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1.
This research was conducted to assess the contamination of heavy metals in the water, sediment, aquatic plants and animals around a municipal landfill. The heavy metals were analyzed by inductively coupled plasma optical emission spectrometry (ICP-OES). The concentrations of cadmium (Cd), chromium (Cr), and lead (Pb) in water and sediment were Not detected (ND), 0.05 ± 0.98, and 0.02 ± 0.01 mg/L; and 0.47 ± 0.23, 18.65 ± 11.39, and 5.36 ± 2.08 mg/kg, respectively. A total of 24 aquatic plants from 4 species were collected from the municipal landfill. Cd concentrations in all plant species were within the standard, while Cr and Pb exceeded the standard. Forty-four fish from 4 species, 29 freshwater snails from 3 species, 10 freshwater prawns from 1 species, and 9 freshwater crabs from 1 species were collected. Cd and Cr concentrations in 2 species of fish samples exceeded the standard and Pb concentration in all fish species exceeded the standard. Cd and Pb concentrations in all freshwater snails were within the standard, except Cr. Meanwhile, Cd and Pb in freshwater prawns and snails were within the standard, except Cr. Five species of frogs were collected. Cd and Cr concentrations in 2 species exceeded the standard. Pb concentrations in all frog species exceeded the standard. The pattern of metal accumulation was fish > frogs > freshwater snails > freshwater prawns = freshwater crab (Cd), freshwater prawn > frogs > freshwater crab = freshwater snail > fish (Cr), and freshwater prawn > fish > frogs > freshwater snail > freshwater crab (Pb).  相似文献   

2.
To assess the extent and potential hazards of heavy metal pollution at Shanghai Laogang Landfill, the largest landfill in China, surface soil samples were collected near the landfill and concentrations of Cu, Zn, Cd, Pb, and Cr were determined. The results revealed that the concentrations of heavy metals, except Pb, were higher in the surface soil near the landfill than in the background soil. Principal component analysis and hierarchical cluster analysis suggested that the enrichment of Cu in soil was probably related to agricultural activities and Cd and Pb to landfill leachates, whereas Zn and Cr concentrations were probably controlled by soil matrix characteristics. The pollution indices (PIs) of the metals were: Cd > Cu > Cr > Zn > Pb. Among the five measured metals, Cd showed the largest toxic response and might cause higher ecological hazards than other metals. The integrated potential eco-risk index (RI) of the five metals ranged from 26.0 to 104.9, suggesting a low-level eco-risk potential. This study indicated the accumulations of Cu, Zn, Cd, Pb, and Cr did not reach high pollution levels, and therefore posed a low eco-risk potential in surface soil near the landfill.  相似文献   

3.
The concentrations of heavy metals in rice grains and soils from Ada cultivated fields were investigated. Rice and soil samples were digested and the heavy metal concentrations determined using atomic absorption spectrophotometer. The results showed the following concentrations of metals (mg/kg): soil—Pb (4.64 ± 2.18), Cd (0.83 ± 0.83), Zn (20.26 ± 18.60), Mn (68.90 ± 19.91), Ni (3.46 ± 2.42), and Cr (21.41 ± 14.6); rice—Pb (3.99 ± 1.43), Cd (1.10 ± 0.53), Zn (65.37 ± 58.09), Mn (37.81 ± 5.82), Ni (3.12 ± 1.49), and Cr (10.87 ± 6.47). The Canadian, Nigerian and Chinese maximum allowable concentration for cadmium in soil were exceeded by 15%, 30%, and 85% of the soil samples, respectively. Heavy metals in all the rice samples evaluated were found to be above the World Health Organization (WHO) maximum permissible limit for lead, cadmium, and chromium. Strong positive and significant correlations were observed between some metal pairs in soil and rice indicating the similarity in origin. The estimated daily intakes of Pb and Cd from rice grown on the fields were higher than the safety levels established by WHO and the Joint FAO/WHO Expert Committee Food Additive, respectively. Hazard quotients and total hazard index for Pb and Cd were greater than 1. This indicates that consumption of rice from these fields will likely induce adverse health effects arising largely from Pb and Cd exposure.  相似文献   

4.
In recent years, heavy metal contamination in suburban vegetable soils calls for significant concerns due to the rapid urbanization and industrialization. In present study, 110 suburban vegetable soil samples from Yanbian, Northeast China, were collected. Concentration characteristics, pollution level, health risk, and source identification were evaluated by using different quantitative indices. Concentrations of Pb, Cr, Cu, Ni, Zn, Cd, and As in suburban soils were measured. Mean concentrations of Pb, Cr, Cu, Ni, Zn Cd, and As were 34.9 ± 10.5, 73.5 ± 44.4, 29.6 ± 19.4, 23.4 ± 12.0, 88.5 ± 26.7, 0.16 ± 0.16, and 9.24 ± 3.79 mg/kg, which were showed significantly higher than corresponding background values of Jilin province, respectively. The soils were moderately heavy polluted by Cu and Cd based on the results of geo-accumulated index and pollution indices. The pollution load index indicated that almost all of the study area were middle or heavy polluted, especially in Antu County and Helong City. Children in Yanbian may pose non-carcinogenic and carcinogenic risks with the major exposure pathway of ingestion. Principle component analysis results suggested that Pb, Cu, Zn, and Cd were mainly associated with agricultural activities, Ni and Cr were defined as combined source (lithogenic and anthropogenic), and As was tended to be from excessive application of pesticides and industrial activities.  相似文献   

5.
Abstract

This study was performed heavy metals (As, Cd, Cr, and Pb) in water, soil and frogs around an electronic-waste dump site. The bioaccumulation factors (BAFs) of heavy metals in three frog species and potential human health risks were assessed. Heavy metals were analyzed using inductively coupled plasma-optical emission spectrometry. The Cd and Pb concentrations in water samples and As and Pb concentrations in soil samples from within the e-waste dump site exceeded the standards. The heavy metal concentrations in the muscles of three frog species were as follows: Cr?>?Pb?>?As?>?Cd, and there were no significant differences among frog species except in the case of Pb (p?<?0.05). Only the Cr concentrations exceeded the food quality standards. The relative order of the BAFs for heavy metals in frogs as a result of uptake from the water and soil was Cr?>?As?>?Pb?>?Cd and Cr?>?As?>?Cd?>?Pb, respectively, which indicated that the uptake from water was greater than that from the soil. The assessment of the health risk index and carcinogenic risk (CR) indicated potential human health effects from As, Cr, and Pb via the consumption of frogs.  相似文献   

6.
This study was aimed to assess the bioaccumulation and concentration level of three heavy metals such as Chromium (Cr), Cadmium (Cd) and Lead (Pb) in the riverine water and edible fish, Channa punctatus obtained from River Kosi, Rampur, Uttar Pradesh, India. These toxic heavy metals are released into the environment because of E-waste, industrial activities, municipal urban runoff, coal burning, fertilizers etc., then paved the way into the aquatic system due to direct input, atmospheric deposition, and erosions caused by rain. There is every apprehension of aquatic animals getting exposed to elevated levels of heavy metals, thus possessing harmful effects both to flora and fauna. The concentrations of Cd, Cr and Pb in water were found to be 0.051 ± 0.026, 1.091 ± 0.408, and 0.019 ± 0.002 whereas in the kidneys of Channa punctatus, as 0.076 ± 0.208, 0.482 ± 0.059, and 0.127 ± 0.705 respectively.  相似文献   

7.
In this study, paddy soil and rice grain samples were collected from the vicinity around the Xinqiao mine in Tongling, China to test for the presence of heavy metals (Cd, Ni, Cr, Cu, Zn, and Pb) in soil-rice system. Results indicated that the soil samples were primarily contaminated with Cd and Cu and followed with Zn and Pb. In rice grains, Cd, Cu, and Cr concentrations exceeded recommended guidelines. However, the regional distribution of heavy metals in rice grains and soil was inconsistent. The bioaccumulation factor of heavy metals in rice grains decreased in the order of Cd > Zn > Cu > Ni > Cr > Pb. The BAF was significantly positively correlated with TCLP-extractable metals and significantly negatively correlated with soil pH. However, the relationship between soil organic matter and the BAF in rice grains was complex. Health risk assessment through rice intake showed that hazard quotients of Cu and Cd were greater than 1 and could pose a considerable non-cancer health risk to adults and children; meanwhile, Cr, Ni, and Cd could pose an unacceptable cancer risk. The results indicated that the government must take measures to reduce heavy metal contents in paddy soil and rice.  相似文献   

8.
Concentration of heavy metals (lead (Pb), cadmium (Cd), chromium (Cr), and copper (Cu)) was determined in the liver, gills, kidneys, and muscles of eight edible fish species (Channa punctata, Cirrhinus reba, Labeo rohita, Heteropneustes fossilis, Mystus cavasius, Oreochromis niloticus, Puntius sophore, and Wallago attu) from upstream and downstream zones of the Nullah Aik and Palkhu tributaries of the River Chenab located in the Sialkot district known for its tanning industries worldwide. The pattern of metal accumulation in studied organs was in the order: Cr > Pb > Cu > Cd. Liver showed greater metal accumulation, followed by gills, kidneys, and muscles. Accumulation of Pb and Cr was significantly different in organs between upstream and downstream zones. Accumulation was greater in fish species dwelling downstream, indicating impairment of ambient stream water due to untreated discharge of industrial and municipal effluents into studied streams. Highest concentration of Pb and Cr and lowest of Cd was detected in H. fossilis whereas Cu showed higher concentration and Cr lowest concentration in P. sophore. In contrast, lower concentration of Pb and Cu was recorded in M. cavasius, O. niloticus, and W. attu. Mean concentrations of Cd, Cr, and Cu were higher in pre-monsoon compared to post-monsoon season. Measured concentrations of Pb, Cd, and Cr in muscles of species such as C. punctata, W. attu, L. rohita, P. sophore, and O. niloticus were above permissible limits of heavy metals for human consumption, indicating potential health risks. Therefore, these fish species from studied locations should be avoided for human diet.  相似文献   

9.
&#  &#  &#  &#  &#  &#  &#  &#  H. A. C. C. PERERA  &#  &#  &#  &#  &#  &#  &#  &#  &#  &#  &#  &#  &#  &# 《水生生物学报》2015,39(5):861-868
为了解三峡水库蓄水后鱼体重金属富集现状及其潜在的生态风险和食品安全, 测定了三峡水库上、中、下游不同年龄组铜鱼(Coreius heterodon)和圆口铜鱼(C. guichenoti)肌肉和肝脏中重金属含量。利用等离子吸收光谱法、石墨炉原子吸收光谱法、原子荧光光谱法检测样品中Cu、Zn、Cr、Pb、Cd、Hg、As 等 7种重金属含量。结果表明: 7 种重金属在铜鱼和圆口铜鱼体内的含量水平基本一致, 重金属在铜鱼和圆口铜鱼肌肉中含量大小均为Zn Cu Cr Hg AsPb Cd, 在铜鱼肝脏中含量大小为Zn Cu Pb Cd Cr As Hg, 而在圆口铜鱼肝脏中含量大小为Zn Cu Pb Cr Cd Hg As。铜鱼和圆口铜鱼肝脏中重金属含量显著高于肌肉(P0.05)。两种鱼类间大部分重金属在库区上、中、下游无显著差异(P 0.05)。铜鱼和圆口铜鱼肌肉(可食用部分)中7 种重金属含量均未超过国家食品安全卫生标准, 属于安全食用范围;肝脏中除Cd 和Pb 外的其他元素含量均未超过国家标准。相关结果反映了三峡水库175 m 蓄水后底栖土著经济鱼类重金属的污染状况, 对了解该地区水产品质量安全状况及水产品安全评价提供了参考依据。    相似文献   

10.
为了明确调水调沙工程长期影响下黄河口近岸沉积物中重金属含量的分布特征及其生态风险,基于2012年黄河口近岸27个站位的表层沉积物样品,通过ICP-MS测定重金属(Zn、Cr、Ni、Pb、Cu、Cd)和砷(As)含量,并运用潜在生态风险指数法(RI)对其进行生态风险评估。结果表明:近岸沉积物中重金属和As的平均含量表现为AsZnCrNiPbCuCd。Cr、Ni、Cu和Pb四种元素的分布规律较为一致,整体呈现出近岸和近黄河口高而远离河口和岸线低的空间分异特征。Ni、Cu、Pb、Zn与粘土均呈极显著或显著正相关(P0.01或P0.05),而Cd、Cr和As与其相关性均未达到显著水平(P0.05)。近岸沉积物中6种重金属和As的平均单项潜在生态风险指数大小顺序整体表现为CdAsNiPbCuCrZn。就潜在生态风险(RI)而言,研究区域18.52%的站位属轻微生态危害,70.07%的站位属中等生态危害,7.41%的站位属强生态危害,Cd和As是造成危害的两种主要元素。近岸沉积物中重金属和As的来源复杂且多样,主要是由于农业化肥使用、海上石油开采和泄漏、化石燃料燃烧以及河口污染物输入所致。对比研究发现,随着调水调沙工程的长期实施,除Cd和As外沉积物中其他重金属含量均呈下降趋势,说明二者的生态风险将会随调水调沙的长期实施呈增加趋势,而其他重金属的生态风险将呈降低趋势,故未来应重点关注近岸沉积物中Cd和As的生态毒理风险。  相似文献   

11.
The present study was conducted to assess the suitability of sewage sludge amendment (SSA) in soil for Beta vulgaris var. saccharifera (sugar beet) by evaluating the heavy metal accumulation and physiological responses of plants grown at a 10%, 25%, and 50% sewage sludge amendment rate. The sewage sludge amendment was modified by the physicochemical properties of soil, thus increasing the availability of heavy metals in the soil and consequently increasing accumulation in plant parts. Cd, Pb, Ni, and Cu concentrations in roots were significantly higher in plants grown at 25% as compared to 50% SSA; however, Cr and Zn concentration was higher at 50% than 25% SSA. The concentrations of heavy metal showed a trend of Zn > Ni > Cu > Cr > Pb > Cd in roots and Zn > Cu > Ni > Cr > Pb > Cd in leaves. The only instance in which the chlorophyll content did not increase after the sewage sludge treatments was 50%. There were approximately 1.12-fold differences between the control and 50% sewage sludge application for chlorophyll content. The sewage sludge amendment led to a significant increase in Pb, Cr, Cd, Cu, Zn, and Ni concentrations of the soil. The heavy metal accumulation in the soil after the treatments did not exceed the limits for the land application of sewage sludge recommended by the US Environmental Protection Agency (US EPA). The increased concentration of heavy metals in the soil due to the sewage sludge amendment led to increases in heavy metal uptake and the leaf and root concentrations of Ni, Zn, Cd, Cu, Cr, Pb, and Zn in plants as compared to those grown on unamended soil. More accumulation occurred in roots and leaves than in shoots for most of the heavy metals. The concentrations of Cd, Cr, and Pb were more than the permissible limits of national standards in the edible portion of sugar beet grown on different sewage sludge amendment ratios. The study concludes that the sewage sludge amendment in the soil for growing sugar beet may not be a good option due to risk of contamination of Cr, Pb, and Cd.  相似文献   

12.
武汉市蔬菜重金属污染现状的调查与评价   总被引:3,自引:0,他引:3  
通过对武汉市6种蔬菜的供食部位及所对应的土壤中重金属Hg(汞)、Cu(铜)、Pb(铅)、Cd(镉)、Cr(铬)、Zn(锌)、As(砷)含量及分布特征进行了检测,结果表明:Pb、Cr是武汉市蔬菜中主要的污染元素;Hg、Cd只在个别叶菜类上超标;Zn、Cu、As无超标样。在所时应的土样中,普遍存在污染的是Cd,其它6种重金属元素均未超标。  相似文献   

13.
The present research reports the heavy metal (Fe, Cr, Pb, As, and Co) contamination in caviar of Persian sturgeon (Acipenser persicus) caught from Southern Caspian Sea sampling site using ICP-OES. Heavy metal concentrations (microgram per gram, wet weight; means?±?S.D.) in caviar samples were: Fe, 71.33?±?0. 37; Cr, 0.27?±?0.019; Pb, <0.01?±?0.002; As, <0.01?±?0.002; and Co, <0.01?±?0.001, respectively. Comparative evaluation of these metals in different samples showed that except Fe, the average concentrations of Cr, Pb, As, and Co are significantly lower than adverse level for the species themselves and for human consumption when compared with FAO/WHO permissible limits. Therefore, their contribution to adverse health effects on human body can be considered as negligibly small.  相似文献   

14.
Environmental and health risk posed by heavy metals from municipal landfill cannot be over emphasized. However, the toxicity and fate of metal in the soil is dependent on its chemical form and therefore quantification of the different forms of metal is more meaningful than the estimation of its total concentration. This study investigated the chemical form and potential hazards of heavy metal pollution at two municipal landfills in Sagamu, Ogun state, Nigeria. Soil samples were collected around the landfills and chemical form of Cu, Zn, Cd, Pb, and Fe were studied, using the Tessier Five-step sequential chemical extraction procedure. The results showed that Cu and Fe were speciated into residual fractions with averages of 23.9 and 31.3% respectively, while Cd and Zn were associated with Carbonate fractions with respective averages of 20.3 and 20.6%. The order of mobility and bioavailability of these metals are: Cd > Pb > Cu > Zn > Fe. A comparison of the result of total extractible metals with standard set by USEPA reveals that Cd and Cu level in the dumpsite soils are far above the critical permissible limit of 3.0 and 250 mg kg?1, respectively which potent a health risk. Assessment of soil pollution level using geoaccumulation index (Igeo) revealed that the landfill was extremely polluted by Cd (Igeo > 5). Pearson correlation and principal component analysis showed that there were no significant correlations (p < 0.05) among all the metals, suggesting that they are all from different anthropogenic sources. The cancer risk ranged from 1.36E?01 to 2.18E?04 and 5.82E?01 to 9.35E?04 for Children and Adult respectively. The level of cancer risk falls above the threshold values (10?4–10?6) which US Environmental Protection Agency considered as unacceptable risk. Based on the above findings, it was suggested that environmental management policy should be implemented to decrease the environmental risks.  相似文献   

15.
Soil heavy metal contamination is a major environmental concern, and health risk associated with heavy metals is not fully explored. A combination of spatial analysis and Monte Carlo simulation was successfully used to identify the possible sources and health risk of cadmium (Cd), arsenic (As), mercury (Hg), lead (Pb), chromium (Cr), and copper (Cu) in soils collected from a rapidly developing region of China. It was found that mean concentrations of Cd (0.17 mg/kg ), As (8.74 mg/kg ), Hg (0.15 mg/kg ), Pb (27.28 mg/kg ), and Cu (33.32 mg/kg ) were greater than the soil background values. Accumulation and spatial variability of heavy metals were significantly affected by anthropogenic activities and soil properties. The risk assessment indicated that non-carcinogenic risk was not significant. However, 95% of the total cumulative carcinogenic risk of children was greater than 1E-05, implying high potential carcinogenic risk with As and Pb representing the major contributors. Ingestion of heavy metals in the soils was the main exposure pathway compared with the inhalation and the dermal exposure. Concentration of heavy metals in the soils, particulate emission factor, and dermal exposure ratio were the major parameters affecting health risk. This study highlights the importance of assessment of soil direct exposure health risk in studying heavy metal exposures.  相似文献   

16.
Instead of total metal concentration measurements in seafood, bioaccessibility is a more important parameter for human health risk assessment. Therefore, bioaccessibility of Cd, Cr, Cu, Mn, Ni, Pb, and Zn in the edible soft tissues of rapa whelk (Rapana venosa Valenciennes, 1846) collected along the southern Black Sea coast were investigated using an in vitro digestion model. Zn was detected at the highest concentration, whereas Ni was the lowest for total metal concentrations. Total Cd and Pb concentration in the tissues were found to be higher than maximum permissible limits set by European Commission. The bioaccessibility of metals in the tissues was found to be decreased in the order: Cu (77.11%) > Cd (70.13%) > Zn (64.52%) > Ni (61.27%) > Pb (50.53%) > Cr (43.41%) > Mn (22.59%). While significant positive linear regressions were observed between the total and bioaccessible concentrations for Mn, Pb, and Ni, significant negative linear regressions were found for Cd in the tissues (p < 0.05). The hazard quotients (HQ) calculated using bioaccessible heavy metal amount were detected lower than the limit value (HQ < 1), which may not pose a potential hazard to humans declared by US Environmental Protection Agency. However, the consumption of rapa whelk may cause a potential risk concerning human health for the Cd and Pb levels in case of increased serving sizes and portions.  相似文献   

17.
A total of 32 road dust samples were collected from mining areas and a control area in Nandan County, Guangxi, in order to investigate the contamination characteristics of heavy metals and associated health risks to local residents. The results indicated that elevated concentrations of As, Cd, Cu, Pb, Sb, and Zn were found in road dust in mining areas compared with control areas and background values. Pearson's correlation analysis and principal component analysis indicated that As, Cd, Cu, Pb, Sb, and Zn in road dust mainly originated from anthropogenic sources (e.g., vehicles emission, mining activities, and smelting activities), whereas Cr, Co, and Ni were associated with natural sources (e.g., soil weathering). Furthermore, noncarcinogenic hazards to both adults and children were found in mining areas, while noncarcinogenic health risks in the control area were negligible. The health hazard was mostly ascribed to the ingestion, followed by the dermal contact, and the inhalation. The cancer risks from As, Cd, Co, Cr, and Ni in all studied areas were within safe levels as the R values were below the threshold of 1 × 10?6.  相似文献   

18.
A total of 195 farmland soil samples were collected in Yanqi Basin, Xinjiang, northwest China, and the concentrations of As, Cd, Cr, Cu, Ni, Pb, and Zn were analyzed for their concentrations and pollution levels using the Nemerow comprehensive index. The health risk assessment model introduced by USEPA was utilized to evaluate the human health risks of heavy metals. Results indicated that the average concentrations of these seven metals were lower than the allowed soil environmental quality standards of China, while the average concentrations of Cd, Cr, Ni, Pb and Zn exceeded the background values of irrigation soils in Xinjiang. The average contamination factor (CF) for Pb indicated the heavy pollution, whereas the CF for Cd, Zn, Ni, Cu and Cr indicated the moderate pollution. The average PLI of heavy metals indicated the low pollution. The non-carcinogenic hazard index were below the threshold values, and the total carcinogenic risks due to As and Cr were within the acceptable range for both children and adults. As and Pb were the main non-carcinogenic factors, while As was the main carcinogenic factor in the study area. Special attentions should be paid to these priority control metals in order to target the lowest threats to human health.  相似文献   

19.
This study aimed to assess the drinking water quality and human potential health risk in Peshawar, which is the most populous district of Khyber Pakhtunkhwa Province, Pakistan. Water was randomly collected throughout Peshawar District (urban = 45 samples and rural = 29 samples). These samples were analyzed for heavy metal (As, Cd, Co, Cu, Cr, Hg, Ni, Pb, and Zn) concentrations using the atomic absorption spectrometer (Perkin Elmer, AAS-PEA-700). Heavy metal concentrations in drinking water revealed the highest pollution index (PI) values—17.80, 11.92, 7.50, and 5.70 for the Pb, Cr, Cd, and Ni, respectively. The contaminations of Cd and Pb were significantly higher (p < .05) than their maximum allowable limits set by the World Health Organization. Heavy metal contaminations in drinking water were evaluated for health risk assessment: the chronic risk or hazard quotient (HQ) and cancer risk. Results revealed that HQ values were >1 for the Cd and Pb, suggesting that the exposed human beings could be at chronic risk. Therefore, serious measures such as drinking water treatments and contamination controlling policies are needed to avoid the hazardous effects of toxic heavy metals.  相似文献   

20.
In this study, concentrations of heavy metals (Cd, Cr, Cu, Pb, and Zn) were determined in three edible mushroom species (Lactarius deliciosus, Russula delica, and Rhizopogon roseolus) collected in five sampling sites in Canakkale province, Turkey. Mean values of Cd, Cr, Cu, Pb, and Zn were 0.72, 0.26, 28.34, 1.53, and 64.62 mg/kg, respectively. The highest concentrations of Cd, Cu, Pb, and Zn were determined in species R. delica, while Cr was observed in L. deliciosus. In terms of the nutritional aspect, taking into account the concentration of Provisional Tolerable Weekly Intake recommended by FAO/WHO, the maximum concentration of Cd is a restrictive factor for consumption of the collected mushroom species. The concentrations of the other elements have no health risks when consumed at optimal levels.  相似文献   

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