混合材对水泥与减水剂适应性的影响研究

通过对掺高效减水剂水泥净浆流动性及流动性损失的测定试验，研究了3种混合材(粉煤灰、水淬高炉矿渣和沸石)在不同替代率情况下对减水剂作用效果的影响。结果表明：水淬高炉矿渣有利于改善减水剂与水泥的适应性，而掺粉煤灰和沸石(尤其是沸石)则会导致减水剂塑化作用的降低，而且浆体流动性损失也有增大趋势。     

混合材对水泥与聚羧酸减水剂相容性的影响

通过对聚羧酸高效减水剂水泥净浆流动度及流动度损失的测定试验,研究了粉煤灰和水淬高炉矿渣在不同替代率及不同配比情况下对减水剂效果的影响。研究结果表明:水淬高炉矿渣有利于改善水泥与减水剂的相容性,而掺粉煤灰则会导致减水剂塑化作用的降低,而且浆体流动度损失也有增大趋势。     

聚羧酸减水剂与水泥-粉煤灰胶凝体系的相容性研究

采用水泥浆体流动性的实验方法,通过测量浆体流动度和观察实验现象评价高效减水剂与水泥以及粉煤灰的相容性。经过测试,聚羧酸减水剂与水泥的相容性好,并且粉煤灰对减水剂与水泥的相容性具有改善作用。聚羧酸减水剂在水泥浆体上有饱和点和离析点。各条减水剂掺量-浆体流动度曲线之间有一定的相关性。60min流动度的经时损失较30min更能反映减水剡与水泥的相容性。     

粉煤灰对水泥胶凝体系与高效减水剂相容性影响的研究

从水泥、粉煤灰和高效减水剂的作用机理出发,通过净浆流动度试验测定饱和点值和流动度经时损失两个指标来检测和评价水泥以及不同掺量、不同细度粉煤灰胶凝材料体系与高效减水剂的相容性问题.     

多羧酸系高效减水剂与水泥的相容性

研究了不同高效减水剂(多羧酸系、萘系)对普通硅酸盐水泥、中热硅酸盐水泥、矿渣硅酸盐水泥及快硬硅酸盐水泥浆体的流动度及流动度经时损失情况。结果表明,多羧酸系高效减水剂比萘系高效减水剂与水泥具有更好的相容性;多羧酸系和萘系高效减水剂与不同水泥之间的相容性规律基本相同,即与矿渣水泥相容性较好,而与普通硅酸盐水泥相容性较差;多羧酸系高效减水剂适宜的使用温度为10～30℃。     

造纸废液接枝脂肪族单体制备的高效减水剂与水泥的相容性试验研究

通过水泥净浆流动度试验,本文研究了一种从造纸废液获取的木质素磺酸盐中间体接枝脂肪族活性单体制成的新型高效减水剂(LGCA)与不同特性水泥的相容性,主要探讨了水泥中混合材的种类(粉煤灰和矿渣)及掺量、碱含量、铝酸三钙(C3A)含量和水泥的细度等因素对LGCA与水泥的相容性的影响.研究表明,LGCA具有一定的缓凝作用;碱含量的升高、C3A含量的增大以及水泥细度的提高均使得掺LGCA水泥净浆的初始流动度下降;而适量掺入混合材有助于改善LGCA与水泥的相容性.     

复掺混合材水泥流变性及其与高效减水剂相容性的研究

根据工厂实际情况设计混合材正交配比水平,通过Marsh时间和水泥净浆流动度实验,比较复掺矿渣、粉煤灰、石灰石对水泥流变性的影响,发现粉煤灰对浆体流变性的影响最大;并从中挑选流变性较好的几组试样,测试其与高效减水剂的相容性,得出最佳配比.即当掺入0.6%的萘系高效减水剂时,最佳复掺混合材配比为矿渣21%,粉煤灰3%,石灰...     

减水剂对阿利特-硫铝酸盐水泥适应性的研究

研究了高效减水剂对阿利特-硫铝酸盐水泥的饱和点、水泥浆体的流动度及流动度经时损失的影响。结果表明,对于阿利特-硫铝酸盐水泥,萘磺酸盐高效减水剂的饱和点掺量明显高于聚羧酸盐和氨基磺酸盐高效减水剂;不同高效减水剂对阿利特-硫铝酸盐水泥浆体的流动度及流动度经时损失的作用效果亦不同,聚羧酸盐高效减水剂最好,氨基磺酸盐次之,萘磺酸盐较差;阿利特-硫铝酸盐水泥中掺加矿物掺合料可以改善其与减水剂的适应性,矿物掺合料掺量越大,水泥净浆的流动度越大,流动度经时损失越小,矿渣粉的作用效果优于粉煤灰。     

高效减水剂对水泥熟料的助磨作用及与水泥熟料相容性问题的探讨

研究了不同类型的高效减水剂对水泥熟料的助磨作用，并进一步探讨了不同水泥熟料与高效减水剂之间的相容性问题，结果表明，高效减水剂对水泥熟料具有不同程度的助磨作用，作用的大小与减水剂掺量及熟料自身物料特性有关；高效减水剂与水泥熟料之间存在相容性问题，同一种水泥熟料与不同减水剂，同一种减水剂与不同水泥熟料之间的适应性不同。采用内掺高效减水剂的方法既改善了水泥熟料的易磨性，又增强了减水剂与水泥熟料的相容性，减水效果增加，流动度损失减小。     

矿渣微粉-粉煤灰-高效减水剂与水泥净浆的流动度

通过矿渣微粉单掺、矿渣微粉与不同的高效减水剂双掺、矿渣微粉与粉煤灰双掺以及矿渣微粉、粉煤灰与高效减水剂三掺来研究水泥浆体的流动度与矿渣微粉之间的关系.结果表明:矿渣微粉的减水作用只有在和高效减水剂同时使用时才能得到充分发挥.     

利用电炉氧化钢渣制备混凝土矿物掺合料的研究

研究了磨细电炉氧化钢渣对水泥标准稠度需水量、水泥净浆流动度以及混凝土抗压强度、抗渗性、抗冻性、抗碳化等性能指标的影响.研究结果表明,磨细钢渣具有令人满意的减水效果且与混凝土减水剂有较好的适应性;适量磨细钢渣掺入混凝土中对混凝土抗压强度以及耐久性能影响不大;将磨细钢渣与磨细粉煤灰或矿渣混掺可以发挥复合效应,提高掺合料的活性,改善混凝土的性能.     

The fluidity of fly ash-cement paste with superplasticizer

The influence of various fly ashes on the fluidity of fly ash-cement paste with superplasticizer was investigated in connection with the amounts of superplasticizer adsorbed on fly ashes, the change of ζ-potential and the physical properties of fly ashes. Fly ash indicates a high negative ζ-potential, and by adding superplasticizer, an even higher negative ζ-potential is indicated. However, the fluidity of fly ash paste is not improved by addition of superplasticizer as much as in the case of cement. The fluidity of fly ash-cement paste mixed with superplasticizer is influenced by the kinds of fly ashes. The bulk specific gravity of fly ash may be an index for judging the influence of fly ash on the fluidity of fly ash-cement paste.     

混合材料微粉对水泥砂浆性能的影响

用不同掺量的矿渣粉及粉煤灰对水泥砂浆流动性和抗压强度进行了试验研究。结果表明：矿渣粉和粉煤灰都可以提高砂浆的流动性,它们对水泥砂浆的流动度及抗压强度的影响与水泥品种及砂浆配合比有关。     

钢渣粉和粉煤灰对钢渣混凝土力学性能的影响特点

探讨钢渣粉和粉煤灰等量取代水泥后钢渣混凝土的力学属性变化特点和规律。实验对比表明 :与强度等级为 32 .5的纯水泥钢渣混凝土对比 ,掺入钢渣粉的砼强度略有降低 ,但能改善混凝土的和易性。掺入粉煤灰将增大混凝土的粘聚性和可塑性 ,改善混凝土的和易性 ,减小混凝土的膨胀性。     

粉煤灰和矿渣粒度分布对混凝土微观结构和抗氯离子渗透性的影响

针对胶凝材料比表面积和粒度分布等物理性质存在的差异,将P·Ⅱ水泥,Ⅰ级、Ⅱ级粉煤灰和S95级、S105级矿渣进行互掺,固定水泥用量,设计了4种粉煤灰和矿渣的组合方式,通过流动度试验分析了组合方式对净浆流动性的影响,并将粒度分布曲线与Fuller分布曲线进行了比较。在净浆配合比的基础上,对不同组合方式的混凝土进行了工作性、力学性能及自由氯离子浓度测试,探讨了粉煤灰和矿渣的粒度分布对混凝土强度和抗氯离子渗透性的影响,并对硬化浆体水化产物的微观形貌和化学组成进行了分析,揭示了影响机理。研究结果表明,矿物掺合料的粒度分布是决定颗粒级配优劣的重要因素。Ⅰ级粉煤灰具有更强的滚珠效应,在提高流动性方面起了关键性作用。粉煤灰和矿渣的水化及火山灰反应程度影响着混凝土的力学性能和耐久性能,由于Ⅰ级粉煤灰有更大的比表面积,火山灰活性也较高,因此Ⅰ级粉煤灰和S95/S105级矿渣组合的净浆流动度,混凝土的工作性、抗压强度和抗氯离子渗透性均明显高于Ⅱ级粉煤灰和S95/S105级矿渣组合。其中Ⅰ级粉煤灰和S95级矿渣组合的胶凝材料粒度分布曲线与Fuller曲线最为接近,粒度分布最优,水化浆体中Ca(OH)₂含量最低,火山灰反应最为充分,对应的混凝土微观结构致密,抗氯离子渗透性最好。     

The fluidity of fly ash-cement paste containing naphthalene sulfonate superplasticizer

The zeta potential measurement indicated that the surface potential of fly ash was different from ordinary Portland cement (OPC) in both sign and value. Hence, the Derjaguin-Landau-Verway-Overbeek (DLVO) theory for dispersion-flocculation of heterogeneous particles with different surface potentials was applied to explain the influence of fly ash on the rheology of cement paste containing naphthalene sulfonate superplasticizer. For the fly ash-cement paste without superplasticizer, the sign of zeta potential of fly ash was different from OPC. Thus, the extent of the potential energy barrier between particles was small or even showed negative value, and the change in the rheology of the fly ash-cement paste was mainly dependent on the bulk solid volume of fly ash, which was related to available free water for fluidizing paste. For the fly ash-cement paste with naphthalene sulfonate superplasticizer, fly ash and cement had the same sign and dispersed well due to higher potential barrier. The extent of potential energy barrier depended on the absolute value of surface potential, which was represented by a function of the amount of adsorbed superplasticizer. The bulk solid volume of fly ash also affected the change in flow ability, but the effect of potential energy barrier between particles was superior to that of the bulk solid volume of fly ash.     

Rheology of latex-modified grouts

The rheology of grouts containing latex was investigated. The two latex additives used were carboxylated styrene-butadiene and acrylic. The influences of superplasticizer, fly ash, and blast furnace slag on the rheology of latex-modified grouts were addressed. Shear stress-shear rate curves were determined for a variety of mix proportions. The time-dependent behaviour of selected grouts was also studied. It was determined that the yield stress and apparent viscosity are influenced by latex content and that the grouts are shear thinning at low water/cement ratios. Latex imparts stability and thixotropy in grouts. Partial replacement of cement with either fly ash or slag diminishes the effect of latex on rheology.