Size segregated aerosol mass concentration measurements over the Arabian Sea during ICARB

Mass concentration and mass size distribution of total (composite) aerosols near the surface are essential inputs needed in developing aerosol models for radiative forcing estimation as well as to infer the environment and air quality. Using extensive measurements onboard the oceanographic research vessel, Sagar Kanya, during its cruise SK223B in the second phase of the ocean segment of the Integrated Campaign for Aerosols, gases and Radiation Budget (ICARB), the spatial distribution of the mass concentration and mass size distribution of near-surface aerosols are examined for the first time over the entire Arabian Sea, going as far as 58°E and 22°N, within a span of 26 days. In general, the mass concentrations (M _T ) were found to be low with the mean value for the entire Arabian Sea being 16.7 ± 7 μg m^?3; almost 1/2 of the values reported in some of the earlier campaigns. Coarse mode aerosols contributed, on an average, 58% to the total mass, even though at a few pockets accumulation mode contribution dominated. Spatially, significant variations were observed over central and northern Arabian Sea as well as close to the west coast of India. In central Arabian Sea, even though the M _T was quite low, contribution ofs accumulation aerosols to the total mass concentration was greater than 50%. Effective radius, a parameter important in determining scattering properties of aerosol size distribution, varied between 0.07 and 0.4 μm with a mean value of 0.2 μm. Number size distributions, deduced from the mass size distributions, were approximated to inverse power-law form and the size indices (ν) were estimated. It was found to vary in the range 3.9 to 4.2 with a mean value of 4.0 for the entire oceanic region. Extinction coefficients, estimated using the number-size distributions, were well-correlated with the accumulation mode mass concentration with a correlation coefficient of 0.82.     

Chemical characteristics of PM<Subscript>10</Subscript> aerosols and airmass trajectories over Bay of Bengal and Arabian Sea during ICARB

For the first time, chemical characterization of PM₁₀ aerosols was attempted over the Bay of Bengal (BoB) and Arabian Sea (AS) during the ICARB campaign. Dominance of SO ₄ ^2? , NH ₄ ⁺ and NO ₃ ^? was noticed over both the regions which indicated the presence of ammonium sulphate and ammonium nitrate as major water soluble particles playing a very important role in the radiation budget. It was observed that all the chemical constituents had higher concentrations over Bay of Bengal as compared to Arabian Sea. Higher concentrations were observed near the Indian coast showing influence of landmass indicating that gaseous pollutants like SO₂, NH₃ and NO _x are transported over to the sea regions which consequently contribute to higher SO ₄ ^2? , NH ₄ ⁺ and NO ₃ ^? aerosols respectively. The most polluted region over BoB was 13°?19°N and 70°?90°E while it was near 11°N and 75°E over AS. Although the concentrations were higher over Bay of Bengal for all the chemical constituents of PM₁₀ aerosols, per cent non-sea salt (nss) fraction (with respect to Na) was higher over Arabian Sea. Very low Ca2+ concentration was observed at Arabian Sea which led to higher atmospheric acidity as compared to BoB. Nss SO ₄ ^2? alone contributed 48% of total water soluble fraction over BoB as well as AS. Ratios SO ₄ ^2? /NO _? ³ over both the regions (7.8 and 9 over BoB and AS respectively) were very high as compared to reported values at land sites like Allahabad (0.63) and Kanpur (0.66) which may be due to very low NO.3 over sea regions as compared to land sites. Air trajectory analysis showed four classes: (i) airmass passing through Indian land, (ii) from oceanic region, (iii) northern Arabian Sea and Middle East and (iv) African continent. The highest nss SO ₄ ^2? was observed during airmasses coming from the Indian land side while lowest concentrations were observed when the air was coming from oceanic regions. Moderate concentrations of nss SO2. 4 were observed when air was seen moving from the Middle East and African continent. The pH of rainwater was observed to be in the range of 5.9–6.5 which is lower than the values reported over land sites. Similar feature was reported over the Indian Ocean during INDOEX indicating that marine atmosphere had more free acidity than land atmosphere.     

The mass of the compact object in the X-ray binary 4U 1700-37

The results of a systematic analysis of master radial-velocity curves for the X-ray binary 4U 1700-37 are presented. The dependence of the mass of the X-ray component on the mass of the optical component is derived in a Roche model based on a fit of the master radial-velocity curve. The parameters of the optical star are used to estimate the mass of the compact object in three ways. The masses derived based on information about the surface gravity of the optical companion and various observational data are 2.25 _?0.24 ^+0.23 M_⊙ and 2.14 _?0.56 ^+0.50 M_⊙. The masses based on the radius of the optical star, 21.9R_⊙, are 1.76 _?0.21 ^+0.20 M_⊙ and 1.65 _?0.56 ^+0.78 M_⊙. The mass of the optical component derived from the mass-luminosity relation for X-ray binaries, 27.4M_⊙, yields masses for the compact object of 1.41 _?0.08 ⁺ M_⊙ and 1.35 _?0.18 ^+0.18 M_⊙.     

Physical and optical characteristics of atmospheric aerosols during ICARB at Manora Peak,Nainital: A sparsely inhabited,high-altitude location in the Himalayas

Collocated measurements of the optical and physical properties of columnar and near-surface aerosols were carried out from Manora Peak, Nainital (a sparsely inhabited, high altitude location, ～2 km above mean sea level, in the Himalayas), during the Integrated Campaign for Aerosols, gases and Radiation Budget (ICARB) under the Geosphere Biosphere Programme of the Indian Space Research Organization (ISRO-GBP). Under this, observational data of spectral aerosol optical depths (AOD), mass concentration of aerosol black carbon (M _B ), mass concentration (M _T ) and number concentration (N _t ) of composite (total) aerosols near the surface and meteorological parameters were collected during the period February 15 to April 30, 2006. Though very low (<0.1 at 500 nm) AODs were observed during clear days, as much as a four-fold increase was seen on hazy days. The Ångström exponent (α), deduced from the spectral AODs, revealed high values during clear days, while on hazy days α was low; with an overall mean value of 0.69 ± 0.06 for the campaign period. BC mass concentration varied between 0.36 and 2.87 μg m^?3 and contributed in the range 0.7 to 1.8% to the total aerosol mass. Total aerosol number concentration and BC mass concentration showed diurnal variation with a midnight and early morning minimum and a late afternoon maximum; a pattern quite opposite to that seen in low altitude stations. These are attributed to the dynamics of the atmospheric boundary layer.     

Interpretation of the light curves of “quiescent” X-ray novae in a model with a noncollisional interaction between the flow and disk. The XTE J1118+480 system

We have analyzed the orbital light curve of the X-ray nova XTE J1118+480 in a “disk + hot line” model based on three-dimensional gas-dynamical computations of gas flows in interacting binary systems. As a result, we have been able to derive reliable parameters for the system: i = 80 _?4 ⁺⁴ degrees, _MBH = 7.1 _?0.1 ^+0.5 M_⊙, M _opt = 0.39 _?0.07 ^+0.15 M_⊙.     

Chemical characteristics of aerosols in MABL of Bay of Bengal and Arabian Sea during spring inter-monsoon: A comparative study

The chemical composition of aerosols in the Marine Atmospheric Boundary Layer (MABL) of Bay of Bengal (BoB) and Arabian Sea (AS) has been studied during the spring and inter-monsoon (March-May 2006) based on the analysis of water soluble constituents (Na⁺, NH ₄ ⁺ , K⁺, Mg²⁺, Ca²⁺, Cl^?, NO ₃ ^? and SO ₄ ^2? ), crustal elements (Al, Fe, and Ca) and carbonaceous species (EC, OC). The total suspended particulates (TSP) ranged from 5.2 to 46.6 μg m^?3 and 8.2 to 46.9 μg m^?3 during the sampling transects in the BoB and AS respectively. The water-soluble species, on average, accounted for 44% and 33% of TSP over BoB and AS respectively, with dominant contribution of SO ₄ ^2? over both the oceanic regions. However, distinct differences with respect to elevated abundances of NH ₄ ⁺ in the MABL of BoB and that of Na⁺ and Ca²⁺ in AS are clearly evident. The non-sea-salt component of SO ₄ ^2? ranging from 82 to 98% over BoB and 35 to 98% over AS; together with nss-Ca²⁺/nss-SO ₄ ^2? equivalent ratios 0.12 to 0.5 and 0.2 to 1.16, respectively, provide evidence for the predominance of anthropogenic constituents and chemical transformation processes occurring within MABL. The concentrations of OC and EC average around 1.9 and 0.4 μg m^?3 in BoB and exhibit a decreasing trend from north to south; however, abundance of these carbonaceous species are not significantly pronounced over AS. The abundance of Al, used as a proxy for mineral aerosols, varied from 0.2 to 1.9 μg m^?3 over BoB and AS, with a distinctly different spatial pattern — decreasing north to south in BoB in contrast to an increasing pattern in the Arabian Sea.     

Heat capacity of hydrous trachybasalt from Mt Etna: comparison with CaAl<Subscript>2</Subscript>Si<Subscript>2</Subscript>O<Subscript>8</Subscript> (An)–CaMgSi<Subscript>2</Subscript>O<Subscript>6</Subscript> (Di) as basaltic proxy compositions

The specific heat capacity (C _p) of six variably hydrated (~3.5 wt% H₂O) iron-bearing Etna trachybasaltic glasses and liquids has been measured using differential scanning calorimetry from room temperature across the glass transition region. These data are compared to heat capacity measurements on thirteen melt compositions in the iron-free anorthite (An)–diopside (Di) system over a similar range of H₂O contents. These data extend considerably the published C _p measurements for hydrous melts and glasses. The results for the Etna trachybasalts show nonlinear variations in, both, the heat capacity of the glass at the onset of the glass transition (i.e., C _p ^g ) and the fully relaxed liquid (i.e., C _p ^l ) with increasing H₂O content. Similarly, the “configurational heat capacity” (i.e., C _p ^c  = C _p ^l  ? C _p ^g ) varies nonlinearly with H₂O content. The An–Di hydrous compositions investigated show similar trends, with C _p values varying as a function of melt composition and H₂O content. The results show that values in hydrous C _p ^g , C _p ^l and C _p ^c in the depolymerized glasses and liquids are substantially different from those observed for more polymerized hydrous albitic, leucogranitic, trachytic and phonolitic multicomponent compositions previously investigated. Polymerized melts have lower C _p ^l and C _p ^c and higher C _p ^g with respect to more depolymerized compositions. The covariation between C _p values and the degree of polymerization in glasses and melts is well described in terms of SM_hydrous and NBO/T _hydrous. Values of C _p ^c increase sharply with increasing depolymerization up to SM_hydrous ~ 30–35 mol% (NBO/T _hydrous ~ 0.5) and then stabilize to an almost constant value. The partial molar heat capacity of H₂O for both glasses (\( C_{{{\text{p}}\;{\text{H}}_{2} {\text{O}}}}^{\text{g}} \)) and liquids (\( C_{{{\text{p}}\;{\text{H}}_{2} {\text{O}}}}^{\text{l}} \)) appears to be independent of composition and, assuming ideal mixing, we obtain a value for \( C_{{{\text{p}}\;{\text{H}}_{2} {\text{O}}}}^{\text{l}} \) of 79 J mol^?1 K^?1. However, we note that a range of values for \( C_{{{\text{p}}\;{\text{H}}_{2} {\text{O}}}}^{\text{l}} \) (i.e., ~78–87 J mol^?1 K^?1) proposed by previous workers will reproduce the extended data to within experimental uncertainty. Our analysis suggests that more data are required in order to ascribe a compositional dependence (i.e., nonideal mixing) to \( C_{{{\text{p}}\;{\text{H}}_{2} {\text{O}}}}^{\text{l}} \).     

Influence of the <Emphasis Type="Italic">X</Emphasis>-site composition on tourmaline’s crystal structure: investigation of synthetic K-dravite,dravite, oxy-uvite,and magnesio-foitite using SREF and Raman spectroscopy

The crystal structures of synthetic K-dravite [^XK^YMg ₃ ^Z Al ₆ ^T Si₆O₁₈(BO₃) ₃ ^V (OH) ₃ ^W (OH)], dravite [^XNa^YMg ₃ ^Z Al ₆ ^T Si₆O₁₈(BO₃) ₃ ^V (OH) ₃ ^W (OH)], oxy-uvite [^XCa^YMg ₃ ^Z Al ₆ ^T Si₆O₁₈(BO₃) ₃ ^V (OH) ₃ ^W O], and magnesio-foitite [^X?^Y(Mg₂Al)^ZAl ₆ ^T Si₆O₁₈(BO₃) ₃ ^V (OH) ₃ ^W (OH)] are investigated by polarized Raman spectroscopy, single-crystal structure refinement (SREF), and powder X-ray diffraction. The use of compositionally simple tourmalines characterized by electron microprobe analysis facilitates the determination of site occupancy in the SREF and band assignment in the Raman spectra. The synthesized K-dravite, oxy-uvite, and magnesio-foitite have significant Mg–Al disorder between their octahedral sites indicated by their respective average 〈Y–O〉 and 〈Z–O〉 bond lengths. The Y- and Z-site compositions of oxy-uvite (^YMg_1.52Al_1.48(10) and ^ZAl_4.90Mg_1.10(15)) and magnesio-foitite (^YAl_1.62Mg_1.38(18) and ^ZAl_4.92Mg_1.08(24)) are refined from the electron densities at each site. The Mg–Al ratio of the Y and Z sites is also determined from the relative integrated peak intensities of the Raman bands in the O–H stretching vibrational range (3250–3850 cm^?1), producing values in good agreement with the SREF data. The unit cell volume of tourmaline increases from magnesio-foitite (1558.4(3) ų) to dravite (1569.5(4)–1571.7(3) ų) to oxy-uvite (1572.4(2) ų) to K-dravite (1588.1(2) ų), mainly due to lengthening of the crystallographic c-axis. The increase in the size of the X-site coordination polyhedron from dravite (Na) to K-dravite (K) is accommodated locally in the crystal structure, resulting in the shortening of the neighboring O1–H1 bond. In oxy-uvite, Ca²⁺ is locally associated with a deprotonated W (O1) site, whereas vacant X sites are neighbored by protonated W (O1) sites. Increasing the size of the X-site-occupying ion does not detectably affect bonding between the other sites; however, the higher charge of Ca and the deprotonated W (O1) site in oxy-uvite are correlated to changes in the lattice vibration Raman spectrum (100–1200 cm^?1), particularly for bands assigned to the T ₆O₁₈ ring. The Raman spectrum of magnesio-foitite shows significant deviations from those of K-dravite, dravite, and oxy-uvite in both the lattice and O–H stretching vibrational ranges (100–1200 and 3250–3850 cm^?1, respectively). The vacant X site is correlated with long- and short-range changes in the crystal structure, i.e., deformation of the T ₆O₁₈ ring and lengthening of the O1–H1 and O3–H3 bonds. However, X-site vacancies in K-dravite, dravite, and oxy-uvite result only in the lengthening of the neighboring O1–H1 bond and do not result in identifiable changes in the lattice-bonding environment.     

Development of a technique for IR spectroscopic determination of nitrogen content and aggregation degree in diamond crystals

A technique for IR spectroscopic determination of the total nitrogen content N _S in the form of A-and B ₁-defects is suggested. It provides for the computer processing and decomposition of IR spectra into constituent bands, calculation of the total absorption band area S _N and individual areas S _A and S _B1 and their normalization with respect to the total area of the diamond intrinsic absorption S ₀, with the normalization coefficients K _S , K _A , and K _B1 being calculated. Based on the analysis of the IR spectra of 60 octahedral diamond crystals from the Mir and Yubileinaya pipes (Sakha-Yakutiya), the empirical functions N _S = 911.85 K _S ^0.9919 ppm (R ² = 0.9859), N _A = 1185.6 K _A ^1.1511 ppm (R ² = 0.8703), and N _B1 = 911.85 K _S ^0.9919 ? 1185.6 K _A ^1.1511 ppm have been defined.     

Physical properties of molecular clouds as functions of their Galactocentric distance from CS and C<Superscript>34</Superscript>S observations

Twenty-eight CS molecular clouds toward HII regions with Galactocentric distances from ～ 4 to 20 kpc have been studied based on observations obtained in the J=2→1 lines of CS and C³⁴S on the 20-meter radio telescope of the Onsala Space Observatory (Sweden) in March 2001. All 28 clouds have been mapped with an angular resolution of ～40″. The peak intensity in the C³⁴S line has been measured for 20 objects. An LTE analysis has been performed and the parameters of the molecular cloud cores derived. The core sizes are d_A=0.3–4.8 pc, with a median value of ～1.6 pc. The mean hydrogen densities in the cloud cores are n_H2=3.5×10²–3.7 × 10⁴ cm^?3, with a median value of ～7.2×10³ cm^?3. The value of n_H2 ends to decrease with increasing Galactocentric distance of the cloud. The masses of most clouds are 10²?6×10³M_⊙, with the most probable value being M_CS～10³M_⊙. The data follow the dependence M_CS ∝d _A ^(2.4–3.2) . As a rule, the cloud masses are lower than the virial masses for M_CS<10³M_⊙.     

Optical and radiative properties of aerosols over Abu Dhabi in the United Arab Emirates

The present study is on the aerosol optical and radiative properties in the short-wave radiation and its climate implications at the arid city of Abu Dhabi (24.42 ^°N, 54.61 ^°E, 4.5 m MSL), in the United Arab Emirates. The direct aerosol radiative forcings (ARF) in the short-wave region at the top (TOA) and bottom of the atmosphere (BOA) are estimated using a hybrid approach, making use of discrete ordinate radiative transfer method in conjunction with the short-wave flux and spectral aerosol optical depth (AOD) measurements, over a period of 3 years (June 2012–July 2015), at Abu Dhabi located at the south-west coast of the Arabian Gulf. The inferred microphysical properties of aerosols at the measurement site indicate strong seasonal variations from the dominance of coarse mode mineral dust aerosols during spring (March–May) and summer (June–September), to the abundance of fine/accumulation mode aerosols mainly from combustion of fossil-fuel and bio-fuel during autumn (October–November) and winter (December–February) seasons. The monthly mean diurnally averaged ARF at the BOA (TOA) varies from ?13.2 Wm^?2 (～?0.96 Wm^?2) in November to ?39.4 Wm^?2 (?11.4 Wm^?2) in August with higher magnitudes of the forcing values during spring/summer seasons and lower values during autumn/winter seasons. The atmospheric aerosol forcing varies from + 12.2 Wm^?2 (November) to 28.2 Wm^?2 (June) with higher values throughout the spring and summer seasons, suggesting the importance of mineral dust aerosols towards the solar dimming. Seasonally, highest values of the forcing efficiency at the surface are observed in spring (?85.0 ± 4.1 W m^?2 τ ^?1) followed closely by winter (?79.2 ± 7.1 W m^?2 τ ^?1) and the lowest values during autumn season (?54 ± 4.3 W m^?2 τ ^?1). The study concludes with the variations of the atmospheric heating rates induced by the forcing. Highest heating rate is observed in June (0.39 K day ^?1) and the lowest in November (0.17 K day ^?1) and the temporal variability of this parameter is linearly associated with the aerosol absorption index.     

Vertical stability and the Brunt-Väisäla frequency of deep natural waters by the example of Lake Baikal,Lake Tanganyika,and the World Ocean

Theoretical analysis, calculations, and comparison with the results of observations in Lake Baikal, Lake Tanganyika, and the World Ocean are performed for the vertical stability E and the Brunt-Väisäla frequency N in the form of N ² with regard to all components (at the constant temperature T and the salinity S, the common adiabatic form at T, S Const). The adiabatic stability E _ad and the Väisäla frequency N in the form of N _ad ² are always positive; at a change from the inverse to the direct temperature stratification, they have deep minimums reaching 10^?16 m^?1 and 10^?15 s^?2 and less; the minimums have the form of a special point, a reversal point of the first kind called a “cusp.” The reality of these reversal points is confirmed by the analysis of the investigation procedure, comparison with the results of previous theoretical (Sherstyankin, et al., 2007), and experimental (observations in Baikal, Shimaraev et al., 1994) works. The features of vertical profiles of E _ad , E andN _ad ² , N ², as well as the layers where the Brunt-Väisäla frequency is less than the inertial frequency, are studied. The analysis with regard to all components of the stability E _ad and the Brunt-Väisäla frequency N makes a great contribution to understanding of mixing processes in theoretical and experimental investigations; it is valid in all reservoirs of the Earth with inverse and direct temperature stratification, including Lake Baikal, Lake Tanganyika, and the World Ocean.     

Integrated Campaign for Aerosols,gases and Radiation Budget (ICARB): An overview

During March–May 2006, an extensive, multi-institution, multi-instrument, and multi-platform integrated field experiment ‘Integrated Campaign for Aerosols, gases and Radiation Budget’ (ICARB) was carried out under the Geosphere Biosphere Programme of the Indian Space Research Organization (ISRO-GBP). The objective of this largest and most exhaustive field campaign, ever conducted in the Indian region, was to characterize the physico-chemical properties and radiative effects of atmospheric aerosols and trace gases over the Indian landmass and the adjoining oceanic regions of the Arabian Sea, northern Indian Ocean, and Bay of Bengal through intensive, simultaneous observations. A network of ground-based observatories (over the mainland and islands), a dedicated ship cruise over the oceanic regions using a fully equipped research vessel, the Sagar Kanya, and altitude profiling over selected regions using an instrumented aircraft and balloonsondes formed the three segments of this integrated experiment, which were carried out in tandem. This paper presents an overview of the ICARB field experiment, the database generated, and some of its interesting outcomes though these are preliminary in nature.

The ICARB has revealed significant spatio-temporal heterogeneity in most of the aerosol characteristics both over land and ocean. Observed aerosol loading and optical depths were comparable to or in certain regions, a little lower than those reported in some of the earlier campaigns for these regions. The preliminary results indicate:

• low (< 0.2) aerosol optical depths (AOD) over most part of the Arabian Sea, except two pockets; one off Mangalore and the other, less intense, in the central Arabian Sea at ～18°N latitude
• High Ångström exponent in the southern Arabian Sea signifying steep AOD spectra and higher abundance of accumulation mode particles in the southern Arabian Sea and off Mangalore
• Remarkably low Ångström exponents signifying increased concentration of coarse mode aerosols and high columnar abundance in the northern Arabian Sea
• Altitude profiles from aircraft showed a steady BC level up to 3 km altitude with structures which were associated with inversions in the atmospheric boundary layer (ABL)
• A surprisingly large increase in the BC mass fraction with altitude
• Presence of a convectively mixed layer extending up to about 1 km over the Arabian Sea and Bay of Bengal
• A spatial off shore extent of <100 km for the anthropogenic impact at the coast; and
• Advection of aerosols, through airmass trajectories, from west Asia and NW arid regions of India leading to formation of elevated aerosol layers extending as far as 400 km off the east coast.

     

Effects of salt solutions on the hydro-mechanical behavior of compacted GMZ01 Bentonite

In this study, the effects of salinity of infiltrating solutions on the swelling strain, compressibility, and hydraulic conductivity of compacted GMZ01 Bentonite were investigated. After swelling under vertical load using either distilled water or NaCl solutions with concentrations of 0.1, 0.5 M, and 1 M, laboratory oedometer tests were conducted on the compacted GMZ01 Bentonite. Based on the oedometer test results, hydraulic conductivity was determined using the Casagrande’s method. Results show that the swelling strain of highly compacted GMZ01 Bentonite decreases as the concentration of NaCl solution increases. The compression index C _c ^* increases and then turns to decrease with an increase in the vertical stress or a decrease in the void ratio for different solutions, and the C _c ^* decreases as the concentration of NaCl solution increases. The secondary consolidation coefficient C _α increases linearly with the increase of the compression index C _c ^* . Furthermore, a bi-linear relationship between the swelling index C _s ^* and the secondary consolidation coefficient C _α can be characterized clearly. The hydraulic conductivity increases as the concentration of NaCl solution increases, however, this increase can be prevented if a high confining stress is applied.     

The radio brightness distribution along the solar limb observed on the Siberian Solar Radio Telescope

The radio brightness distribution at 5.2 cm has been obtained along the entire solar limb down to a level of 0.01 of brightness temperature at the disk center T ₀ ^c during the solar minimum. The measurements are based on strip scans from the Siberian Solar Radio Telescope. Data reduction included model fitting of an actual solar scan for each position angle. The maximum limb brightness, 1.37 T ₀ ^c , in the derived distribution is at equatorial direction, where the radio radius exceeds the photosphere radius by 7%. Toward the poles, the brightness peak and radio radius gradually decrease to 1.01 T ₀ ^c and 1.005 R₀. The derived two-dimensional brightness distribution was used to calculate radio radius as a function of position angle for several wavelengths from 4 to 31.6 cm. These dependences are consistent with RATAN-600 observations at position angles 0° and 25°.     

Simulation of molecular mass distributions and evaluation of O<Superscript>2−</Superscript> concentrations in polymerized silicate melts

A new statistical model is proposed for the molecular mass distributions (MMD) of polymerized anions in silicate melts. The model is based on the known distribution of Q ⁿ species in the MeO-Me₂O-SiO₂ system. In this model, chain and ring complexes are regarded as a random series of Q ⁿ structons with various concentrations of bridging bonds (1 ≤ n ≤ 4, Q ⁰ corresponds to SiO ₄ ^4? ). This approach makes it possible to estimate the probability of formation of various ensembles of polymer species corresponding to the general formula (Si _i O_3i+1?j )^2(i+1?j)?, where i is the size of the ion, and j is the cyclization number of intrachain bonds. The statistical model is utilized in the STRUCTON computer model, which makes use of the Monte Carlo method and is intended for the calculation of the composition and proportions of polyanions at a specified degree of polymerization of silicate melts (STRUCTON, version 1.2; 2007). Using this program, we simulated 1200 MMD for polyanions in the range of 0.52 ≤ p ≤98, where p is the fraction of nonbridging bonds in the silicon-oxygen matrix. The average number of types of anions in this range was determined to increase from three (SiO ₄ ^4? , Si₂O ₇ ^6? , and Si₃O ₁₀ ^8? ) to 153, and their average size increases from 1 to 7.2. A special option of the STRUCTON program combines MMD reconstructions in silicate melts with the formalism of the Toop-Samis model, which enables the calculation of the mole fraction of the O^2? ion relative to all anions in melts of specified composition. It is demonstrated that, with regard for the distribution and average size of anion complexes, the concentration of the O^2? ion in the MeO-SiO₂ system is characterized by two extrema: a minimum at 40–45 mol % SiO₂, which corresponds to the initial stages of the gelenization of the polycondensated silicate matrix, and a maximum, which is predicted for the range of 60–80 mol % SiO₂.     

Physical Parameters of the Eclipsing System V1176 Cas

The first high-accuracy CCDUBV RI light curves for the recently discovered eclipsing system V1176 Cas (P = 6 _. ^d 33, V = 11 _. ^m 1) have been obtained. A photometric solution for the light curves and physical characteristics of the component stars are derived. The orbital eccentricity is negligible, e = 0.009; both components have physical parameters similar to the Sun, but they are younger and may have an overabundance of metals. The orientation of the orbital ellipse and the low eccentricity make studies of the apsidal motion difficult. Nevertheless, the high accuracy of the available measurements of the timings of minima has enabled derivation of an upper limit for the rate of apsidal rotation, which agrees with a theoretical estimate of this effect.     

Atmospheric chemical abundances of the components of the quadruple system ADS 11061. 40 Draconis

As part of our study of the components of the hierarchic quadruple system ADS 11061, we acquired spectroscopic observations of the binary 40 Dra. Echelle spectra showing the separation of the components’ lines were obtained in the spectral range 3700–9200 Å. Effective temperatures and surface gravities were derived for the components from BV photometry and the hydrogen-line profiles. The components of the 40 Dra system have parameters close to T _eff ^a = 6420 K, log g _a = 4.17, T _eff ^b = 6300 K, and log g _b = 4.20. We find the microturbulence velocity in the component atmospheres to be V _t = 2.6 km/s. The abundances of iron, carbon, nitrogen, and oxygen in the atmospheres of both components are estimated to be log N(Fe)^a = 7.50, log N(Fe)^b = 7.46, log N(C)^a = 8.39, log N(C)^b = 8.45, log N(N)^a = 8.12, log(N)^b = 8.15, log N(O)^a = 8.77, log N(O)^b = 8.74.     

Characteristics of spectral aerosol optical depths over India during ICARB

Spectral aerosol optical depth (AOD) measurements, carried out regularly from a network of observatories spread over the Indian mainland and adjoining islands in the Bay of Bengal and Arabian Sea, are used to examine the spatio-temporal and spectral variations during the period of ICARB (March to May 2006). The AODs and the derived Ångström parameters showed considerable variations across India during the above period. While at the southern peninsular stations the AODs decreased towards May after a peak in April, in the north Indian regions they increased continuously from March to May. The Ångström coefficients suggested enhanced coarse mode loading in the north Indian regions, compared to southern India. Nevertheless, as months progressed from March to May, the dominance of coarse mode aerosols increased in the columnar aerosol size spectrum over the entire Indian mainland, maintaining the regional distinctiveness. Compared to the above, the island stations showed considerably low AODs, so too the northeastern station Dibrugarh, indicating the prevalence of cleaner environment. Long-range transport of aerosols from tshe adjoining regions leads to remarkable changes in the magnitude of the AODs and their wavelength dependencies during March to May. HYSPLIT back-trajectory analysis shows that enhanced long-range transport of aerosols, particularly from the west Asia and northwest coastal India, contributed significantly to the enhancement of AOD and in the flattening of the spectra over entire regions; if it is the peninsular regions and the island Minicoy are more impacted in April, the north Indian regions including the Indo Gangetic Plain get affected the most during May, with the AODs soaring as high as 1.0 at 500 nm. Over the islands, the Ångström exponent (α) remained significantly lower (～1) over the Arabian Sea compared to Bay of Bengal (BoB) (～1.4) as revealed by the data respectively from Minicoy and Port Blair. Occurrences of higher values of α, showing dominance of accumulation mode aerosols, over BoB are associated well with the advection, above the boundary layer, of fine particles from the east Asian region during March and April. The change in the airmass to marine in May results in a rapid decrease in α over the BoB.     

A Refined Model for Solid Particle Rock Erosion

A procedure for the estimation of distribution parameters of a Weibull distribution model K₁ = f(K_Ic^12/4/σ_C^23/4) for solid particle erosion, as recently suggested in Rock Mech Rock Eng, doi: 10.1007/s00603-014-0658-x, 2014, is derived. The procedure is based on examinations of elastic–plastically responding rocks (rhyolite, granite) and plastically responding rocks (limestone, schist). The types of response are quantified through SEM inspections of eroded surfaces. Quantitative numbers for the distribution parameter K₁ are calculated for 30 rock materials, which cover a wide range of mechanical properties. The ranking according to the parameter K₁ is related to qualitative rock classification schemes. A modified proposal for the erosion of schist due to solid particle impingement at normal incidence is introduced.