Theoretical and experimental investigation of an ammonia–water power and refrigeration thermodynamic cycle

A combined thermal power and cooling cycle proposed by Goswami is under intensive investigation, both theoretically and experimentally. The proposed cycle combines the Rankine and absorption refrigeration cycles, using a binary ammonia–water mixture as the working fluid. This cycle can be used as a bottoming cycle using waste heat from a conventional power cycle or an independent cycle using low temperature sources such as geothermal and solar energy. Initial parametric studies of the cycle showed the potential for the cycle to be optimized for first or second law efficiency, as well as work or cooling output. For a solar heat source, optimization of the second law efficiency is most appropriate, since the spent heat source fluid is recycled through the solar collectors. The optimization results verified that the cycle could be optimized using the generalized reduced gradient method. Theoretical results were extended to include realistic irreversibilities in the cycle, in preparation for the experimental study. An experimental system was constructed to demonstrate the feasibility of the cycle and to compare the experimental results with the theoretical simulation. Results showed that the vapor generation and absorption condensation processes work experimentally. The potential for combined turbine work and refrigeration output was evidenced in operating the system. Analysis of losses showed where improvements could be made, in preparation for further testing over a broader range of operating parameters.     

低温地热发电有机朗肯循环的优化

采用(火用)分析方法及PR状态方程,建立了低温地热发电有机朗肯循环的工质优选及主要参数优化热力学方法.比较计算了以10种干流体有机工质为循环工质的低温地热发电有机朗肯循环的输出功率、(火用)效率及其余主要热力性能.结果表明,低温地热发电有机朗肯循环的性能极大地受工质的物性及蒸发温度的影响.总体来看,随着工质临界温度的升...     

First and second law analysis of a new power and refrigeration thermodynamic cycle using a solar heat source

The first and second laws of thermodynamics were used to analyze a novel thermodynamic cycle proposed by Goswami in 1995 that uses an ammonia–water binary mixture as the working fluid, while producing both power and refrigeration simultaneously. The thermodynamic performance of the cycle was optimized for maximum second law efficiency using a commercially available optimization program. A maximum second law efficiency of 65.8% was obtained at a heat source temperature of 420 K. An exergy analysis was performed to study losses in different components of the cycle. It is seen that the largest contribution to cycle irreversibility comes from the absorber, with the rectifier and solution heat exchanger also contributing significantly. Irreversibility generation in the boiler is high at very low heat source temperatures, but drops at higher temperatures.     

Design and optimization of a downhole coaxial heat exchanger for an enhanced geothermal system (EGS)

The present study considers the design, performance analysis and optimization of a downhole coaxial heat exchanger for an enhanced geothermal system (EGS). The optimum mass flow rate of the geothermal fluid for minimum pumping power and maximum extracted heat energy was determined. In addition, the coaxial pipes of the downhole heat exchanger were sized based on the optimum geothermal mass flow rate and steady-state operation. Transient effect or time-dependent cooling of the Earth underground, and the optimum amount and size of perforations at the inner pipe entrance region to regulate the flow of the geothermal fluid were disregarded to simplify the analysis. The paper consists of an analytical and numerical thermodynamic optimization of a downhole coaxial heat exchanger used to extract the maximum possible energy from the Earth's deep underground (2 km and deeper below the surface) for direct usage, and subject to a nearly linear increase in geothermal gradient with depth. The thermodynamic optimization process and entropy generation minimization (EGM) analysis were performed to minimize heat transfer and fluid friction irreversibilities. An optimum diameter ratio of the coaxial pipes for minimum pressure drop in both limits of the fully turbulent and laminar fully-developed flow regime was determined and observed to be nearly the same irrespective of the flow regime. Furthermore, an optimum geothermal mass flow rate and an optimum geometry of the downhole coaxial heat exchanger were determined for maximum net power output. Conducting an energetic and exergetic analysis to evaluate the performance of binary power cycle, higher Earth's temperature gradient and lower geofluid rejection temperatures were observed to yield maximum first- and second-law efficiencies.     

Second law analysis of a fossil-geothermal hybrid power plant with thermodynamic optimization of geothermal preheater

There is an urgent and compelling need to develop innovative and more effective ways to integrate sustainable renewable energy solutions into the already existing systems or, better yet, create new systems that all together make use of renewable energy. This study aims to establish the optimum working conditions of a geothermal preheater in a power plant that makes use of both renewable and nonrenewable energy resources, where renewable (geothermal) energy is used to boost the power output in an environmentally sustainable way. Hence, two models, one, a simplified model of a Rankine cycle with single reheat and regeneration, and another, with a geothermal preheater substituting the low-pressure feedwater heater (LPFWH), were compared. The Engineering Equations Solver software was used to perform an analysis of the thermodynamic performance of the two models designed. An analysis was done to evaluate the energetic and exergetic effects of replacing a LPFWH with a geothermal preheater sourcing heat from a low temperature geothermal resource (100°C-160°C). Results from the thermodynamic analysis reveal that the hybridization boosts the power output by approximately 4% and it is superior in terms of the second law. Entropy generation minimization analysis was then employed to establish optimal working conditions of the hybrid system (ie, the geothermal preheater modeled as a downhole coaxial heat exchanger).     

低温地热双循环式发电系统横管喷淋降膜蒸发器传热性能实验研究

以R245fa为工质,搭建有机朗肯循环（ORC）发电系统横管喷淋降膜蒸发器传热测试平台,研究有机工质喷淋密度,地热水初温及流率等因素对管外换热系数的影响。实验结果表明：随着有机工质喷淋密度、地热水初温、地热水流率的增大,传热系数均先增大后减小。最后,根据实验结果,对现有横管喷淋降膜蒸发器的管外传热系数经验公式的参数进行修正。     

Optimum design criteria for an Organic Rankine cycle using low-temperature geothermal heat sources

A cost-effective optimum design criterion for Organic Rankine power cycles utilizing low-temperature geothermal heat sources is presented. The ratio of the total heat exchanger area to net power output is used as the objective function and was optimized using the steepest descent method. Evaporation and condensation temperatures, geothermal and cooling water velocities are varied in the optimization method. The optimum cycle performance is evaluated and compared for working fluids that include ammonia, HCFC123, n-Pentane and PF5050. The optimization method converges to a unique solution for specific values of evaporation and condensation temperatures and geothermal and cooling water velocities. The choice of working fluid can be greatly affect the objective function which is a measure of power plant cost and in some instances the difference could be more than twice. Ammonia has minimum objective function and maximum geothermal water utilization, but not necessarily maximum cycle efficiency. Exergy analysis shows that efficiency of the ammonia cycle has been largely compromised in the optimization process than that of other working fluids. The fluids, HCFC 123 and n-Pentane, have better performance than PF 5050, although the latter has most preferable physical and chemical characteristics compared to other fluids considered.     

Second Law Efficiency Analysis of Heat Exchangers

Analytical analysis of unbalanced heat exchangers is carried out to study the second law thermodynamic performance parameter through second law efficiency by varying length‐to‐diameter ratio for counter flow and parallel flow configurations. In a single closed form expression, three important irreversibilities occurring in the heat exchangers—namely, due to heat transfer, pressure drop, and imbalance between the mass flow streams—are considered, which is not possible in first law thermodynamic analysis. The study is carried out by giving special influence to geometric characteristics like tube length‐to‐diameter dimensions; working conditions like changing heat capacity ratio, changing the value of maximum heat capacity rate on the hot stream and cold stream separately and fluid flow type, i.e., laminar and turbulent flows for a fully developed condition. Further, second law efficiency analysis is carried out for condenser and evaporator heat exchangers by varying the effectiveness and number of heat transfer units for different values of inlet temperature to reference the temperature ratio by considering heat transfer irreversibility. Optimum heat exchanger geometrical dimensions, namely length‐to‐diameter ratio can be obtained from the second law analysis corresponding to lower total entropy generation and higher second law efficiency. Second law analysis incorporates all the heat exchanger irreversibilities. © 2013 Wiley Periodicals, Inc. Heat Trans Asian Res; Published online in Wiley Online Library ( wileyonlinelibrary.com/journal/htj ). DOI 10.1002/htj.21109     

Thermodynamic analysis and optimization of various power cycles for a geothermal resource

In this study, geothermal resources in Kutahya-Simav region having geothermal water at a temperature suitable for power generation is considered. The study is aimed to yield the method of the most effective use of the geothermal resource and a rational thermodynamic comparison of various cycles for a given resource. Maximum first law efficiencies vary between 6.9 to 10.6% while the second law efficiencies vary between 38.5 to 59.3% depending on the cycle considered. The maximum power output, the first law, and the second law efficiencies are obtained for Kalina cycle followed by combined cycle and binary cycle.     

Parametric sensitivity study of operating and design variables in wellbore heat exchangers

A numerical study was conducted to evaluate the potential for using Wellbore Heat Exchangers (WBHX) to extract heat for use in electricity generation. Variables studied included operational parameters such as wellbore geometries, working fluid properties, circulation rates, and regional properties including basal heat flux and formation rock type. Energy extraction is strongly affected by fluid residence time, heat transfer contact area, and formation thermal properties. Water appears to be the most appropriate working fluid. The effects of tubing properties and casing lengths are of second-order.On the basis of a sensitivity study, a Best Case model was simulated, and results compared against the geothermal fluid requirements of existing power generation plants that use low-temperature geothermal fluids. Even assuming ideal work conversion to electricity, a WBHX cannot supply sufficient energy to generate 200 kWe at the onset of pseudo-steady-state (PSS) conditions. Using realistic conversion efficiencies it is unlikely that the system would be able to generate 50 kWe at the onset of PSS.     

Analysis of power and cooling cogeneration using ammonia-water mixture

Development of innovative thermodynamic cycles is important for the efficient utilization of low-temperature heat sources such as solar, geothermal and waste heat sources. This paper presents a parametric analysis of a combined power/cooling cycle, which combines the Rankine and absorption refrigeration cycles, uses ammonia-water mixture as the working fluid and produces power and cooling simultaneously. This cycle, also known as the Goswami Cycle, can be used as a bottoming cycle using waste heat from a conventional power cycle or as an independent cycle using solar or geothermal energy. A thermodynamic study of power and cooling cogeneration is presented. The performance of the cycle for a range of boiler pressures, ammonia concentrations and isentropic turbine efficiencies are studied to find out the sensitivities of net work, amount of cooling and effective efficiencies. The roles of rectifier and superheater on the cycle performance are investigated. The cycle heat source temperature is varied between 90-170 °C and the maximum effective first law and exergy efficiencies for an absorber temperature of 30 °C are calculated as 20% and 72%, respectively. The turbine exit quality of the cycle for different boiler exit scenarios shows that turbine exit quality decreases when the absorber temperature decreases.     

Potential of thermoelectric waste heat recovery in a combined geothermal,fuel cell and organic Rankine flash cycle (thermodynamic and economic evaluation)

The present work aim is performance improvement of an integrated geothermal system by proposing the integration of organic Rankine flash cycle (ORFC) with the Proton exchange membrane fuel cell (PEMFC) and waste heat recovery from condensers using thermoelectric generator (TEG) modules. To achieve this goal, a novel integrated system is proposed, thermodynamically modeled, investigated, and compared with the conventional system. To assess the performance of proposed system, thermodynamic and economic evaluations are performed. The results indicate that R123 as working fluid, has the best performance for the conventional and proposed systems. The findings demonstrate that with employing TEG modules an increase of 2.7% and 2.8%, for the first and second law efficiencies can be obtained respectively. Additionally, the results of parametric analysis indicate that however the geothermal fluid temperature increment decreases the first and second law efficiencies of the system, it leads to the net output power enhancement. Also, enhancement of the flash vessel pressure ratio increases the first and second law efficiency as well. Additionally, the simple payback method showed that a payback time between 1.25 years and 25 years according to the TEG modules cost can be achieved.     

Thermodynamic analysis of binary-fluid Rankine cycles for geothermal power plants

The performance of geothermal power plants using binary-fluid Rankine cycles is studied here using the thermal cycle efficiency (first law), cycle effectiveness and the second law cycle efficiency. The study is restricted to operation at less than supercritical conditions, and numerical results are shown for R-113 working fluid. It is seen that only the second law approach helps to identify optimal working conditions for maximizing the work output. The sensitivity of these optimal conditions to perturbations in the cycle parameters is also shown. The results indicate the advantages in using hybrid-cycles over single low-temperature source power cycles.     

Exergetic analysis of various types of geothermal power plants

Based on available surveys, it has been shown that Iran has substantial geothermal potential in the north and north-western provinces, where in some places the temperature reaches 240 °C. In order to better exploit these renewable resources, it is necessary to study this area. Thus, the aim of this paper is a comparative study of the different geothermal power plant concepts, based on the exergy analysis for high-temperature geothermal resources. The considered cycles for this study are a binary geothermal power plant using a simple organic Rankine cycle (ORC), a binary geothermal power plant using an ORC with an internal heat exchanger (IHE), a binary cycle with a regenerative ORC, a binary cycle with a regenerative ORC with an IHE, a single-flash geothermal power plant, a double-flash geothermal power plant and a combined flash-binary power plant. With respect to each cycle, a thermodynamic model had to be developed. Model validation was undertaken using available data from the literature. Based on the exergy analysis, a comparative study was done to clarify the best cycle configuration. The performance of each cycle has been discussed in terms of the second-law efficiency, exergy destruction rate, and first-law efficiency. Comparisons between the different geothermal power plant concepts as well as many approaches to define efficiencies have been presented. The maximum first-law efficiency was found to be related to the ORC with an IHE with R123 as the working fluid and was calculated to be 7.65%. In contrast, the first-law efficiency based on the energy input into the ORC revealed that the binary cycle with the regenerative ORC with an IHE and R123 as the working fluid has the highest efficiency (15.35%). Also, the maximum first-law efficiency was shown to be given by the flash-binary with R123 as the working fluid and was calculated to be 11.81%.     

Comparative analysis of natural and conventional working fluids for use in transcritical Rankine cycle using low‐temperature geothermal source

Theoretical analyses of natural and conventional working fluids‐based transcritical Rankine power cycles driven by low‐temperature geothermal sources have been carried out with the methodology of pinch point analysis using computer models. The regenerator has been introduced and analyzed with a modified methodology considering the considerable variation of specific heat with temperature near the critical state. The evaluations of transcritical Rankine cycles have been performed based on equal thermodynamic mean heat rejection temperature and optimized gas heater pressures at various geothermal source temperature levels ranging from 80 to 120°C. The performances of CO₂, a natural working fluid most commonly used in a transcritical power cycle, have been indicated as baselines. The results obtained show: optimum thermodynamic mean heat injection temperatures of transcritical Rankine cycles are distributed in the range of 60 to 70% of given geothermal source temperature level; optimum gas heater pressures of working fluids considered are lower than baselines; thermal efficiencies and expansion ratios (Exp_r) are higher than baselines while net power output, volume flow rate at turbine inlet (V₁) and heat transfer capacity curves are distributed at both sides of baselines. From thermodynamic and techno‐economic point of view, R125 presents the best performances. It shows 10% higher net power output, 3% lower V₁, 1.0 time higher Exp_r, and 22% reduction of total heat transfer areas compared with baselines given geothermal source temperature of 90°C. With the geothermal source temperature above 100°C, R32 and R143a also show better performances. R170 shows nearly the same performances with baselines except for the higher V₁ value. It also shows that better temperature gliding match between fluids in the gas heater can lead to more net power output. Copyright © 2010 John Wiley & Sons, Ltd.     

Regenerative vapor cycle with isobutane as working fluid

One of the methods of generating geothermal power is to use a suitable working fluid which extracts heat from geothermal fluids and generates power in a closed cycle. This paper presents a discussion of an improvement of the basic closed cycle with isobutane as a working fluid. A regenerative heat exchanger is added for heating the cold condensate of isobutane with the highly superheated exhaust. The addition of this heat exchanger can result in a significant reduction in the size of heat rejection equipment. Furthermore, the waste brine of the improved system is at such a high temperature that the waste heat can be economically utilized for desalting water for industrial uses.     

用低沸点工质的朗肯循环(ORC)方法回收低位工业余热

我国的中低温余热发电技术尚不很成熟。本文介绍以低沸点的有机物 (正戊烷N - pantane)作为工质来回收废气余热、汽化进入汽轮机膨胀作功 ,带动发电机发电的有机朗肯循环 (ORC)余热发电技术 ,对于低位工业余热及地热能的开发 ,都有重要的参考价值。     

有机工质余热发电技术的研究进展及其应用前景

工业余热、太阳能热、地热、生物质能、海洋温差等都是低品位热源,有机朗肯循环(ORC)可以有效提高低品位热源的利用效率。提高ORC效率的关键是根据应用对象的特点选择合适的有机工质,国内外学者对各种领域内应用的ORC工质进行了大量深入的工作,并且取得很多成果,我国低温余热资源十分丰富,而能源利用率却不高,采用ORC提高能源回收以及利用率,在我国各行各业在都有着广阔的应用前景。     

Study on Heat Transfer in Heat Exchangers for a New Supercritical Organic Rankine Cycle

Electrical power from geothermal heat is hardly efficient, if the temperature level of geothermal water is low. This situation is predominant in middle Europe, for example, in Germany, where even in hot-spot areas like Norddeutsches Becken, Oberrheingraben, and Molassebecken the temperature of geothermal water is less than 160°C. For this, efforts have to be made in optimizing the power cycle efficiency. Supercritical fluids provide a higher net energy output per unit mass than subcritical fluids but their physical properties strongly depend on temperature variations, especially close to the supercritical point. Based on the requirements of a new modular and mobile supercritical power cycle MONICA (modular low temperature power cycle Karlsruhe), which will be built within the next few years, different heat exchanger types are investigated within this study in order to determine the most compact design with respect to mobility, mountability, and efficiency. Changes in physical properties of propane, the working fluid of the new cycle, are taken into account by iterative, stepwise calculation of heat exchanger types like double-pipe, shell-and-tube, and plate heat exchangers. For this, common Nusselt number correlations are implemented in the stepwise iteration. Influence of geometry on flow conditions and analysis of part load sensitivity are provided.     

Electrical power from moderated temperature geothermal sources with modular mini-power plants

Organic Rankine Cycle geothermal recovery mini-power plants using moderate temperature (85–150°C) (185–300°F and higher) have been pioneered by ORMAT and are made in sizes of 300–1300 kW factory-integrated and tested modules. The skid-mounted power package module comprises heat exchangers, turbine, generator, control system and low voltage switch-gear as well as valves, safety circuits and piping. Two or more units can be combined for applications where the geothermal or industrial waste heat source is sufficient to permit larger power plants to be economically installed. Experience has been acquired in operation in low enthalpy geothermal projects in Nevada, Utah, California, Oregon and, outside the United States, in Mexico and other countries. Several typical power plants rated 800 kW, 3.2 and 30 MW are described. Reference is made to practical field experience with the units in commercial power generation and to automation in the operation of the power plants.