Synergistic planning of an integrated energy system containing hydrogen storage with the coupled use of electric-thermal energy

Regional integrated energy systems (RIES) can economically and efficiently use regional renewable energy resources, of which energy storage is an important means to solve the uncertainty of renewable energy output, but traditional electrochemical energy storage is only single electrical energy storage, and the energy efficiency level is low. Hydrogen energy storage has the advantages of large energy storage capacity, long storage time, clean and pollution-free, and can realize the synergistic and efficient utilization of electricity and thermal power. Based on this, this paper proposes a synergistic planning method for an integrated energy system with hydrogen storage taking into account the coupled use of electric-thermal energy, which effectively reduces the system carbon emission and improves the comprehensive energy efficiency level. Firstly, this paper constructs an electric-thermal coupling model of the hydrogen energy storage unit and proposes an optimization strategy for the integrated energy system containing hydrogen storage taking into account the utilization of electricity and thermal power. Secondly, a planning optimization model with the lowest economy and carbon emission and the highest comprehensive energy efficiency was constructed. Third, the CSPO-GE optimization algorithm is proposed for solving the problem, which significantly improves the solution efficiency. Finally, a planning optimization simulation of RIES for a residential community W in northern China verifies the effectiveness of the model and method proposed in this paper. The comparative analysis of the three schemes shows that compared with the integrated energy system with conventional electrochemical energy storage and heat storage tank as the main form of energy storage and the integrated energy system with only hydrogen storage, the integrated energy system with hydrogen storage and heat storage tank can reduce carbon emissions by 43.8% and 7.61%, respectively, and improve the integrated energy efficiency level by 337.14% and 14.44%.     

Wind-hydrogen utilization for methanol production: An economy assessment in Iran

This study investigates the feasibility to synthesis methanol from its flue gas and wind hydrogen. The concept is to mitigate CO₂ emission through flue gas recovery. Synthesizing methanol, on the other hand requires hydrogen at the rate of 3 kmol/kmol of carbon dioxide. Electrolysis is one method by which hydrogen can be produced cleanly from renewable source. Here it is assumed that the electrolysis unit is fed with the electricity from neighbor wind farms. Oxygen will be produced as a byproduct in electrolysis unit. However, electrolytic oxygen could be utilized for partial oxidation of methane in autothermal reactor (ATR). Onboard water electrolysis facilitates the oxygen and hydrogen storage, delivery and marketing. This study focuses on an integrated system of methanol production which enables green methanol synthesis through a system with zero carbon emission. Green methanol synthesis is comprised of CO₂ capturing and recycling along with renewable hydrogen generation. The produced hydrogen and CO₂ will be directed to methanol synthesis unit. By employing the integrated system for methanol synthesis, we could reduce the cost of using renewable energy technology.     

Thermodynamic analysis of high‐temperature helium heated fuel reforming for hydrogen production

In order to take full advantage of the heat from high temperature gas cooled reactor, thermodynamic analysis of high‐temperature helium heated methane, ethanol and methanol steam reforming for hydrogen production based on the Gibbs principle of minimum free energy has been carried out using the software of Aspen Plus. Effects of the reaction temperature, pressure and water/carbon molar ratio on the process are evaluated. Results show that the effect of the pressure on methane reforming is small when the reaction temperature is over 900 °C. Methane/CO conversion and hydrogen production rate increase with the water/carbon molar ratio. However the thermal efficiency increases first to the maximum value of 61% and then decreases gradually. As to ethanol and methanol steam reforming, thermal efficiency is higher at lower reaction pressures. With an increase in water–carbon molar ratio, hydrogen production rate increases, but thermal efficiency decreases. Both of them increase with the reaction temperature first to the highest values and then decrease slowly. At optimum operation conditions, the conversion of both ethanol and methanol approaches 100%. For the ethanol and methanol reforming, their highest hydrogen production rate reaches, respectively, 88.69% and 99.39%, and their highest thermal efficiency approaches, respectively, 58.58% and 89.17%. With the gradient utilization of the high temperature helium heat, the overall heat efficiency of the system can reach 70.85% which is the highest in all existing system designs. Copyright © 2014 John Wiley & Sons, Ltd.     

Hybrid system of hydrogen generation by water electrolysis and methane partial oxidation

Hydrogen technology is one of the promising solutions to the problems of decentralization and reducing the carbon intensity of the energy sector. This is true even despite the current technological, economic and political barriers to its large-scale use. This paper proposes a concept of combining two technologies for producing hydrogen - partial oxidation of methane with oxygen and water electrolysis, a byproduct of which is oxygen. The analysis and evaluation of the proposed scheme showed that: 1) the synergy of water electrolysis and methane partial oxidation technologies allows the production of hydrogen with a low carbon footprint; 2) the hybrid system allows optimizing electricity and natural gas consumption using energy demand management technologies; 3) the technology synergy allows using excess thermal energy released during methane partial oxidation to increase the electrolysis temperature and its efficiency; 4) it was found that LCOH of the proposed system is 4.66 USD/kg that meets the average estimates in existing studies. At the same time, breakeven price of the project is 9.658 USD/kg H2, which is too high to be competitive without state support.     

Techno-economic analysis of hydrogen transportation infrastructure using ammonia and methanol

The transformation from a fossil fuels economy to a low carbon economy reshapes how energy is transmitted. Since most renewable energy is harvested in the form of electricity, hydrogen obtained from water electrolysis using green electricity is considered a promising energy vector. However, the storage and transportation of hydrogen at large scales pose challenges to the existing energy infrastructures, both regarding technological and economic aspects. To facilitate the distribution of renewable energy, a set of candidate hydrogen transportation infrastructures using methanol and ammonia as hydrogen carriers were proposed. A systematical analysis reveals that the levelized costs of transporting hydrogen using methanol and ammonia in the best cases are $1879/t-H₂ and $1479/t-H₂, respectively. The levelized cost of energy transportation using proposed infrastructures in the best case is $10.09/GJ. A benchmark for hydrogen transportation infrastructure design is provided in this study.     

Integration of large-scale hydrogen storages in a low-carbon electricity generation system

This study investigates the overall feasibility of large energy storages with hydrogen as energy carrier onsite with a pre-combustion carbon capture and storage coal gasification plant and assesses the general impacts of such a backup installation on an electricity generation system with high wind power portion. The developed system plant configuration consists of four main units namely the gasification unit, main power unit, backup power unit including hydrogen storage and ancillary power unit. Findings show that integrating a backup storage in solid or gaseous hydrogen storage configuration allows to store excessive energy under high renewable power output or low demand and to make use of the stored energy to compensate low renewable output or high power demand. The study concludes that the developed system configuration reaches much higher load factors and efficiency levels than a plant configuration without backup storage, which simply increases its power unit capacity to meet the electricity demand. Also from an economical point of view, the suggested system configurations are capable to achieve lower electricity generation costs.     

Hydrogen energy storage systems to improve wind power plant efficiency considering electricity tariff dynamics

One of the limitations of the efficiency of renewable energy sources is the stochastic nature of generation; consequently, it is necessary to use high-capacity energy storage systems such as hydrogen storage for its integration into existing power networks. At the same time, electricity market tariffs for large enterprises change during the day. Therefore, it can be assumed that storing energy during cheaper hours and usage in more expensive hours allows increasing the efficiency of renewable energy sources. Evaluation of the economic efficiency of an energy storage system requires simulation with a step of at least 1 h for several years since the use of averaged production volume and averaged electricity tariffs will not allow obtaining an adequate to the task accuracy. A simulation model and software have been implemented to perform simulations and calculate the economic efficiency of a wind turbine with and without a hydrogen storage device. The methodology has been approved on three-year real data of wind speeds and electricity tariffs in the Novosibirsk region and Krasnodar Territory (Russian Federation).     

Hydrogen key technology to cover the energy storage needs of NEOM City

NEOM City is supposed to be a renewable-energy-only city in Saudi Arabia. The project has planned a huge capacity of non-dispatchable wind and solar photovoltaic but has not addressed yet the issue of a long time, large storage of energy. Battery energy storage is the only product off-the-shelf, and we know already only works for the storage of small amounts of energy over short time frames. The other solutions for energy storage are not off-the-shelf products, but in many cases, only nice ideas to be proven workable. The only other opportunity to make NEOM a truly renewable-energy-only City today is to use the extra wind and solar photovoltaic power to produce hydrogen through electrolyzers, and then partially use this hydrogen to produce the missing electricity to stabilize the grid, and export the excess hydrogen. Adopting extra wind and solar photovoltaic to make NEOM a hydrogen production hub in addition to a renewable-energy-only city is an even more attractive proposition. As NEOM has not fully acknowledged this issue, same as the scientific community, the most likely solution without an urgent debate within the scientific community will be to import electricity from the combustion of hydrocarbon fuels while paying carbon credits, with is inconsistent with the renewable-energy-only aspiration.     

Hydrogen fuel as an important element of the energy storage needs for future smart cities

A considerable amount of non-dispatchable photovoltaic and wind power have always been planned in smart cities, however, the problem of massive energy storage has not yet been solved which limits the use of green energy on larger scale. At present the only battery energy storage is available, and it is effective only for storing modest quantities of energy for short periods of time. The other storage technology options are not often commercially available items; rather, they are just good concepts that need to be tested for viability. Currently, the only alternative options for turning an urban development into one that exclusively uses green energy is to use that energy to generate hydrogen through electrolyzers, then use this fuel to generate the required electricity in order to stabilize the grid. Even more appealing is the idea of using wind and photovoltaic energy to transform smart communities into a centre for producing hydrogen in addition to a city that solely uses renewable energy. The most likely solution, absent an urgent debate inside the science establishment, will be to import electricity from the burning of hydrocarbons while continuing to pay carbon offsets, which is incompatible with the goal of using only renewables. The smart city has not officially accepted this issue, just like the science establishment.     

A critical review on global trends in biogas scenario with its up-gradation techniques for fuel cell and future perspectives

Renewable biogas production technology is an excellent method for eradication of greenhouse gas emission and thereby reducing global warming. This review discusses extensively on global biomass potential, energy need and method of satisfying the energy demand through sustainable techniques. One of the best alternative technological developments for the conversion of waste into useful energy is anaerobic digestion to produce biogas. It is recognized as one among leading green energy to manage the environmental and meet the current energy tasks to tackle globally. Generally, biogas can be utilized for cooking, heat and electricity generation. In order to extend the scope of application, traces of carbon dioxide, hydrogen sulphide has to be removed by several upgrading technologies to produce high purity methane (90%). This study discusses on biogas up-gradation using physical and chemical absorption, membrane separation, cryogenic separation, hybrid technology etc. Among the various up-gradation techniques, hybrid technology yields methane purity of 97%. In addition, this work reviews about benefits and problems in anaerobic integrated Solid Oxide Fuel Cell (SOFC) with latest real-world achievement in SOFC. Several SOFC systems with dynamic model development were reviewed based on efficiency of power generation. SOFC generates 45% more electricity than generator with heat engine. This review extends the scope for further research in biogas upgradation and global warming mitigation potential with carbon credits.     

Low-carbon hydrogen production via electron beam plasma methane pyrolysis: Techno-economic analysis and carbon footprint assessment

Electron beam plasma methane pyrolysis is a hydrogen production pathway from natural gas without direct CO₂ emissions. In this work, two concepts for a technical implementation of the electron beam plasma pyrolysis in a large-scale hydrogen production plant are presented and evaluated in regards of efficiency, economics and carbon footprint. The potential of this technology is identified by an assessment of the results with the benchmark technologies steam methane reforming, steam methane reforming with carbon capture and storage as well as water electrolysis. The techno-economic analysis shows levelized costs of hydrogen for the plasma pyrolysis between 2.55 €/kg H₂ and 5.00 €/kg H₂ under the current economic framework. Projections for future price developments reveal a significant reduction potential for the hydrogen production costs, which support the profitability of plasma pyrolysis under certain scenarios. In particular, water electrolysis as direct competitor with renewable electricity as energy supply shows a considerably higher specific energy consumption leading to economic advantages of plasma pyrolysis for cost-intensive energy sources and a high degree of utilization. Finally, the carbon footprint assessment indicates the high potential for a reduction of life cycle emissions by electron beam plasma methane pyrolysis (1.9 kg CO₂ eq./kg H₂ – 6.4 kg CO₂ eq./kg H₂, depending on the electricity source) compared to state-of-the-art hydrogen production technology (10.8 kg CO₂ eq./kg H₂).     

Integration of methane cracking and direct carbon fuel cell with CO2 capture for hydrogen carrier production

Hydrogen fuel production from methane cracking is a sustainable process compared to the ones currently in practice due to zero greenhouse gas emissions. Also, carbon black that is co-produced is valuable and can be marketed to other industries. As this is a high-temperature process, using solar energy can further improve its sustainability. An integrated solar methane cracking system is proposed where hydrogen and carbon products are sent to fuel cells to generate electricity. The CO₂ exhaust stream from the carbon fuel cell is captured and reacted with hydrogen in the CO₂ hydrogenation unit to produce liquid fuels – Methanol and dimethyl ether. The process is simulated in Aspen Plus®, and its energy and exergy efficiencies are evaluated by carrying out a detailed thermodynamic analysis. In addition, a sensitivity analysis is performed on various input parameters of the system. The overall energy efficiency of 41.9% and exergy efficiency of 52.3% were found.     

A conceptual chemical looping combustion power system design in a power-to-gas energy storage scenario

Increasing global energy demand and the continued reliance on non-renewable energy sources, especially in developing countries, will cause continued increases in greenhouse gas emissions unless alternative electricity generation methods are employed. Although renewable energy sources can provide a clean way to produce electricity, the intermittent nature of many existing renewable energy sources, such as energy from the wind or sun, can cause instability in the energy balance. Energy storage systems such as power-to-gas may provide a clean and efficient way to store the overproduced electricity. In this work, a power-to-gas energy storage system coupled with a chemical looping combustion combined-cycle power generation system is proposed to provide base and intermediate load power from the unused electricity from the grid. Enhanced process integration was employed to achieve optimal heat and exergy recovery. The simulation results using ASPEN Plus V8.8 suggest that electric power generation with an overall energy efficiency of 56% can be achieved by using a methane chemical looping combustion power generation process with additional hydrogen produced from a solid oxide electrolysis cell. The proposed system was also evaluated to further improve the system's total energy efficiency by changing the key operating parameters.     

Cogeneration of power and substitute of natural gas using biomass and electrolytic hydrogen

Storing renewable energy sources is becoming a very important issue to allow a further reduction of greenhouse gas emissions. Most of such energy sources generate electric power which not always can be conveniently transferred to the grid and also its conversion to hydrogen presents some critical aspects connected mainly to hydrogen distribution and storage.Electrolysis generates not only hydrogen, but also oxygen which could be used to burn biomass or waste products (oxycombustion) in power plants with the result to obtain an exhaust gas containing mainly water and CO₂. This last can be converted into a mixture of methane and hydrogen by reacting with electrolytic hydrogen, so that the power used for electrolysis is stored into a fuel which can be distributed and stored just like natural gas.In this paper, an innovative biomass fuelled plant has been designed and simulated for different layouts with an internal combustion engine as a main power system. Utilizing hydrogen and oxygen produced through electrolysis and applying a hydrogasification process, the plant produces electricity and a substitute of natural gas. The result of such simulations is that the electricity can be stored in a useful and versatile fuel with a marginal efficiency up to 60%.     

Methanol production using hydrogen from concentrated solar energy

Concentrated solar thermal technology is considered a very promising renewable energy technology due to its capability of producing heat and electricity and of its straightforward coupling to thermal storage devices. Conventionally, this approach is mostly used for power generation. When coupled with the right conversion process, it can be also used to produce methanol. Indeed methanol is a good alternative fuel for high compression ratio engines. Its high burning velocity and the large expansion occurring during combustion leads to higher efficiency compared to operation with conventional fuels. This study is focused on the system level modeling of methanol production using hydrogen and carbon monoxide produced with cerium oxide solar thermochemical cycle which is expected to be CO₂ free. A techno-economic assessment of the overall process is done for the first time. The thermochemical redox cycle is operated in a solar receiver-reactor with concentrated solar heat to produce hydrogen and carbon monoxide as the main constituents of synthesis gas. Afterwards, the synthesis gas is turned into methanol whereas the methanol production process is CO₂ free. The production pathway was modeled and simulations were carried out using process simulation software for MW-scale methanol production plant. The methanol production from synthesis gas utilizes plug-flow reactor. Optimum parameters of reactors are calculated. The solar methanol production plant is designed for the location Almeria, Spain. To assess the plant, economic analysis has been carried out. The results of the simulation show that it is possible to produce 27.81 million liter methanol with a 350 MW_th solar tower plant. It is found out that to operate this plant at base case scenario, 880685 m² of mirror's facets are needed with a solar tower height of 220 m. In this scenario a production cost of 1.14 €/l Methanol is predicted.     

Comprehensive assessment on a hybrid PEMFC multi-generation system integrated with solar-assisted methane cracking

A hybrid proton exchange membrane fuel cell (PEMFC) multi-generation system model integrated with solar-assisted methane cracking is established. The whole system mainly consists of a disc type solar Collector, PEMFC, Organic Rankine cycle (ORC). Methane cracking by solar energy to generate hydrogen, which provides both power and heat. The waste heat and hydrogen generated during the reaction are efficiently utilized to generate electricity power through ORC and PEMFC. The mapping relationships between thermodynamic parameters (collector temperature and separation ratio) and economic factors (methane and carbon price) on the hybrid system performance are investigated. The greenhouse gas (GHG) emission reductions and levelized cost of energy (LCOE) are applied to environmental and economic performance evaluation. The results indicate that the exergy utilization factor (EXUF) and energy efficiency of the novel system can reach 21.9% and 34.6%, respectively. The solar-chemical energy conversion efficiency reaches 40.3%. The LCOE is 0.0733 $/kWh when the carbon price is 0.725 $/kg. After operation period, the GHG emission reduction and recovered carbon can reach 4 × 10⁷ g and 14,556 kg, respectively. This novel hybrid system provides a new pathway for the efficient utilization of solar and methane resources and promotes the popularization of PEMFC in zero energy building.     

CO2-free hydrogen production via microwave-driven methane pyrolysis

Hydrogen will play an integral role in achieving net-zero emissions by 2050. Many studies have been focusing on green hydrogen, but this method is highly electricity intensive. Alternatively, methane pyrolysis can produce hydrogen without direct CO₂ emissions and with modest electricity inputs, serving as a bridge from fossil fuels to renewable energies. Microwaves are an efficient method of adding the required energy for this endothermic reaction. This study introduces a new method of CO₂-free hydrogen production via non-plasma methane pyrolysis using microwaves and carbon products of this process. Carbon particles in the fluidized bed absorb microwave energy and create a hot medium (>1200 °C) in contact with flowing methane. As a result, methane decomposes into hydrogen and solid carbon achieving over 90% hydrogen selectivity with ∼500 cumulative hours of experiments This modular pyrolysis system can be built anywhere with access to natural gas and electricity, enabling distributed hydrogen production.     

Seasonal storage of hydrogen in stationary systems with liquid organic hydrides

A comparison of energy storage media for carbon free systems was made on a cost and weight basis for application with renewable energy sources such as hydropower. On a seasonal timescale (summer to winter), storage of hydrogen in liquid organic hydrides was equivalent to other carbon free alternatives and superior to zero emission systems like batteries.Seasonal energy storage is illustrated by the methylcyclohexane-toluene-hydrogen (MTH) system. Low cost summer electricity is used for water electrolysis to yield hydrogen for hydrogenation of toluene. Dehydrogenation in winter gives hydrogen for heat and power generation by fuel cells with an estimated overall electrical efficiency of 41%. Recent laboratory results using commercial, dehydrogenation catalysts in fixed bed reactors show how catalyst efficiency was increased (low by-products) to reduce the carbon emissions to 0.01 kgC/kWh_e. Hydrogen separation membranes and new molecular reactions are being investigated to further increase efficiencies. Economic analyses show that the seasonal storage of hydroelectric power with hydrogen by the MTH system is economically competitive with new hydropower projects.     

Re-envisioning the role of hydrogen in a sustainable energy economy

This paper addresses the fundamental question of where hydrogen might fit into a global sustainable energy strategy for the 21st century that confronts the three-pronged challenge of irreversible climate change, uncertain oil supply, and rising pollution. We re-envision the role of hydrogen at national and international strategic levels, relying entirely on renewable energy and energy efficiency. It is suggested the time for an exclusive ‘hydrogen economy’ has passed, since electricity and batteries would be used extensively as well. Yet hydrogen would still play a crucial role: in road and rail vehicles requiring a range comparable to today’s petrol and diesel vehicles; in coastal and international shipping; in air transport; and for longer-term seasonal storage on electricity grids relying mainly on renewables. Hydrogen fuel cell vehicles are proposed where medium and long distance trips are required, with plug-in battery electric vehicles reserved for just short trips. A hierarchy of spatially-distributed hydrogen production, storage and distribution centers relying on local renewable energy sources and feedstocks would be created to limit the required hydrogen pipeline network to the main metropolitan areas and regions by complementary use of electricity as a major energy vector. Bulk hydrogen storage would provide the strategic energy reserve to guarantee national and global energy security in a world relying increasingly on renewable energy. It is recommended that this vision next be applied to specific countries by conducting detailed energy-economic-environmental modeling to quantify its net benefits.     

Life-cycle energy efficiency estimation of large-scale ammonia fuel energy storage system

本文讨论了氨作为燃料使用会具备与传统化石燃料显著不同的环境效益,并进一步探讨了氨作为储能介质的特点,包括储能密度和规模大、受地理条件约束小、便于运输存储等。本文还针对目前的合成氨路线从理论分析和工业实际两个方面对合成效率进行了估算和评价。针对目前国内核能、风能、太阳能等清洁能源电力的低谷或弃电问题,建议采用以制氨的方式存储或外运,以便于在电力不足时将其用于发电。建议并评估了几条基于制氨并发电的路线,并基于现有氨燃料的发电效率计算了各路线在全生命周期内的总储能效率（25%～40%）和以电换电的效率[2.5～4.0(度/10度）]。