The origin of high δ<Superscript>18</Superscript>O zircons: marbles,megacrysts, and metamorphism

The oxygen isotope ratios (δ¹⁸O) of most igneous zircons range from 5 to 8‰, with 99% of published values from 1345 rocks below 10‰. Metamorphic zircons from quartzite, metapelite, metabasite, and eclogite record δ¹⁸O values from 5 to 17‰, with 99% below 15‰. However, zircons with anomalously high δ¹⁸O, up to 23‰, have been reported in detrital suites; source rocks for these unusual zircons have not been identified. We report data for zircons from Sri Lanka and Myanmar that constrain a metamorphic petrogenesis for anomalously high δ¹⁸O in zircon. A suite of 28 large detrital zircon megacrysts from Mogok (Myanmar) analyzed by laser fluorination yields δ¹⁸O from 9.4 to 25.5‰. The U–Pb standard, CZ3, a large detrital zircon megacryst from Sri Lanka, yields δ¹⁸O = 15.4 ± 0.1‰ (2 SE) by ion microprobe. A euhedral unzoned zircon in a thin section of Sri Lanka granulite facies calcite marble yields δ¹⁸O = 19.4‰ by ion microprobe and confirms a metamorphic petrogenesis of zircon in marble. Small oxygen isotope fractionations between zircon and most minerals require a high δ¹⁸O source for the high δ¹⁸O zircons. Predicted equilibrium values of Δ¹⁸O(calcite-zircon) = 2–3‰ from 800 to 600°C show that metamorphic zircon crystallizing in a high δ¹⁸O marble will have high δ¹⁸O. The high δ¹⁸O zircons (>15‰) from both Sri Lanka and Mogok overlap the values of primary marine carbonates, and marbles are known detrital gemstone sources in both localities. The high δ¹⁸O zircons are thus metamorphic; the 15–25‰ zircon values are consistent with a marble origin in a rock-dominated system (i.e., low fluid_(external)/rock); the lower δ¹⁸O zircon values (9–15‰) are consistent with an origin in an external fluid-dominated system, such as skarn derived from marble, although many non-metasomatized marbles also fall in this range of δ¹⁸O. High δ¹⁸O (>15‰) and the absence of zoning can thus be used as a tracer to identify a marble source for high δ¹⁸O detrital zircons; this recognition can aid provenance studies in complex metamorphic terranes where age determinations alone may not allow discrimination of coeval source rocks. Metamorphic zircon megacrysts have not been reported previously and appear to be associated with high-grade marble. Identification of high δ¹⁸O zircons can also aid geochronology studies that seek to date high-grade metamorphic events due to the ability to distinguish metamorphic from detrital zircons in marble.     

Sedimentary dynamics and ecological state of Nakta tidal flat （littoral）, South of Sfax, Gulf of Gabès, Tunisia）

The tidal flat of Nakta is located in the northern part of the gulf of Gabes and in the southern coast of Sfax. It corresponds to a flat reef protected from less topography, with a slope ranging between 2° and 4°, which borders the Gargour Wadi. The study sector is renowned to have moderate hydrodynamics which lasts almost for two millenary （14C isotopic dating）. The sedimentological study of the Nakta tidal flat revealed different facies： fine-grained sand in the intertidal zone and carbonated muddy sand in the infratidal zone. Equilibrium state of the Nakta ecosystem depends entirely on tide currents, which mainly inhibit drift currents. The Nakta tidal flat is characterized by a variety of faunal species （Cerastoderma glaucum, Arca hoe, Cardita antiquatus, Chlamys varied, Ruditapes deccussatus, Tapes rhomboids, Pinctada radiate, etc.） and floristic diversities （Halocnemum strobilacum, Halimione portulacoides, Enteromorpha linza, Ulva rigida, Cymodocea nodosa, Posidonia oceanica）. The species are abundant in the infratidal zone, while in its intertidal zone, faunal species remain little diversified and are dominated by limivorous diggering. The paleogeographic study of the Nakta tidal flat showed the alternation of regression and transgression periods.     

Spectroscopic studies of synthetic and natural ringwoodite, γ-(Mg,Fe)<Subscript>2</Subscript>SiO<Subscript>4</Subscript>

Synthetic ringwoodite γ-(Mg_1?x Fe _x )₂SiO₄ of 0.4 ≤ x ≤ 1.0 compositions and variously colored micro-grains of natural ringwoodite in shock metamorphism veins of thin sections of two S6-type chondrites were studied by means of microprobe analysis, TEM and optical absorption spectroscopy. Three synthetic samples were studied in addition with Mössbauer spectroscopy. The Mössbauer spectra consist of two doublets caused by ^VIFe²⁺ and ^VIFe³⁺, with IS and QS parameters close to those established elsewhere (e.g., O’Neill et al. in Am Mineral 78:456–460, 1993). The Fe³⁺/Fe_total ratio evaluated by curve resolution of the spectra, ranges from 0.04 to 0.1. Optical absorption spectra of all synthetic samples studied are qualitatively very similar as they are directly related to the iron content. They differ mostly in the intensity of the observed absorption features. The spectra consist of a very strong high-energy absorption edge and a series of absorption bands of different width and intensity. The three strongest and broadest absorptions of them are attributed to splitting of electronic spin-allowed ⁵ T _2g → ⁵ E _g transitions of ^VIFe²⁺ and intervalence charge-transfer (IVCT) transition between ferrous and ferric ions in adjacent octahedral sites of the ringwoodite structure. The spin-allowed bands at ca. 8,000 and 11,500 cm^?1 weakly depend on temperature, whilst the Fe²⁺/Fe³⁺ IVCT band at ~16,400 cm^?1 displays very strong temperature dependence: i.e., with increasing temperature it decreases and practically disappears at about 497 K, a behavior typical for bands of this type. With increasing pressure the absorption edge shifts to lower energies while the spin-allowed bands shift to higher energy and strongly decreases in intensity. The IVCT band also strongly weakens and vanishes at about 9 GPa. We assigned this effect to pressure-induced reduction of Fe³⁺ in ringwoodite. By analogy with synthetic samples three broad bands in spectra of natural (meteoritic) blue ringwoodite are assigned to electronic spin-allowed transitions of ^VIFe²⁺ (the bands at ~8,600 and ~12,700 cm^?1) and Fe²⁺/Fe³⁺ IVCT transition (~18,100 cm^?1), respectively. Spectra of colorless ringwoodite of the same composition consist of a single broad band at ca. 12,000 cm^?1. It is assumed that such ringwoodite grains are inverse (Fe, Mg)₂SiO₄-spinels and that the single band is caused by the split spin-allowed ⁵ E → ⁵ T ₂ transition of ^IVFe²⁺. Ringwoodite of intermediate color variations between dark-blue and colorless are assumed to be partly inversed ringwoodite. No glassy material between the grain boundaries in the natural colored ringwoodite aggregates was found in our samples and disprove the cause of the coloration to be due to light scattering effect (Lingemann and Stöffler in Lunar Planet Sci 29(1308), 1998).     

Re–Os and <Superscript>40</Superscript>Ar/<Superscript>39</Superscript>Ar ages of the Jiguanshan porphyry Mo deposit,Xilamulun metallogenic belt,NE China,and constraints on mineralization events

The large Jiguanshan porphyry Mo deposit, with more than 100 Mt of ore and grades ranging from 0.08% to 0.11%, is located in the newly identified Xilamulun metallogenic belt along the northern margin of the North China Craton. The Mo mineralization is predominantly disseminated in the host granite porphyry, but locally occurs as stockworks in lithic tuff and rhyolitic rocks. ⁴⁰Ar/³⁹Ar dates of samples from groundmass material in the host granite porphyry, post-ore diabase, and quartz porphyry dikes show plateau ages of 155.1 ± 1.9, 149.4 ± 0.9, and 147.6 ± 0.9 Ma, with inverse isochron ages of 156.0 ± 1.8, 149.3 ± 1.3, and 148.3 ± 1.2 Ma, respectively. Seven samples of disseminated molybdenite yielded a weighted average ¹⁸⁷Re-¹⁸⁷Os age of 155.3 ± 0.9 Ma, whereas six veinlet-type molybdenite samples yielded a weighted average ¹⁸⁷Re-¹⁸⁷Os age of 153.0 ± 0.9 Ma, providing direct timing constraints for the Mo mineralization at 153–155 Ma. The regional geological setting together with the emplacement of post-ore diabase and quartz porphyry dikes in the Jiguanshan deposit, are indicative of an extensional regime in Late Jurassic, which was probably linked to lithospheric extension in northeast China.     

Abundances of carbon,nitrogen, oxygen,and other elements in the atmospheres of the giants 15 ori and 22 <Emphasis Type="Italic">ɛ</Emphasis> sex

We have used high-resolution spectra to study the giants 15 Ori and 22 ? Sex. The effective temperature T _eff = 7060 K, gravity log g = 3.16, and microturbulence velocity ξ _t = 3.5 km/s were determined for 15 Ori, with T _eff = 7350 K and log g = 3.90 for 22 ? Sex (the microturbulence velocity for 22 ? Sex was assumed to be ξ _t = 2.7 km/s). We estimated the abundances of C, N, O, Na, Si, Ca, Fe, and Ba (N and Ba, for 15 Ori only). The abundances of carbon, iron, and oxygen in 22 ? Sex are higher than the solar values by +0.31 dex, +0.33 dex, and +0.18 dex, respectively, while the calcium abundance is ?0.19 dex below the solar level. For 15 Ori, we find a slight carbon excess (+0.19 dex), a slight nitrogen deficiency (?0.13 dex), and a considerable deficiency of silicon (?0.42 dex). The abundances of the remaining elements in both stars are near-solar. We find no substantial differences between the abundances derived for 15 Ori and 22 ? Sex and the results of earlier studies of giants by both ourselves and Erspamer and North. A comparison of the atmospheric elemental abundances of giants and δ Scuti stars indicates that the abundances of some lighter elements (oxygen, sodium, silicon, and possibly nitrogen) are somewhat lower for δ Scuti stars than for A-F giants. We determined the masses, radii, luminosities, and ages for 15 Ori and 22 ? Sex.     

Influence of temperature,composition, silica activity and oxygen fugacity on the H<Subscript>2</Subscript>O storage capacity of olivine at 8 GPa

Olivine crystals were grown in the presence of a hydrous silicate fluid during multi-anvil experiments at 8 GPa and 1,000–1,600°C. Experiments were conducted both in a simple system (FeO–MgO–SiO₂–H₂O) and in a more complex system containing additional elements (CaO–Na₂O–Al₂O₃–Cr₂O₃–TiO₂–FeO–MgO–SiO₂–H₂O). Silica activity was buffered by the presence of either pyroxene (high a _SiO2) or ferropericlase (low a _SiO2), and was buffered by the presence of Ni + NiO or Fe + FeO, or constrained by the presence of Fe₂O₃. Raman spectroscopy was used to identify pyroxene polymorphs in the run products. Clinoenstatite was present in the 1,000°C experiment, and enstatite in experiments at 1,400–1,520°C. The H₂O content of olivine was measured using secondary ion mass spectroscopy, and infrared spectroscopy was used to investigate the nature of hydrous defects. The H₂O storage capacity of olivine decreases with increasing temperature at 8 GPa. In contrast to previous experimental results at ≤2 GPa, no significant effect of varying oxygen fugacity is evident, but H₂O storage capacity is enhanced under conditions of low silica activity. No significant growth of low wavenumber (<3,400 cm⁻¹) peaks, generally associated with high at low pressure, was observed in the FTIR spectra of olivine from the high experiments. Our experiments show that previous high pressure H₂O storage capacity measurements for olivine synthesized under more oxidizing conditions than the Earth’s mantle are not likely to be compromised by the of the experiments. However, the considerable effect of temperature on H₂O storage capacity in olivine must be taken into account to avoid overestimation of the bulk upper mantle H₂O storage capacity.     

U–Pb,Re–Os,and <Superscript>40</Superscript>Ar/<Superscript>39</Superscript>Ar geochronology of the Nambija Au-skarn and Pangui porphyry Cu deposits,Ecuador: implications for the Jurassic metallogenic belt of the Northern Andes

New U–Pb, Re–Os, and ⁴⁰Ar/³⁹Ar dates are presented for magmatic and hydrothermal mineral phases in skarn- and porphyry-related ores from the Nambija and Pangui districts of the Subandean zone, southeastern Ecuador. Nambija has been one of the main gold-producing centers of Ecuador since the 1980s due to exceptionally high-grade ores (average 15 g/t, but frequently up to 300 g/t Au). Pangui is a recently discovered porphyry Cu–Mo district. The geology of the Subandean zone in southeastern Ecuador is dominated by the I-type, subduction-related, Jurassic Zamora batholith, which intrudes Triassic volcanosedimentary rocks. The Zamora batholith is in turn cut by porphyritic stocks, which are commonly associated with skarn formation and/or porphyry-style mineralization. High precision U–Pb and Re–Os ages for porphyritic stocks (U–Pb, zircon), associated prograde skarn (U–Pb, hydrothermal titanite), and retrograde stage skarn (Re–Os, molybdenite from veins postdating gold deposition) of the Nambija district are all indistinguishable from each other within error (145 Ma) and indicate a Late Jurassic age for the gold mineralization. Previously, gold mineralization at Nambija was considered to be Early Tertiary based on K–Ar ages obtained on various hydrothermal minerals. The new Jurassic age for the Nambija district is slightly younger than the ⁴⁰Ar/³⁹Ar and Re–Os ages for magmatic–hydrothermal minerals from the Pangui district, which range between 157 and 152 Ma. Mineralization at Nambija and Pangui is associated with porphyritic stocks that represent the last known episodes of a long-lived Jurassic arc magmatism (∼190 to 145 Ma). A Jurassic age for mineralization at Nambija and Pangui suggests that the Northern Andean Jurassic metallogenic belt, which starts in Colombia at 3° N, extends down to 5° S in Ecuador. It also adds a new mineralization style (Au-skarn) to the metal endowment of this belt. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

The major ion, δCa, δCa, and δMg geochemistry of granite weathering at pH = 1 and T = 25 °C: power-law processes and the relative reactivity of minerals

We dissolved Boulder Creek Granodiorite in a plug flow reactor for 5794 h at pH = 1 and T = 25 °C. The primary purpose of the experiment was to identify controls on dissolved δ^44/40Ca, δ^44/42Ca, and δ^26/24Mg values during granite weathering. Herein, we also examine the origin of Ca and Mg isotopic variability among minerals composing the Boulder Creek Granodiorite, and we constrain fundamental characteristics of granite weathering important for quantifying the elemental and isotopic geochemistry of the reactor output. Nine Ca-bearing minerals display an 8.80‰ range of δ^44/40Ca values and a 0.51‰ range of δ^44/42Ca values. Three Mg-bearing minerals display a 1.53‰ range of δ^26/24Mg values. These ranges expressed at the mineralogical scale are higher than the ranges thus far reported for bulk igneous rocks. Most of the δ^44/40Ca variability reflects ⁴⁰Ca enrichment in K-feldspar, and to a lesser extent, biotite, due to the radioactive decay of ⁴⁰K over the 1.7 Ga age of the rock, whereas the entire range of δ^44/42Ca values reflects mass-dependent isotope fractionation during igneous differentiation and crystallization. The range of δ^26/24Mg values may represent either fractionation during the chloritization of biotite or interaction of the Boulder Creek Granodiorite with Mg-rich metamorphic fluids having low δ^26/24Mg values.The elemental and isotopic composition of the reactor output varied substantially during the experiment. We synthesize the mineralogical and fluid data using coupled mass-conservation equations solved at non-steady-state. Model calculations reveal an intricate balance between increasing specific surface area and decreasing mineral concentrations. While surface area normalized dissolution rate constants were time-invariant, specific surface area increased as a power-law function of time through positive feedbacks between mechanical disaggregation, chemical dissolution, and mineral depletion. Variations in dissolved δ^44/40Ca, δ^44/42Ca, and δ^26/24Mg values reflect conservative mixing rather than fractionation. Apatite and calcite initially control δ^44/40Ca and δ^44/42Ca values, followed by biotite, titanite, epidote, hornblende, and plagioclase. The release of radiogenic ⁴⁰Ca clearly defines the period where biotite dissolution dominates. The brucite layer of chlorite initially controls δ^26/24Mg values, followed by biotite, the TOT layer of chlorite, and hornblende. Through direct isotopic tracking, these results demonstrate that trace minerals, such as apatite and calcite in the case of Ca and brucite in the case of Mg, dominate elemental release during the incipient stages of granite weathering. The results further show that biotite dissolution dominates the middle stages of granite weathering and that plagioclase dissolution only becomes important during relatively late stages. The Ca and Mg isotope variations associated with these stages are distinct and potentially resolvable in soil mineral weathering studies.     

Mineralogy and Mode of Occurrence of Gold, Silver and Bismuth of the Caijiaying Lead-Zine-Silver Deposit, Hebei Province

The deposit under study is a hydrothermal filling-metasomatic vein type lead-zinc-silver deposit, in whichgold and silver can be recovered as by-products. These metals mainly occur as microgranular native gold,electrum, stephanite, acanthite, pyraragyrite, freibergite, and native silver. Gold minerals tend to be associatedwith galenobismutite, native bismuth and unnamed Bi_2Te. They are either enclosed in pyrite, marmatite,iron-bearing sphalerite and galens or fill the microfissures of these minerals. Silver minerals usually occur incleavages or fissures of galena, marmatite and pyrite, but are not associated with gold and bismuth minerals.Gold and silver mineralizations occurred later than lead and zinc, while the silver mineralization was precededby that of gold.     

Spatio-temporal variations of δ<Superscript>2</Superscript>H and δ<Superscript>18</Superscript>O in precipitation and shallow groundwater in the Hilly Loess Region of the Loess Plateau,China

Groundwater is of utmost significance to socio-economic development and ecological recovery for the Loess Plateau. However, studies regarding the mechanism governing groundwater recharge over this area appear to be inadequate. This study is to examine the spatio-temporal variations of δ²H and δ¹⁸O in precipitation and shallow groundwater. On the basis of this, the mechanisms governing shallow groundwater recharge were explored. Precipitation and groundwater were sampled monthly from May to October during the period 2004–2006 at 13 sites in the Chabagou Catchment (187 km²). In the Caopingxigou Experimental Watershed (0.1 km²), meteorological variables were observed and rainfall larger than 5 mm was sampled immediately after each rain event. Across the area, 90% of the precipitation occurred from May to September primarily in the form of heavy rains or rainstorms with great spatial variability. There were about 30 localized rains in each year. It was indicated that there existed notable seasonality and pronounced spatial variability in precipitation isotopic compositions. Contributing factors and indications of isotopic compositions, as well as their climatic indications such as monsoon intensities and mixing processes of water vapor, were investigated. The δ²H–δ¹⁸O relation of groundwater was found to be δ²H = 3.22 × δ¹⁸O − 38.1, deviating from the local meteoric water line δ²H = 7.57 × δ¹⁸O + 3.9. The range of δ values in groundwater is shrunken to be 15–21% of that in individual precipitations, and groundwater in the middle reaches shows a wider range of δ values. Isotopic results showed that groundwater originates from precipitation with hydrogen and oxygen isotopic compositions being −69 and −9.7‰, respectively, and most groundwater experiences serious evaporation and adequate mixing with old water during infiltration or percolation in the aerated zone. It was also founded that obvious fluctuations of isotopic compositions in groundwater mainly appear in the middle reaches especially at sites that are close to valleys, suggesting varying sources of groundwater from precipitation, precipitation runoff, isotopically enriched surface water and/or lateral recharge of adjacent groundwater.     

Rb–Sr and <Superscript>147</Superscript>Sm–<Superscript>143</Superscript>Nd systematics of gabbro and dolerites from fragments of ophiolite complexes of the Middle Urals

The Rb–Sr and ¹⁴⁷Sm–¹⁴³Nd age data obtained for sheeted dolerite dykes and rocks of the Platinum Belt of the Urals within the Tagil segment of the paleoceanic spreading structure (Middle Urals) are discussed. The study of the Rb–Sr isotope systematics of gabbro allowed us to reveal errochronous dependencies, which yielded ages of 415 and 345 Ma at (⁸⁷Sr/⁸⁶Sr)₀ = 0.70385 ± 0.00068 and 0.7029 ± 0.0010, correspondingly. The ¹⁴⁷Sm–¹⁴³Nd isotope age data demonstrate a specific coincidence of the chronometric ages of the sheeted dolerite dyke complex (426 ± 54, 426 ± 34, and 424 ± 19 Ma) and gabbro from the Revda gabbro–ultramafic massif (431 ± 27 Ma) and from screens between dolerite dykes in the sheeted dyke complex (427 ± 32 Ma, 429 ± 26 Ma). The proximity of the ¹⁴⁷Sm–¹⁴³Nd ages of gabbro and dolerite can be explained by the thermal effect of the basaltic melt, which is the protolith for the dyke complex, on the hosting gabbro.     

Isotopic (Sm–Nd,Pb–Pb,and δ<Superscript>34</Superscript>S) and Geochemical Characteristics of the Metasedimentary Rocks of the Baikal–Patom Belt (Northern Transbaikalia) and Evolution of the Sedimentary Basin in the Neoproterozoic

This paper reports the results of a detailed isotopic (Sm–Nd, Pb–Pb, and δ³⁴S) and geochemical studies of Neoproterozoic metasedimentary rocks from the Patom and Bodaibo domains of the Baikal–Patom belt (northern Transbaikalia). It was shown that the metasedimentary rocks of these domains are strongly variable in their geochemical and isotope geochemical characteristics. Regular variations in these characteristics were observed, and their correlation with the main stages of the evolution of the sedimentary paleobasin in the Neoproterozoic was established.     

Active tectonic and palaeoseismological features of the western section of Mustafakemalpaşa Fault; Bursa,NW Anatolia

The Mustafakemalpa?a Fault (MF), located among Manyas, Ulubat and Orhaneli faults, is a right lateral strike-slip and 47 km in length. The MF begins with a pressure ridge at the west and exhibits complex jog terminations at east ends in restraining left stepovers. The western section of the fault bounds Miocene and Quaternary units and continues towards ?lyasç?lar. The central segment of the fault, starts with approximately 750-m leftward stepover, exhibits a sinusoidal geometry between Kapakl?oluk and Kabulbaba. In this section, MF traverses mountainous terrain and cuts Ophiolite, Jurassic limestones and Miocene detritals, forming dextral faulting features and gaining reverse component. The eastern section exhibits left stepping en-echelon pattern and consists 2.5-km offset on the Orhaneli River. In this study, palaeoseismological findings related to the Holocene activity and active tectonic properties of the MF are presented. The trenches exposed mismatched stratigraphy, demonstrating evidence of events across the fault. We identified three events (before BC 2190, later AD 1425 and 1850) that have occurred during the past 4000 years. We suggest a long non-characteristic recurrence interval and ~0.7 mm/y slip-rate for MF, based on trench data and offset of the Late Pliocene drainage of Orhaneli River.     

Assessment of NO<Subscript>3</Subscript><Superscript>−</Superscript> contamination in a karstic aquifer,with the use of geochemical data and spatial analysis

Kopaida plain is a cultivated region of Eastern Greece, with specific characteristic related with the paleogeographic evolution and the changes in land use. The present article examines the contamination that derives from nitrates, in terms of contaminant levels, definition of sources and spatial distribution of contaminant plume. For this purpose, 50 water samples were collected from the karstic aquifer and analyzed for 15 parameters including major ions, trace elements, physicochemical parameters, and stable isotopes. The assessment of the above parameter values along with the notes derived by the statistical process revealed the existence of nitrate contamination which has been spatial defined with the aid of spatial interpolation techniques. The correlation of NO₃ ⁻ concentrations with the stable isotope values, defined the infiltration conditions and showed contaminant transport. Nitrate values revealed the potential environmental threat for local people, as 10% of the samples exceeded the parametric value of 50 ppm and 54% of them are above 25 ppm, indicating no optimal quality conditions. The origin of nitrate contamination seems to derive exclusively from the application of N-fertilizers, since the rest of potential sources were not verified by analytical data and field works.     

Competitiveness versus ‘clean and green’? The regulation and governance of GMOs in Australia and the UK

It is increasingly argued that we are entering into a “biotech century”, in which biotechnology promises major advances in agricultural productivity. The development of biotechnology is not a straightforward affair, however, and the advent of GMOs has led to public protest and consumer resistance. This paper draws upon a comparative Australian-UK project concerned with the role of regulation and governance in mediating the debates and managing the associated risks. Regulatory responses and the mediation of conflicts by the Australian and UK governments have been shaped by the institutional and policy environments in these two countries. The implications of these public debates and regulatory responses for the capture of competitive opportunities are considered. The fact that the two countries have broadly similar systems of governance and regulation reveals how alike the circumstances are in many respects. But at the same time there are important differences in both the style and the content of the policy debates. In both the UK and Australia, the respective central governments remain committed to a ‘biotechnology future’. Against this background, there is little doubt that the choices about biotechnology will play a defining role in shaping the future of rural places.     

Sr chemostratigrphy, δ<Superscript>13</Superscript>C,and δ<Superscript>18</Superscript>O of rocks in the Crimean carbonate platform (Late Jurassic,northern Peri-Tethys)

The paper presents the results of study of the Sr, C, and O isotope compositions in Upper Jurassic carbonate rocks of the Baidar Valley and Demerdzhi Plateau in the Crimean Mountains represented by different facies of the carbonate platform at the northern active margin of the Tethys. The ⁸⁷Sr/⁸⁶Sr value in them varies from 0.70699 to 0.70728. Based on the Sr chemostratigraphic correlation, the age of massive and layered limestones in the western part of the Ai-Petri and Baidar yailas (pastures) is estimated as late Kimmeridgian–early Tithonian, whereas the age of flyschoids of the Baidar Valley are estimated as late Tithonian–early Berriasian. The nearly synchronous formation of carbonate breccias of the Baidar Valley and Demerdzhi Plateau in late Tithonian–early Berriasian is substantiated. A summary section of Upper Jurassic rocks is compiled based on the Sr chemostratigraphic data. It has been established that δ¹⁸O values in the studied carbonate sediments vary from–2.9 to 1.3‰ (V-PDB). At the same time, shallow-water sediments in the internal part and the edge of the Crimean carbonate platform are depleted in ¹⁸O (–2.9 to +0.1‰) relative to sediments on the slope and foothill (–0.5 to +1.3‰). It is demonstrated that δ¹³C values do not depend on the facies properties and decrease in younger carbonate sediments from 3–3.5‰ to 1–1.5‰ in line with the Late Jurassic general trend. The δ¹³C values obtained for the Crimean carbonate platform turned out to be 0.5–1‰ higher than the values typical of the deep-water marine setting at the western margin of the Tethys. These discrepancies are likely related to peculiarities of water circulation and high bioproductivity in marine waters of the northern Peri-Tethys.     

Geochemistry of О, Н, C,S, and Sr isotopes in the water and sediments of the Aral basin

The paper presents original authors' data on the O, H, C, S, and Sr isotopic composition of water and sediments from the basins into which the Aral Sea split after its catastrophic shoaling: Chernyshev Bay (CB), the basin of the Great Aral in the north, Lake Tshchebas (LT), and Minor Sea (MS). The data indicate that the δ¹⁸О, δD, δ¹³C, and δ³⁴S of the water correlate with the mineralization (S) of the basins (as of 2014): for CB, S = 135.6‰, δ¹⁸О = 4.8 ± 0.1‰, δD = 5 ± 2‰, δ¹³C (dissolved inorganic carbon, DIC) = 3.5 ± 0.1‰, δ³⁴S = 14.5‰; for LT, S = 83.8‰, δ¹⁸О = 2.0 ± 0.1‰, δD =–13.5 ± 1.5‰, δ¹³C = 2.0 ± 0.1‰, δ³⁴S = 14.2‰; and for MS, S = 9.2‰, δ¹⁸О =–2.0 ± 0.1‰, δD =–29 ± 1‰, δ¹³C =–0.5 ± 0.5‰, δ³⁴S = 13.1‰. The oxygen and hydrogen isotopic composition of the groundwaters are similar to those in MS and principally different from the artesian waters fed by atmospheric precipitation. The mineralization, δ¹³С, and δ³⁴S of the groundwaters broadly vary, reflecting interaction with the host rocks. The average δ¹³С values of the shell and detrital carbonates sampled at the modern dried off zones of the basins are similar: 0.8 ± 0.8‰ for CB, 0.8 ± 1.4‰ for LT, and –0.4 ± 0.3‰ for MS. The oxygen isotopic composition of the carbonates varies much more broadly, and the average values are as follows: 34.2 ± 0.2‰ for CB, 32.0 ± 2.2‰ for LT, and 28.2 ± 0.9‰ for MS. These values correlate with the δ¹⁸O of the water of the corresponding basins. The carbonate cement of the Late Eocene sandstone of the Chengan Formation, which makes up the wave-cut terrace at CB, has anomalously low δ¹³С up to –38.5‰, suggesting origin near a submarine methane seep. The δ³⁴S of the mirabilite and gypsum (11.0 to 16.6‰) from the bottom sediments and young dried off zone also decrease from CB to MS in response to increasing content of sulfates brought by the Syr-Darya River (δ³⁴S = 9.1 to 9.9‰) and weakening sulfate reduction. The ⁸⁷Sr/⁸⁶Sr ratio in the water and carbonates of the Aral basins do not differ, within the analytical error, and is 0.70914 ± 0.00003 on average. This value indicate that the dominant Sr source of the Aral Sea is Mesozoic–Cenozoic carbonate rocks. The Rb–Sr systems of the silicate component of the bottom silt (which is likely dominated by eolian sediments) of MS and LT plot on the Т = 160 ± 5 Ma, I₀ = 0.7091 ± 0.0001, pseudochron. The Rb–Sr systems of CB are less ordered, and the silt is likely a mixture of eolian and alluvial sediments.     

Solubility of columbite, (Mn,Fe)(Nb,Ta)<Subscript>2</Subscript>O<Subscript>6</Subscript>, in granitoid and alkaline melts at 650–850°C and 30–400 MPa: An experimental investigation

This paper reports experimental data on columbite solubility in model water-saturated Li- and F-rich silicic melts with different contents of alumina and alkalis. It was found that the columbite solubility is strongly affected by melt composition and is maximal in peralkaline melt. The maximum contents of Ta and Nb in subaluminous and peraluminous melts at the contact with columbite are lower by at least an order of magnitude. The peralkaline melt is relatively enriched in Nb, and the peraluminous melt is enriched in Ta. The temperature dependence of solubility is positive but less pronounced than the effect of melt composition. It is most distinct in the subaluminous melts. The Nb/Ta ratio of melt usually decreases with decreasing temperature. The effect of pressure is relatively small. It was shown that columbite cannot crystallize on the liquidus of both peralkaline and peraluminous magmas. Perhaps, columbite crystallization from a melt is possible only at final near-solidus stages at the high degrees of crystallization of strongly evolved low-temperature melts.     

Thermodynamics of arsenates,selenites, and sulfates in the oxidation zone of sulfide ores: IV. Eh-pH diagrams of the Me-Se-H<Subscript>2</Subscript>O systems (Me = Co,Ni, Fe,Cu, Zn,Pb) at 25°C

The behavior of selenium at the Earth’s surface and nearby at low temperatures and pressures is controlled by variations of the redox potential and the acidity of solutions. These parameters determine the migration of selenium and its precipitation as various solid phases. Understanding the mechanism of selenium’s behavior under surface conditions, which is important for solving environmental problems, is an urgent task of contemporary mineralogy and geochemistry. The activities of components in natural waters beyond the zones of natural (oxidation zones) and man-made contamination with selenium (a _ΣSe = 10⁻⁹, a _ΣFe = 10⁻⁵, a _ΣCu = 10⁻⁷, a _ΣZn = 5 × 10⁻⁷, a _ΣCo = 10⁻⁸, a _ΣNi = 6 × 10⁻⁸, a _ΣPb = 10⁻⁸) and in waters formed in the oxidation zone (a _ΣSe = 10⁻⁵–10⁻⁴, a _ΣFe = 10⁻², a _ΣCu = 10⁻², a _ΣZn = 5 × 10⁻², a _ΣCo = 10⁻³, a _ΣNi = 10⁻², a _ΣPb = 10⁻⁴) have been estimated. Eh-pH diagrams were calculated and plotted using the Geochemist’s Workbench (GMB 7.0) software package. The database comprises the thermodynamic parameters of 46 elements, 47 main particles, 48 redox pairs, 551 particles in solution, 624 solid phases, and 10 gases. The Eh-pH diagrams of the Me-Se-H₂O systems (Me = Co, Ni, Fe, Cu, Zn, Pb) were plotted for the average contents of these elements in underground water and for their contents in oxidation zones of sulfide deposits. The formation of Co, Ni, Fe, Cu, Zn, and Pb selenites and selenates at the surface is discussed.