环保型GSF胶结料水化硬化机理研究

GSF胶结料是利用石膏尾矿、高炉矿渣、粉煤灰等工业废渣与少量激发剂混合配制的一种新型胶凝材料。着重研究了GSF胶结料水化动力学特征、水化产物和硬化机理,研究表明GSF胶结料水化硬化机理有别于普通硅酸盐水泥。     

粉状耐酸胶结料配制的耐酸混凝土及密实机理

采用耐酸胶结料、粉料和骨料配制了耐酸混凝土，研究了混凝土的强度及耐酸性能，探讨了耐酸胶结料的固化硬化密实机理．研究表明，采用粉状耐酸胶结料配制的耐酸混凝土强度可达32．8MPa，高于采用液体水玻璃配制的混凝土强度(25．1MPa)，并具有良好的耐酸性和抗高温性能．     

煅烧猛渣取代水泥胶结料水化机理

本文借助Ｘ射线衍射、差热分析等试验手段，分析了煅烧锰渣取代水胶结料的水水化产物，剖析了其强度形成和稳定发展的机理。     

磷石膏矿渣胶结材料性能的研究

本文采用正交试验法较系统地研究了磷石膏矿渣化，石灰，硫酸钠，硫酸亚铁等因素对胶结材的强度的影响，找出了影响胶结材强度的主要因素和生产的最佳条件，并对该胶结材的性能和水化硬化特点进行了初步探讨。     

水泥强度诱导提高方法研究

利用物理性能检测、水化放热测定和孔结构测定方法研究了通过掺加微细矿渣、高铝组分和水化硬化浆体诱导提高硅酸盐水泥强度的方法，并对其作用机理进行了探讨，试验表明，适量的微细高铝组分、矿渣组分及水化硬化浆体能够明显提高硅酸盐水泥强度。     

高水速凝固结材料性能和硬化机理研究

研究了高水材料性能的影响因素。运用ＸＲＤ、ＴＧ－ＤＴＡ、ＳＥＭ等研究了高水材料的水化和硬化机理。分析了石膏、生石灰等对高水材料性能影响的机理,以及非结合水在高水材料硬化浆体结构中的作用。     

金矿尾矿胶结充填用胶凝材料的制备及其性能表征

以矿渣微粉、水泥(P.O 42.5)、粉煤灰、氧化钙和硫酸钙为原料制备早强型尾矿胶结胶凝材料(尾矿胶结料),将尾矿胶结料用于胶结充填中位直径D_(50)为11.3μm的金矿细粒尾矿,表征分析充填试样的力学性能与流动性能。结果表明:相同胶砂质量比和尾矿浆固含量下,用尾矿胶结料胶结固化尾矿的效果优于P.O 42.5水泥;胶砂质量比1∶12时,充填试样28 d抗压强度为P.O 42.5水泥的4.9倍,尾矿胶结料的水化产物量高于P.O 42.5水泥;尾矿胶结料的胶砂质量比为1∶6、尾矿浆固质量分数为70%时,加入0.15%(质量分数)聚羧酸减水剂的充填料浆坍落度为278 mm,其力学性能和充填流动性能均可满足矿山充填要求。     

高水速凝固结材料性能和硬化机理研究

研究了高水材料性能的影响因素。运用ＸＲＤ、ＴＧ－ＤＴＡ、ＳＥＭ等研究了高水材料的水化和硬化机理,分析了石膏、生石灰等对高水材料性能影响的机理,以及非结合水在高水材料硬化浆体结构中的作用。     

DGF胶结材耐水性研究

脱硫石膏粉煤灰胶结材是以未经煅烧的脱硫石膏和粉煤灰为主要原料配制的新型宫基胶结材。它具有比石膏制品高的强度和耐水性。本文依据ＸＲＤ，ＳＥＭ／ＥＤＸＡ的测试结果，从水化产物和硬化体的微观结构阐述了这种胶结材耐水性较好的原因。     

Na2C2O4对硬石膏水化硬化的影响及作用机理

研究了草酸钠对硬石膏水化进程、硬化体显微结构与强度、液相离子浓度与二水石膏析晶过饱和度的影响,从二水石膏晶体成核与生长的角度探讨了草酸钠的作用机理.草酸钠使硬石膏水化率提高,水化热集中,水化潜伏期缩短,水化进程加快;草酸钠使二水石膏晶体细化,硬化体结构致密,强度提高,是硬石膏水化活性的高效激发剂.草酸钠作用机理归纳为：草酸钠与硬石膏反应形成草酸钙沉淀与可溶硫酸盐,使液相SO2-4浓度大幅提高;提高二水石膏析晶过饱和度,使二水石膏临界晶核半径减小,晶体成核与生长速率加快;草酸钠促进硬石膏溶解.     

Comparison of hydration properties between cement-GGBS-fly ash blended binder and cement-GGBS-steel slag blended binder

The hydration properties of cement-GGBS-fly ash blended binder and cement-GGBS-steel slag blended binder were compared. The experimental results show that the hydration rate of cement-GGBS- steel slag blended binder is higher than that of cement-GGBS-fly ash blended binder within 28 days, but lower than the latter after 28 days. The hydration of cement-GGBS-steel slag blended binder tends to produce more Ca（OH）2 than the hydration of cement-GGBS-fly ash blended binder, especially at late ages. Cement-GGBS- steel slag mortar exhibits higher strength than cement-GGBS-fly ash mortar within 28 days, but at late ages, it exhibits similar compressive strength with eement-GGBS-fly ash mortar and even slightly lower bending strength than cement-GGBS-fly ash mortar. Cement-GGBS-steel slag paste has finer early pore structure but coarser late pore structure than cement-GGBS-fly ash paste. Cement-GGBS-steel slag paste can get satisfied late pore structure and cement-GGBS-steel slag mortar can get satisfied late strength as compared with pure cement paste and pure cement mortar, respectively.     

粉煤灰混凝土绝热温升的试验研究

目的 研究不同粉煤灰的掺量和不同水肢比条件下粉煤灰混凝土的绝热温升和胶凝材料水化速率的发展规律．方法 利用混凝土绝热温升仪测试混凝土绝热温升．结果 在水胶比0．53条件下，混凝土的绝热温升值随着粉煤灰掺量的增加而下降；在水胶比0．25条件下。绝热温升值先随着粉煤灰掺量的增加而增大，当掺量达40％以后绝热温升值开始下降。混凝土中胶凝材料的水化速率峰值随粉煤灰掺量增加而下降．结论 粉煤灰混凝土的绝热温升受水胶比和粉煤灰掺量共同影响，低水胶比条件下只有适当增加粉煤灰的掺量才能降低粉煤灰混凝土的绝热温升；高水胶比条件下。粉煤灰混凝土的绝热温升随粉煤灰掺量增加而下降。     

复合胶凝材料钢管混凝土拱肋水化过程截面温度场试验及数值模拟分析

针对复合胶凝材料钢管混凝土拱肋水化过程,对混凝土水化热作用下的钢管拱肋截面温度场进行了连续试验观测,以热传导理论结合有限元方法建立了钢管混凝土水化热分析模型,并进行了数值模拟分析。研究考虑了初始条件下水泥水化热的计算模型,并讨论了钢管厚度、管径等参数对钢管混凝土拱肋成型过程截面温度特性的影响。结果表明,对于复合胶凝材料钢管混凝土水化热的计算模型采用双曲线函数式较为合理;钢管拱壁厚对其截面温度场的影响较小,最大差值在2～3℃,而管径的大小对其影响较大,最大差值达20℃。     

适用于聚羧酸减水剂的混凝土激发剂研究

提出一种适用于聚羧酸减水剂的复合矿物混凝土激发剂,研究了在不同养护条件、不同掺量下,激发剂对混凝土工作性能及各龄期强度的影响,结合XRD,SEM物相检测探讨了激发剂作用机理,并在连江可门港口泊位工程中试用,测试了掺激发剂混凝土的耐久性能.宏观测试结果表明所研激发剂I型对混凝土工作性能影响不大,能够提高混凝土早期强度,且对后期强度及长期耐久性能无不良影响;微观分析表明激发剂I型的掺入加速了C2S,C3S等矿物的水化,并激发了粉煤灰、矿粉的二次水化反应,混凝土强度发展拐点提前出现.     

Influence of Binder Composition and Concrete Pore Structure on Chloride Diffusion Coefficient in Concrete

The influence of binder composition and pore structure of concrete on chloride diffusion coefficient in concrete were investigated by the natural immersion test, MIP test, SEM and EDS test, respectively. The experimental results showed that the effect of binder composition on chloride diffusion coefficient was the comprehensive result of concrete pore structure and binder hydration products, and the porosity and pore size distribution were the main factors that influence the changes of diffusion coefficient...     

Properties and mechanism of mine tailings solidified and filled with fluorgypsum-based binder material

The properties and microscopic structure of tailings solidification bodies, the hardening mechanism of the fluorgypsum-based binder material (FBBM) and tailings solidification mechanism were investigated. FBBM consisted of 40% fluorgypsum,25%-50% blast furnace slag,10%-35% ordinary Portland cement clinker(OPCC) and 1% activator, which was good material in binding iron ore tailings.XRD analysis showed that the properties of tailings solidification bodies was related to its ettringite content.SEM and XRD analyses of tailings solidification bodies showed that the chemical reaction was produced between FBBM and tailings in the whole hydration process. The hydration of the resulting gel material covered the surface of the tailings particles and formed a gel structure. A large number of ettringite crystals and the remaining board-like gypsum crystals took each end and constituted the structural skeleton. The filamentous network-like calcium-silicate-hydrate(C-S-H) gel bonded firmly together with ettringite crystals, dehydrated gypsum crystals and granular tailings, and formed an extremely dense whole.     

硅酸盐-硫铝酸盐水泥混合体系的试验研究

研究了不同比例的硅酸盐、硫铝酸盐水泥混合体系的凝结时间、水泥砂浆的强度性能,并对一定混合比例的OPC-SAC水泥进行了XRD、SEM和水化量热测试。结果表明,硅酸盐水泥与硫铝酸盐水泥混合,SAC中的C4A3-S矿物与OPC中的C3S矿物在共同水化过程中有相互促进的作用,会使混合水泥水化和凝结加速;混合水泥的强度性能与两种水泥的混合比例有关。本研究可对硅酸盐-硫铝酸盐水泥混合体系的应用提供借鉴。     

Activation of anhydrate phosphogypsum by K<Subscript>2</Subscript>SO<Subscript>4</Subscript> and hemihydrate gypsum

Lime pretreated phosphogypsum(PG) was calcined at 500 ℃ to produce anhydrate gypsum cement. Due to the slow hydration of anhydrate gypsum, additives, K2SO4 and hemihydrate gypsum were selected to accelerate the hydration of anhydrate. The hydration characteristics, the resistance to hydrodynamic water, and the mineralogical studies were investigated. The experimental results suggest that activated by K2SO4 and hemihydrate, anhydrate PG hydrates much more rapidly than that in the presence of only K2SO4 or in the absence of additives. The binder has proper setting time, good strength development, and relatively better resistance to water. The hardened binder has hydrated products of rod or stick like shaped dihydrate gypsum crystals.     

Influence of colloidal nanosilica on hydration kinetics and properties of CaO/CaSO4-activated slag binder

To solve the energy consumption and CO₂ emission during cement production, the new binders must be developed as an alternative to cement. CaO/CaSO₄-activated slag binder is an eco-friendly and safe cementitious material; however, its low strength during initial stages limits its applications. In this study, colloidal nanosilica (CNS) was employed as an additive to improve the strength of CaO/CaSO₄-activated slag binder, and the effects of CNS on the workability, hydration kinetics, hydration products (type, quantity, and polymerization degree), and binder microstructure were thoroughly investigated. A moderate CNS content, through its nucleation effect, significantly increased the hydration rate of the nucleation and crystal growth (NG), phase boundary interaction (I) and diffusion (D) processes, which generated large quantities of calcium aluminosilicate hydrate (C-A-S-H) gel in the initial hydration stage. Meanwhile, the addition of CNS improved the polymerization degree of C-A-S-H gel. This amorphous reactant well-filled the pore space between slag particles and yielded a compact microstructure, consequently enhancing the binder strength. Considering the reduction in fluidity and the increase in production cost, the CNS mass fraction was controlled as ～3%, and the binder reached the satisfactory strengths of 3.87, 24.47, 31.43, and 41.78 MPa at 1, 3, 7, and 28 d, respectively.     

Correlative mechanism of hydraulic-mechanical property in cemented paste backfill

Hydraulic characteristic is a good indication of binder hydration, which determines the strength development of cemented paste backfill (CPB). Therefore, the hydraulic characteristic should be communicated with the mechanical property to provide an advanced knowledge that can help mine workers make a rational strategy and reduce the mining cycle. An experimental program was performed to obtain the hydraulic (monitored by suction and volumetric water content) and mechanical properties (unconfined compressive strength (UCS) test) of CPB at the 28 days curing age. According to the monitoring and testing results, the relationships between the hydration reaction rate and volumetric water content (VWC), suction and VWC, suction and UCS were established. The hydration degree showed a liner rise as the VWC decreased. Curves of the VWC and UCS were featured with a nonlinear reduction and nonlinear growth (both are exponential functions) as the suction rising, respectively. These established relationships validated the strong correlative mechanism of hydraulic and mechanics behavior for CPB. Also, the results of the present research indicated that the hydraulic characteristics and mechanical property were strongly coupled. These correlations and couplings will be of great importance to understand the hardening process of CPB and bring to a safe CPB field operation.