Nutrient,heavy metal and organic pollutant composition of suspended and bed sediments in the Rhone River

The environmental quality of the Rhone River (Switzerland-France) has been assessed with a geochemical survey of the pollutants bound to suspended sediments. Ten samples were collected between Lake Geneva and the Mediterranean Sea in Nobember 1989 by continuous flow centrifugation and analysed for grain size distribution, carbonate, organic C, N, forms of particulate P, trace metals, and organic compounds (chlorobenzenes, organochlorine pesticides, PCBs, and PAHs). Four bed sediment samples were also studied for comparative purposes. The suspended solids provide lower variance by parameter than the bed sediments and are clearly most suitable for synoptic monitoring.The Upper Rhone River carries a glacial derived sediment with a low nutrient content, the stretch from Geneva to Lyon provides a sediment dominated by carbonate, and in the Lower Rhone the organic matter and phosphorus are relatively increased, mainly due to wastewater effluents and to an industrial P source. High concentrations of metals and organic micropollutants downstream of Lyon indicate a multiple contamination in the Lower Rhone, whereas more specific inputs are located downstream of Geneva and Arles.The comparison with data from other polluted major systems, the Rhine, the Niagara and the Detroit rivers, shows on overall similarity confirming that the Rhone quality is degraded downstream of Lyon. The levels of particular concern are for Hg, DDT metabolites which reveal a recent release in the basin, PCBs with a likely high chlorine content, and PAHs.The statistical evaluation of the compositional variables indicates a limited number of well defined associations, suggesting that the contamination of the suspended sediments results from the combination of numerous and intermittent point and diffuse sources in the Rhone River basin.     

Recovery and concentration of suspended solids in the upper rhone river by continuous flow centrifugation

Six stations along the Rhône River from the Rhône Glacier to Lake Geneva were sampled by continuous flow centrifuge for recovery of suspended sediment. The samples were taken four times in the year in both 1982 and 1983. In addition, the mouth of the river was sampled in a like manner every two weeks during 1982 until August 1983. Concentration of sediment and composition did not vary as a function of depth or location across the river. Concentrations varied in time and as a function of flow and samples showed both increasing concentration in suspension and an increase in the proportion of finer particles moving downstream from source to mouth. Only slight variations in texture could be observed down the river as a function of time and appeared to relate to freezing and melting of the Rhône and other headwater glaciers as the primary sediment source. Little variation was observed annually in the texture and composition of the sediment at the river mouth despite large changes in concentration between the high flow summer and low flow winter discharges. These findings are consistent with a well-mixed system in which the suspended sediments are directly related to the primary supply of material from the glaciers.     

Contamination des sédiments superficiels des principales rivières du Canton de Genève par les Polychlorobiphényles et DDT

The concentrations of PCBs and DDT at the surface of sediments of rivers in the Canton of Geneva were examined. Concentration variations observed along the rivers are discussed. In the case of the Rhône River, recent pollution at the surface of sediments is compared with that of aged underlying layers.     

Badlands as a hot spot of petrogenic contribution to riverine particulate organic carbon to the Gulf of Lion (NW Mediterranean Sea)

Determining the riverine carbon fluxes to oceans is critical for an improved understanding of C budgets and biogeochemical cycles (C, O) over a broad range of spatial and time scales. Among the particulate organic carbon (POC) involved in these fluxes, those yielded by sedimentary rocks (petrogenic POC: pPOC) remain somewhat uncertain as to their source on continental surfaces. Based on time series from long‐term observatories, we refine the POC and sediments flux of the Rhône River, one of the major tributaries to the Mediterranean Sea. Radiocarbon measurements on a set of riverine samples and forward modelling were used to (i) determine a modelled pPOC content and pPOC/POC ratio for each sample set, (ii) assess pPOC flux delivered to the NW Mediterranean Sea, and (iii) estimate the badlands contribution from the Durance catchment to both the pPOC and to sediment discharges. The weighted pPOC flux contributes up to 26% of the POC flux (145 Gg yr^‐1) discharged into the Mediterranean Sea, whereas the weighted pPOC content reaches 0.31 wt%. Despite their low contributive surface area (0.2%), badlands provide, respectively, 12, 3.5 and 14% of the pPOC, POC and sediment fluxes to the Rhône River. Consequently, such rocks can be considered as a major source of pPOC and sediments for the NW Mediterranean Sea and potentially for oceans. We suggest that river‐dominated ocean margins, such as the Rhône River, with badlands in their catchment could export a significant amount of pPOC to the oceans. Copyright © 2018 John Wiley & Sons, Ltd.     

Hydrological regime of the Rhône Delta and dynamics of its coastline

Specific features of the hydrological regime of the Rhône River and the nearshore zone of its mouth are discussed. The processes of seawater intrusion into the delta branches are described. The information on the history of the delta evolution and development is presented along with the reconstruction of the Holocene evolution of the Rhône Delta and analysis of formation peculiarities of the present-day delta. Channel processes in the Rhône Delta and the dynamics of the delta coastline are described; characteristics of the deep-water fan are discussed, and the data on sediment balance are given.     

La Morte du Sauget,un ancien méandre du Rhône: bilan hydrologique et biogéochimique

The ‘Morte du Sauget’, a typical oxbow-lake in process of eutrophication and encroachment, is located in the alluvial plain of the French Upper Rhône River. Studies during 1983 have shown that, although the ‘Morte du Sauget’ is seasonally inundated by the Rhône, the impact of flooding is only temporary and is minimized by the biological activity of the waters and sediments of this system.     

Long term high frequency sediment observatory in an alpine catchment: The Arc-Isère rivers,France

We present a dataset on to the Arc-Isère long-term environmental research observatory, which is part of the Rhône Basin Long Term Environmental Research Observatory. This alpine catchment located in the French Alps is characterized by high Suspended Particulate Matter (SPM) in anthropogenized valleys. Suspended Sediment Concentrations (SSC) naturally observed in the river are very high, ranging from a few tens of milligrams per litre at low flow to tens of grams per litre during major natural hydrological events (floods, debris flows) or river dam hydraulic flushes. One research objective related to this site is to better understanding the SSC dynamics along the river using a system of nested catchments (Arvan, Arc, and Isère) in order to assess both temporal and spatial dynamics. The data allow the quantification of fine sediment yields and also the evaluation of possible morphological changes due to fine sediment deposition or resuspension. Additionally, the observatory database support studies on contaminants (either dissolved or particulate contaminants). Our monitoring includes six stations with high frequency (2–30 min) streamflow, SSC measurement using turbidity sensors, and associated automatic sampling. Discharge is measured via water level measurements and a rating curve. The oldest station (Grenoble-campus) started recording discharge and concentration data from April 2006 while others stations were built between 2009 and 2011. Data are available in an online data website called ‘Base de Données des Observatoires en Hydrologie’ (Hydrological observatory database, https://bdoh.irstea.fr/ARC-ISERE/ ) with a DOI reference for the dataset. The hydrological and sediment transport time series are stored, managed and made available to a wide community with unfettered access in order to be used at their full extent. This database is used as a data exchange tool for both scientists and operational end-users and there is an associated online tool to compute integrated fluxes.     

Structure et fonctionnement des écosystèmes du haut Rhône français. VII. Le complexe hydrographique de la Lône des Pêcheurs (un ancien méandre du Rhône)

The hydrological analysis of one of the old meanders of the french upper Rhône, called the ‘Lône des Pêcheurs’, is carried out from September 1976 to November 1977. The principal components analysis of the physico-chemical characteristics of the water shows an ecological tripartition along the longitudinal axe of the ‘lône’, according to the mixing processus of two types of waters, the one influenced by the lateral underflow, the other flowing in from the Rhône, and related with the overflow. Partitional analogies are also noted between the structure of phytoplanctonic community and the hydrological environment.     

Dissolved and particulate trace metals in meltwater from the Rhône glacier

Glacial meltwater and sediment at the source of the River Rhône have been analyzed to determine: 1. the partitioning of Al, Cd, Co, Cu, Cr. Fe, Mn, Ni, Pb and Zn between the water and particulate phase. 2. the particle size ranges which affect the dissolved trace metal ion composition of the meltwater and 3. the availability (potential release) of the ten trace metal ions from the sediment. Greater than 80% of the total Cd, Cu, Mn, Ni and Zn were found to be in operationally-defined (0.4 μm) dissolved forms. Fe and Al in the meltwater are primarily associated with particles in the size range 0.4–8 μm, while Cd. Cu, Mn, Ni and Zn occur with particles smaller than 0.1 μm. For the sediment, Cu, Ni and Pb were significantly present as exchangeable forms; only Cu, Ni, Pb and Zn were determined as organicallybound forms.     

不同前处理对湖泊沉积物粒度测量结果的影响

选择两个不同湖泊的沉积物为研究对象,通过对比不同前处理后的测量结果,比较了各种前处理方法的优劣,并提出两种较好的前处理方法.结果显示不同湖泊沉积物和同一湖泊的不同样品对各种前处理方法的响应并不相同,从整体上来看,经过去离子水浸泡后并用超声波分散的方法效果最好,目前最常用的传统的前处理方法结果也较好.测量结果还显示,经过(NaPO3)6处理后再用超声波分散容易使频率分布曲线出现细粒次峰,产生双峰分布的型式,原因也许与(NaPO3)6的分散作用使颗粒絮凝作用减小,增强超声波对颗粒的直接撞击作用,使颗粒被击碎从而产生双峰分布有关.     

Terrigenous transportation to the Okinawa Trough and the influence of typhoons on suspended sediment concentration

The source and transport mechanisms of land-derived Okinawa Trough sediments were studied using the field data of temperature, salinity and turbidity in the East China Seas. The results suggest that there are two primary sediments sources from the Chinese Mainland to the Okinawa Trough: one is the Old Huanghe River submarine delta, and the other is the Changjiang River sediments, which are distributed at the Changjiang River estuary and the off-coast of Zhejiang and Fujian provinces. It is difficult for the Huanghe River suspended sediments to arrive in the Okinawa Trough via the new estuary. Although the Taiwan warm current blocks the seaward terrigenous transportation to a certain extent, part of the coastal suspended sediments are transported to the outer shelf. Suspended particulate matter is unable to get through the barrier of the Kuroshio Current under normal conditions. However, episodic events, such as winter storms, internal-tidal waves and turbidity flows, are capable of transporting suspended particulate matter into the Okinawa Trough. The super typhoon “Ewiniar” induced strong waves and influenced the thermocline depth and suspended sediment concentration of the East China Seas. The typhoon-induced waves pushed the thermocline depth down to around 40 m and caused the resuspension of large volumes of sediments in its path. In the other East China Seas regions, the typhoon-induced swells deepened the thermocline depth by about 5 m and increased suspended sediment concentrations. The typhoon effect on suspended sediment concentration of the East China Seas disappeared within 2 weeks.     

Vertical changes of POC flux and indicators of early degradation of organic matter in the South China Sea

Tie-series sediment trap materials at different water depths and surface sediments in northern and central South China Sea (SCS) were analyzed for organic carbon, amino acids, amino sugars and carbohydrates. Results show that particulate organic carbon (POC) is mainly derived from marine plankton, only 1.4%–1.6% of primary production sinks into deep SCS water column and less than 0.22 % of primary production ultimately reaches the sediments. The ranineralization and dissolution of organic matter as well as the compositional alterations of organic matter mixtures may mainly take place in the upper few hundred meters of water column, deep carbonate (opal) lysocline zones, and interface layers between sediments and water column, rather than in mid-waters. The organic geochemical parameters such as (T ^aa +T ^sug )OC%, AA/AS, Gluam/Galam, Arom. AA/non-prot. AA, ASP/b-ALA, Glu/g-ABA decrease from living marine plankton (or planktonic shells), to settling particulate matter and to sediments suggesting that they appear to be gad early degraded indicators of organic matter. Project supported by the National Natural Science Foundation of China (Grant No. 49776297). Cruises financially supported by State Oceanic Administration and German Federal Ministry of Research and Technology.     

Spatiotemporal variations of deep-sea sediment components and their fluxes since the last glaciation in the northern South China Sea

Sediment components and their fluxes of Cores MD12-3428(water depth: 903 m), MD12-3433(water depth: 2125 m),and MD12-3434(water depth: 2995 m), obtained along a transect on the continental slope of the northern South China Sea, have been conducted to reveal the spatiotemporal variations and the controlling factors of the sediment components and of their fluxes.Results show that deep-sea sediments in the northern South China Sea are composed mainly of terrigenous(59–89%) and carbonate(6–38%) particles, with minor components of opal(1.6–9.4%) and organic matter(0.7–1.9%). Fluxes of terrigenous and carbonate particles reach up to 2.4–21.8 and 0.4–6.5 g cm–2 kyr–1, respectively, values that are one to two orders of magnitude higher than the fluxes of opal and organic matter. Temporal variations of the percentages and fluxes of deep-sea sediment components have displayed clear glacial-interglacial cyclicity since the last glaciation. Terrigenous, opal, and organic matter percentages and their fluxes increas clearly during marine isotope stage 2, while carbonate percentages and fluxes show an opposite variation pattern or are characterized by an unremarkable increase. This implies that deep-sea carbonate in the South China Sea is affected by the dilution of terrigenous inputs during the sea-level lowstand. With increasing water depth along the transect, the terrigenous percentage increases but with largely decreased fluxes. Both the percentage and flux of carbonate decrease, while the percentages and fluxes of opal and organic matter display much more complicated variational features. The spatiotemporal variations of deep-sea sediment components and of their fluxes since the last glaciation in the northern South China Sea are strongly controlled by sea-level fluctuations. Simultaneously, terrigenous supply associated with monsoonal rainfall, marine primary productivity,and the dilution effect between terrigenous and biogenic particles, also play interconnected roles in the sediment accumulation processes.     

Evolution of Heterogeneous Mixed Siliciclastic/Carbonate Aquifers Containing Metastable Sediments

Mixed carbonate and siliciclastic marine sediments commonly become freshwater aquifers in eastern coastal regions of the United States and many other global locations. As these deposits age, the carbonate fraction of the sediment is commonly removed by dissolution and the aquifer can become a solely siliciclastic system or contain zones or beds of pure quartz sand. During aquifer evolution, the sediment grain size characteristics, hydraulic conductivity, and porosity change. An investigation of these changes using mixed carbonate/siliciclastic sediment samples collected from a modern barrier island beach in southern Florida showed that the average mean grain diameter decreased with removal of the carbonate fraction, but the average hydraulic conductivity and porosity increased slightly, but not to statistical significance. This counterintuitive result occurs because of the change in the pore types from a combined shelter and intergranular pore system producing a dual porosity system in the mixed sediments to a single intergranular pore system in the siliciclastic sediment fraction. Within the mixed carbonate/siliciclastic sediment, in the pure carbonate fraction, large shell fractions form grain‐supported large pores, which become filled with sand‐sized quartz as the shell fragments decrease in size or as the sediment becomes compacted. The hydraulic conductivity increases because the shell fragments that were oriented perpendicular to flow caused an increase in the length of the flow path, or a larger scale tortuosity, compared with the flow through pure quartz sand.     

Runoff‐induced sediment yield over dune slopes in the Negev Desert. 2: Texture,carbonate and organic matter

Runoff‐induced sediments were collected in the Hallamish dune field for four years (1990–1994). Runoff and consequently water‐transported sediments were generated on the dunes owing to the presence of a thin microbiotic crust. These sediments were analysed for their particle‐size distribution and carbonate content. In addition, the organic matter content was calculated by measuring the chlorophyll content within the runoff. The results were compared to the slope parent material, i.e. the crust and the underlying sand, as well as to playa sediments, which are scattered within the Hallamish interdunal areas, and which were previously hypothesized to originate from runoff‐induced sediments. Higher amounts of fines (silt and clay) and carbonate characterize the footslopes in comparison to the midslopes. Intermediate contents of fines (17 per cent) and carbonate (8 per cent) characterized the sediments in comparison to the fines (27 per cent) and carbonate (15 per cent) of the crust and to the fines (4 per cent) and carbonate (4 per cent) of the underlying sand. The runoff‐induced fines and carbonate contents were significantly different from those of the playas, suggesting that the playa flats do not originate from runoff‐induced sediments. The sediments were enriched with organic matter. Organic matter which originates from the crust amounted to 0·3–0·4 per cent as compared to ≤0·1 per cent in the bare sand. Nevertheless, the crust was found to be relatively resilient to water flow. Only 0·1–0·5 per cent of the crust was annually eroded off the slope by water, with south‐facing crusts showing higher resilience than north‐facing crusts. The data may thus assist in the evaluation of the crust's residence time. Copyright © 2001 John Wiley & Sons, Ltd.     

Annual fossil organic carbon delivery due to mechanical and chemical weathering of marly badlands areas

A key issue in the study of the carbon cycle is constraining the stocks and fluxes in and between C‐reservoirs. Among these, the role and importance of fossil organic carbon (FOC) release by weathering of outcropping sedimentary rocks on continental surfaces is still debated and remains poorly constrained. Our work focuses on FOC fluxes due to chemical and mechanical weathering of marls in two experimental watersheds with typical badlands geomorphology (Draix watersheds, Laval and Moulin, Alpes de Haute Provence, France). Organic matter from bedrock, soil litter and riverine particles are characterized by Rock‐Eval 6 pyrolysis. FOC fluxes due to mechanical weathering are then estimated by monitoring the annual particulate solid exports at the outlets of the watersheds (1985–2005 period). FOC fluxes from chemical weathering were calculated using Ca²⁺ concentrations in dissolved loads (year 2002) to assess the amount of FOC released by the dissolution of the carbonate matrix. Results show that FOC delivery is mainly driven by mechanical weathering, with a yield ranging from 30 to 59 t km^‐2 yr^‐1 in the Moulin (0.08 km²) and Laval (0.86 km²) catchments, respectively, (1985–2005 average). The release of FOC attributed to chemical weathering was 2.2 to 4.2 t km^‐2 for the year 2002. These high FOC fluxes from badlands are similar to those observed in tectonically active mountain catchments. At a regional scale, badland outcropping within the Durance watershed does not exceed 0.25% in area of the Rhône catchment, but could annually deliver 12 000 t yr^‐1 of FOC. This flux could correspond to 27% of the total particulate organic carbon (POC) load exported by the Rhône River to the Mediterranean Sea. At a global scale, our findings suggest that erosion of badlands may contribute significantly to the transfer of FOC from continental surfaces to depositional environments. Copyright © 2012 John Wiley & Sons, Ltd.     

Muddy waters: temporal variation in sediment discharging from a karst spring

Karst aquifers are capable of transporting and discharging large quantities of suspended sediment, which can have an important impact on water quality. Here we present the results of intensive monitoring of sediment discharging from a karst spring in response to two storm events, one following a wet season and the other following a dry season; we describe temporal changes in total suspended solids (TSS), mineralogy, and particle size distribution. Peak concentrations of suspended sediment coincided with changes in aqueous chemistry indicating arrival of surface water, suggesting that much of the discharging sediment had an allochthonous origin. Concentrations of suspended sediment peaked 14–16 h after rainfall, and the bulk of the sediment (approximately 1 metric ton in response to each storm) discharged within 24 h after rainfall. Filtered material included brightly colored fibers and organic matter. Suspended sediments consisted of dolomite, calcite, quartz, and clay. Proportions of each mineral constituent changed as the aquifer response to the storm progressed, indicating varying input from different sediment sources. The hydraulic response of the aquifer to precipitation was well described by changes in parameters obtained from the particle size distribution function, and corresponded to changes seen in TSS and mineralogy. Differences between storms in the quantity and mineralogy of sediment transported suggest that seasonal effects on surface sediment supply may be important. The quantity of sediment discharging and its potential to sorb and transport contaminants indicates that a mobile solid phase should be included in contaminant monitoring and contaminant transport models of karst. Temporal changes in sediment quantity and characteristics and differences between responses to the two storms, however, demonstrate that the process is not easily generalized.     

In situ oxygen uptake rates by coastal sediments under the influence of the Rhône River (NW Mediterranean Sea)

The influence of riverine inputs on biogeochemical cycling and organic matter recycling in sediments on the continental shelf off the Rhône River mouth (NW Mediterranean Sea) was investigated by measuring sediment oxygen uptake rates using a combination of in situ and laboratory techniques. Four stations were investigated during two cruises in June 2001 and June 2002, with depths ranging from 9 to 192 m and over a distance to the Rhône River mouth ranging from 4 to 36 km. Diffusive oxygen uptake (DOU) rates were determined using an in situ sediment microprofiler and total oxygen uptake (TOU) rates were measured using sediment core incubations. There was good agreement between these two techniques which indicates that the non-diffusive fraction of the oxygen flux was minimal at the investigated stations. DOU rates ranged from 3.7±0.4 mmol O₂ m⁻² d⁻¹ at the continental shelf break to 19.3±0.5 mmol O₂ m⁻² d⁻¹ in front of the Rhône River mouth. Sediment oxygen uptake rates mostly decreased with increasing depth and with distance from the Rhône mouth. The highest oxygen uptake rate was observed at 63 m on the Rhône prodelta, corresponding to intense remineralization of organic matter. This oxygen uptake rate was much larger than expected for the increasing bathymetry, which indicates that biogeochemical cycles and benthic deposition are largely influenced by the Rhône River inputs. This functioning was also supported by the detailed spatial distribution of total organic carbon (TOC), total nitrogen (TN) and C/N atomic ratio in surficial sediments. Sediments of the Rhône prodelta are enriched in organic carbon (2–2.2%) relative to the continental shelf sediments (<1%) and showed C/N ratios exceeding Redfield stoichiometry for fresh marine organic matter. A positive exponential correlation was found between DOU and TOC contents (r²=0.98, n=4). South-westward of the Rhône River mouth, sediments contained highly degraded organic matter of both terrestrial and marine origin, due to direct inputs from the Rhône River, sedimentation of marine organic matter and organic material redeposition after resuspension events.     

Oligochaetes, organic sedimentation, and trophic state: how to assess the biological recovery of sediments in lakes?

Oligochaete communities were used to assess the biological recovery of sediments after the abatement of eutrophication in Lake Geneva (Switzerland). In 1995, mean relative abundance of oligotrophic worm species (OS) was around 30% in areas of low organic sedimentation (LOS) whereas, in areas of high organic sedimentation (HOS), it was below 15%. The abundance of OS observed in LOS areas was close to values predicted from total phosphorus (TP) concentrations in the water. Recovery from eutrophication proceeded at the same pace in the water (TP) and in the sediment (OS) of LOS areas, whereas it was delayed in the sediment of HOS areas. Lake Geneva was mesotrophic according to the oligochaete communities of LOS areas, but it was meso-eutrophic according to those of HOS areas.     

Potential of turbidity monitoring for measuring the transport of suspended solids in streams

Investigating the transport of suspended solids by water sampling usually leads to an underestimation of loads and an unrealistically high sampling frequency is required to properly characterize temporal trends. An alternative method is to use in situ optical turbidimeters to estimate the suspended solids concentration; however, the relationship between turbidity and suspended solids concentration is potentially confounded by variations in particle size, particle composition and water colour. Field measurements, and laboratory measurements using the type of natural material suspended in streamwater, were made to quantify the influences of these factors on nephelometric turbidity (Hach 2100A) and attenuance turbidity (Partech 7000 3RP MKII). The attenuance turbidity was approximately 2.5 times higher than nephelometric turbidity. The turbidity instruments were most sensitive to dispersions with a median diameter of 1.2-1.4γm. Particle size variation can cause the turbidity to vary by a factor of four for the same concentration of suspended solids. However, the numerous close correlations between turbidity and suspended solids concentration reported previously suggests that either the particle size variations are not usually great, or that particle size variations are often associated with variations in suspended solids concentration. For the same concentration and particle size, organic particles gave attenuance turbidity values two to three times higher than mineral particles. However, shortterm temporal variations from purely organic to purely mineral particle loads are rare in nature, so variations in the percentage of organic matter in the paniculate load will not confound turbidity to this extent. Coloured dissolved organic matter is unlikely to alter the turbidity reading by more than 10%. An adequate relationship between turbidity measured in the field and suspended solids concentration should be expected in most situations. Some variance can be tolerated because a continuous estimate of suspended solids concentration overcomes the problem of infrequent sampling, which is the greatest source of error in the estimation of stream sediment loads.