Solid-wall U-values: heat flux measurements compared with standard assumptions

The assumed U-values of solid walls represent a significant source of uncertainty when estimating the energy performance of dwellings. The typical U-value for UK solid walls used for stock-level energy demand estimates and energy certification is 2.1?Wm^?2?K^?1. A re-analysis (based on 40 brick solid walls and 18 stone walls) using a lumped thermal mass and inverse parameter estimation technique gives a mean value of 1.3?±?0.4?Wm^?2?K^?1 for both solid wall types. Among the many implications for policy, this suggests that standard UK solid-wall U-values may be inappropriate for energy certification or for evaluating the investment economics of solid-wall insulation. For stock-level energy modelling, changing the assumed U-value for solid walls reduces the estimated mean annual space heating demand by 16%, and causes a proportion of the stock to change Energy Performance Certification (EPC) band. The analysis shows that the diversity of energy use in domestic buildings may be as much influenced by heterogeneity in the physical characteristics of individual building components as it is by variation in occupant behaviour. Policy assessment and guidance material needs to acknowledge and account for this variation in physical building characteristics through regular grounding in empirical field data.     

Bestimmung thermischer Eigenschaften der Gesteine des Unteren und Mittleren Buntsandsteins

For accurate planning of vertical borehole heat exchanger systems, knowledge of thermo-physical ground parameters is critical. This study reports laboratory-measured thermal conductivity and diffusivity values of Mesozoic sandstones (Lower and Middle Buntsandstein) from four wells. The measurements were made on drill core using an optical scanning method. The mean thermal conductivities of the sandstones range between 2.6?±?0.3 W?/?(m?·?K) and 3.1?±?0.4 W?/?(m?·?K) for dry conditions and between 3.6?±?0.3 W?/?(m?·?K) and 4.1?±?0.6 W?/?(m?·?K) after saturation with water. The mean thermal diffusivity values range between (1.6?±?0.2)?·?10??6 m²?/?s for dry and (2.0?±?0.6)?·?10??6 m²?/?s for water-saturated sandstones. Thermal properties are closely related to the petrography and lithostratigraphy of the sandstones. Additionally, three temperature correction methods were applied for the purpose of evaluating the comparative accuracy and the correction schemes with respect to local in-situ conditions. The results show that the temperature corrections proposed by Somerton (Thermal properties on temperature-related behavior of rock/fluid systems, Elsevier, New York, S 257, 1992) and Sass et al. (J Geophys Res, 97:5017–5030, 1992) are most suited for the respective sandstone data set.     

Assessment of gaseous emissions and radiative forcing in Indian forest fires

This paper reports a study of the gaseous emissions from Indian forest fires from 2005 to 2016 and their potential impact on radiative forcing. Initially, forest burned area is quantified using MODIS-MCD45A1 data. Results showed that annual burned area of the study period ranges from 8439 km² to 25,442 km² and the maximum forest area is burned during February, March, and April in any year. Gaseous emissions are estimated using emission factors, the mass of fuel available for combustion, combustion factor, and burned area. CO₂, CO, and CH₄ are the major emissions during forest fires with an annual average of 105 × 10⁶ tonnes, 6 × 10⁶ tonnes, and 3.25 × 10⁵ tonnes, respectively. The average radiative forcing (RF) for CO₂, CH_4, and N₂O is estimated as 1.8 Wm^?2, 0.49 Wm^?2, and 0.177 Wm^?2, respectively. An important finding in the present study is the recurrence of forest fires during the pre-monsoon season.     

Predicting the Fire Dynamics of Exposed Timber Surfaces in Compartments Using a Two-Zone Model

There is an increasing desire to use more engineered timber products in buildings, due to the perceived aesthetics of timber and desire for more sustainable architecture. However, there are concerns about fire performance of these products especially in taller buildings. This has led to renewed research to understand the behaviour of timber surfaces in compartments exposed to fire. This paper describes a two-zone calculation model for determining the fire environment within a compartment constructed from timber products where varying amounts of timber are exposed on the walls and ceiling. A set of eight full-scale compartment experiments previously reported in the literature are used to assess the capability of the model. The fire load energy density in the experiments ranged from 92 MJ/m² to 366 MJ/m² comprising either wood cribs or bedroom furniture with the largest compartment having dimensions 4.5?×?3.5?×?2.5 m high with an opening 1.069 m wide?×?2.0 m high. The experiments were ventilation-controlled. It is shown that the model can be used to provide conservative predictions of the fire temperatures for compartments with timber exposed on the walls and/or ceiling as part of an engineering analysis. There are several limitations that are discussed including the need to consider the debonding of layers in the case of cross-laminated timber. It is recommended that further benchmarking of the model be done for different ventilation conditions and with engineered timber products where debonding does not occur. This will test the model under a wider range of conditions than examined in this paper.     

Quantifying spatial-temporal changes of aboveground carbon stocks using Landsat time series data: A case study of Miombo woodlands

ABSTRACT

There is a need for accurate reporting of the second-growth forest in accounting for the contribution of secondary forests to achieving global carbon sequestration strategies. This study develops a model relating aboveground live biomass (AGLB) to Landsat reflectance measurements, and this method is used on multi spatial-temporal Landsat data (1998, 2001, 2004, 2011 and 2016) to assess changes in Miombo woodlands in Zambia. Results showed that the enhanced vegetation index was a better predictor of AGLB (r² = 0.96; RMSE = 0.24 t ha^?1) than the other assessed vegetation indices. Forest carbon stocks increased by an average rate of 3.65 ± standard error (SE): 0.56 t ha^?1 yr^?1 from 1998 to 2001, but a continual decline was evident for the periods 2001–2004 (?0.60 t ha^?1 yr^?1), 2004–2011 (?0.88 t ha^?1 yr^?1) and 2011–2016 (?2.03 t ha^?1 yr^?1). The study provides an empirical model for evaluating carbon stock changes.     

Environmental Gamma radiation measurement using TLDs around TNRC,tripoli

The outdoors absorbed dose rate in the air around the Tajoura nuclear research centre (TNRC), Tripoli has been measured. The measurements were performed using calcium fluoride dysprosium (CaF₂: Dy) thermoluminescence dosimeters (TLD‐200) at 9 locations, all 1 m above the ground level.

The average outdoors absorbed dose rate in air, effective dose and the collective effective dose were calculated to be 54?±?4.6 nGyh^??1, 66.23 μSvy^??1 and 99.35 manSvy^??1, respectively, based on the analysis of thermoluminescence dosimeters data.     

New Approaches to Evaluate the Performance of Firefighter Protective Clothing Materials

This paper presents new proposals in the evaluation and determination of the optimum materials suitable for use in the design and development of firefighter protective clothing by simultaneously addressing the conflicting factors of thermal protection [heat transfer index (HTI), radiant heat transfer index (RHTI) and thermal threshold index (TTI)] and anti-heat stress [water vapor resistance (WVR) and total heat loss (THL)]. To achieve this, this paper proposes new indices for the materials, two types of “total performance” indices, which are defined as the sum and the product of the competing factors of thermal protection and anti-heat stress. The results showed that the candidate materials of firefighter protective clothing were easily rated when the new indices were applied. Of five candidate materials viz. A, B, B₁, B₂ and C, the B sample, with values for HTI₂₄?=?13.2?±?0.2 s, RHTI₂₄?=?18.0?±?0.8 s, TTI?=?1132?±?33 J/m², WVR?=?17.5?±?0.3 m² Pa/W and THL?=?266.2?±?4.1 W/m², was found to exhibit the best total performance. However, the methods proposed to the scientific community in this paper have so far been validated on a limited data set only, and will require further validation by a wider group of researchers and with more samples. Lastly, comments on ISO 11999-3:2015 were also made for the further improvement and development of technical standards.     

Statistical evaluation of U-value of a window with inter-pane blinds

This paper statistically evaluates the simulated U-values from WINDOW 6 software and those determined from guarded heater plate apparatus for double glazed window with inter-pane blinds, so as to explore its performance potential as per composite climate in India. The simulation results are statistically validated by calculating a linear regression followed by ANOVA (analysis of variance) to judge the fit of the model. An R² value of 0.88 for the regression equation asserted a satisfactory agreement of simulated results with experimental ones. Optimum levels for control parameters are predicted on the basis of analyses of Signal/noise, that is, S/N ratio. ANOVA is once again carried out for both simulated and experimental results separately, to quantify the contributions of important parameters in estimating the U-value. The lowest percentage contribution of outside temperature (0.24%) in influencing the U-value of identified glazing system establishes its credibility for usage in composite Indian climate.     

Sustainable earth walls to meet the building regulations

The thermal conductivity and diffusivity of un-fired clay bricks, a straw clay mixture and straw bales have been measured using a thermal probe technique, with an iterative method for data analysis. The steady-state air-to-air thermal transmittance, or U-value, and the time-dependent thermal properties of some proposed sustainable earth wall constructions are presented. Sustainable cavity walls of un-fired clay bricks with paper, straw or wool cavity insulation have thermal transmittances less than 0.35 W/m² K, and therefore meet the current United Kingdom Building Regulations. A review of possible methods for thermally up-grading existing earth walls, by adding an internal insulated timber frame construction, again demonstrates possible compliance with the current UK thermal regulations.     

Radioactive element contents of some granites used as building materials: insights into the radiological hazards

This study was conducted to investigate the radioactive potential hazard of granite, which is widely used as building material in Turkey. Natural radiation levels of 18 various, globally-distributed industrial granite samples imported by Turkey, were analyzed using gamma-ray spectrometer. The results are compared with the formerly published findings of granite samples from Turkey. Radioactivity levels of ²³⁸U, ²³²Th, and ⁴⁰K natural radioactive series elements of the selected 18 specimens were measured, which were from 2.4 ± 0.5 to 88.8 ± 3.6 Bq kg^?1 for ²³⁸U, from 2.4 ± 0.7 to 273 ± 0.9 Bq kg^?1 for ²³²Th, and from 169 ± 24 to 1,479 ± 94 Bq kg^?1 for ⁴⁰K. Radium equivalent activities (Ra_eq) were calculated for the granite samples to assess their radiation hazards in the construction of dwellings. The Ra_eq values of granite samples varied in the range of 39.05–570 Bq kg^?1, only one sample exceeded the safe limit value of 370 Bq kg^?1 set by the OECD-NEA (Nuclear Energy Agency. Exposure to radiation from natural radioactivity in building materials. Report by NEA Group of Experts 1979). Absorbed dose rates in air were found between 18.74 and 261 nGy h^?1 and radiogenic heat production values were calculated in the range of 0.45–6.53 μW m^?3. All rock samples used in this study were also analysed mineralogically and defined their compositions.     

Levels of heavy metals in outdoor and indoor dusts in Muscat,Oman

The concentrations of lead, copper, nickel, zinc and chromium in outdoor and indoor dusts collected from different sites in Muscat, Oman, were determined by flame atomic absorption. Results showed a wide range of concentrations, the means in the outdoor dust being, 65?±?50, 124?±?316, 47?±?45, 930?±?666 and 64?±?26 mg kg^??1 for lead, zinc, copper, nickel and chromium, respectively. The 2001 Omani phasing out of leaded fuel resulted in low levels of lead in outdoor dust compared to those reported in the literature. Outstanding was the high nickel concentration in outdoor dust when compared to that in the literature, the reason being natural soil pollution due to the local geology of the northern parts of Oman. The concentrations of chromium, copper and zinc are lower than or comparable to these in other cities around the world. The results also showed that the industrial activities in Muscat do not contribute significantly to metal pollution in street dusts.

On the other hand, the mean concentrations of lead, zinc, copper, nickel and chromium in indoor dust were 108?±?65, 753?±?1162, 108?±?91, 130?±?125 and 34?±?14 mg kg^??1, respectively. In general, zinc and nickel levels are higher than those reported in the literature while lead, copper and chromium levels are lower or comparable.

When outdoor and indoor dusts were correlated, the ratios between indoor–outdoor mean concentrations revealed that lead, zinc, and copper were generated internally, while nickel and chromium were from external sources.     

A decade’s (2014–2024) perspective on cassava’s (Manihot esculenta Crantz) contribution to the global hydrogen cyanide load in the environment

In recent years, developing countries have increased their cassava (Manihot esculenta) production for food security. Cassava contains cyanogen glycosides, mainly as linamarin, which through bio-catalysis, i.e. enzyme hydrolysis, results in hydrogen cyanide (HCN). HCN is released into the environment through numerous ways with subsequent volatilisation. Thus, the HCN released during the period 2002–2013 was estimated between 0.025?×?10^?3 to 6.71 ppq (African), 0.012?×?10^?3 to 1.01 ppq (Asian) and 0.007?×?10^?3 to 0.920?×?10^?3 ppq (South American). Furthermore, a decade’s (2014–2024) projection of HCN volatilisation displays increases of 60.5% (Africa), 57.7% (Asia) and 50.5% (South America) when compared with the current production. Furthermore, gas released during cassava plants’ growth, i.e. HCN, NH₃, and NO₂, was quantified in healthy plants. Varying concentrations of HCN were released. These further indicated the presence of a pseudo-halogenic gas in the environment – a contributor to climate change.     

Meta-analysis of indoor temperatures in new-build housing

ABSTRACT

Despite growing concerns about overheating, a lack of evidence exists on the scale of the problem, particularly in contemporary UK housing. This paper presents the results of a meta-analysis of indoor temperatures in selected low-energy housing. Temperature data recorded at five-minute intervals in 60 dwellings across 19 demonstration projects (2012–14) were collated and analysed to investigate the prevalence of overheating. Findings evidence high summertime temperatures, with 27% of living rooms exceeding 28°C during August. Based on the Chartered Institution of Building Services Engineers (CIBSE) threshold of 5% annual occupied hours > 25°C, 57% of bedrooms and 75% of living rooms were classified as having overheated. Overall, 30% of living rooms exceeded the adaptive comfort threshold of > 3% occupied hours ΔT?≥?1?K. The results suggest a fundamental relationship between ventilation and indoor temperatures. The higher minimum and average summertime temperatures observed in mechanical ventilation with heat recovery (MVHR) homes (p?<?0.05) and lower temperature range (p?<?0.001) suggest the need for greater attention to adequate summertime ventilation provision in airtight homes. The results demonstrate a high prevalence of overheating in exemplary housing, indicating the need for greater efforts to ensure the effective implementation of strategies to minimize overheating and improve ventilation in low-energy homes.     

Performance assessment of empirical models for prediction of daily and monthly average global solar radiation: the case study of Ibadan,Nigeria

In this study, the performance assessment of empirical models for modelling global solar radiation in Ibadan is presented. The empirical models are derived from the three basic models: Angstrom–Prescott model, Garcia model and Hargreaves–Sammani model. The data used in the analysis consist of daily average global solar radiation, daily average sunshine hours, daily average maximum temperature and daily average minimum temperature collected over a period of nine years (2000–2008). Regression constants are determined for each of the model for each months of the year. The study reveals that Garcia Quadratic model puts up the best overall performance. The model can predict the daily average global solar irradiation with Mean Absolute Error of 1.86?MJ?m^?2?day^?1, Root Mean Square Error of 2.7?MJ?m^?2?day^?1, Mean Absolute Percentage Error 9.34% and Coefficient of Determination (R²) of 0.68.     

Matrix versus fracture permeability in a regional sandstone aquifer (Wajid sandstone,SW Saudi Arabia)

Sandstones are often characterized as fractured aquifers. We present a case study of the Wajid sandstone, which forms a regional aquifer system in SW Saudi Arabia, where matrix, fracture, and large-scale hydraulic conductivities are coincident. The measurements deal with different scales and methods and are based on porosity and permeability measurements in the laboratory, as well as pumping tests in the field. Porosities of the sandstone samples in general are high and range between less than 5?% and more than 45?%. Gas permeabilities for strongly cemented samples are <?1 mD, whereas most samples range in between 500 and 5,000 mD. There is only a weak anisotropy with preference of the horizontal x-, y-directions. Hydraulic conductivities of the matrix samples (5.5?·?10^?6 m/s and 1.1?·?10^?5 m/s for the Upper and Lower Wajid sandstone, respectively) were in the same order of magnitude compared to hydraulic conductivities derived from pumping tests (8.3?·?10^?5 m/s and 2.2?·?10^?5 m/s for the Upper and Lower Wajid sandstone, respectively).     

A comparative performance analysis of solar heat exchangers for solar hot water application under controlled laboratory conditions

The paper presents the experimental performance evaluation of a novel retrofit heat exchanger (‘SolaPlug’) developed for solar hot water storage applications. The performance of this system was compared with a traditional dual-coil (‘Coil’) solar cylinder under controlled operating conditions. The tests were conducted under different solar-simulated conditions with a 30 and 20 evacuated tube collector. The results showed that after a 6-h test period, the average water temperatures within the store for the ‘SolaPlug’ system were 58.8°C and 40.5°C at 860 and 459?W?m^?2, respectively, and for the ‘Coil’ system were 60.5°C and 40.6°C when a 30 tube collector was used. The performance of the ‘SolaPlug’ system was marginally better than the ‘Coil’ system under the low solar input condition. Under high insolation condition, the overall ‘SolaPlug’ system efficiency was found to be 4.3% lower than that of the ‘Coil’ system. The ‘SolaPlug’ heat exchanger rating was 222?W?K^?1.     

The use of indigenous coal reserves for the removal of lead(II) from the aquatic environment by adsorption

Activated carbon was prepared as an adsorbent from low cost Lakhra coal (LC) (Lignite grade) by chemical activation for the removal of Pb(II) from aqueous solution. The variables of pH, adsorbent dose, agitation time, ionic strength and temperature were investigated. The sorption process followed pseudo-first-order kinetics, intra-particle diffusion and Langmuir isotherm models. Evaluation of thermodynamic parameters affirmed the spontaneity of the process. The study also included the surface properties of activated Lakhra coal (ALC) by FTIR, scanning electron microscope and energy dispersive spectroscopy. The maximum Pb(II) removal capacity of ALC was 758?±?8?mg?g^?1 at 32?°C, approximately 300 times higher than without activation. This value was higher than other previously reported values. Thus, this study demonstrated that indigenous LC has excellent potential to be used as an economically feasible adsorbent after activation for the treatment of wastewater bearing Pb(II).     

Zur Absch?tzung von W?rmeleitf?higkeiten der oberfl?chennahen Lockergesteinsschichtenfolge in Norddeutschland

In the course of a groundwater investigation program in east Schleswig-Holstein, groundwater temperature measurements were performed in groundwater observation wells. First, the heat flux density of the investigation area was determined. The heat flow ranged from 20 to 77?mW?m^?2. Near the boundaries of the area, subsurface salt structures cause an increase in heat flow to the earth’s surface. In the centre of this region the heat flow is due to convective processes, and is somewhat low. Here the groundwater recharge as well as the influx from top to bottom affects the temperature field. By means of heat flux densities and the measured temperature gradients, the thermal conductivity was estimated. For clays in the study area the thermal conductivity averaged 1.4?W?m^?1?K^?1 ranging between 1.1 and 1.7?W?m^?1?K^?1. For the coarse grained sand the conductivity was 3.0?W?m^?1?K^?1 and for the fine sands it was 2.8?W?m^?1?K^?1. Due to its heterogeneity, the thermal conductivity of the till ranged between 1.6 and 2.8?W?m^?1?K^?1, depending on the mineralogical composition, the bulk density and the water content of the till. The average thermal conductivity was 2.1?W?m^?1?K^?1.     

Assessment of heavy metals contamination and its effects on oyster (Saccostrea cucullata) biometry parameters in the Asaluyeh port coasts,Persian Gulf,Iran

The current study examines biometric parameters and concentration of some heavy metals in soft tissues of Saccostrea cucullata in the Asaluyeh coast, Persian Gulf, Iran. The metals concentration in the soft tissue of the Saccostrea cucullata ranged as: Zn: 765–3411 mg kg^?1, Cu: 120.3–580.6 mg kg^?1, Cd: 0.13–3.5 mg kg^?1, As: 0.39–3.3 mg kg^?1, Pb: 0.05–1.64 mg kg^?1, Ni: 0.02–0.44 mg kg^?1, V: 0.06–0.32 mg kg^?1, Cr: 0.02–0.16 mg kg^?1 and Hg: 0.002–0.068 mg kg^?1. The results showed that the concentration of total heavy metals in oysters of the control station (CA) is usually lower. The results also indicated lack of correlation between oyster biometric parameters and bioaccumulated heavy metals, except between Cu and longitudinal diameter (R = 0.77). The concentration of heavy metals is higher than limits recommended by the World Health Organization, except for Cd and Pb.     

Eigenschaften geothermischer Nutzhorizonte im baden-württembergischen und französischen Teil des Oberrheingrabens

The project entitled ?Development of an Internet Based Geothermal System for Germany” includes the design of a geothermal information system for the deep hydrogeothermal resources of Germany. For the first time, hydraulic data from the entire Upper Rhine Graben in Baden-Württemberg and France were collected and interpreted. They give hydraulic conductivities in the geothermal reservoirs of the Hauptrogenstein, Oberer Muschelkalk and Buntsandstein. The mean value of the Hauptrogenstein south of Freiburg is T/H = 1,8?·?10^–6?m/s, and the Oberer Muschelkalk average is T/H = 2,0?·?10^–6?m/s. For the Buntsandstein, the hydraulic conductivity is T/H > 2,4?·?10^–7?m/s. Estimated hydraulic conductivities derived from productivity indices and permeability data are used for further comparative considerations.