Shocked gas around Cepheus A: evidence for multiple outflows from H2S and SO2 observations

The Cepheus A star-forming region has been investigated through a multiline H₂S and SO₂ survey at millimetre wavelengths. Large-scale maps and high-resolution line profiles reveal the occurrence of several outflows. Cep A East is associated with multiple mass-loss processes: in particular, we detect a 0.6-pc jet-like structure which shows for the first time that the Cep A East young stellar objects are driving a collimated outflow moving towards the south.
The observed outflows show different clumps associated with definitely different H₂S/SO₂ integrated emission ratios, indicating that the gas chemistry in Cepheus A has been altered by the passage of shocks. H₂S appears to be more abundant than SO₂ in high-velocity clumps, in agreement with chemical models. However, we also find quite small H₂S linewidths, suggestive of regions where the evaporated H₂S molecules had enough time to slow down but not to freeze out on to dust grains. Finally, comparison between the line profiles indicates that the excitation conditions increase with the velocity, as expected for a propagation of collimated bow shocks.     

Class II maser candidates in substituted methanol: CH3OD, 13CH3OH, CH318OH and CH3SH

We investigate the possibility of interstellar masers in transitions of the methanol isotopomers CH₃OD, ¹³CH₃OH and CH₃¹⁸OH, and of CH₃SH. The model used, in which masers are pumped through the first and second torsionally excited states by IR radiation, has accounted successfully for the Class II masers in main species methanol, ¹²CH₃¹⁶OH. Several potential maser candidates are identified for CH₃OD, their detectability depending on the enrichment of this species in star-forming regions. In ¹³CH₃OH and CH₃¹⁸OH the best maser candidates are direct counterparts of the well-known 6.7- and 12.2-GHz methanol masers, but the lower interstellar abundance of these substituted species means that the expected brightness is greatly reduced. The maser candidates in CH₃SH are also weak. By comparing these species we find that the large b -component of the dipole moment in methanol plays a significant role in its propensity to form masers, as does the strong torsion–rotation interaction due to the light hydroxyl frame. Thus the exceptional brightness of interstellar methanol masers is due to a favourable combination of molecular properties as well as high interstellar abundance.     

Unlocking the Keyhole: H2 and PAH emission from molecular clumps in the Keyhole Nebula

To better understand the environment surrounding CO emission clumps in the Keyhole Nebula, we have made images of the region in H₂ 1–0 S(1) (2.122-μm) emission and polycyclic aromatic hydrocarbon (PAH) emission at 3.29 μm. Our results show that the H₂ and PAH emission regions are morphologically similar, existing as several clumps, all of which correspond to CO emission clumps and dark optical features. The emission confirms the existence of photodissociation regions (PDRs) on the surface of the clumps. By comparing the velocity range of the CO emission with the optical appearance of the H₂ and PAH emission, we present a model of the Keyhole Nebula whereby the most negative velocity clumps are in front of the ionization region, the clumps at intermediate velocities are in it and those which have the least negative velocities are at the far side. It may be that these clumps, which appear to have been swept up from molecular gas by the stellar winds from η  Car, are now being overrun by the ionization region and forming PDRs on their surfaces. These clumps comprise the last remnants of the ambient molecular cloud around η Car.     

Calculations on the rates, mechanisms, and interstellar importance of the reactions between C and NH2 and between N and CH2

The attempt to understand the temperature dependence of the HNC/HCN abundance ratio in interstellar clouds has been long standing and indecisive. In this paper we report quantum chemical and dynamical studies of two neutral–neutral reactions thought to be important in the formation of HNC and HCN, respectively – C+NH₂→HNC+H, and N+CH₂→HCN+H. We find that although these reactions do lead initially to the products suggested by astronomers, there is so much excess energy available in both reactions that the HCN and HNC products are able to undergo efficient isomerization reactions after production. The isomerization leads to near equal production rates of the two isomers, with HNC slightly favoured if there is sufficient rotational excitation. This result has been incorporated into our latest chemical model network of dense interstellar clouds.     

On the detection of the linear C5 molecule in the interstellar medium

An upper limit of the column density of the C₅ linear molecule in translucent interstellar clouds is estimated from high-resolution ( R =80 000) and very high signal-to-noise ratio (∼1000) echelle spectra. It is 10¹² cm⁻² per E ( B − V )=1 (two orders of magnitude lower than that of C₂).     

H3+ in diffuse interstellar gas

A model is constructed of the material in front of the star Cygnus OB2 no. 12 in which dense cores are embedded in diffuse clumps of gas. The model reproduces the measured abundances of C₂ and CO, and predicts a column density of 910¹⁰ cm² for HCO⁺.     

The distribution of C2S and NH3 in two Bok globules at different evolutionary stages: CB246 and CB34

Two Bok globules, L1253 (CB246) and CB34, have been mapped in the C₂S (2₁–1₀) transition and in the NH₃ (1, 1) and NH₃ (2, 2) inversion transitions, respectively. By comparing the C₂S map of L1253 (CB246) with the NH₃ map of the same globule from Lemme et al., a clumped onion structure results as a consequence of the chemical and dynamical evolution of the object. From the derived parameters it appears that both L1253 (CB246) and CB34 are close to virial equilibrium.     

A source of extended HCO+ emission in young stellar objects

Anomalous molecular line profile shapes are the strongest indicators of the presence of the infall of gas that is associated with star formation. Such profiles are seen for well-known tracers, such as HCO⁺, CS and H₂CO. In certain cases, optically thick emission lines with appropriate excitation criteria may possess the asymmetric double-peaked profiles that are characteristic of infall. However, recent interpretations of the HCO⁺ infall profile observed towards the protostellar infall candidate B335 have revealed a significant discrepancy between the inferred overall column density of the molecule and that which is predicted by standard dark cloud chemical modelling.
This paper presents a model for the source of the HCO⁺ emission excess. Observations have shown that, in low-mass star-forming regions, the collapse process is invariably accompanied by the presence of collimated outflows; we therefore propose the presence of an interface region around the outflow in which the chemistry is enriched by the action of jets. This hypothesis suggests that the line profiles of HCO⁺, as well as other molecular species, may require a more complex interpretation than can be provided by simple, chemically quiescent, spherically symmetric infall models.
The enhancement of HCO⁺ depends primarily on the presence of a shock-generated radiation field in the interface. Plausible estimates of the radiation intensity imply molecular abundances that are consistent with those observed. Further, high-resolution observations of an infall-outflow source show HCO⁺ emission morphology that is consistent with that predicted by this model.     

Imaging and integral-field spectroscopy of shocked H2 around G25.65+1.05

The results of B -band CCD imaging linear polarimetry obtained for stars from the Hipparcos catalogue are used to re-examine the distribution of the local interstellar medium towards the IRAS 100-μm emission void in the Lupus dark clouds. The analysis of the obtained parallax–polarization diagram assigns to the dark cloud Lupus 1 a distance between 130 and 150 pc and assures the existence of a low column density region coincident with the observed infrared void. Moreover, there are clear indications of the existence of absorbing material at distances closer than 60–100 pc, which may be associated with the interface boundary between the Local Bubble and its neighbourhood Loop I superbubble.     

A study of the behaviour of the Na i/K i column density ratio in the interstellar medium using the Na ultraviolet doublet

Here we make a new study of the behaviour of the Na  i /K  i column density ratio in the interstellar medium, using a sample of new observations of 28 stars obtained at the Nordic Optical Telescope (NOT) in 1996 and 1997, and previously published observations (obtained by some of the authors) of 21 stars. The sightlines cover a range of distances and directions, including into the Galactic halo. We make use of new observations of the Na  i ultraviolet (UV) doublet for some 18 stars. This doublet is much weaker than the Na  i D doublet and so is less susceptible to saturation effects, and it is well known that it can be used to obtain more accurate Na  i column densities with a smaller error range. We find an average N (Na  i )/ N (K  i ) ratio from the Na  i UV data of about 90, which is rather higher than that found previously by Hobbs and Lequeux. The Na  UV–K  i   ratio shows a small increase in value with increasing column density, while we also find a sample of low N (Na  i )/ N (K  i ) ratio clouds generally seen towards distant objects on high-latitude sightlines that reach into the halo, so that the ratio decreases more sharply at lower column densities. As the values of the ratio for these halo clouds  (10–20)  bracket the cosmic Na/K abundance ratio, we suggest that these ratios result from a harder radiation field in the lower halo, such that the ionized fractions of Na  i and K  i become similar. Clearly caution needs to be applied in using any kind of 'standard value' for the Na  i /K  i column density ratio.     

New models of interstellar gas–grain chemistry – III. Solid CO2

Solid CO₂ is observed to be an abundant interstellar ice component towards both quiescent clouds and active star-forming regions. Our recent models of gas–grain chemistry, appropriate for quiescent regions, severely underproduce solid CO₂ at the single assumed gas density and temperature. In this paper, we investigate the sensitivity of our model results to changes in these parameters. In addition, we examine how the nature of the grain surface affects the results and also consider the role of the key surface reaction between O and CO. We conclude that the observed high abundance of solid CO₂ can be reproduced at reasonable temperatures and densities by models with diffusive surface chemistry, provided that the diffusion of heavy species such as O occurs efficiently.     

Additional ultra-high-resolution observations of Ca+ ions in the local interstellar medium

We present ultra-high-resolution (0.35 km s⁻¹ FWHM) observations of the interstellar Ca K line towards seven nearby stars. The spectral resolution was sufficient to resolve the line profiles fully, thereby enabling us to detect hitherto unresolved velocity components, and to obtain accurate measurements of the velocity dispersions ( b values). Absorption components with velocities similar to those expected for the Local Interstellar Cloud (LIC) and the closely associated 'G cloud' were identified towards six of the seven stars. However, in most cases the b values deduced for these components were significantly larger than the b  ≈ 2.2 km s⁻¹ (i.e. T _k ≈ 7000 K, v _t ≈ 1 km s⁻¹) expected for the LIC, and it is argued that this results from the presence of additional, spectrally unresolved, components having similar velocities and physical conditions. For two stars (δ Vel and α Pav) we detect interstellar components with much smaller b values (1.1 ± 0.3 and 0.8 ± 0.1 km s⁻¹, respectively) than are expected for low-density clouds within the Local Bubble. In the case of the narrow α Pav component, we also find an anomalously large Na  i /Ca  ii column density ratio, which is indicative of a relatively high density. Thus it is possible that, in addition to LIC-type clouds, the local interstellar medium contains a population of previously undetected cooler and denser interstellar clouds.     

The excitation and kinematical properties of H2 and [Fe ii] in the HH 46/47 bipolar outflow

Long-slit spectra of the molecular outflow Herbig–Haro (HH) 46/47 have been taken in the J and K near-infrared bands. The observed H₂ line emission confirms the existence of a bright and extended redshifted counter-jet outflow south-west of HH 46. In contrast with the optical appearance of this object, we show that this outflow seems to be composed of two different emission regions characterized by distinct heliocentric velocities. This implies an acceleration of the counter-jet.
The observed [Fe  ii ] emission suggests an average extinction of 7–9 visual magnitudes for the region associated with the counter-jet.
Through position–velocity diagrams, we show the existence of different morphologies for the H₂ and [Fe  ii ] emission regions in the northern part of the HH 46/47 outflow. We have detected for the first time high-velocity (−250 km s⁻¹) [Fe  ii ] emission in the region bridging HH 46 to HH 47A. The two strong peaks detected can be identified with the optical positions B8 and HH 47B.
The H₂ excitation diagrams for the counter-jet shock suggest an excitation temperature for the gas of T _ex≈2600 K . The lack of emission from the higher energy H₂ lines, such as the 4–3 S(3) transition, suggests a thermal excitation scenario for the origin of the observed emission. Comparison of the H₂ line ratios with various shock models yielded useful constraints about the geometry and type of these shocks. Planar shocks can be ruled out whereas curved or bow shocks (both J- and C-type) can be parametrized to fit our data.     

On the identification of the C60+ interstellar features

The identity of the carriers of the diffuse interstellar bands (DIBs) is one of the most fascinating puzzles of modern spectroscopy. Over the last few years the number of known DIBs has grown substantially. In this paper we discuss the two recently discovered near-infrared weak interstellar features which have already been proposed as fingerprints of the buckminsterfullerene We present and discuss measurements of the two related DIBs within a larger sample of reddened targets, observed with different spectrometers, telescopes and site conditions. We provide additional arguments in favour of the interstellar origin of the two bands. We find evidence around the 9577-Å DIB of far-wing structures, which may affect broad-band measurements. We estimate corrections and errors for telluric and stellar blends, and show that the cores of the two DIBs are well correlated with a ratio near unity within 20 per cent. Finally, we discuss their relation to the laboratory spectra of and the search for two expected weaker transitions.     

Detection of HCO+ towards Cygnus OB2 No. 12

HCO⁺ has been detected for the first time towards the star Cygnus OB2 No. 12 through emission of the 1–0 rotational transition at 89 GHz. The CO( J =2−1) transition has also been observed. The observations are consistent with a model of dense regions embedded in a low-density clump gas. If actually present, the dense component would have an aggregate size L 1300 au, in agreement with estimates of small-scale density fluctuations observed along diffuse lines of sight.     

Discovery of a dense bipolar outflow from a new class 0 protostar in NGC 2068/LBS 17

We report the discovery of high-velocity dense gas from a bipolar outflow source near NGC 2068 in the L1630 giant molecular cloud. CO and HCO⁺ J =3→2 line wings have a bipolar distribution in the vicinity of LBS 17-H with the flow orientated roughly east–west and perpendicular to the elongation of the submillimetre dust continuum emission. The flow is compact (total extent ∼0.2 pc) and contains of the order of 0.1 M_⊙ of swept-up gas. The high-velocity HCO⁺ emission is distributed over a somewhat smaller area <0.1 pc in extent.
A map of C¹⁸O J =2→1 emission traces the LBS 17 core and follows the ambient HCO⁺ emission reasonably well, with the exception of the direction towards LBS 17-H where there is a significant anticorrelation between the C¹⁸O and HCO⁺. A comparison of beam-matched C¹⁸O and dust-derived H₂ column densities suggests that CO is depleted by up to a factor of ∼50 at this position if the temperature is as low as 9 K, although the difference is substantially reduced if the temperature is as high as 20 K. Chemical models of collapsing clouds can account for this discrepancy in terms of different rates of depletion on to dust grains for CO and HCO⁺.
LBS 17-H has a previously known water maser coincident with it but there are no known near-infrared, IRAS or radio continuum sources associated with this object, leading to the conclusion that it is probably very young. A greybody fit to the continuum data gives a luminosity of only 1.7 L_⊙ and a submillimetre-to-bolometric luminosity ratio of 0.1, comfortably satisfying the criteria for classification as a class 0 protostar candidate.