Dry matter partitioning and quality of Miscanthus,Panicum, and Saccharum genotypes in Arkansas,USA

The partitioning and quality of aboveground biomass have important ramifications for crop management and biomass conversion. In preliminary studies, Saccharum sp. × Miscanthus sp. hybrids exhibited stubble cold tolerance in west-central Arkansas, unlike Saccharum sp. × Saccharum spontaneum hybrids. The objective was to examine foliar and stem quality of the C₄ grasses Miscanthus sinensis (‘Gracillimus’), Miscanthus x giganteus (Q42641, proprietary), Panicum virgatum (‘Alamo’), and two F₁ hybrids of Saccharum sp. × Miscanthus sp. (US84-1028 and US84-1058) in a field study during 2004 (plant cane) and 2005 (first stubble) near Booneville, AR. Switchgrass produced more stems m^?2 than the other entries both years, and there was little difference in stem number among other entries. Clone US84-1028 yielded more dry mass m^?2 than other entries in plant cane, while switchgrass, US84-1028, and M. x giganteus did not differ in first stubble. Clone US84-1028 also had more stem dry mass and leaf dry mass than other entries both yr. Tissue N concentrations were low for these entries, but leaves contained about twice the N of stems (≤15.2 and 7.8 g kg^?1, respectively). Leaves represented as much as one-third of total biomass, and had large cellulose (≤482 g kg^?1) and lignin (167 g kg^?1) concentrations. The competitively high biomass yield of this small sample of sugarcane alleles should encourage the expansion of the crop beyond its current production regions. Sugarcane and M. x giganteus should be examined in higher-input temperate systems because of their bioenergy potential.     

The influence of CO2 mitigation incentives on profitability of eucalyptus production on clay settling areas in Florida

Fast growing, short-rotation tree crops provide unique opportunities to sequester carbon on phosphate-mined lands in central Florida and, if used as a biofuel, can reduce CO₂ emissions associated with electricity generation. Base case land expectation values (LEVs) of phosphate-mined land under Eucalyptus amplifolia (EA) forestry range from 762 to 6507 $ ha^?1 assuming real discount rates of 10% and 4%, respectively. Assuming 5 $ Mg^?1 C, these LEVs increase from 3% to 24% with incentives for in situ carbon sequestration benefits, or 21% to 73% given in situ carbon sequestration with additional incentives for reducing CO₂ emissions through the use of EA as an energy feedstock. Potential benefits from below-ground C sequestration and mine land reclamation are estimated to be worth an additional 5642–11,056 $ ha^?1.     

Char oxidation study of sugar cane bagasse,cotton stalk and Pakistani coal under 1% and 3% oxygen concentrations

Chars of Sugar cane bagasse (1 & 2), Cotton stalk and low rank Pakistani coal have been studied by TGA under low oxidative environments with O₂ concentrations of 1% and 3%. The maximum reactivity of the chars was found to be greater by a factor of 2 under 3% oxygen compared to 1% O₂ conditions. Overall conversion levels at 3% O₂ for Sugar cane bagasse-2 increased from 63% to 100%, Sugar cane bagasse-1; 54% to 97%, Cotton stalk; 45% to 100% and Pakistani coal; 63% to 90% in comparison to 1% O₂. The maximum average rate of weight loss was found in Region III compared to Region I and II supported by CO/CO₂ FTIR Chemigram analysis. On the other hand, % conversion was maximum in Region II under 1% and 3% O₂ concentration. Overall average rates of weight losses were dependant on O₂ concentration and temperature ranges, however for all the regions % conversion and average weight loss were twice in 3% compared to 1% O₂ concentration. Biomass chars were found to be more reactive than the coal studied here during each region of the oxidation process. Evaluated apparent energy of activations for biomass chars was found within range of 41.2–105.8 kJ mole^?1 under 1%, 46.9–125.6 kJ mole^?1 under 3% compared to coal; 70.3–183.9 kJ mole^?1 under 1% and 83.1–167.4 kJ mole^?1 in 3% O₂ concentration for order of reaction (n) varying between 0.5 ≤ n ≤ 2. From the tests carried under O₂ levels of 1% and 3%, it is possible to give the following sequence to the apparent activation energies under any of the fixed value of n, obtained for the biomasses and coal; Pakistani coal > Cotton stalk > Sugar cane bagasse-2 > Sugar cane bagasse-1.     

Influence of NaCl,Na2SO4 and O2 on power generation from microbial fuel cells with non-catalyzed carbon electrodes and natural inocula

Microbial fuel cells (MFCs) are facing several technological challenges before they can be considered as reliable energy sources. Although several feasible inocula, materials and catalysts have been employed to produce energy, the design of a MFC should be done under realistic conditions: abundant and economic feedstock. In this study, two different MFC designs (parallel plate and tank reactors) are tested with non-catalyzed carbon electrodes and natural inocula. In both approaches cathodic oxygen reduction is performed on two different non-catalyzed carbon materials: carbon fabric and reticulate vitreous carbon. This study shows that power and current densities can be boosted by systematically decreasing the catholyte resistance (by additions of NaCl or Na₂SO₄) and dissolved oxygen concentration. In the parallel plate cell configuration, a mixed culture coming from sludge wastewater was used and power outputs up to 73 mW m^?2 (2867 mW m^?3) coupled to 187 mA m^?2 (anode surface area), were achieved. In the Sediment MFC cell configuration, lagoon sediment was used as both organic source of energy and natural supply of bacteria. Under this approach, the concentration of the organic matter is limited but it is demonstrated that bacteria can be adapted to degrade acetate. Power outputs up to 3.9 mW m^?2 normalized to the anodic electrode footprint area, coupled to 13 mA m^?2 were achieved.     

Kudzu [Pueraria montana (Lour.) Merr. Variety lobata]: A new source of carbohydrate for bioethanol production

We determined the amount of standing biomass of kudzu (Pueraria montana var lobata) in naturally infested fields in Maryland and Alabama, USA. At each site, we evaluated the carbohydrate content of roots, stems, and leaves. For a third site from Georgia, we evaluated the carbohydrate content of kudzu roots of varying diameters. Belowground biomass in Alabama exceeded 13 t ha^?1, and contained an average of 37% fermentable carbohydrates (sucrose, glucose, and starch). Roots from Georgia of all size classes contained over 60% fermentable carbohydrates. Biomass and carbohydrate levels in roots from Maryland were low compared to plants growing in Alabama and Georgia, producing 5 t ha^?1 of roots with 20% non-structural carbohydrate. Stems from Alabama and Maryland contained 1–3% carbohydrates. Based on the yield and carbohydrate content, we estimate wild kudzu stands in Alabama and Georgia could produce 5–10 t ha^?1 of carbohydrate, which would rival carbohydrate production from maize and sugar cane fields. If economical harvesting and processing techniques could be developed, the kudzu infesting North America has the potential to supplement existing bioethanol feedstocks, which could be of significance to the rural economy of the southeastern USA.     

Comparison of physicochemical characteristics and photofermentative hydrogen production potential of wastewaters produced from different olive oil mills in Western-Anatolia,Turkey

Olive oil extraction produces a dark-colored wastewater that contains nutrients that can be further processed using biotechnology, in parallel with treatment for disposal. For instance, olive mill wastewater (OMW) can be used as a substrate for photofermentative hydrogen production by purple bacteria. A comparative study was investigated with several OMW samples from different olive oil mills in Western-Anatolia, Turkey. The composition of OMW varies significantly for each mill; thus, a detailed physicochemical analysis of each sample has been carried out. Subsequently, samples were assessed for their functioning in anaerobic photofermentative hydrogen production by Rhodobacter sphaeroides O.U.001. The highest hydrogen production potential (19.9 m³ m^?3) was obtained by the OMW sample with the highest organic content (mainly acetic acid, 9.71 kg m^?3) and the highest carbon-to-nitrogen (C/N) molar ratio (73.8 M M^?1). The organic content was found to be composed of primarily acetic, aspartic, and glutamic acids. There was a linear relationship between C/N ratio and hydrogen production potential across the different OMW samples. This study is unique due to the wide range of analyses of OMW samples and the comparison of many parameters for hydrogen production from wastewater. The results obtained throughout this study can aid in the design of systems using wastewater for biohydrogen production. Particularly, the C/N ratio was found to be the best parameter for choosing a proper substrate.     

Production of methane by co-digestion of cassava pulp with various concentrations of pig manure

Cassava pulp is a major by-product produced in a cassava starch factory, containing 50–60% of starch (dry basis). Therefore, in this study we are considering its potential as a raw material substrate for the production of methane. To ensure sufficient amounts of nutrients for the anaerobic digestion process, the potential of co-digestion of cassava pulp (CP) with pig manure (PM) was further examined. The effect of the co-substrate mixture ratio was carried out in a semi-continuously fed stirred tank reactor (CSTR) operated under mesophilic condition (37 °C) and at a constant OLR of 3.5 kg VS m^?3 d^?1 and a HRT of 15 days. The results showed that co-digestion resulted in higher methane production and reduction of volatile solids (VS) but lower buffering capacity. Compared to the digestion of PM alone, the specific methane yield increased 41% higher when co-digested with CP in concentrations up to 60% of the incoming VS. This was probably due to an increase in available easily degradable carbohydrates as the CP ratio in feedstock increased. The highest methane yield and VS removal of 306 mL g^?1 VS_added and 61%, respectively, were achieved with good process stability (VFA:Alkalinity ratio < 0.1) when CP accounted for 60% of the feedstock VS. A further increase of CP of the feedstock led to a decrease in methane yield and solid reductions. This appeared to be caused by an extremely high C:N ratio of the feedstock resulting in a deficiency of ammonium nitrogen for microbial growth and buffering capacity.     

Energy policy tools for agricultural residues utilization for heat and power generation: A case study of sugarcane trash in Thailand

Cane trash could viably substitute fossil fuels in heat and power generation projects to avoid air pollution from open burning and reduce greenhouse gas (GHG) emission. It is competitive with bituminous and other agro-industrial biomass. Using cane trash for heat generation project could provide a higher reliability and return on investment than power generation project. The heat generation project could be viable (Financial Internal Rate of Return, FIRR = 36–81%) without feedstock subsidy. With current investment and support conditions, the capacity of 5 MW option of power generation project is the most viable (FIRR = 13.6–15.3%); but 30 MW, 1 MW and 10 MW options require feedstock subsidy 450–1100 Baht/t-cane trash to strengthen financial viability. Furthermore, the revenue from carbon credit sales could compensate the revenue from current energy price adder and increases 0.5–1.0% FIRR of power generation project. Using cane trash for 1 MW power generation could reduce GHG emission 637–861 t CO₂eq and avoid air pollutant emissions of 3.35 kg nitrogen oxides (NO_x), 0.41 kg sulfur oxides (SO_x) and 2.05 kg volatile organic compounds (VOC). Also, 1 t steam generation from cane trash could avoid pollutant emissions of 0.6 kg NO_x, 0.07 kg SO_x, and 0.37 kg VOC. The potential of cane trash to cause fouling/slagging as well as erosion are not significantly different from other biomass, but chlorinated organic compounds and NO_x could be higher than bituminous and current biomass feedstock at sugar mill (bagasse and rice husk).     

Effect of biomass species and plant size on cellulosic ethanol: A comparative process and economic analysis

The effects of five different biomass species and their chemical composition on the overall process efficiency and economic performance considering feedstock availability and feedstock costs to manufacture ethanol from lignocellulose were studied. First is a comparison of ethanol production and excess electricity generated between different biomass species. Results show that, at the same feedstock rate of 2000 Mg day^?1, aspen wood has larger ethanol production than switchgrass, hybrid poplar and corn stover, while the excess electricity generated is as follows in increasing order: aspen < corn stover < hybrid poplar/switchgrass. Second, our results show that the ethanol production is largely linear with holocellulose (cellulose plus hemicellulose) composition of the various biomass species. However, the relationship between excess electricity generated and non-holocellulose combustible component is nonlinear. Last, on environmental performance, it is found that the water losses per unit ethanol production are in the following order: aspen wood < corn stover < hybrid poplar < switchgrass. While corn stover is a potential feedstock to produce cellulosic ethanol with the lowest ethanol production cost at the present time, hybrid poplar and switchgrass are the two promising future energy crops.The effects of plant size analysis showed that the estimated feedstock delivered costs, ethanol production, excess electricity generated and solid and gaseous waste emissions all increase with plant size for the various biomass species. The ethanol production costs decrease with the increase in plant size with optimal plant sizes for corn stover in the range from 2000 dry Mg day^?1 to 4000 dry Mg day^?1.     

Biomass estimates,characteristics, biochemical methane potential,kinetics and energy flow from Jatropha curcus on dry lands

In this study, we examined the production of Jatropha curcus plants on 1 ha of rain fed dry lands. All of the plant components that would result from plantation tending, fruit harvesting and processing were sampled for their yield and chemical composition, and then subjected to the biochemical methane potential (BMP) assay. The component parts exhibited significant variation in BMP which was reflected in their ultimate methane yield which ranged from 0.08 to 0.97 L g^?1 VS added, and their first order kinetics which ranged from 0.07 to 0.14 d^?1. We examined two integrated utilization schemes: the first which converted plant prunings, fruit hulls and de-oiled seed cake to methane, and the oil to fatty acid methyl-ester (FAME); the second was to convert the seeds, plant prunings and fruit hulls entirely to methane. The basis for the plantation was, a density of 4444 plant ha^?1 (1.5 m × 1.5 m spacing), with a seed yield of 0.911 kg TS plant^?1 (1 kg total weight) with an oil content of 35% providing an annual oil yield of 1.42 t y^?1. The corresponding yields of pruned leaves, fruit hulls and de-oiled cake are 0.97, 1.0, and 2.35 t VS ha y^?1, respectively. An integrated scheme of producing biogas by means of anaerobic digestion of the latter components and oil for biodiesel would produce 90 GJ ha^?1 y^?1 in total with the oil being 54 GJ. The alternative biogas only option which would convert the seed oil into methane instead of biodiesel would produce 97 GJ ha^?1 y^?1.     

Utilization of summer legumes as bioenergy feedstocks

Sunn hemp (Crotolaria juncea), is a fast growing, high biomass yielding tropical legume that may be a possible southeastern bioenergy crop. When comparing this legume to a commonly grown summer legume – cowpeas (Vigna unguiculata), sunn hemp was superior in biomass yield (kg ha^?1) and subsequent energy yield (GJ ha^?1). In one year of the study after 12 weeks of growth, sunn hemp had 10.7 Mg ha^?1 of biomass with an energy content of 19.0 Mg ha^?1. This resulted in an energy yield of 204 GJ ha^?1. The energy content was 6% greater than that of cowpeas. Eventhough sunn hemp had a greater amount of ash, plant mineral concentrations were lower in some cases of minerals (K, Ca, Mg, S) known to reduce thermochemical conversion process efficiency. Pyrolytic degradation of both legumes revealed that sunn hemp began to degrade at higher temperatures as well as release greater amounts of volatile matter at a faster rate.     

100 t/a-Scale demonstration of direct dimethyl ether synthesis from corncob-derived syngas

Direct conversion of biomass-derived syngas (bio-syngas) to dimethyl ether (DME) at pilot-scale (100 t/a) was carried out via pyrolysis/gasification of corncob. The yield rate of raw bio-syngas was 40–45 Nm³/h with less than 20 mg/Nm³ of tar content when the feedrate of dried corncob was 45–50 kg/h. After absorption of O₂, S, Cl by a series of absorbers and partial removal of CO₂ by the pressure-swing adsorption (PSA) unit sequentially, the obtained bio-syngas (H₂/CO≈1) was directly synthesized to DME over Cu/Zn/Al/HZSM-5 catalyst in the fixed-bed tubular reactor. CO conversion and DME space-time yield (STY) were 67.7% and 281.2 kg/m_cat³/h respectively at 260 °C, 4.3 MPa and 3000 h^?1(GHSV, syngas hourly space velocity). Synthesis performance would be increased if the tail gas (H₂/CO > 2) was recycled to the reactor when GHSV was 650–3000 h^?1.     

Assessing the influence of four bonding methods on the thermal contact resistance of open-cell aluminum foam

A thermal application of open-cell aluminum foam typically requires it to be bonded on a substrate. The resulting thermal contact resistance is investigated for four bonding methods. This is done by minimizing the difference between the calculated heat transfer via a zeroth order model and experimental data. The bonded metal foam, used to obtain the experimental data, are manufactured in-house. This allows varying pore size, porosity, aluminum alloy, foam height, air mass flow rate, air inlet temperature and bonding method. The latter is found to have an overwhelming impact. The resulting four thermal contact resistances are: 0.7 × 10^?3 m²K/W for brazing, 0.88 × 10^?3 m²K/W for co-casting, 1.25 × 10^?3 m²K/W for a single-epoxy bonding and 1.88 × 10^?3 m²K/W for a press-fit bonding. The uncertainty on these values is 11%.     

An economic analysis of hardwood fiber production on dryland irrigated sites in the US Southeast

Although there is renewed interest in intensively managed, short-rotation plantations as a source of hardwood for pulp mills, few have been established in the Southeast. Understanding all the costs associated with these plantations will help determine their feasibility. Using a model developed to summarize all the costs, a break-even analysis was completed to determine the delivered cost for plantations of eastern cottonwood (Populus deltoides Bartr.) from a hypothetical fiber farm in 2003. Using current yield from an experimental fiber farm, short-rotation cottonwood plantations were not cost effective, as delivered cost to a pulp mill averaged 78$ t⁻¹. If yield can be increased by 40% through improvements in genetics and silvicultural practices, delivered cost is reduced to 60$ t⁻¹. Thus, finding this additional yield is key to the cost feasibility of intensively managed, short-rotation hardwood plantations.     

Engineering,nutrient removal,and feedstock conversion evaluations of four corn stover harvest scenarios

Crop residue has been identified as a near-term source of biomass for renewable fuel, heat, power, chemicals and other bio-materials. A prototype one-pass harvest system was used to collect residue samples from a corn (Zea mays L.) field near Ames, IA. Four harvest scenarios (low cut, high-cut top, high-cut bottom, and normal cut) were evaluated and are expressed as collected stover harvest indices (CSHI). High-cut top and high-cut bottom samples were obtained from the same plot in separate operations. Chemical composition, dilute acid pretreatment response, ethanol conversion yield and efficiency, and thermochemical conversion for each scenario were determined. Mean grain yield in this study (10.1 Mg ha⁻¹ dry weight) was representative of the average yield (10.0 Mg ha⁻¹) for the area (Story County, IA) and year (2005). The four harvest scenarios removed 6.7, 4.9, 1.7, and 5.1 Mg ha⁻¹ of dry matter, respectively, or 0.60 for low cut, 0.66 for normal cut, and 0.61 for the total high-cut (top+bottom) scenarios when expressed as CSHI values. The macro-nutrient replacement value for the normal harvest scenario was $57.36 ha⁻¹ or $11.27 Mg⁻¹. Harvesting stalk bottoms increased stover water content, risk of combine damage, estimated transportation costs, and left insufficient soil cover, while also producing a problematic feedstock. These preliminary results indicate harvesting stover (including the cobs) at a height of approximately 40 cm would be best for farmers and ethanol producers because of faster harvest speed and higher quality ethanol feedstock.     

Mathematical modeling of thin-layer drying of fermented and non-fermented sugarcane bagasse

This work reports hot-air convective drying of thin-layer fermented and non-fermented sugarcane bagasse. For this purpose, experiments were carried out in a laboratory-scale dryer assessing the effects of solid-state fermentation (SSF) on the drying kinetics of the processing material. The fermented sugarcane bagasse in SSF was obtained with the use of Kluyveromyces marxianus NRRL Y-7571. Drying experiments were carried out at 30, 35, 40 and 45 °C, at volumetric air flow rates of 2 and 3 m³ h^?1. The ability of ten different thin-layer mathematical models was evaluated towards representing the experimental drying profiles obtained. Results showed that the fermented sugarcane bagasse presents a distinct, faster drying, behavior from that verified for the non-fermented material at the same conditions of temperature and volumetric air flow rate. It is shown that the fermented sugarcane bagasse presented effective diffusion coefficient values of about 1.3 times higher than the non-fermented material. A satisfactory agreement between experimental data and model results of the thin-layer drying of fermented and non-fermented sugarcane bagasse was achieved at the evaluated experimental conditions.     

Low temperature anaerobic digestion of mixtures of llama,cow and sheep manure for improved methane production

Biogas production in anaerobic digestion in farm-scale units is typically performed under mesophilic conditions when used for producing domestic fuel and stabilizing animal waste for the use of digested manure as a fertilizer. Previous studies on the digestion of llama and cow manure have shown the feasibility of producing biogas under altiplano conditions (low pressure and low temperature) and of llama manure as a promising feedstock. The present study concerns the utilization of various mixtures of feedstocks from the Bolivian altiplano under low temperature conditions (18–25 °C). Laboratory scale experiments were performed on the digestion of mixtures of llama, sheep and cow manure in a semi-continuous process using ten 2-L stainless steel digesters to determine the effects of organic loading rate (OLR) and the feed composition. The semi-continuous operation of mixture of llama–cow–sheep manure proved to be a reliable system, which could be operated with good stability. The results suggest that in a system digesting a mixture of llama-cow-sheep manure at low temperature (18–25 °C) the maximum OLR value is between 4 and 6 kg VS m³ d^?1. The methane yields obtained in the mixture experiments were in the range 0.07–0.14 m³ kg^?1 VS added, with a methane concentration in the gas of between 47 and 55%.     

Potential of geothermal heat exchangers for office building climatisation

Low depth geothermal heat exchangers can be efficiently used as a heat sink for building energy produced during summer. If annual average ambient temperatures are low enough, direct cooling of a building is possible. Alternatively the heat exchangers can replace cooling towers in combination with active cooling systems. In the current work, the performance of vertical and horizontal geothermal heat exchangers implemented in two office building climatisation projects is evaluated.A main result of the performance analysis is that the ground coupled heat exchangers have good coefficients of performance ranging from 13 to 20 as average annual ratios of cold produced to electricity used. Best performance is reached, if the ground cooling system is used to cool down high temperature ambient air. The maximum heat dissipation per meter of ground heat exchanger measured was lower than planned and varied between 8 W m^?1 for the low depth horizontal heat exchangers up to 25 W m^?1 for the vertical heat exchangers.The experimental results were used to validate a numerical simulation model, which was then used to study the influence of soil parameters and inlet temperatures to the ground heat exchangers. The power dissipation varies by ±30% depending on the soil conductivity. The heat conductivity of vertical tube filling material influences performance by another ±30% for different materials. Depending on the inlet temperature level to the ground heat exchanger, the dissipated power increases from 2 W m^?1 for direct cooling applications at 20 °C up to 52 W m^?1 for cooling tower substitutions at 40 °C. This directly influences the cooling costs, which vary between 0.12 and 2.8€ kW h^?1.As a result of the work, planning and operation recommendations for the optimal choice of ground coupled heat exchangers for office building cooling can be given.     

Implementation of an UASB anaerobic digester at bagasse-based pulp and paper industry

Upflow anaerobic sludge blanket (UASB) reactor was installed to replace the conventional anaerobic lagoon treating bagasse wash wastewater from agro-based pulp and paper mill, to generate bio-energy and to reduce greenhouse gas emissions. The plant was designed to treat 12 ML d⁻¹ of wastewater having two 5 ML capacity reactors, 5.75 kg COD m⁻³ d⁻¹ organic loading rate and 20 h hydraulic retention time. In the plant 80–85% COD reduction was achieved with biogas production factor of 520 L kg⁻¹ COD reduced. In 11 months 4.4 million m³ of biogas was generated from bagasse wash wastewater utilizing UASB process. Utilization of the biogas in the Lime Kiln saved 2.14 ML of furnace oil in 9 months. Besides significant economic benefits, furnace oil saving reduced 6.4 Gg CO₂ emission from fossil fuel and conversion of the anaerobic lagoon into anaerobic reactor reduced 2.1 Gg methane emission which is equal to 43.8 Gg of CO₂.     

Comparison of numerical and experimental performance criteria of an ammonia–water bubble absorber using plate heat exchangers

A mathematical model for ammonia–water bubble absorbers was developed and compared with experimental data using a plate heat exchanger. The analysis was performed carrying out a sensitive study of selected operation parameters on the absorber thermal load and mass absorption flux. Regarding the experimental data, the values obtained for the solution heat transfer were in the range 0.51–1.21 kW m^?2 K^?1 and those of the mass absorption flux in the range 2.5–5.0 × 10^?3 kg m^?2 s^?1. The comparison between experimental and simulation results was acceptable being the maximum difference of 11.1% and 28.4% for the absorber thermal load and the mass absorption flux, respectively.