A feasibility study of using thermal energy storage in a conventional air‐conditioning system

An Erratum has been published for this article in International Journal of Energy Research 2004; 28 (13): 1213. This paper deals with the simulation of thermal energy storage (TES) system for HVAC applications. TES is considered to be one of the most preferred demand side management technologies for shifting cooling electrical demand from peak daytime hours to off peak night hours. TES is incorporated into the conventional HVAC system to store cooling capacity by chilling ethylene glycol, which is used as a storage medium. The thermodynamic performance is assessed using exergy and energy analyses. The effects of various parameters such as ambient temperature, cooling load, and mass of storage are studied on the performance of the TES. A full storage cycle, with charging, storing and discharging stages, is considered. In addition, energy and exergy analysis of the TES is carried out for system design and optimization. The temperature in the storage is found to be as low as 6.4°C after 1 day of charging without load for a mass of 250 000 kg. It is found that COP of the HVAC system increases with the decrease of storage temperature. Energy efficiency of the TES is found to be 80% for all the mass flow rate of the discharging fluid, whereas exergy efficiency varies from 14 to 0.5%. This is in fact due to the irreversibilities in a TES process destroy a significant amount of the input exergy, and the TES exergy efficiencies therefore become always lower than the corresponding energy efficiencies. Copyright © 2004 John Wiley & Sons, Ltd.     

Thermal modeling of a packed bed thermal energy storage system during charging

The process of charging of an encapsulated ice thermal energy storage device (ITES) is thermally modeled here through heat transfer and thermodynamic analyses. In heat transfer analysis, two different temperature profile cases, with negligible radial and/or stream-wise conduction are investigated for comparison, and the temperature profiles for each case are analyzed in an illustrative example. After obtaining temperature profiles through heat transfer analysis, a comprehensive thermodynamic study of the system is conducted. In this regard, energy, thermal exergy and flow exergy efficiencies, internal and external irreversibilities corresponding to flow exergy, as well as charging times are investigated. The energy efficiencies are found to be more than 99%, whereas the thermal exergy efficiencies are found to vary between 40% and 93% for viable charging times. The flow exergy efficiency varies between 48% and 88% for the flows and inlet temperatures selected. For a flow rate of 0.00164 m³/s, the maximum flow exergy efficiency occurs with an inlet temperature of 269.7 K, corresponding to an efficiency of 84.3%. For the case where the flow rate is 0.0033 m³/s, the maximum flow exergy efficiency becomes 87.9% at an inlet temperature of 270.7 K. The results confirm the fact that energy analyses, and even thermal exergy analyses, may lead to some unrealistic efficiency values. This could prove troublesome for designers wishing to optimize performance. For this reason, the flow exergy model provides the most useful information for those wishing to improve performance and reduce losses in such ITES systems.     

Evaluation of a new geothermal based multigenerational plant with primary outputs of hydrogen and ammonia

Increasing environmental concerns and decreasing fossil fuel sources compel engineers and scientists to find resilient, clean, and inexpensive alternative energy options Recently, the usage of renewable power resources has risen, while the efficiency improvement studies have continued. To improve the efficiency of the plants, it is of great significance to recover and use the waste heat to generate other useful products. In this paper, a novel integrated energy plant utilizing a geothermal resource to produce hydrogen, ammonia, power, fresh water, hot water, heated air for drying, heating, and cooling is designed. Hydrogen, as an energy carrier, has become an attractive choice for energy systems in recent years due to its features like high energy content, clean, bountiful supply, non-toxic and high efficiency. Furthermore in this study, hydrogen beside electricity is selected to produce and stored in a hydrogen storage tank, and some amount of hydrogen is mixed with nitrogen to compound ammonia. In order to determine the irreversibilities occurring within the system and plant performance, energy and exergy analyses are then performed accordingly. In the design of the plant, each sub-system is integrated in a sensible manner, and the streams connecting sub-systems are enumerated. Then thermodynamic balance equations, in terms of mass, energy, entropy and exergy, are introduced for each unit of the plant. Based on the system inputs and outputs, the energy and exergy efficiencies of the entire integrated plant is found to be 58.68% and 54.73% with the base parameters. The second part of the analysis contains some parametric studies to reveal how some system parameters, which are the reference temperature, geothermal resource temperature and mass flow rate, and separator inlet pressure in the geothermal cycle, affect both energy and exergy efficiencies and hence the useful outputs.     

Energy and exergy analyses of a hybrid molten carbonate fuel cell system

This study deals with the energy and exergy analysis of a molten carbonate fuel cell hybrid system to determine the efficiencies, irreversibilities and performance of the system. The analysis includes the operation of each component of the system by mass, energy and exergy balance equations. A parametric study is performed to examine the effect of varying operating pressure, temperature and current density on the performance of the system. Furthermore, thermodynamic irreversibilities in each component of the system are determined. An overall energy efficiency of 57.4%, exergy efficiency of 56.2%, bottoming cycle energy efficiency of 24.7% and stack energy efficiency of 43.4% are achieved. The results demonstrate that increasing the stack pressure decreases the overpotential losses and, therefore, increases the stack efficiency. However, this increase is limited by the remaining operating conditions and the material selection of the stack. The fuel cell and the other components in which chemical reactions occur, show the highest exergy destruction in this system. The compressor and turbine on the other hand, have the lowest entropy generation and, thus, the lowest exergy destruction.     

Heat transfer and exergy analysis of cascaded latent heat storage with gravity-assisted heat pipes for concentrating solar power applications

A thermal network model is developed to predict the performance of latent heat thermal energy storage (LHTES) systems including cascaded phase change materials (PCMs) and embedded heat pipes/thermosyphons. Because the design of LHTES systems involves a compromise between the amount of energy stored, the heat transfer rate, and the quality of the released thermal energy, an exergy analysis is also carried out to identify the preferred LHTES design. It is found that the LHTES with the lowest melting temperature PCM yields the highest exergy efficiency. However, a cascaded LHTES recovers the largest amount of exergy during a 24 h charging–discharging cycle. Quantitatively, the cascaded LHTES recovers about 10% more exergy during a 24 h charging–discharging cycle compared to the best non-cascaded LHTES considered in this work.     

Exergetic comparison of wind energy storage with ice making cycle versus mini-hydrogen economy cycle in off-grid district cooling

For the feasible and continuous utilization of intermittent wind and solar energy sources for electricity generation in district energy systems in hot-climates, where cooling loads are dominant, ice storage may be an option. In this study, the rationality of the ice storage system for wind energy was investigated using the Rational Exergy Management Model, REMM for two options and compared with a base scenario, which comprises a wind turbine system, grid connection, conventional chillers, and the district cooling system. The main objective is to minimize exergy destructions and thus to improve the exergy performance. The first ice storage option is composed of wind turbines, deep chillers for ice making, ice storage tanks, and the district cooling system. The second option is similar to the first option but it also includes a ground-source heat pump upstream the deep chiller. These options were also compared against a mini-hydrogen economy (District size) alternative, which encompasses a hydrogen-water cycle with excess renewable energy-powered PEM electrolysis unit, hydrogen tank, fuel cell, absorption chiller, gas compression chiller, and the district cooling system. These two options and the hydrogen-water cycle alternative were compared in terms of their REMM efficiency, First and Second-law efficiencies, and the primary energy ratio. A new Sustainability Performance Index, namely SPI was also defined. SPI is the product of the REMM efficiency, First-Law Efficiency, and the load coincidence factor, CF of wind energy. In order to establish a realistic application background for the comparisons, first a nearly-net-zero exergy farmland (nZEXF) utilizing biogas, cogeneration, solar photovoltaics, heat, absorption cycle, ground-source heat pump, Organic Rankine Cycle, and wind turbines was introduced as a model. The primary objective of this study is to determine the best option with the least avoidable CO₂ emissions responsibility of the systems considered in terms of the REMM efficiency in thermal or hydrogen storage systems. Results have been compared in terms of SPI with the base scenario and it has been concluded that the second option (SPI = 0.88) is better than the first option (SPI = 0.38). However, hydrogen storage is an even better alternative with an SPI value of 1.06. These figures according to REMM with the coincidence factor being considered, mean that the avoidable CO₂ emissions may be reduced by up to 54% compared to the base case. Hydrogen cycle option may also be used with the same effectiveness in district heating, while ice storage options are limited to district cooling only. This paper provides the relevant theory, shows the fundamental calculations about the option rankings based on a unit cooling load, makes recommendations for future district energy systems, and refers to a conceptual hydrogen economy driven city.     

A new solar based multigeneration system with hot and cold thermal storages and hydrogen production

A multigeneration system based on solar thermal energy associated with hot and cold thermal storage is designed and analyzed energetically and exergetically. The system produces electricity, a heating effect, a cooling effect, hydrogen, and dry sawdust biomass as outputs by means of organic Rankine cycles, a heat pump, two absorption chillers, an electrolyser, and a belt dryer. The intermittent behavior of the renewable energy source is addressed through the incorporation of hot and cold thermal storage systems to operate an organic Rankine cycle and provide cooling at night. The performance assessment indicates that the overall (day and night) energy and exergy efficiencies are 20.7% and 13.7%, respectively. The majority of the total exergy destruction is attributable to the sawdust belt dryer, at about 64.0%.     

Energetic and exergetic investigation on lauric and stearic acid phase‐change material–based thermal energy storage system integrated with engine exhaust

Energy and exergy analysis comparison of lauric and stearic acid phase‐change material (PCM)–based energy storage system integrated with engine exhaust have been investigated in the present study, which provides more realistic assessment than the conventional energy analysis. On the basis of thermodynamic laws, energy, exergy, charging efficiencies, and availability of PCM thermal storage with various mass fractions have been investigated at engine full load. The exergy saved for PCMs in the overall system is quantified and were compared. The results revealed a considerable enhancement in energy and exergy efficiency for thermal energy storage with lauric acid PCM due to its enhanced thermophysical properties. Energy and exergy of the storage medium for lauric acid PCM with 0.4 kg mass fraction, increased by 68% and 57.5% compared with stearic acid PCM thermal storage integrated with a diesel engine. Also, energy and exergy efficiency of charging and integrating the system with stearic acid PCM decrease with increase in mass fractions. Thus, lauric acid PCM can be used as thermal storage medium at high temperatures for exhaust heat recovery from engines and also an option for green technology.     

A method to determine stratification efficiency of thermal energy storage processes independently from storage heat losses

A new method for the calculation of a stratification efficiency of thermal energy storages based on the second law of thermodynamics is presented. The biasing influence of heat losses is studied theoretically and experimentally. Theoretically, it does not make a difference if the stratification efficiency is calculated based on entropy balances or based on exergy balances. In practice, however, exergy balances are less affected by measurement uncertainties, whereas entropy balances can not be recommended if measurement uncertainties are not corrected in a way that the energy balance of the storage process is in agreement with the first law of thermodynamics. A comparison of the stratification efficiencies obtained from experimental results of charging, standby, and discharging processes gives meaningful insights into the different mixing behaviors of a storage tank that is charged and discharged directly, and a tank-in-tank system whose outer tank is charged and the inner tank is discharged thereafter. The new method has a great potential for the comparison of the stratification efficiencies of thermal energy storages and storage components such as stratifying devices.     

Experimental study on the discharge characteristics of two eutectic solder packed bed latent heat storage systems

Metallic solder based PCMs possess higher thermal conductivities, larger storage masses and exhibit lower subcooling effects compared to their organic or inorganic counterparts. It is thus justified to investigate their potential usage for medium temperature applications. These solders are relatively expensive and can be combined with cheaper PCMs in cascaded storage systems which are more thermodynamically efficient compared to single PCM systems as reported recently. The aim of the research is thus to compare two packed bed storage systems during discharging cycles using eutectic solder (Sn63/Pb37), that is widely available worldwide. The single PCM system (40 capsules) consists of encapsulated spheres of eutectic solder, whereas the second cascaded system consists of encapsulated spheres of eutectic solder and erythritol in an equal storage ratio in the tank. For the cascaded system, the eutectic solder capsules are placed at the top and erythritol at the bottom of the storage tank (20 capsules at the top and 20 at the bottom). The effect of the discharging flow-rates of 4 mL/s, 6 mL/s and 8 mL/s is investigated in relation to the temperature profiles, energy rates and exergy rates. Increasing the flow-rate, increases heat transfer rate thus shortening the discharging time as well as increasing thermal profile reversals during discharging. The peak energy and exergy rates increase with the increase in the flow-rate for the two storage systems. The single PCM system shows slightly higher average energy and exergy rates compared to the cascaded system possibly due to its higher thermal conductivity. The cascaded PCM system shows higher average stratification numbers at all the flow rates considered. The non-cascaded system exhibited slightly higher exergy recovery efficiencies compared to the cascaded PCM system possibly due to its higher thermal conductivity at all flow-rates considered. The effect of the initial discharging temperature is also investigated with a discharging flow-rate of 6 mL/s after charging with set heater temperatures of 260°C, 280°C and 300°C, respectively. Comparable thermal profiles are seen for both systems for the three set temperatures; however, the single PCM system shows slightly higher storage temperatures. The single PCM shows slightly higher but comparable peak and average discharging energy rates compared to the cascaded system. The exergy rates for the two systems are also comparable. However, the cascaded system shows slightly higher exergy rate values for the lowest set temperature whereas the single PCM system shows slightly higher exergy rate values for the other two set temperatures. Energy and exergy rates are almost independent of the initial storage tank temperatures induced by different set charging temperatures. The average stratification number shows no correlation with set temperature for both storage systems. The cascaded system shows slightly higher average stratification numbers at different set temperatures. Exergy recovery efficiencies for different set heater temperatures are comparable for the two storage systems and vary only marginally with the increase in the set temperature. Overall, the effect of the flow-rate is more pronounced than the effect of the set heater temperature.     

Energy and exergy analyses of a solar driven Mg–Cl hybrid thermochemical cycle for co-production of power and hydrogen

Analysis and performance assessment of a solar driven hydrogen production plant running on an Mg–Cl cycle, are conducted through energy and exergy methods. The proposed system consists of (a) a concentrating solar power cycle with thermal energy storage, (b) a steam power plant with reheating and regeneration, and (c) a hybrid thermochemical Mg–Cl hydrogen production cycle. The results show that higher steam to magnesium molar ratios are required for full yield of reactants at the hydrolysis step. This ratio even increases at low temperatures, although lowering the highest temperatures appears to be more favorable for linking such a cycle to lower temperature energy sources. Reducing the maximum cycle temperature decreases the plant energy and exergy efficiencies and may cause some undesirable reactions and effects. The overall system energy and exergy efficiencies are found to be 18.8% and 19.9%, respectively, by considering a solar heat input. These efficiencies are improved to 26.9% and 40.7% when the heat absorbed by the molten salt is considered and used as a main energy input to the system. The highest exergy destruction rate occurs in the solar field which accounts for 79% of total exergy destruction of the integrated system.     

A new integrated renewable energy system for clean electricity and hydrogen fuel production

In this paper, a new renewable energy-based cogeneration system for hydrogen and electricity production is developed. Three different methods for hydrogen production are integrated with Rankine cycle for electricity production using solar energy as an energy source. In addition, a simple Rankine cycle is utilized for producing electricity. This integrated system consists of solar steam reforming cycle using molten salt as a heat carrier, solar steam reforming cycle using a volumetric receiver reactor, and electrolysis of water combined with the Rankine cycle. These cycles are simulated numerically using the Engineering Equation Solver (EES) based on the thermodynamic analyses. The overall energetic and exergetic efficiencies of the proposed system are determined, and the exergy destruction and entropy generation rates of all subcomponents are evaluated. A comprehensive parametric study for evaluating various critical parameters on the overall performance of the system is performed. The study results show that both energetic and exergetic efficiencies of the system reach 28.9% and 31.1%, respectively. The highest exergy destruction rates are found for the steam reforming furnace and the volumetric receiver reforming reactor (each with about 20%). Furthermore, the highest entropy generation rates are obtained for the steam reforming furnace and the volumetric receiver reforming reactor, with values of 174.1 kW/K and 169.3 kW/K, respectively. Additional parametric studies are undertaken to investigate how operating conditions affect the overall system performance. The results report that 60.25% and 56.14% appear to be the highest exergy and energy efficiencies at the best operating conditions.     

Comparative exergy analyses of gasoline and hydrogen fuelled ICEs

Comparative exergy models for naturally aspirated gasoline and hydrogen fuelled spark ignition internal combustion engines were developed according to the second law of thermodynamics. A thorough analysis of heat transfer, work, thermo mechanical, and chemical exergy functions was made. An irreversibility function was developed as a function of entropy generation and graphed. A second law analysis yielded a fractional exergy distribution as a percentage of chemical exergy of the intake. It was found that the hydrogen fuelled engine had a greater proportion of its chemical exergy converted into work exergy, indicating a second law efficiency of 41.37% as opposed to 35.74% for a gasoline fuelled engine due to significantly lower irreversibilities and lower specific fuel consumption associated with a hydrogen fuelled ICE. The greater exergy due to heat transfer or thermal availability associated with the hydrogen fuelled engine occurs due to a greater amount of convective heat transfer associated with hydrogen combustion. However, this seemingly high available thermal energy or thermal ‘exergy’ is misleading due to the higher cooling load which decreases the power of a hydrogen fuelled ICE. Finally, a second law analysis of both hydrogen and gasoline combustion reactions indicate a greater combustion irreversibility associated with gasoline combustion. A percentage breakdown of the combustion irreversibilities were also constructed according to information found in literature searches.     

Thermal management of metal hydride hydrogen storage using phase change materials for standalone solar hydrogen systems: An energy/exergy investigation

This paper reports on an energy/exergy analysis of a standalone solar-hydrogen system with a metal hydride (MH) system thermally managed using a phase change material (PCM). This is a self-contained thermal management arrangement that stores the heat released from the MH unit, when it is being charged and transfers it back to the MH while discharging hydrogen. The first and second laws of thermodynamics were used to develop a mathematical model in MATLAB to simulate this system and quality its performance from the energy and exergy viewpoints. The model was then applied on a passive standalone house, with ～3.8 MWh/year electricity demand, located in southeast Australia. The exergy efficiencies of the solar PV, electrolyser, fuel cell and the whole solar hydrogen system were found to be 6.5%, 88%, 50.6%, and 3.74%, respectively. The paper also provides the detailed entropy generation and exergy analysis on the MH hydrogen storage unit together with its PCM-based thermal management arrangement. The results show that the annual entropy generation, exergy destruction and exergy efficiency of the MH hydrogen storage unit were 173 Wh/K, 51.5 kWh, and 98.8%, respectively.     

Performance assessment of a direct steam solar power plant with hydrogen energy storage: An exergoeconomic study

Power generation and its storage using solar energy and hydrogen energy systems is a promising approach to overcome serious challenges associated with fossil fuel-based power plants. In this study, an exergoeconomic model is developed to analyze a direct steam solar tower-hydrogen gas turbine power plant under different operating conditions. An on-grid solar power plant integrated with a hydrogen storage system composed of an electrolyser, hydrogen gas turbine and fuel cell is considered. When solar energy is not available, electrical power is generated by the gas turbine and the fuel cell utilizing the hydrogen produced by the electrolyser. The effects of different working parameters on the cycle performance during charging and discharging processes are investigated using thermodynamic analysis. The results indicate that increasing the solar irradiation by 36%, leads to 13% increase in the exergy efficiency of the cycle. Moreover, the mass flow rate of the heat transfer fluid in solar system has a considerable effect on the exergy cost of output power. Solar tower has the highest exergy destruction and capital investment cost. The highest exergoeconomic factor for the integrated cycle is 60.94%. The steam turbine and PEM electrolyser have the highest share of exergoeconomic factor i.e., 80.4% and 50%, respectively.     

Comparison of energy,exergy, and entropy balance methods for analysing double‐stage absorption heat transformer cycles

The energy, exergy and entropy balance methods are used to analyse a double‐stage LiBr‐water absorption heat transformer cycle. An energy balance comparing component energy transfer is used to determine energy calculations. An exergy balance is employed to evaluate exergy destruction, and an entropy balance to verify entropy generation. A comparison of the results by the second law exergy and entropy balances indicates that they are consistent in identifying the location and relative significance of key non‐idealities within the system. The results obtained clearly show the influence of irreversibilities of individual components on deterioration of the effectiveness and the coefficient of performance of the system. The second law analysis offers an alternative view of cycle performance and provides an insight that the first law analysis cannot. The differences between the first law analysis by energy balance method and second law analysis by exergy and entropy balance methods are illustrated quantitatively for the double‐stage absorption heat transformer cycle, and the limitations and advantages of these methods are presented and discussed. Copyright © 2004 John Wiley & Sons, Ltd.     

Energy and exergy analyses of a combined molten carbonate fuel cell - Gas turbine system

This study deals with the thermodynamic analysis of molten carbonate fuel cell combined with a gas turbine, based on the first- and second-law of thermodynamics. The mass, energy, entropy and exergy balance equations are written and applied to the system and its components. Some parametric studies are performed to investigate the change of system performance through energy and exergy efficiencies with the change of operating conditions. The irreversibilities occuring in different devices of the integrated system are also investigated through the exergy destruction analysis in these devices. The maximum output work of the MCFC is estimated to be 314.3 kW for an operating temperature of 650 °C. The overall energy and exergy efficiencies achieved for this system are 42.89% and 37.75%, respectively.     

Thermodynamic analysis of polymer-electrolyte-membrane fuel-cell performance under varying cooling conditions

The cooling capacity and cooling load of a fuel-cell cooling loop govern the operating temperature of the fuel-cell module and its electrical output, efficiency and other thermodynamic aspects. The aim of this work was to analyze the performance of a polymer-electrolyte-membrane fuel-cell (PEMFC) under changing cooling conditions. A back-iteration algorithm was employed to determine the operating temperature of a PEMFC for which thermodynamic performance models were developed for the entropy generation, exergy-destruction and second-law efficiency using an entropy-analysis method. Electrochemical equations for the calculation of the voltage, power and first-law efficiency of the cell were also formulated. A parametric study was performed to evaluate the effects of varying cooling conditions on the energy and exergy efficiency of the PEMFC. The parameters considered include the electric-current density governing the cooling load, the mass flow rate of the coolant and the external thermal resistance of the cooler, which together determine the cooling ability of the fuel-cell cooling loop. Their influences on operating temperature, voltage, power, energy and exergy efficiencies were numerically investigated. The results indicate that although the power output and exhaust heat of PEMFC is mainly dominated by the electric-current density, the impacts of the coolant's mass flow rate and the cooler's external thermal resistance on the voltage, energy and exergy efficiencies of PEMFC module can't be neglected. In the investigated ranges, the gross energy and exergy efficiencies increase with the cooler's external thermal resistance by 3.2% and 2.45%, and decrease with the increase in coolant's mass flow rate by 1.2% and 0.92%, respectively.     

Comparison of energy and exergy efficiencies of an underground solar thermal storage system

In this experimental study, solar energy was stored daily using the volcanic material with the sensible heat technique. The external heat collection unit consisted of 27 m² of south‐facing solar air collectors mounted at a 55° tilt angle. The dimensions of the packed‐bed heat storage unit were 6 × 2 × 0.6 m deep. The packed‐bed heat storage unit was built under the soil. The heat storage unit was filled with 6480 kg of volcanic material. Energy and exergy analyses were applied in order to evaluate the system efficiency. During the charging periods, the average daily rates of thermal energy and exergy stored in the heat storage unit were 1242 and 36.33 W, respectively. Since the rate of exergy depends on the temperature of the heat transfer fluid and surrounding, the rate of exergy increased as the difference between the inlet and outlet temperatures of the heat transfer fluid increased during the charging periods. It was found that the average daily net energy and exergy efficiencies in the charging periods were 39.7 and 2.03%, respectively. The average daily net energy efficiency of the heat storage system remained nearly constant during the charging periods. The maximum energy and exergy efficiencies of the heat storage system were 52.9 and 4.9%, respectively. Copyright © 2004 John Wiley & Sons, Ltd.