Effects of hydrogenation of fossil fuels with hydrogen and hydroxy gas on performance and emissions of internal combustion engines

Energy security is an important consideration for development of future transport fuels. Among the all gaseous fuels hydrogen or hydroxy (HHO) gas is considered to be one of the clean alternative fuels. Hydrogen is very flammable gas and storing and transporting of hydrogen gas safely is very difficult. Today, vehicles using pure hydrogen as fuel require stations with compressed or liquefied hydrogen stocks at high pressures from hydrogen production centres established with large investments.Different electrode design and different electrolytes have been tested to find the best electrode design and electrolyte for higher amount of HHO production using same electric energy. HHO is used as an additional fuel without storage tanks in the four strokes, 4-cylinder compression ignition engine and two-stroke, one-cylinder spark ignition engine without any structural changes. Later, previously developed commercially available dry cell HHO reactor used as a fuel additive to neat diesel fuel and biodiesel fuel mixtures. HHO gas is used to hydrogenate the compressed natural gas (CNG) and different amounts of HHO-CNG fuel mixtures are used in a pilot injection CI engine. Pure diesel fuel and diesel fuel + biodiesel mixtures with different volumetric flow rates are also used as pilot injection fuel in the test engine. The effects of HHO enrichment on engine performance and emissions in compression-ignition and spark-ignition engines have been examined in detail. It is found from the experiments that plate type reactor with NaOH produced more HHO gas with the same amount of catalyst and electric energy. All experimental results from Gasoline and Diesel Engines show that performance and exhaust emission values have improved with hydroxy gas addition to the fossil fuels except NO_x exhaust emissions. The maximum average improvements in terms of performance and emissions of the gasoline and the diesel engine are both graphically and numerically expressed in results and discussions. The maximum average improvements obtained for brake power, brake torque and BSFC values of the gasoline engine were 27%, 32.4% and 16.3%, respectively. Furthermore, maximum improvements in performance data obtained with the use of HHO enriched biodiesel fuel mixture in diesel engine were 8.31% for brake power, 7.1% for brake torque and 10% for BSFC.     

Hydrogen enriched waste oil biodiesel usage in compression ignition engine

In the present study, hydrogen enrichment for biodiesel-diesel blends was evaluated to investigate the performance and emission characteristics of a compression ignition engine. Biodiesel was obtained from waste oil and blended to pure diesel fuel by volume fraction of 0%, 10% and 20%. After that, pure hydrogen was introduced through the intake air at different flow rates. Effects of pure hydrogen on performance and emission characteristics were investigated by evaluating power, torque, specific fuel consumption, CO, CO₂ and NO_x emissions. Experimental study revealed that waste oil biodiesel usage deteriorated performance and emission parameters except CO emissions. However, the enrichment test fuels with hydrogen fuel can improve performance characteristics and emission parameters, whereas it increased NO_x emissions. Brake thermal efficiency and specific fuel consumption were improved when the test fuels enriched with hydrogen gas. Because of absence of carbon atoms in the chemical structure of the hydrogen fuel, hydrogen addition dropped CO and CO₂ emissions but increment in cylinder temperature caused rising in NO_x emissions.     

Review of NOx reduction technologies in CI engines fuelled with oxygenated biomass fuels

Oxygenated fuels like biodiesel and alcohols have the potential to provide a reliable and a cost effective alternative to India's increasing future energy demands. They have a prospective future since they are renewable and can be produced easily in India's rural areas. Due to rapid industrialization and the increased number of vehicles on the road, the energy needs of the country are increasing rapidly. Oxygenated fuels can substantially replace the large demand for diesel to generate power for the industries and to fuel diesel engines of the vehicles. In spite of the many advantages of using them, most of the researchers have reported higher NO_x emissions, which is a deterrent to the market expansion of these fuels. The present program aims to review the NO_x emissions from the CI engines fuelled with oxygenated fuels. To meet the stringent emission norms, the various NO_x reduction technologies like use of additives, retarded fuel injection timing, biodiesel emulsion with water, and exhaust gas recirculation are reviewed. The results of the most effective and low cost technique of EGR in DI diesel engine fuelled with biodiesel–diesel blends and tri-compound oxygenated diesel fuel blends (ethanol–biodiesel–diesel fuel blends and methanol–biodiesel–diesel fuel blends) are presented.     

Experimental investigation of control of NOx emissions in biodiesel-fueled compression ignition engine

Biodiesel is an alternative fuel consisting of the alkyl esters of fatty acids from vegetable oils or animal fats. Vegetable oils are produced from numerous oil seed crops (edible and non-edible), e.g., rapeseed oil, linseed oil, rice bran oil, soybean oil, etc. Research has shown that biodiesel-fueled engines produce less carbon monoxide (CO), unburned hydrocarbon (HC), and particulate emissions compared to mineral diesel fuel but higher NO_x emissions. Exhaust gas recirculation (EGR) is effective to reduce NO_x from diesel engines because it lowers the flame temperature and the oxygen concentration in the combustion chamber. However, EGR results in higher particulate matter (PM) emissions. Thus, the drawback of higher NO_x emissions while using biodiesel may be overcome by employing EGR. The objective of current research work is to investigate the usage of biodiesel and EGR simultaneously in order to reduce the emissions of all regulated pollutants from diesel engines. A two-cylinder, air-cooled, constant speed direct injection diesel engine was used for experiments. HCs, NO_x, CO, and opacity of the exhaust gas were measured to estimate the emissions. Various engine performance parameters such as thermal efficiency, brake specific fuel consumption (BSFC), and brake specific energy consumption (BSEC), etc. were calculated from the acquired data. Application of EGR with biodiesel blends resulted in reductions in NO_x emissions without any significant penalty in PM emissions or BSEC.     

Effect of induction on exhaust gas recirculation and hydrogen gas in compression ignition engine with simarouba oil in dual fuel mode

Biofuels extracted from non-edible oil is sustainable and can be used as an alternative fuel for internal combustion engines. This study presents the performance, emission and combustion characteristic analysis by using simarouba oil (obtained from Simarouba seed) as an alternative fuel along with hydrogen and exhaust gas recirculation (EGR) in a compression ignition (CI) engine operating on dual fuel mode. Simarouba biofuel blend (B20) was prepared on volumetric basis by mixing simarouba oil and diesel in the proportion of 20% and 80% (v/v), respectively. Hydrogen gas was introduced at the flow rate of 2.67 kg/min, and EGR concentration was maintained at 30% of total air introduction. Performance, combustion and emission characteristics analysis were examined with biodiesel (B20), biodiesel with hydrogen substitution and biodiesel, hydrogen with EGR and were compared with neat diesel operation. Results indicate that BTE of the engine operating with biodiesel B20 was decreased when compared to neat diesel operation. However, introducing hydrogen along with B20 blend into the combustion chamber shows a slight increase in the BTE by 1%. NO_x emission was increased to 18.13% with the introduction of hydrogen than that of base fuel (diesel) operation. With the introduction of EGR, there is a significant reduction in NO_x emission due to decrease in in-cylinder temperature by 19.07%. A significant reduction in CO, CO_2, and smoke emissions were also noted with the introduction of both hydrogen and EGR. The ignition delay and combustion duration were increased with the introduction of hydrogen, EGR with biodiesel than neat diesel operation. Hence, the proposed biodiesel B20 with H₂ and EGR combination can be applied as an alternative fuel in CI engines.     

Effect of hydrogen supplementation on engine performance and emissions

Vehicular Pollution and environmental degradation are on the rise with increasing vehicles and to stop this strict regulation have been put on vehicular emissions. Also, the depleting fossil fuels are of great concern for energy security. This has motivated the researchers to invest considerable resources in finding cleaner burning, sustainable and renewable fuels. However renewable fuels independently are not sufficient to deal with the problem at hand due to supply constraints. Hence, advanced combustion technologies such as homogeneous charge compression ignition (HCCI), low-temperature combustion (LTC), and dual fuel engines are extensively researched upon. In this context, this work investigates dual fuel mode combustion using a constant speed diesel engine, operated using hydrogen and diesel. The engine is operated at 25, 50 and 75% loads and substitution of diesel energy with hydrogen energy is done as 0, 5, 10 and 20%. The effect of hydrogen energy share (HES) enhancement on engine performance and emissions is investigated. In the tested range, slightly detrimental effect of HES on brake thermal efficiency (BTE) and brake specific fuel consumption (BSFC) is observed. Comparision of NO and NO₂ emissions is done to understand the non-thermal influence of H₂ on the NO_x emissions. Hence, HES is found beneficial in reducing harmful emissions at low and mid loads.     

Effect of natural antioxidant additive on hydrogen-enriched biodiesel operated compression ignition engine

The environmental degradation and depletion of fossil fuel, urges the need of renewable fuel for IC engines. Among the renewable fuel, biodiesel are widely used as alternative fuel but for recent years hydrogen is also considered as alternative fuel because of zero emission but it possess higher auto ignition temperature. In order to reduce the self-ignition temperature of hydrogen and another liquid fuel is mixed and operated as a dual fuel mode condition in CI engine. The current investigation aims to analyse the impact of natural antioxidant additive on hydrogen-enriched biodiesel operation in a diesel engine. During the experimentation process hydrogen is admitted at the intake manifold and B20 blend of juliflora biodiesel is injected in combustion cylinder. The three test fuel samples are used for the experimentation process such as diesel, B20 and B20 with hydrogen in different flow rates such as 8, 10, 12, 16,20lpm. B20 with hydrogen shows an increment of brake thermal efficiency (BTE). Among the test fuels B20 + 16lpm and B20 + 20lpm blends have better improvement of BTE of 28.815% and 28.32%, which is higher than the conventional engine at maximum load CO, HC emission is also lower for B20 + 16lpm and B20 + 20lpm than other blends but the NO_x emission increases of 26 and 28% than diesel respectively. In order to minimize the NO_x emission, natural antioxidant additive Melia Azedarach (MA) of 1000 ppm is added to B20 + 16lpm and found that B20 + 16lpm with MA shows an improvement of BTE 2.17% higher than B20 + 16lpm without additive and the NO_x emission for B20 + 16lpm with additive is 1079 ppm, which is 21.9% lower than B20 + 16lpm without additives. Therefore B20 + 16lpm with additive is superior than other test blends.     

Effect of ethanol blending with biodiesel on engine performance and exhaust emissions in a CI engine

The use of biodiesel as an alternative diesel engine fuel is increasing rapidly. However, due to technical deficiencies, they are rarely used purely or with high percentages in unmodified diesel engines. Therefore, in this study, we used ethanol as an additive to research the possible use of higher percentages of biodiesel in an unmodified diesel engine. Commercial diesel fuel, 20% biodiesel and 80% diesel fuel, called here as B20, and 80% biodiesel and 20% ethanol, called here as BE20, were used in a single cylinder, four strokes direct injection diesel engine. The effect of test fuels on engine torque, power, brake specific fuel consumption, brake thermal efficiency, exhaust gas temperature, and CO, CO₂, NO_x and SO₂ emissions was investigated. The experimental results showed that the performance of CI engine was improved with the use of the BE20 especially in comparison to B20. Besides, the exhaust emissions for BE20 were fairly reduced.     

Biodiesel production from inedible animal tallow and an experimental investigation of its use as alternative fuel in a direct injection diesel engine

In this study, a substitute fuel for diesel engines was produced from inedible animal tallow and its usability was investigated as pure biodiesel and its blends with petroleum diesel fuel in a diesel engine. Tallow methyl ester as biodiesel fuel was prepared by base-catalyzed transesterification of the fat with methanol in the presence of NaOH as catalyst. Fuel properties of methyl ester, diesel fuel and blends of them (5%, 20% and 50% by volume) were determined. Viscosity and density of fatty acid methyl ester have been found to meet ASTM D6751 and EN 14214 specifications. Viscosity and density of tallow methyl esters are found to be very close to that of diesel. The calorific value of biodiesel is found to be slightly lower than that of diesel. An experimental study was carried out in order to investigate of its usability as alternative fuel of tallow methyl ester in a direct injection diesel engine. It was observed that the addition of biodiesel to the diesel fuel decreases the effective efficiency of engine and increases the specific fuel consumption. This is due to the lower heating value of biodiesel compared to diesel fuel. However, the effective engine power was comparable by biodiesel compared with diesel fuel. Emissions of carbon monoxide (CO), oxides of nitrogen (NO_x), sulphur dioxide (SO₂) and smoke opacity were reduced around 15%, 38.5%, 72.7% and 56.8%, respectively, in case of tallow methyl esters (B100) compared to diesel fuel. Besides, the lowest CO, NO_x emissions and the highest exhaust temperature were obtained for B20 among all other fuels. The reductions in exhaust emissions made tallow methyl esters and its blends, especially B20 a suitable alternative fuel for diesel and thus could help in controlling air pollution. Based on this study, animal tallow methyl esters and its blends with petroleum diesel fuel can be used a substitute for diesel in direct injection diesel engines without any engine modification.     

Performance and emission analysis of cottonseed oil methyl ester in a diesel engine

In this study, performance and emissions of cottonseed oil methyl ester in a diesel engine was experimentally investigated. For the study, cottonseed oil methyl ester (CSOME) was added to diesel fuel, numbered D2, by volume of 5%(B5), 20%(B20), 50%(B50) and 75%(B75) as well as pure CSOME (B100). Fuels were tested in a single cylinder, direct injection, air cooled diesel engine. The effects of CSOME-diesel blends on engine performance and exhaust emissions were examined at various engine speeds and full loaded engine. The effect of B5, B20, B50, B75, B100 and D2 on the engine power, engine torque, bsfc's and exhaust gasses temperature were clarified by the performance tests. The influences of blends on CO, NO_x, SO₂ and smoke opacity were investigated by emission tests. The experimental results showed that the use of the lower blends (B5) slightly increases the engine torque at medium and higher speeds in compression ignition engines. However, there were no significant differences in performance values of B5, B20 and diesel fuel. Also with the increase of the biodiesel in blends, the exhaust emissions were reduced. The experimental results showed that the lower contents of CSOME in the blends can partially be substituted for the diesel fuel without any modifications in diesel engines.     

Investigation on combustion and emission characteristics of hydrogen-enriched dual-fuel engine operated under waste frying oil biodiesel

Using nonedible waste frying oil (WFO) as biodiesel and hydrogen in the mix composition may partly replace significant quantities of diesel fuel and help reduce fossil fuel reliance. The combination of diesel fuel, waste-fired biodiesel, and hydrogen gas can improve the performance, combustion, and emissions of single-fuel and dual-fuel diesel engines. This may lead to a novel alternative fuel mix pattern and modification for diesel engines, which is the research gap. Although there has been some research on waste-fired biodiesel and hydrogen gas-powered dual-fuel engines with the goal of partly replacing fossil fuels to a larger degree, there has been very little progress in this area. As a result, the current research effort focuses on using diesel fuel (100%, 30%, and 60%), waste-fired biodiesel (at 100%, 70%, and 40%), and hydrogen gas as fuel sources (5 and 10 liters per minute [LPM]). According to the current experiment, it was perceived in both dual-fuel and single-fuel modes. Under duel-fuel mode, the engine results for WFOB70D30 + H10 fuel blend had higher 4.2% (brake thermal efficiency [BTE]), 19.72% (oxides of nitrogen [NO_x]), and 9.09% (ignition delay [ID]) with a minimal range of (in-cylinder pressure, MFB, volumetric efficiency and heat release rate [HRR]) and a dropped rate of 4.34% (brake-specific energy consumption [BSEC]), 33.33% (carbon monoxide [CO]), 39.28% (hydrocarbons [HC]), 9.43% (smoke), and 6.97% (combustion duration [CD]) related to diesel fuel at peak load. However, single-fuel powered diesel engines provide minimal performance for the WFOB40D60 fuel blend with (11.32% lower BTE and 2.04% higher BSEC) and minimal rate of combustion (lower cylinder pressure, 2.12% minimal CD, 14.72% higher ID, minimal HRR combustion, volumetric efficiency, and MFB). Emitted fewer emissions (9.09% less CO, 4.87% less HC, 0.92% higher NO_x, and 1.69% more smoke) than diesel fuel at peak load. Therefore, it was concluded that adding 10 LPM of hydrogen gas to the biodiesel under a dual-fuel condition leads to better combustion, better performance, and less pollution than the single-fuel mode of operation.     

Optimization of diesel engine input parameters running on Polanga biodiesel to improve performance and exhaust emission using MOORA technique with standard deviation

Fast exhausting fossil fuel reserves and high rise in the air pollution levels due to combustion of these fuels bound us to discover some cleaner and environment-friendly fuels for the engines. Biodiesel from edible and non-edible seed oils has been identified as a better alternate of the diesel fuel in engines with a little sacrifice in terms of power output but with an improvement in exhaust emissions. The aim of the present research work is to optimize the input parameters of diesel engine running on Polanga biodiesel to improve performance and exhaust emissions. The input parameters selected for optimization are fuel injection timing, fuel injection pressure, Polanga biodiesel blend, and engine load with respect to brake thermal efficiency, brake specific fuel consumption, hydrocarbon emission, smoke opacity, and emission of nitrogen oxides. Relative weights of the response variables were calculated by standard deviation. The optimum combination of input parameters was obtained by Taguchi-based Multi-Objective Optimization by Ratio Analysis. Experiments were performed according to Taguchi’s L₁₆ orthogonal array in a random manner in which three replicates of each experiment were noted. The optimum combination of input parameters for maximum performance and minimum exhaust emissions found to be as fuel injection timing 27° bTDC, fuel injection pressure –? 220 bar, biodiesel blend –? B40, and engine load –? 60%. The optimum values of the response variables, at the obtained optimum combination of input parameters, were predicted by Taguchi method and then verified experimentally and a good relation was found between them. These optimum values found to be as brake thermal efficiency –? 36.351%, brake specific fuel consumption –? 0.322 kg/kW-h, hydrocarbon emission –? 2.193 ppm, smoke opacity –? 80.925 HSU, and NO_x emission –? 690.987 ppmv.     

Biofuels and thermal barrier: A review on compression ignition engine performance,combustion and exhaust gas emission

The performance of an internal combustion engine is affected when renewable biofuels are used instead of fossil fuels in an unmodified engine. Various engine modifications were experimented by the researchers to optimise the biofuels operated engine performance. Thermal barrier coating is one of the techniques used to improve the biofuels operated engine performance and combustion characteristics by reducing the heat loss from the combustion chamber. In this study, engine tests results on performance, combustion and exhaust emission characteristics of the biofuels operated thermal barrier coated engines were collated and reviewed. The results found in the literature were reviewed in three scenarios: (i) uncoated versus coated engine for fossil diesel fuel application, (ii) uncoated versus coated engine for biofuels (and blends) application, and (iii) fossil diesel use on uncoated engine versus biofuel (and blends) use on coated engine. Effects of injection timing, injection pressure and fuel properties on thermal barrier coatings were also discussed. The material type, thickness and properties of the coating materials used by the research community were presented. The effectiveness and durability of the coating layer depends on two key properties: low thermal conductivity and high thermal expansion coefficient. The current study showed that thermal barrier coatings could potentially offset the performance drop due to use of biofuels in the compression ignition engines. Improvements of up to 4.6% in torque, 7.8% in power output, 13.4% in brake specific fuel consumption, 15.4% in brake specific energy consumption and 10.7% in brake thermal efficiency were reported when biofuels or biofuel blends were used in the thermal barrier coated engines as compared to the uncoated engines. In coated engines, peak cylinder pressure and exhaust gas temperature were increased by up to 16.3 bar and 14% respectively as compared to uncoated condition. However, changes in the heat release rates were reported to be between ?27% and +13.8% as compared to uncoated standard engine. Reductions of CO, CO₂, HC and smoke emissions were reported by up to 3.8%, 11.1%, 90.9% and 63% respectively as compared to uncoated engines. Significant decreases in the PM emissions were also reported due to use of thermal barrier coatings in the combustion chamber. In contrast, at high speed and at high load operation, increase in the CO and CO₂ emissions were also reported in coated engines. Coated engines gave higher NO_x emissions by about 4–62.9% as compared to uncoated engines. Combined effects of thermal barrier coatings and optimisation of fuel properties and injection parameters produced further performance and emissions advantages compared to only thermal barrier coated engines. Overall, current review study showed that application of thermal barrier coatings in compression ignition engines could be beneficial when biofuels or biofuel blends are used instead of standard fossil diesel. However, more research is needed combining coatings, types of biofuels and other engine modifications to establish a concrete conclusion on the effectiveness of the thermal barrier when biofuels are used in the compression ignition engine. Reduction of NO_x emissions is another important R & D area.     

A critical review: Application of methanol as a fuel for internal combustion engines and effects of blending methanol with diesel/biodiesel/ethanol on performance,emission, and combustion characteristics of engines

This article presents a comprehensive overview of methanol as a potential oxygenated fuel for internal combustion engines. Here two approaches have been examined to evaluate the utilization of methanol, namely blending with diesel/biodiesel/methanol and premixing with intake air or fumigation. In conventional compression ignition engines, up to 95% and 25% diesel can be replaced by methanol through fumigation and blending, respectively. Higher latent heat of vaporization of alcohol led to lower peak in-cylinder pressure and NO_x; however, it negatively affects thermal efficiency and hydrocarbon and carbon monoxide emissions. Fumigation of alcohol requires modifications in the existing engine, whereas blending needed surfactants or additives to produce stable alcohol–diesel blends. High injection pressure and late direct injection, methanol–diesel blends have shown lower emissions and proved their potential as a suitable replacement for ethanol–diesel blends from the components durability perspective.     

Analysis of the effects of reformate (hydrogen/carbon monoxide) as an assistive fuel on the performance and emissions of used canola-oil biodiesel

Evolving technology and a reoccurring energy crisis creates a continued investigation into the search for sustainable and clean-burning renewable fuels. One possibility is hydrogen that has many desirable qualities such as a low flammability limit promoting ultra-lean combustion, high laminar flame speed for increased thermal efficiency and low emissions. However, past research discovered certain limiting factors in its use such as pre-ignition in spark ignition engines and inability to work as a singular fuel in compression ignition engines. To offset these issues, this work documents manifold injection of a hydrogen/carbon monoxide mixture in a dual-fuel methodology with biodiesel. While carbon monoxide does degrade some of the desirable properties of hydrogen, it acts partially like a diluent to restrict pre-ignition. The result of this mixture addition allows the engine to maintain power while reducing biodiesel fuel consumption with a minimal NO_x emissions increase.     

Determination of ecological efficiency in internal combustion engines: The use of biodiesel

This paper evaluates and quantifies the environmental impact from the use of some renewable fuels and fossils fuels in internal combustion engines. The following fuels are evaluated: gasoline blended with anhydrous ethyl alcohol (anhydrous ethanol), conventional diesel fuel, biodiesel in pure form and blended with diesel fuel, and natural gas. For the case of biodiesel, its complete life cycle and the closed carbon cycle (photosynthesis) were considered. The ecological efficiency concept depends on the environmental impact caused by CO₂, SO₂, NO_x and particulate material (PM) emissions. The exhaust gases from internal combustion engines, in the case of the gasoline (blended with alcohol), biodiesel and biodiesel blended with conventional diesel, are the less polluting; on the other hand, the most polluting are those related to conventional diesel. They can cause serious problems to the environment because of their dangerous components for the human, animal and vegetable life. The resultant pollution of each one of the mentioned fuels are analyzed, considering separately CO₂, SO₂, NO_x and particulate material (PM) emissions. As conclusion, it is possible to calculate an environmental factor that represents, qualitatively and quantitative, the emissions in internal combustion engines that are mostly used in urban transport. Biodiesel in pure form (B100) and blended with conventional diesel as fuel for engines pollute less than conventional diesel fuel. The ecological efficiency for pure biodiesel (B100) is 86.75%; for biodiesel blended with conventional diesel fuel (B20, 20% biodiesel and 80% diesel), it is 78.79%. Finally, the ecological efficiency for conventional diesel, when used in engines, is 77.34%; for gasoline, it is 82.52%, and for natural gas, it is 91.95%. All these figures considered a thermal efficiency of 30% for the internal combustion engine.     

Combustion performance and emission reduction characteristics of automotive DME engine system

This article is a condensed overview of a dimethyl ether (DME) fuel application for a compression ignition diesel engine. In this review article, the spray, atomization, combustion and exhaust emissions characteristics from a DME-fueled engine are described, as well as the fundamental fuel properties including the vapor pressure, kinematic viscosity, cetane number, and the bulk modulus. DME fuel exists as gas phase at atmospheric state and it must be pressurized to supply the liquid DME to fuel injection system. In addition, DME-fueled engine needs the modification of fuel supply and injection system because the low viscosity of DME caused the leakage. Different fuel properties such as low density, viscosity and higher vapor pressure compared to diesel fuel induced the shorter spray tip penetration, wider cone angle, and smaller droplet size than diesel fuel. The ignition of DME fuel in combustion chamber starts in advance compared to diesel or biodiesel fueled compression ignition engine due to higher cetane number than diesel and biodiesel fuels. In addition, DME combustion is soot-free since it has no carbon–carbon bonds, and has lower HC and CO emissions than that of diesel combustion. The NO_x emission from DME-fueled combustion can be reduced by the application of EGR (exhaust gas recirculation). This article also describes various technologies to reduce NO_x emission from DME-fueled engines, such as the multiple injection strategy and premixed combustion. Finally, the development trends of DME-fueled vehicle are described with various experimental results and discussion for fuel properties, spray atomization characteristics, combustion performance, and exhaust emissions characteristics of DME fuel.     

Performance and emission characteristics of a Kirloskar HA394 diesel engine operated on fish oil methyl esters

The high viscosity of fish oil leads to problem in pumping and spray characteristics. The inefficient mixing of fish oil with air leads to incomplete combustion. The best way to use fish oil as fuel in compression ignition (CI) engines is to convert it into biodiesel. It can be used in CI engines with very little or no engine modifications. This is because it has properties similar to mineral diesel. Combustion tests for methyl ester of fish oil and its blends with diesel fuel were performed in a kirloskar H394 DI diesel engine, to evaluate fish biodiesel as an alternative fuel for diesel engine, at constant speed of 1500 rpm under variable load conditions. The tests showed no major deviations in diesel engine's combustion as well as no significant changes in the engine performance and reduction of main noxious emissions with the exception on NO_x. Overall fish biodiesel showed good combustion properties and environmental benefits.     

Hydrogen dual-fuelling of compression ignition engines with emulsified biodiesel as pilot fuel

Dual-fuel compression ignition (CI) engine operation with hydrogen is a promising method of using hydrogen gas in CI engines via high-cetane pilot fuel ignition. However, hydrogen dual-fuel operation with neat pilot fuels typically produce: high NO_x emissions; and high combustion chamber pressure rise rates (leading to increased “Diesel knock” tendencies). While water-in-fuel emulsions have been used during normal CI engine operation to cool the charge and slow combustion rates in an effort to reduce NO_x emissions, these water-in-fuel emulsions have not been tested as pilot fuels during hydrogen dual-fuel combustion. In this work two water-in-biodiesel emulsions are tested as pilot fuels during hydrogen dual-fuel operation. Hydrogen dual-fuel operation generally produces at best comparable thermal efficiencies compared with normal CI engine operation, while the emulsified biodiesel pilot fuels generally increase thermal efficiencies when compared with the neat biodiesel pilot fuel during dual-fuel operation. There is also a clear reduction in NO_x emissions with emulsified pilot fuel use compared with the neat pilot fuel. The thermal efficiency increase is more apparent at higher engine speeds, while the NO_x reduction is more apparent at lower speeds. This is due to two conflicting effects (exclusive to emulsified pilot fuel) that occur in tandem. The first is the cooling effect of water vapourisation on the charge, while the second is the microexplosion phenomenon which enhances fuel-air mixing. The NO_x emission reduction is due to the emulsified pilot fuel lowering pressure rise rates compared with the neat pilot fuel, while the efficiency increase is due to a more homogeneous charge resulting from the violent microexplosion of the emulsified pilot fuel. Smoke, CO, HC and CO₂ emissions remain comparable to neat pilot fuel tests. Overall, emulsified pilot fuels can reduce NO_x emissions and increase thermal efficiencies, however not at the same instance and under different operating conditions. The general trends of reduced power output, reduced CO₂ and increased water vapour emission during hydrogen dual-fuel operation (with neat pilot fuels) are also maintained.     

Numerical model to analyze Nox reduction by ammonia injection in diesel-hydrogen engines

Nowadays, the even increasing stringent environmental legislations have promoted interest in alternative fuels for internal combustion engines. Particularly, hydrogen is becoming a promising fuel due to its high specific energy and low emissions production. Environmentally, the main disadvantage of hydrogen is the high level of nitrogen oxides (NO_x) which produces. In this regard, this work proposes a NO_x reduction method which consists on direct injection of ammonia (NH₃) into the combustion chamber. A numerical model validated with experimental measurements was carried out to analyze emissions and brake specific consumption in a commercial engine operating with diesel-hydrogen blends. Comparing to diesel operation, a 10% hydrogen content increases a 5.3% the peak pressure and 5.7% the maximum temperature. The CO₂, CO and HC emissions are reduced but NO_x emissions increase up to 18.3%. Several injection instants and ammonia flow rates were analyzed, obtaining more than 70% NO_x reductions with a negligible effect on other emissions and brake specific consumption. It was found that the start of ammonia injection is too critical since the maximum NO_x reduction takes place when the temperature is around 1200 K. The NO_x reduction increases with the ammonia flow rate but an excessive quantity of ammonia can lead to un-reacted ammonia slip to the exhaust.