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1.
In plasma spraying, the arc-root fluctuations, modifying the length and characteristics of the plasma jet, have an important influence on particle thermal treatment. These voltage fluctuations are strongly linked to the thickness of the cold boundary layer (CBL), surrounding the arc column. This thickness depends on the plasma spray parameters (composition and plasma forming gas mass flow rate, arc current, etc.) and the plasma torch design (anode-nozzle internal diameter and shape, etc.). In order to determine the influence of these different spray parameters on the CBL properties and voltage fluctuations, experiments were performed with two different plasma torches from Sulzer Metco. The first one is a PTF4 torch with a cylindrical anode-nozzle, working with Ar-H2 plasma gas mixtures and the second one is a 3MB torch with either a conical or a cylindrical anode-nozzle, working with N2-H2 plasma gas mixtures. Moreover, arc voltage fluctuations influence on particle thermal treatment was studied through the measurements of transient temperature and velocity of particles, issued from an yttria partially stabilized zirconia powder with a size distribution between 5 and 25 μm. This article is an invited paper selected from presentations at the 2007 International Thermal Spray Conference and has been expanded from the original presentation. It is simultaneously published in Global Coating Solutions, Proceedings of the 2007 International Thermal Spray Conference, Beijing, China, May 14-16, 2007, Basil R. Marple, Margaret M. Hyland, Yuk-Chiu Lau, Chang-Jiu Li, Rogerio S. Lima, and Ghislain Montavon, Ed., ASM International, Materials Park, OH, 2007.  相似文献   

2.
Wear at the electrode surfaces of a one-cathode plasma torch changes the characteristic fluctuation pattern of the plasma jet. This affects the trajectory of the particles injected into the plasma jet in a non-controllable way, which degrades the reproducibility of the process. Time-based voltage measurements and Fourier analysis were carried out on a one-cathode F4 torch at different wear conditions to determine the evolution of wear dependant characteristics. A significant correlation is observed between increasing torch wear and decreasing voltage roughness and high frequency noise. Furthermore, by means of particle diagnostic systems, the change in the particle velocity and temperature has been measured. The variations of the particle characteristics are significant and thus an influence on the sprayed coating microstructure is to be expected. This article is an invited paper selected from presentations at the 2007 International Thermal Spray Conference and has been expanded from the original presentation. It is simultaneously published in Global Coating Solutions, Proceedings of the 2007 International Thermal Spray Conference, Beijing, China, May 14-16, 2007, Basil R. Marple, Margaret M. Hyland, Yuk-Chiu Lau, Chang-Jiu Li, Rogerio S. Lima, and Ghislain Montavon, Ed., ASM International, Materials Park, OH, 2007.  相似文献   

3.
Plasma spraying using liquid feedstock makes it possible to produce thin coatings (<100 μm) with more refined microstructures than in conventional plasma spraying. However, the low density of the feedstock droplets makes them very sensitive to the instantaneous characteristics of the fluctuating plasma jet at the location where they are injected. In this study, the interactions between the fluctuating plasma jet and droplets are explored by using numerical simulations. The computations are based on a three-dimensional and time-dependent model of the plasma jet that couples the dynamic behaviour of the arc inside the torch and the plasma jet issuing from the plasma torch. The turbulence that develops in the jet flow issuing in air is modeled by a large Eddy simulation model that computes the largest structures of the flow which carry most of the energy and momentum. This article is an invited paper selected from presentations at the 2007 International Thermal Spray Conference and has been expanded from the original presentation. It is simultaneously published in Global Coating Solutions, Proceedings of the 2007 International Thermal Spray Conference, Beijing, China, May 14-16, 2007, Basil R. Marple, Margaret M. Hyland, Yuk-Chiu Lau, Chang-Jiu Li, Rogerio S. Lima, and Ghislain Montavon, Ed., ASM International, Materials Park, OH, 2007.  相似文献   

4.
Finely structured ceramic coatings can be obtained by solution precursor plasma spraying. The final structure of the coating highly depends on the droplet size and velocity distribution at the injection, the evolution of the spray in the jet, and droplet breakup and collision within the spray. This article describes a 3D model to simulate the transport phenomena and the trajectory and heating of the solution spray in the process. O’Rourke’s droplet collision model is used to take into account the influence of droplet collision. The influence of droplet breakup is also considered by implementing TAB droplet breakup models into the plasma jet model. The effects of droplet collisions and breakup on the droplet size, velocity, and temperature distribution of the solution spray are investigated. The results indicate that droplet breakup and collision play an important role in determining the final particle size and velocity distributions on the substrate. This article is an invited paper selected from presentations at the 2007 International Thermal Spray Conference and has been expanded from the original presentation. It is simultaneously published in Global Coating Solutions, Proceedings of the 2007 International Thermal Spray Conference, Beijing, China, May 14-16, 2007, Basil R. Marple, Margaret M. Hyland, Yuk-Chiu Lau, Chang-Jiu Li, Rogerio S. Lima, and Ghislain Montavon, Ed., ASM International, Materials Park, OH, 2007.  相似文献   

5.
This article presents what is our present knowledge in plasma spraying of suspension, sol, and solution in order to achieve finely or nano-structured coatings. First, it describes the different plasma torches used, the way liquid jet is injected, and the different measurements techniques. Then, drops or jet fragmentation is discussed with especially the influence of arc root fluctuations for direct current plasma jets. The heat treatment of drops and droplets is described successively for suspensions, sols, and solutions both in direct current or radio-frequency plasmas, with a special emphasize on the heat treatment, during spraying, of beads and passes deposited. The resulting coating morphologies are commented and finally examples of applications presented: Solid Oxide Fuel Cells, Thermal Barrier coatings, photocatalytic titania, hydroxyapatite, WC-Co, complex oxides or metastable phases, and functional materials coatings.  相似文献   

6.
Solution precursor plasma spraying has been used to produce finely structured ceramic coatings with nano- and sub-micrometric features. This process involves the injection of a solution spray of ceramic salts into a DC plasma jet under atmospheric condition. During the process, the solvent vaporizes as the droplet travel downstream. Solid particles are finally formed due to the precipitation of the solute, and the particle are heated up and accelerated to the substrate to generate the coating. This article describes a 3D model to simulate the transport phenomena and the trajectory and heating of the solution spray in the process. The jet-spray two-way interactions are considered. A simplified model is employed to simulate the evolution process and the formation of the solid particle from the solution droplet in the plasma jet. The temperature and velocity fields of the jet are obtained and validated. The particle size, velocity, temperature, and position distribution on the substrate are predicted. This article is an invited paper selected from presentations at the 2007 International Thermal Spray Conference and has been expanded from the original presentation. It is simultaneously published in Global Coating Solutions, Proceedings of the 2007 International Thermal Spray Conference, Beijing, China, May 14-16, 2007, Basil R. Marple, Margaret M. Hyland, Yuk-Chiu Lau, Chang-Jiu Li, Rogerio S. Lima, and Ghislain Montavon, Ed., ASM International, Materials Park, OH, 2007.  相似文献   

7.
The effect of powder injecting location of the plasma spraying on spraying properties was studied. Three different powder-injecting methods were applied in the experiment. In the first method, the particles were axially injected into the plasma flow from the cathode tip. In the second method, the particles were radially injected into the plasma flow just downstream of the anode arc root inside the anode nozzle. In the third method, the particles were radially injected into the plasma jet at the nozzle exit. The alumina particles with a mean diameter of 20 μm were used to deposit coatings. Spraying properties, such as the deposition efficiency, the melting rate of the powder particles, and the coating quality were investigated. The results show that the spraying with axial particle injecting can heat and melt the powder particles more effectively, produce coatings with better quality, and have higher deposition efficiency. This article is an invited paper selected from presentations at the 2007 International Thermal Spray Conference and has been expanded from the original presentation. It is simultaneously published in Global Coating Solutions, Proceedings of the 2007 International Thermal Spray Conference, Beijing, China, May 14-16, 2007, Basil R. Marple, Margaret M. Hyland, Yuk-Chiu Lau, Chang-Jiu Li, Rogerio S. Lima, and Ghislain Montavon, Ed., ASM International, Materials Park, OH, 2007.  相似文献   

8.
Nowadays, wire-arc spraying of chromium steel has gained an important market share for corrosion and wear protection applications. However, detailed studies are the basis for further process optimization. In order to optimize the process parameters and to evaluate the effects of the spray parameters DoE-based experiments had been carried out with high-speed camera shoots. In this article, the effects of spray current, voltage, and atomizing gas pressure on the particle jet properties, mean particle velocity and mean particle temperature and plume width on X46Cr13 wire are presented using an online process monitoring device. Moreover, the properties of the coatings concerning the morphology, composition and phase formation were subject of the investigations using SEM, EDX, and XRD-analysis. These deep investigations allow a defined verification of the influence of process parameters on spray plume and coating properties and are the basis for further process optimization. This article is an invited paper selected from presentations at the 2007 International Thermal Spray Conference and has been expanded from the original presentation. It is simultaneously published in Global Coating Solutions, Proceedings of the 2007 International Thermal Spray Conference, Beijing, China, May 14-16, 2007, Basil R. Marple, Margaret M. Hyland, Yuk-Chiu Lau, Chang-Jiu Li, Rogerio S. Lima, and Ghislain Montavon, Ed., ASM International, Materials Park, OH, 2007.  相似文献   

9.
Different posttreatment methods, such as heat treatment, mechanical processing, sealing, etc., are known to be capable to improve microstructure and exploitation properties of thermal spray coatings. In this work, a plasma electrolytic oxidation of aluminum coatings obtained by arc spraying on aluminum and carbon steel substrates is carried out. Microstructure and properties of oxidized layers formed on sprayed coating as well as on bulk material are investigated. Oxidation is performed in electrolyte containing KOH and liquid glass under different process parameters. It is shown that thick uniform oxidized layers can be formed on arc-sprayed aluminum coatings as well as on solid material. Distribution of alloying elements and phase composition of obtained layers are investigated. A significant improvement of wear resistance of treated layers in two types of abrasive wear conditions is observed. This article is an invited paper selected from presentations at the 2007 International Thermal Spray Conference and has been expanded from the original presentation. It is simultaneously published in Global Coating Solutions, Proceedings of the 2007 International Thermal Spray Conference, Beijing, China, May 14-16, 2007, Basil R. Marple, Margaret M. Hyland, Yuk-Chiu Lau, Chang-Jiu Li, Rogerio S. Lima, and Ghislain Montavon, Ed., ASM International, Materials Park, OH, 2007.  相似文献   

10.
Among other methods, inductively coupled plasma (ICP) torches can be used for the synthesis of nanoparticles. In this process, the precursor material is vaporized in the first step in the plasma core. In the second step, nucleation and condensation occur in the synthesis chamber where the plasma gets colder and high-purity nanoparticles are synthesized, the growth of which is stopped by gas quenching. From their low velocity and high temperature, induction plasmas are particularly adapted for this application. Numerical modeling is a good way to achieve a better knowledge and understanding of the process since non-intrusive diagnostics are fairly difficult to implement. In the present article, a two-dimensional model of an ICP torch was developed and validated on the basis of comparisons with data obtained by some other authors. Finally, the current frequency (13.56 MHz), pressure level (0.04 MPa), and gas flow rates were adjusted for the specific conditions of nanoparticles synthesis. This article is an invited paper selected from presentations at the 2007 International Thermal Spray Conference and has been expanded from the original presentation. It is simultaneously published in Global Coating Solutions, Proceedings of the 2007 International Thermal Spray Conference, Beijing, China, May 14-16, 2007, Basil R. Marple, Margaret M. Hyland, Yuk-Chiu Lau, Chang-Jiu Li, Rogerio S. Lima, and Ghislain Montavon, Ed., ASM International, Materials Park, OH, 2007.  相似文献   

11.
The use of computational fluid dynamics (CFD) to model the operation of thermal-spray processes has gained interest in the thermal-spray community, able to provide an understanding as to how a process functions, and better how to make a process work better. Advancements to the science of modeling now permits the ability to create a comprehensive model of a plasma gun that not only simulates the dynamics of the gas, but also the mechanics of arcs (plasma), thermodynamics, and entrained particulates to form a nearly complete model of a working thermal-spray process. Work presented includes the methods and procedures used to validate the model to a Sulzer Metco TriplexProTM-200 plasma gun and exploration of the operating regime to give an in depth and insightful look into the physics behind the operation of a triple-arc cascaded plasma gun. This article is an invited paper selected from presentations at the 2007 International Thermal Spray Conference and has been expanded from the original presentation. It is simultaneously published in Global Coating Solutions, Proceedings of the 2007 International Thermal Spray Conference, Beijing, China, May 14-16, 2007, Basil R. Marple, Margaret M. Hyland, Yuk-Chiu Lau, Chang-Jiu Li, Rogerio S. Lima, and Ghislain Montavon, Ed., ASM International, Materials Park, OH, 2007.  相似文献   

12.
Perovskite-type LaMnO3 powders and coatings have been prepared by a novel technique: reactive suspension plasma spraying (SPS) using an inductively coupled plasma of approximately 40 kW plate power and an oxygen plasma sheath gas. Suitable precursor mixtures were found on the basis of solid state reactions, solubility, and the phases obtained during the spray process. Best results were achieved by spraying a suspension of fine MnO2 powder in a saturated ethanol solution of LaCl3 with a 1 to 1 molar ratio of lanthanum and manganese. A low reactor pressure was helpful in diminishing the amount of corrosive chlorine compounds in the reactor. As-sprayed coatings and collected powders showed perovskite contents of 70 to 90%. After a posttreatment with an 80% oxygen plasma, an almost pure LaMnO3 deposit was achieved in the center of the incident plasma jet. This paper originally appeared in Thermal Spray: Meeting the Challenges of the 21st Century; Proceedings of the 15th International Thermal Spray Conference, C. Coddet, Ed., ASM International, Materials Park, OH, 1998. This proceedings paper has been extensively reviewed according to the editorial policy of the Journal of Thermal Spray Technology.  相似文献   

13.
In conventional plasma spray of SOFC components, the large NiO and YSZ particles used, about 50-150 microns for high porosity coating, reduce the density of three-phase sites for electrode reaction. In this article, the SPPS process was used to synthesize and deposit Ni-YSZ anodes. The results show that several process parameters have significant effects on the microstructure and phase composition of the deposited material. The deposits were composed of tower-like, irregularly shaped agglomerates and smooth surface deposits. The sizes of the agglomerates increase with the decrease of the plasma-torch power and most are not completely molten during the impact. After heat treatment to reduce the NiO present in the as deposited coatings, the coatings were found to contain spherical YSZ particles about 0.5 μm in diameter distributed in a continuous Ni matrix, which is verified by both SEM observation and electrical resistance measurement. The coatings have 30-50% porosity. This article is an invited paper selected from presentations at the 2007 International Thermal Spray Conference and has been expanded from the original presentation. It is simultaneously published in Global Coating Solutions, Proceedings of the 2007 International Thermal Spray Conference, Beijing, China, May 14-16, 2007, Basil R. Marple, Margaret M. Hyland, Yuk-Chiu Lau, Chang-Jiu Li, Rogerio S. Lima, and Ghislain Montavon, Ed., ASM International, Materials Park, OH, 2007.  相似文献   

14.
This investigation deals with a study of the friction, wear, and corrosion behavior of vacuum plasma sprayed quasicrystalline (QC) Ti41.5Zr41.5Ni17 coatings. During pin on disc experiments, a change in the mode of wear has been found to occur with corresponding changes in normal load and sliding velocity. The low thermal conductivity of quasicrystals and its brittleness play a vital role in determining the friction and wear behavior of such materials. When these coatings are subjected to rubbing for a longer period of time, wear occurs by subsurface crack propagation, and subsequent delamination within the coated layer. By comparing the QC to its polycrystalline counterpart during potentiodynamic measurements according to ASTM G 31, higher currents were found over the whole range of potentials for QC when immersed in 1 M HCl solution. This article is an invited paper selected from presentations at the 2007 International Thermal Spray Conference and has been expanded from the original presentation. It is simultaneously published in Global Coating Solutions, Proceedings of the 2007 International Thermal Spray Conference, Beijing, China, May 14-16, 2007, Basil R. Marple, Margaret M. Hyland, Yuk-Chiu Lau, Chang-Jiu Li, Rogerio S. Lima, and Ghislain Montavon, Ed., ASM International, Materials Park, OH, 2007.  相似文献   

15.
The effect of particle size distribution on the degradation behavior of plasma sprayed CoNi- and CoCrAlY coatings during isothermal oxidation was investigated, in terms of the oxygen content, porosity, surface roughness, and oxide scale formation. The results show that the degradation of both coatings was considerably influenced by the starting particle size distribution. It also shows that in the as-sprayed vacuum plasma spray (VPS) coatings the oxygen content on the coating surface increased significantly with decreased average particle size. But after thermal exposure, the difference of the oxygen contents between the coatings with different particle size was decreased. The powder with various particle size resulted in low porosity inside the coatings during the deposition process. The surface roughness of the coatings increased with increased particle size. The small particles produced a relatively smooth surface, and the oxide growth in the coating deposited by small particle was slower than that in the large particle coating. This article is an invited paper selected from presentations at the 2007 International Thermal Spray Conference and has been expanded from the original presentation. It is simultaneously published in Global Coating Solutions, Proceedings of the 2007 International Thermal Spray Conference, Beijing, China, May 14-16, 2007, Basil R. Marple, Margaret M. Hyland, Yuk-Chiu Lau, Chang-Jiu Li, Rogerio S. Lima, and Ghislain Montavon, Ed., ASM International, Materials Park, OH, 2007.  相似文献   

16.
Among processes evaluated to produce some parts of or the whole solid-oxide fuel cell, Suspension Plasma Spraying (SPS) is of prime interest. Aqueous suspensions of yttria partially stabilized zirconia atomized into a spray by an internal-mixing co-axial twin-fluid atomizer were injected into a DC plasma jet. The dispersion and stability of the suspensions were enhanced by adjusting the amount of dispersant (ammonium salt of polyacrylic acid, PAA). A polyvinyl alcohol (PVA) was further added to the suspension to tailor its viscosity. The PVA also improved the dispersion and stability of the suspensions. The atomization of optimized formulations is described implementing Weber and Ohnesorge dimensionless numbers as well as gas-to-liquid mass ratio (ALR) value. Drop size distributions changed from monomodal distributions at low We to multimodal distributions when We number increases. The viscosity of the suspensions has a clear influence on the drop size distribution and suspension spray pattern. The secondary fragmentation of the drops due to the plasma jet was evidenced and the final size of the sheared drops was shown to depend on the characteristics of the suspension. Rather dense zirconia coatings have been prepared, which is a promising way to produce electrolyte.  相似文献   

17.
Use of a comprehensive validated computer model of a thermal spray process enables an ability to improve, optimize, and fine-tune the performance of that thermal spray process. A validated model of the Sulzer Metco TriplexPro™ 200 plasma gun has been used to improve the performance of the actual gun in terms of enhancing gas flow dynamics, thermal management, and overall performance in terms of a robust design. Internal changes to the gun geometry using the model have extended the life of the hardware. In addition the model has permitted the investigation of the fundamental operation of the gun, specific to the behavior and path of the arcs, as well as the ability to operate the plasma gun, under simulation, in operating regimes that currently cannot be supported by the physical hardware. The model has been run at gas pressures above 1.4 Mpa and/or voltages above 300 V that currently cannot be obtained with the physical hardware due to equipment limitations to evaluate the potential to extend the operating window of the Sulzer Metco TriplexPro™ 200 gun beyond current levels in terms of particle velocity and temperature. The end result is an improved process tool for applying thermal spray coatings ranging from ceramics applied at high particle temperature and low particle velocities to carbides and alloys applied at lower temperatures and higher velocities. This article is an invited paper selected from presentations at the 2007 International Thermal Spray Conference and has been expanded from the original presentation. It is simultaneously published in Global Coating Solutions, Proceedings of the 2007 International Thermal Spray Conference, Beijing, China, May 14-16, 2007, Basil R. Marple, Margaret M. Hyland, Yuk-Chiu Lau, Chang-Jiu Li, Rogerio S. Lima, and Ghislain Montavon, Ed., ASM International, Materials Park, OH, 2007.  相似文献   

18.
The sintering of free-standing plasma sprayed TBCs has been modeled, based on variational principles of free energy minimization and comparisons are made with experimental results. Predictions of through-thickness shrinkage and changing pore surface area are compared with the experimental data obtained by dilatometry and BET analysis, respectively. The sensitivity of the predictions to initial pore architecture and material properties is assessed. The model can be used to predict the evolution of the contact area between overlying splats. This is in turn related to the through-thickness thermal conductivity, using a previously developed analytical model (I.O. Golosnoy, et al. J. Therm. Spray Technol., 2005, 14(2), p 205-214). This article is an invited paper selected from presentations at the 2007 International Thermal Spray Conference and has been expanded from the original presentation. It is simultaneously published in Global Coating Solutions, Proceedings of the 2007 International Thermal Spray Conference, Beijing, China, May 14-16, 2007, Basil R. Marple, Margaret M. Hyland, Yuk-Chiu Lau, Chang-Jiu Li, Rogerio S. Lima, and Ghislain Montavon, Ed., ASM International, Materials Park, OH, 2007.  相似文献   

19.
Composite powder was prepared using primary nanoTiO2 powder and polyethylene glycol (PEG). The nanoTiO2 coating was deposited through vacuum cold spray using both the composite powder and the primary nanopowder. The influence of annealing on the coating adhesion and photocatalytic activity was investigated. The coating adhesion was evaluated through erosion test by water jet. The photocatalytic performance of the coatings was evaluated through photodegradation of phenol in water. Results showed that annealing of the coating at a temperature from 450 to 500 °C yielded both higher activity and better adhesion. The adhesion of the coating deposited using the composite powder was better than that using the primary nanoTiO2 powder. It was found that the TiO2 coating, resulting from the composite powder, presented much higher activity than that deposited with the primary nanopowder. The better activity is attributed to the existence of large pores resulting from the stacking of composite powder, which benefits the reactants’ transportation through the porous coating. This article is an invited paper selected from presentations at the 2007 International Thermal Spray Conference and has been expanded from the original presentation. It is simultaneously published in Global Coating Solutions, Proceedings of the 2007 International Thermal Spray Conference, Beijing, China, May 14-16, 2007, Basil R. Marple, Margaret M. Hyland, Yuk-Chiu Lau, Chang-Jiu Li, Rogerio S. Lima, and Ghislain Montavon, Ed., ASM International, Materials Park, OH, 2007.  相似文献   

20.
A key aspect of the operation of conventional non-transferred direct current (dc) plasma torches is the random motion of the arc inside the nozzle. Various plasma gun designs have been developed to limit the arc fluctuations without increasing the heat load to the anode wall that results in surface erosion and anode wear. However, construction of these plasma torches is highly complex, while the conventional dc plasma torch consists of a small number of elements and is simple to manufacture and maintain. A better understanding of the behavior of the arc-anode attachment and how it depends on operating conditions may help in the design and operation of conventional plasma torches so that the fluctuation of the time-voltage, and therefore the time-enthalpy variation, is as low as possible with a fluctuation frequency adapted to the time characteristic of the powder particles in the plasma jet. This study deals with a three-dimensional (3D) time-dependent modeling of the arc and plasma generation in such a torch operating under the so-called “restrike” mode. The latter is characterized by rather large voltage fluctuations, corresponding to a broad range of conditions used in the manufacturing of plasma coatings. The mathematical model is based on the simultaneous solution of the conservation equations of mass, momentum, energy, electric current, and electromagnetic equations. These make it possible to predict the effect of operating parameters of the plasma torch on the motion of the anode root attachment over the anode surface and the time-evolution of arc voltage and flow fields in the nozzle. This article was originally published inBuilding on 100 Years of Success: Proceedings of the 2006 International Thermal Spray Conference (Seattle, WA), May 15–18, 2006, B.R. Marple, M.M. Hyland, Y.-Ch. Lau, R.S. Lima, and J. Voyer, Ed., ASM International, Materials Park, OH, 2006.  相似文献   

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