consider internal and external resistance to the mass transfer. The estimate ef ective diffusivity coefficient was between 2x10-11 to lx10 (m2/s) for the considered products. Heat transfer coefficient was estimated from drying data points in the constant drying rate period when the external resistance to the mass transfer controls the process.     

From hygroscopic single particle to batch fluidized bed drying kinetics

A new normalization concept for convective drying of hygroscopic particulates is introduced. Both, intraparticle drying kinetics and sorption equilibrium are considered separately, and integrated into a new heterogeneous fluid bed model for coupled heat and mass transfer. Experiments were carried out using spherical γ-Al₂O₃ particles. Sorption isotherms, as well as drying curves, for single particles and fluidized beds have been measured. Batch fluid bed drying curves appear to be predictable on the basis of single particle and material equilibrium data and with the help of the model. All model parameters are directly taken, or estimated from fluidization literature, without any fitting.     

Analysis of Fluidized Bed Drying Kinetics on the Basis of Interphase Mass Transfer Coefficient

A particular way to define fluidized bed drying kinetics on the basis of interphase mass transfer coefficient and the conception of general kinetic curve has been described. The presented method, which allows for minimization of laboratory tests, has been checked experimentally. The method for calculating of mass transfer interphase coefficient in the constant rate period of fluidized bed drying based on Kunii and Levenspiel bubbling bed model is shown.     

Analysis of Fluidized Bed Drying Kinetics on the Basis of Interphase Mass Transfer Coefficient

A particular way to define fluidized bed drying kinetics on the basis of interphase mass transfer coefficient and the conception of general kinetic curve has been described. The presented method, which allows for minimization of laboratory tests, has been checked experimentally. The method for calculating of mass transfer interphase coefficient in the constant rate period of fluidized bed drying based on Kunii and Levenspiel bubbling bed model is shown.     

Mathematical Model for Batch Drying in an Inert Medium Fluidized Bed

A modified three-phase model is proposed for batch drying of fine powders in an inert medium fluidized bed. The overall heat and mass transfer coefficients between the interstitial gas and solid phases have been determined by the proposed surface-stripping model in which the Biot number is a governing parameter. The effects of gas velocity, inlet gas temperature and mass ratio of starch to inert particles on the drying characteristics of starch in a 0.083 m ID × 0.80 m high medium fluidized bed have been determined. Based on the proposed model, the internal resistance of mass transfer at the powder is equal to the external resistance. The model predicts well the bed temperature, humidity of outlet gas, moisture content of solid particles, heat and mass transfer in an inert medium fluidized bed.     

HEAT AND MASS TRANSFER DURING DRYING OF A LIQUID FILM FROM THE SURFACE OF A SINGLE INERT PARTICLE

ABSTRACT

This paper presents the results of theoretical and experimental studies on drying of aqueous suspensions of finely dispersed solids sprayed over the surface of an inert ceramic sphere. The effects of temperature and air velocity on kinetics of heat and mass transfer as well as peeling off the layer of a dry material from the sphere surface are described. The mathematical model of a drying process based on simplified ?gradientless? approach to transfer phenomena is proposed. The adequacy of the model developed for drying of the wet coat from a single sphere to the real drying process taking place in a bed of particulate carrier is confirmed by results of drying of several organic dyestuffs in an industrial spouted bed dryer with inert particles.     

Volumetric Heat Transfer Coefficient in Fluidized‐Bed Dryers

In literature, there are several Nu=f(Re) equations to specify the heat transfer coefficient between solids and the drying gas, but these equations differ significantly because of the inaccuracy of determining the contact surface between the two phases. A pilot‐plant fluidized‐bed dryer is developed to study the heat and mass transfer phenomena during the drying process. A volumetric heat transfer coefficient is applied for modeling fluidized‐bed dryers. A modified Nusselt number is defined to compare the experimental results and those of the literature. The modified Nu'=f(Re) equation exhibits a proper correlation between the results of the experiments in the literature and those of our experiments.     

Experimental study and simulation of vibrated fluidized bed drying

The paper addresses numerical simulation for the case of convective drying of seeds (fine-grained materials) in a vibrated fluidized bed, analyzing agreement between the numerical results and the results of corresponding experimental investigation. In the simulation model of unsteady simultaneous one-dimensional heat and mass transfer between gas phase and dried material during drying process it is assumed that the gas-solid interface is at thermodynamic equilibrium, while the drying rate (evaporated moisture flux) of the specific product is calculated by applying the concept of a “drying coefficient”. Mixing of the particles in the case of vibrated fluidized bed is taken into account by means of the diffusion term in the differential equations, using an effective particle diffusion coefficient. Model validation was done on the basis of the experimental data obtained with narrow fraction of poppy seeds characterized by mean equivalent particle diameter (d_S,d = 0.75 mm), re-wetted with required (calculated) amount of water up to the initial moisture content (X₀ = 0.54) for all experiments. Comparison of the drying kinetics, both experimental and numerical, has shown that higher gas (drying agent) temperatures, as well as velocities (flow-rates), induce faster drying. This effect is more pronounced for deeper beds, because of the larger amount of wet material to be dried using the same drying agent capacity. Bed temperature differences along the bed height, being significant inside the packed bed, are almost negligible in the vibrated fluidized bed, for the same drying conditions, due to mixing of particles. Residence time is shorter in the case of a vibrated fluidized bed drying compared to a packed bed drying.     

Modeling the Drying of Grass Seeds (Brachiaria brizantha) in Fluidized Beds

A modified three-phase model is developed to simulate the drying of Brachiaria brizantha in fluidized beds. In this new model, the constitutive equation of drying kinetics is formulated including both the constant rate and the falling rate mechanisms; the seed shrinkage is taken into account during all drying operation and the transition between bubbling to slugging regime is delineated for estimating the bubble velocity and size. Such modifications improve the mathematical model to better simulate the drying of coarse particles in fluidized beds. The best estimation of the five adjustable model parameters, which are required to define heat and mass transfer mechanisms between interstitial gas and seed particles and to specify the heat loss from dryer walls to ambient air, is attained by incorporating an optimization routine into the computer model program. Having been specially designed to supply data for this model, experiments are performed in a bath laboratory-scale fluidized bed. Additional data are generated to validate the model and program routines. Results show a good agreement between simulated and experimental data, validating the approach used to describe drying kinetics and particle shrinkage.     

Determination of PVC powder drying kinetics at particle scale: Experimental study and modeling

An original experimental method is used to determine drying kinetic at particle scale. The particle scale kinetics was obtained by immersion of a small mass of wet polyvinyl chloride (PVC) particles (cake) in a batch dense fluidized bed containing inert hot particles (glass bead). The results are summarized here and prove clearly that the PVC drying is controlled by a competition between internal and external transfers. The drying kinetic was described by a particle scale model taking into account the convective–diffusive (mass transfer) and the convective–evaporative (heat transfer) phenomena. To validate this model with the experimental data, the experimental fluidized bed dryer is modeled following two different approaches: a perfect stirred reactor model and a 3D numerical simulation using the multiphase flow code NEPTUNE_CFD. The aim of this 3D simulation is to simulate the phenomena occurring, at local scale, in a dense fluidized bed dryer and to show the limitations of the perfect stirred reactor model.     

Drying and Heat Transfer Characteristics for a Novel Fluidized Bed Dryer

Abstract

The use of a fluidized bed dryer with a lateral air flow and mechanical agitation to the drying of sludge from a wastewater treatment plant was investigated. Experimental curves of moisture content vs. drying time, as well as heat transfer coefficients and the size characteristics of the products, were determined at temperatures between 80°C and 110°C, a stirring rate of 55 rpm and air velocity of 0.9 m/s for 3 kg sludge batches with initial moisture contents of 0.55 and 0.65 (d.b.). Experimental drying kinetics were compared with values derived from three models based on Fick's second law, namely: the constant diffusivity model, the simplified variable diffusivity model, and the modified quasi-stationary model.     

BATCH VIBRATING FLUID BED DRYER FOR SAWDUST PARTICLES: EXPERIMENTAL RESULTS

ABSTRACT

In a batch experimental equipment, the behavior of a sawdust dryer in a vibrating fluidized bed is analyzed. Empirical data concerning fluidization velocities, pressure drops and drying kinetics was obtained, and advantages of using vibration in the drying chamber, relative to a conventional fluidized bed, are shown. This technique is presented as an alternative to solve problems of solid agglomeration and bed defluidization. Results show that it is possible to dry sawdust with more than 2 kg/kg moisture, in a vibrating bed keeping a high degree of bed homogeneity and high quality of fluidized state.     

DRYTNG OF PEPPER SEEDS USING A COMBINED MICROWAVE/FLUIDIZED BED DRYER

Abstract

The drying rates curves in terms of moisture content versus elapsed drying time for white pepper seeds were obtained experimentally using a fluidized bed and a combined microwave/fluidized bed. The combined microwave/fluidized bed employs a microwave field to assist convective drying. For both procedures, the drying rates were found to be dependent on the inlet air temperature and velocity. Significantly improved drying rates were achieved utilized a combined microwave/fluidized bed drying compared with a conventional fluidized bed.     

惰性粒子振动流化床中膏状物料干燥

报道了采用带浸没加热管的惰性粒子振动流化床干燥膏状物料的实验研究结果。考察了加料速率、振动条件、进气温度、进气速度、加热管功率等参数对干燥过程的影响，提出采用体积传热系数来评价干燥器传热性能，并得出了计算体积传热系数的准数关联式。结果表明，在流化床中增设振动和浸没加热管装置，能大大强化传热、传质，干燥器热效率达60%，干燥强度超过300 kg·m^-3·h^-1，体积传热系数可达25 kW·m^-3·K^-1，激光粒度分析仪的测定结果表明产品的粒度分布范围较窄，该流化床干燥可以直接得到平均粒径为0.35 μm、比表面积为5.024 m²·g^-1的粉状产品。     

On-farm heat pump - assisted fluidized bed dryer and its kinetics calculation

Abstract

The expediency of using the heat pump (HP) as a part of the farm drying plant is considered taking drying corn grain in a batch fluidized bed (FB) as an example. Using the HP, it is possible to heat the air supplied to the dryer to a temperature about 60?°C. The refrigerant R600a (isobutаne) is selected as the working medium. According to analysis of a thermodynamic cycle of the HP, it was found that the energy conversion coefficient is equal to 2.98. The use of the HP allows saving 66% of the energy needed for corn drying. A mathematical model has been developed for the kinetic calculation of a drying plant with a batch FB for granular materials, based on the use of an analytical solution to the problem of mass conductivity and taking into account the changes in drying agent parameters over time and the bed height. The adequacy of model to the real process is shown.     

OPTIMAL DESIGN OF WELL-MLXED FLUIDIZED BED DRYERS

ABSTRACT

In a recent article, Baker described a novel technique for estimating the energy consumption of well-mixed fluidized bed dryers based on the use of experimental drying curves. An integrated approach to performing sizing and energy consumption calculations for such dryers using this technique is described in the present paper. A computer program, which includes not only the dryer simulator but also a heat recovery module and an exhaust air recycle option, is used to evaluate the viability of different energy-conservation strategies. The effects of operating parameters such as bed temperature, solids loading and air velocity on energy consumption and bed area are also explored. The observed drying kinetics are shown to have a major effect on the optimal design and operation of the dryer.