Ta含量对Ti-6Al-3Nb-2Zr-1Mo-xTa合金力学性能和腐蚀性能的影响（英文）

系统研究了Ti-6Al-3Nb-2Zr-1Mo-x Ta (x=0, 0.2, 0.5, 1.0, 3.0, 5.0)合金的微观组织、拉伸性能、夏比冲击韧性和耐海水腐蚀性。结果表明,经α+β两相区锻造后,Ti-6Al-3Nb-2Zr-1Mo-5Ta合金获得片层组织,Ti-6Al-3Nb-2Zr-1Mo-x Ta (x=0, 0.2, 0.5, 1.0, 3.0)均获得双态组织。XRD、TEM和选区电子衍射表明,在添加Ta元素后,Ti-6Al-3Nb-2Zr-1Mo-x Ta合金没有新相产生。对于双态组织Ti-6Al-3Nb-Zr-1M0-x Ta合金,随着Ta含量的增加,其Mo当量逐渐增加,导致其屈服强度、抗拉强度和显微硬度均有所提高。而Ta含量对冲击吸收功的影响规律与屈服强度和抗拉强度的影响规律相反,其大小与冲击断口剪切唇区面积一致。当Ta含量超过1.0%(质量分数)时,由于α和β相之间的标准平衡电位差逐渐增大,Ti-6Al-3Nb-2Zr-1Mo-x Ta合金的耐海水腐蚀逐渐降低。综合考虑强度、冲击韧性和耐海水腐蚀性能,Ti-6Al-3Nb-2Zr-1Mo-1Ta合金综合匹配性最好,具有良好的海洋工程应用潜力。     

退火温度对Ti-6Al-3Nb-2Zr-1Mo合金组织及力学性能的影响

研究了退火温度对Ti-6Al-3Nb-2Zr-1Mo合金组织和力学性能的影响。结果表明:随着退火温度升高,初生α相含量降低,2°～15°小角度晶界逐渐减少;退火温度较高时,退火过程中发生了α相→β相→α相的相变,<0001>//横向织构消失。随着退火温度升高,Ti-6Al-3Nb-2Zr-1Mo合金屈服强度逐渐降低,抗拉强度、延伸率先升高后降低。退火温度升高后,片层组织比例升高,裂纹扩展功占冲击吸收功的比例增大,材料韧性提升。     

Cr、V对多组元Ti-Al合金组织的影响

通过向Ti-44Al-4Nb-1Mo-0.1B合金分别添加Cr、V,研究合金化元素和热处理对合金组织的影响。结果表明,Ti-44Al-4Nb-1Mo-0.1B合金铸态组织由(α_2+γ)片层团、钼化物和B_2相构成;加入Cr或V后,形成Cr B相和Ti_(0.925)V_(0.075)相,片层组织得到细化;随着Cr或V的增多,B2相也增多,细化程度增强。热处理后Ti-44Al-4Nb-1Mo-0.1B合金为双态组织,Ti-44Al-4Nb-1Mo-0.1B-1Cr合金为全片层组织,Ti-44Al-4Nb-1Mo-0.1B-1V合金为近片层组织。Cr对α相转变温度的降低程度强于V。     

低弹性模量Ti-33Nb-4Sn,Ti-31Nb-3Zr-4Sn钛合金在模拟人工体液中的腐蚀行为研究

采用纳米压痕仪研究了Ti-33Nb-4Sn和Ti-31Nb-3Zr-4Sn合金的力学性能。采用动电位极化曲线、电化学阻抗谱研究了新型医用钛合金Ti-33Nb-4Sn、Ti-31Nb-3Zr-4Sn和对比合金Ti-6Al-4V在模拟人体体液中电化学腐蚀行为,并根据扫描电镜和X射线衍射仪对极化测试后的试样表面形貌和相结构进行观察。结果表明,Ti-33Nb-4Sn和Ti-31Nb-3Zr-4Sn合金具有较低的弹性模量;3种合金的腐蚀电流密度按Ti-6Al-4V、Ti-31Nb-3Zr-4Sn和Ti-33Nb-4Sn的顺序递增。     

变钒含量钛铝基合金组织和性能研究

设计了三种钛铝基合金,名义成分为Ti-44Al-4Nb-1Mo-0.1B (1~#),Ti-44Al-4Nb-1Mo-0.1B-1V (2~#)和Ti-44Al-4Nb-1Mo-0.1B-3V(3~#),通过控制钒的含量来研究合金的微观组织及其性能。利用光学显微镜(OM)及扫描电子显微镜(SEM)观察并分析合金的组织转变,进行了抗氧化性能和硬度测试。结果表明:合金铸态下的组织主要由α_2+γ片层和少量B_2相组成,B_2相的数量随V的加入而增多。合金的抗氧化性随V的加入急剧降低;铸态下,硬度随V含量的增加先降低后增大,热处理后的硬度随V含量增加而逐渐增大。     

β-CEZ合金和Ti-6Al-4V合金疲劳性能和断裂性能的比较

近来由于飞机高强框架和喷气发动机元件用β-Ti合金取代α β钛合金。因此，德国的J.D.PETERS和他的老师G.LUTJERING教授比较了高强β-CEZ钛合金和α β的Ti-6Al-4V合金的疲劳和断裂特性，β-Ti合金如Ti-17(Ti-5Al-2Sn-2Zr-4Mo-4Cr)和Ti-10V-2Fe-3Al已分别被用作喷气发动机压缩机和起落架材料，主要是因为它们的强度高于Ti-6Al-4V合金。他们首先比较了喷气发动机常用的Ti-6Al-4V合金和新近研制的β-CEZ(Ti-5Al-2Sn-4Zr-4Mo-2Cr-1Fe)合金的疲劳和断裂特性，以及屈服强度等性能，由于断裂韧性是压缩机和起落架构件设计…     

热加工过程中2种原始组织的Ti-5Al-2Sn-2Zr-4Mo-4Cr合金变形行为（英文）

采用等温压缩试验研究不同原始组织对Ti-5Al-2Sn-2Zr-4Mo-4Cr合金流动应力、应变速率敏感性指数、应变硬化指数和表观变形激活能的影响。结果表明:原始组织为片层组织的Ti-5Al-2Sn-2Zr-4Mo-4Cr合金具有更高的峰值应力和流动软化效应,当变形温度高于或等于810°C、应变速率为0.1~5.0 s-1时,原始组织为等轴组织的Ti-5Al-2Sn-2Zr-4Mo-4Cr合金存在初始屈服现象。当应变为0.5~0.7、变形温度较低、应变速率为0.01 s-1时,原始组织为等轴组织的Ti-5Al-2Sn-2Zr-4Mo-4Cr合金的应变速率敏感性指数值较大,这主要归因于其显微组织演变特征。隋着变形的进行,原始组织为片层组织的Ti-5Al-2Sn-2Zr-4Mo-4Cr合金发生了α片层弯曲和动态球化现象,这使得其应变硬化指数变化显著。当应变为0.15~0.55时,原始组织为片层组织的Ti-5Al-2Sn-2Zr-4Mo-4Cr合金的表观变形激活能更大。     

Ti-22Al-20Nb-7Ta合金的显微组织和力学性能研究

研究了Ti-22Al-20Nb-7Ta合金的显微组织和力学性能,为优化合金的塑性(特别是室温塑性)和强度,采用了多种热机械处理(TMP)工艺.结果表明,合金显微组织与热机械处理工艺密切相关.通过热机械处理可有效地控制合金中α2,O和B2相的形貌,分布状况及相对含量进而获得了具有高的室温及高温屈服强度和优良塑性的O相合金.在(α2+B2+O)和(O+B2)相区热变形及在(O+B2)相区的固溶和时效处理获得的三相复合显微组织具有最佳的力学性能.Ti-22Al-20Nb-7Ta合金的室温屈服强度σ0.2达1200 MPa,延伸率达9.8%,650℃下σ0.2亦达970 MPa,延伸率达14%.     

高强韧Ti-6Al-2Zr-2Sn-3Mo-2Nb-1Cr-0.1Si-xFe钛合金的组织和压缩性能

利用光学显微镜(0M)、扫描电镜(SEM)、X射线衍射(XRD)、维氏硬度计、电子万能试验机和分离式霍普金森压杆(SHPB)等分析测试方法,研究了Ti-6Al-2Zr-2Sn-3Mo-2Nb-1Cr-0.1Si-xFe(x=0,0.4,0.8,质量分数,％)铸态合金双重退火后的组织和力学性能.结果 表明:3种铸态合金的...     

牙科用铸造Ti-15Zr-4Nb-4Ta合金

Ti，Zr，Nb，Ta等金属具有优越的生物相容性．被广泛应用到生物材料中。日本学者Yoshimitsu Okazaki等人研究了铸造Ti-15Zr-4Nb-4Ta合金、Co-Cr-Mo和Ti-6Al-7Nb合金的室温力学性能和疲劳强度，并对Ti-15Zr-4Nb-4Ta合金制作的假牙牙托进行了超过1年的临床观察。     

Characterization of the Ti-10Nb-10Zr-5Ta Alloy for Biomedical Applications. Part 1: Microstructure, Mechanical Properties, and Corrosion Resistance

Ti-10Nb-10Zr-5Ta alloy was investigated as possible material candidate for replacing Ti6Al4V in medical applications. The alloy was prepared in a levitation melting furnace and characterized in terms of elemental and phase composition, microstructure, mechanical properties, and corrosion resistance in simulated body fluid and Fusayama Meyer artificial saliva solutions. The characteristics of the new alloy were compared to those of the Ti6Al4V alloy. The Ti-10Nb-10Zr-5Ta system was found to posses of a polyhedral structure consisting in α′ and β phases. X-ray structural analysis revealed a mixture of hexagonal α′ martensite (main phase, with grain size of about 21 nm) and β bcc phase. The Ti-10Nb-10Zr-5Ta alloy exhibited some better mechanical properties (Young modulus, tensile properties) and corrosion resistance (polarization resistance, corrosion current density, and corrosion rate), as compared to Ti6Al4V alloy.     

Characterization of the Ti-10Nb-10Zr-5Ta Alloy for Biomedical Applications. Part 2: Wettability, Tribological Performance and Biocompatibility

The Ti-10Nb-10Zr-5Ta alloy, prepared in a levitation melting furnace, was investigated as a possible candidate for replacing Ti6Al4V alloy in medical applications. The sessile drop method, pin-on-disc and in vitro tests were used to analyze wettability, wear resistance, and biocompatibility of the new alloy. The characteristics of the Ti-10Nb-10Zr-5Ta alloy were assessed in comparison to those of the Ti6Al4V alloy. The Ti-10Nb-10Zr-5Ta system was found to have hydrophilic characteristics with similar contact angle as the Ti6Al4V alloy. In all environments (deionized water, simulated body fluid and Fusayama Meyer artificial saliva), the friction coefficient showed a stable evolution versus sliding distance, being similar for both alloys. On overall, the wear resistance of Ti-10Nb-10Zr-5Ta alloy was lower than that of Ti6Al4V for all testing environments. The Ti-10Nb-10Zr-5Ta alloy exhibited good biocompatibility characteristics at in vitro test compared to Ti6Al4V alloy. The cell viability on Ti-10Nb-10Zr-5Ta surfaces was higher than the one observed on Ti6Al4V samples, regardless the number of days spent in osteoblast-like cells culture. A high degree of cell attachment and spreading was observed on both alloys.     

Ti-6Al-2Zr-1Mo-3Nb合金微弧氧化陶瓷膜的结构与性能

利用微弧氧化技术,在Ti-6Al-2Zr-1Mo-3Nb合金表面制备陶瓷涂层。用扫描电镜和X射线衍射仪观察并分析陶瓷膜层的组织形貌和相结构,用电子万能材料试验机和数字万用表研究膜层的结合强度和绝缘性,并用MMS-1G高温高速销盘摩擦磨损试验机和YWX/Q-750盐雾试验机考察涂层的摩擦性能和耐腐蚀性能。结果表明:陶瓷层主要由金红石TiO2相和锐钛矿TiO2相构成,膜基结合强度达到30MPa以上,膜层绝缘性和耐腐蚀性良好,耐磨性得到明显改善,涂层的磨损机制表现为轻微的磨粒磨损与粘着磨损。     

Sintering Behavior and Microstructure Formation of Titanium Aluminide Alloys Processed by Metal Injection Molding

The sintering behavior of metal injection molded titanium aluminide alloys, their microstructure formation and resulting mechanical properties were investigated. As reference material, the alloy Ti-45Al-5Nb-0.2B-0.2C at.% (TNB-V5) was selected. Additionally, two other variations with Mo and Mo + Si additions were prepared: Ti-45Al-3Nb-1Mo-0.2B-0.2C at.% and Ti-45Al-3Nb-1Mo-1Si-0.2B-0.2C at.%. The results indicate that the optimum sintering temperature was slightly above the solidus line. With proper sintering parameters, very low porosities (<0.5%) and fine microstructures with a colony size <85 µm could be achieved. Considering the sintering temperatures applied, the phase transformations upon cooling could be described as L + β → β → α + β → α → α + γ → α₂ + γ, which was in agreement with the microstructures observed. The effects of Mo and Si were opposite regarding the sintering behavior. Mo addition led to an increase in the optimum sintering temperature, whereas Si caused a significant decrease.     

油气开采用钛合金石油管材料耐腐蚀性能研究

选取5种油气开发常用钛合金材料(Ti-6Al-4V、Ti-6Al-4V-0.1Ru、Ti-6Al-2Sn-4Zr-6Mo、Ti-3Al-8V-6Cr-4Zr-4Mo和Ti-5.5Al-4.5V-2Zr-1Mo)为研究对象,使用高温高压釜模拟国内典型严酷服役工况环境,研究了不同钛合金材料耐均匀腐蚀、局部腐蚀、点蚀、应力腐蚀开裂(SCC)及缝隙腐蚀的性能,通过使用扫描电镜和能谱分析等手段对腐蚀形貌和腐蚀产物进行了分析,并使用电化学方法对不同合金的耐腐蚀机理进行了研究。结果显示,在所测试工况条件下,所有钛合金材料腐蚀反应均为阳极控制过程,均匀腐蚀速率均低于0.001mm/a,并且对应力腐蚀开裂均有良好的抗力。Ti-6Al-4V和Ti-5.5Al-4.5V-2Zr-1Mo合金出现明显的点蚀和缝隙腐蚀问题。对腐蚀机理研究表明,在工况条件温度下,随着pH值的降低,所有钛合金均发生自腐蚀电位降低,极化电阻减小,腐蚀电流增大,耐腐蚀性能下降,其中Ti-6Al-4V耐腐蚀性能下降的最为明显,研究结果为油气开发工况下钛合金石油管的选材和缝隙腐蚀问题防治提供理论基础。     

Ti-15Mo-3Al-2.7Nb-0.2Si钛合金绝热剪切带的微观结构演化

采用分离式Hopkinson压杆技术对Ti-15Mo-3Al-2.7Nb-0.2Si钛合金的帽形试样进行了强迫剪切试验,通过扫描电镜(SEM)及透射电镜(TEM)研究了Ti-15Mo-3Al-2.7Nb-0.2Si钛合金在动态加载下绝热剪切带的微观结构演化.结果表明:Ti-15Mo-3Al-2.7Nb-0.2Si钛合金由于其组织以bee晶格的a相为主,具有较好的变形能力,因此其绝热剪切带的形成是位错运动的结果;剪切带的微观结构演化过程为:晶粒在外加切应力作用下拉长变形一拉长晶粒的破碎-形成呈一定方向排列的细小等轴晶:带内形成的细小等轴晶尺寸为O.2～0.4ìm.     

Titanium alloys after surface gas nitriding

Experimental studies using differential scanning calorimetry (DSC) for nitriding of four titanium-alloys near α Ti-8Al-1Mo-1V, near α Ti-6Al-2Sn-4Zr-2Mo, α + β Ti-6Al-4V and near β Ti-10V-2Fe-3Al at different temperatures and for different periods of time are presented. The X-ray diffraction (XRD) technique was used in order to study the phase transformations that occur during gas nitriding. As a result of the nitrogen interaction, a nitrided layer was formed that consists of titanium nitrides, followed by an interstitial solution of nitrogen in the hcp α titanium phase. The microstructural changes of these alloys in relation to the alloy composition and processing parameters were studied. It was found that the microstructure of alloys nitrided at temperatures below their β transus temperatures for various periods of time is uniform and homogeneous. With the increase of the temperature above their β transus temperatures the microstructure changes to irregular. Microindentation hardness testing using a Knoop indenter was conducted on the nitrided titanium alloys to analyse their hardness evolution in relation to the nitriding processing parameters and alloy composition. It was found that the microhardness increases with the increase of the temperature and time of nitriding. The surface morphology of the Ti-6Al-2Sn-4Zr-2Mo alloy in relation to the nitriding processing parameters was analysed.     

放电等离子烧结技术制备(Ti-35Nb-7Zr-5Ta)-15HA复合材料微观组织的演变及生物活性

为了提高生物材料的生物活性并降低弹性模量,利用放电等离子烧结技术制备(Ti-35Nb-7Zr-5Ta)-15HA生物复合材料,研究不同烧结温度(950~1150℃)对复合材料相对密度、微观组织演变、力学性能及生物活性的影响。结果表明:随着温度的升高,复合材料相对密度从87.6%提高到97.5%;复合材料主要由β-Ti相、α-Ti相及陶瓷相,如Ti2O、CaZrO3、CaO、Ti5P3和Ca3(PO4)2等组成;复合材料的弹性模量为30~95 GPa、抗压强度为593~1978 MPa,而且随着烧结温度升高呈增大趋势;同时,在模拟体液中浸泡14 d后,复合材料表面能够获得类骨磷灰石,显示出良好的生物活性,但随着温度的升高,类骨磷灰石含量不断减少。因此,950℃下烧结的(Ti-35Nb-7Zr-5Ta)-15HA生物复合材料是潜在的良好的生物植入材料。     

INFLUENCE OF ALLOYING ELEMENTS（Nb，Mo，V） ON MICROSTRUCTURE OF Ti_3Al BASE ALLOYS

ＩＮＦＬＵＥＮＣＥＯＦＡＬＬＯＹＩＮＧＥＬＥＭＥＮＴＳ（Ｎｂ,Ｍｏ,Ｖ）ＯＮＭＩＣＲＯＳＴＲＵＣＴＵＲＥＯＦＴｉ_３ＡｌＢＡＳＥＡＬＬＯＹＳ￥ＳＯＮＧＤａｎ;ＤＩＮＧＪｉｎｊｕｎ;ＷＡＮＧＹａｎｄｏｎｇ（ＡｎａｌｙｓｉｓａｎｄＴｅｓｔｉｎｇＣｅｎｔｅ?..     

新型医用Ti-24Nb-4Zr-8Sn合金在Hanks溶液中的电化学腐蚀行为研究

采用极化曲线分析、电化学阻抗谱（EIS）测试和浸泡实验的方法,并结合XPS,XRD和SEM等分析手段对新型医用Ti-24Nb-4Zr-8Sn合金在37℃的Hanks人工模拟体液中的电化学腐蚀行为进行了研究,并与纯Ti和Ti-6Al-4V合金进行了比较.结果表明:在37℃的Hanks溶液中,Ti-24Nb-4Zr-8Sn合金的腐蚀电流密度与纯Ti相等,并且钝化性能优于纯Ti和Ti-6Al-4V,这与其钝化膜中存在大量的Nb₂O₅密切相关;EIS结果显示,Ti-24Nb-4Zr-8Sn合金表面形成内层致密而外层疏松的双层钝化膜结构,致密层特性对材料的耐蚀性能起到决定性作用;随着浸泡时间的延长,致密内层的电阻大幅度提高,Ti-24Nb-4Zr-8Sn合金的耐蚀性能增强,同时疏松外层中的微缺陷发展成为宏观裂纹,造成疏松外层整体脱落.