Effect of ignition timing and hydrogen fraction on combustion and emission characteristics of natural gas direct-injection engine

An experimental study on the combustion and emission characteristics of a direct-injection spark-ignited engine fueled with natural gas/hydrogen blends under various ignition timings was conducted. The results show that ignition timing has a significant influence on engine performance, combustion and emissions. The interval between the end of fuel injection and ignition timing is a very important parameter for direct-injection natural gas engines. The turbulent flow in the combustion chamber generated by the fuel jet remains high and relative strong mixture stratification is introduced when decreasing the angle interval between the end of fuel injection and ignition timing giving fast burning rates and high thermal efficiencies. The maximum cylinder gas pressure, maximum mean gas temperature, maximum rate of pressure rise and maximum heat release rate increase with the advancing of ignition timing. However, these parameters do not vary much with hydrogen addition under specific ignition timing indicating that a small hydrogen fraction addition of less than 20% in the present experiment has little influence on combustion parameters under specific ignition timing. The exhaust HC emission decreases while the exhaust CO₂ concentration increases with the advancing of ignition timing. In the lean combustion condition, the exhaust CO does not vary much with ignition timing. At the same ignition timing, the exhaust HC decreases with hydrogen addition while the exhaust CO and CO₂ do not vary much with hydrogen addition. The exhaust NOx increases with the advancing of ignition timing and the behavior tends to be more obvious at large ignition advance angle. The brake mean effective pressure and the effective thermal efficiency of natural gas/hydrogen mixture combustion increase compared with those of natural gas combustion when the hydrogen fraction is over 10%. __________ Translated from Transactions of CSICE, 2006, 24(5): 394–401 [译自:内燃机学报]     

Natural-gas fueled spark-ignition (SI) and compression-ignition (CI) engine performance and emissions

Natural gas is a fossil fuel that has been used and investigated extensively for use in spark-ignition (SI) and compression-ignition (CI) engines. Compared with conventional gasoline engines, SI engines using natural gas can run at higher compression ratios, thus producing higher thermal efficiencies but also increased nitrogen oxide (NO_x) emissions, while producing lower emissions of carbon dioxide (CO₂), unburned hydrocarbons (HC) and carbon monoxide (CO). These engines also produce relatively less power than gasoline-fueled engines because of the convergence of one or more of three factors: a reduction in volumetric efficiency due to natural-gas injection in the intake manifold; the lower stoichiometric fuel/air ratio of natural gas compared to gasoline; and the lower equivalence ratio at which these engines may be run in order to reduce NO_x emissions. High NO_x emissions, especially at high loads, reduce with exhaust gas recirculation (EGR). However, EGR rates above a maximum value result in misfire and erratic engine operation. Hydrogen gas addition increases this EGR threshold significantly. In addition, hydrogen increases the flame speed of the natural gas-hydrogen mixture. Power levels can be increased with supercharging or turbocharging and intercooling. Natural gas is used to power CI engines via the dual-fuel mode, where a high-cetane fuel is injected along with the natural gas in order to provide a source of ignition for the charge. Thermal efficiency levels compared with normal diesel-fueled CI-engine operation are generally maintained with dual-fuel operation, and smoke levels are reduced significantly. At the same time, lower NO_x and CO₂ emissions, as well as higher HC and CO emissions compared with normal CI-engine operation at low and intermediate loads are recorded. These trends are caused by the low charge temperature and increased ignition delay, resulting in low combustion temperatures. Another factor is insufficient penetration and distribution of the pilot fuel in the charge, resulting in a lack of ignition centers. EGR admission at low and intermediate loads increases combustion temperatures, lowering unburned HC and CO emissions. Larger pilot fuel quantities at these load levels and hydrogen gas addition can also help increase combustion efficiency. Power output is lower at certain conditions than diesel-fueled engines, for reasons similar to those affecting power output of SI engines. In both cases the power output can be maintained with direct injection. Overall, natural gas can be used in both engine types; however further refinement and optimization of engines and fuel-injection systems is needed.     

Investigation of hydrogen addition to methanol-gasoline blends in an SI engine

In this study, effects of hydrogen-addition on the performance and emission characteristics of Methanol-Gasoline blends in a spark ignition (SI) engine were investigated. Experiments were conducted with a four-cylinder and four stroke spark ignition engine. Performance tests were performed via measuring brake thermal efficiency, brake specific fuel consumption, cylinder pressure and exhaust emissions (CO, CO₂, HC, NOx). These performance metrics were analyzed under three engine load conditions (no load, 50% and 100%) with a constant speed of 2000 rpm. Methanol was added to the gasoline up to 15% by volume (5%, 10% and 15%). Besides, hydrogen was added to methanol-gasoline mixtures up to 15% by volume (3%, 6%, 9% and 15%). Results of this study showed that methanol addition increases BSFC by 26% and decreases thermal efficiency by 10.5% compared to the gasoline. By adding hydrogen to the methanol - gasoline mixtures, the BSFC decreased by 4% and the thermal efficiency increased by 2% compared to the gasoline. Hydrogen addition to methanol – gasoline mixtures reduces exhaust emissions by about 16%, 75% and 15% of the mean average values of HC, CO and CO2 emissions, respectively. Lastly, ?t was concluded that hydrogen addition improves combustion process; CO and HC emissions reduce as a result of the leaning effect caused by the methanol addition; and CO2 and NOx emission increases because of the improved combustion.     

Investigations on operation of CI engine using producer gas and rice bran oil in mixed fuel mode

A naturally aspirated multi cylinder diesel genset (DG) was operated successfully with mixed fuels (fossil-diesel (FD), refined rice bran oil (RRBO) and producer gas from a wood gasifier). Performance of DG set in FD, dual fuel mode (FD+RRBO in different proportion and FD+producer gas) and mixed fuels mode (with preheated blend of 75% RRBO+FD and producer gas) at different engine load conditions are presented in this paper. Performance of DG was evaluated in terms of specific energy consumption (SEC), brake thermal efficiency, exhaust gas temperature and exhaust gas composition. Study revealed that blends containing up to 75% RRBO with FD could be used as engine fuel without any adverse effect on the engine. The blend of RRBO and FD was preheated to 60 °C before use in the compression ignition (CI) engine. In general, exhaust gas temperature and SEC increased in all the three modes compared to FD. However, break thermal efficiency decreased. It may be due to lower calorific value of RRBO and producer gas.It was observed that at 84% engine load having 18.4:1 compression ratio (CR) and operating in dual fuel mode (FD+producer gas), the concentration of pollutants like carbon monoxide (CO), carbon dioxide (CO₂), nitric oxide (NO), nitrogen dioxide (NO₂) reduced by 55%, 19.7%, 82% and 83%, respectively, while hydrocarbon (HC) increased by 67.2% as compared to FD. Similarly at 84% engine load having 17:1 CR and operating in dual fuel mode (FD+RRBO), the concentration of pollutant like CO, CO₂ and HC reduced by 60%, 0.86% and 91%, respectively. However, NO_x increased by 23.48% as compared to FD.In mixed fuel mode (preheated blends of RRBO+FD in the proportion of 3:1 and producer gas) at 84% engine load having 18.4:1 CR, the concentration of pollutants like HC, NO and NO₂ reduced by 48.28%, 61.57% and 80.48%, respectively, while CO increased by 16.31% as compared to FD. In addition to the findings on environmental aspects, the study also proved that the diesel engine could be run safely in mixed fuel mode (53% producer gas, rest RRBO and FD at the ratio of 3:1 and heated at 60 °C).     

Comparative engine performance and emission analysis of CNG and gasoline in a retrofitted car engine

A comparative analysis is being performed of the engine performance and exhaust emission on a gasoline and compressed natural gas (CNG) fueled retrofitted spark ignition car engine. A new 1.6 L, 4-cylinder petrol engine was converted to the computer incorporated bi-fuel system which operated with either gasoline or CNG using an electronically controlled solenoid actuated valve mechanism. The engine brake power, brake specific fuel consumption, brake thermal efficiency, exhaust gas temperature and exhaust emissions (unburnt hydrocarbon, carbon mono-oxide, oxygen and carbon dioxides) were measured over a range of speed variations at 50% and 80% throttle positions through a computer based data acquisition and control system. Comparative analysis of the experimental results showed 19.25% and 10.86% reduction in brake power and 15.96% and 14.68% reduction in brake specific fuel consumption (BSFC) at 50% and 80% throttle positions respectively while the engine was fueled with CNG compared to that with the gasoline. Whereas, the retrofitted engine produced 1.6% higher brake thermal efficiency and 24.21% higher exhaust gas temperature at 80% throttle had produced an average of 40.84% higher NO_x emission over the speed range of 1500–5500 rpm at 80% throttle. Other emission contents (unburnt HC, CO, O₂ and CO₂) were significantly lower than those of the gasoline emissions.     

Experimental research on a blended hydrogen-fuel engine

An experimental study on the performance of a single cylinder engine fueled with hydrogen/gas fule blends was carried out. The performance of engine with different fuel components under the load characteristics of the engine was analyzed. The experimental results showed that with the increase of hydrogen blending ratio, the combustion speed was accelerated, and the maximum torque and maximum pressure in the cylinder were increased; The maximum torque of blended fuel with 40% CO₂ was 68.3% of that without CO₂; The maximum pressure in cylinder of blended fuel with 40% H₂ was 1.6 times higher than that without hydrogen; When the proportion of hydrogen was more than 30%, the torque decreased; When the mixture was blended with 30% N₂, the engine torque reached the maximum at the hydrogen ratio of 15%; With the increase of hydrogen blending ratio, the emission of CO increased and the emission of HC and NOx decreased; When the hydrogen blending ratio remained unchanged, the CO emission was the largest at medium load, the HC emission was the largest at small load, and the NOx emission was the largest at high load; When the mixture was blended with 15% H₂, with the increase of the proportion of nitrogen, emission of CO decreased, emissions of HC and NOx increased. The research of this paper provided an experimental basis for the design and development of gas fuel engines.     

Experimental study on a spark ignition engine fuelled by methane–hydrogen mixtures

In this study, effects on a spark ignition engine of mixtures of hydrogen and methane have been experimentally considered. This article presents the results of a four-cylinder engine test with mixtures of hydrogen in methane of 0, 10, 20 and 30% by volume. Experiments have been made varying the equivalence ratio. Equivalence ratios have been selected from 0.6 to 1.2. Each fuel has been investigated at 2000 rpm and constant load conditions. The result shows that NO emissions increase, HC, CO and _CO2${\mathrm{CO}}_2$ emission values decrease and brake thermal efficiency (BTE) values increase with increasing hydrogen percentage.     

The emission analysis of an IDI diesel engine fueled with methyl ester of waste frying palm oil and its blends

In this study, the exhaust emissions of an unmodified diesel engine fueled with methyl ester of waste frying palm-oil (biodiesel) and its blends with petroleum based diesel fuel (PBDF) were investigated at the full load-variable speed condition. The relationships between the fuel properties and the air–fuel equivalence ratio, fuel line pressure, start of injection (SOI) timing, and ignition delay were also discussed to explain their effects on the emissions. The obtained test results were compared with the reference values which were determined by using PBDF. The results showed that when biodiesel was used in the test engine, the fuel line pressure increased while air–fuel equivalence ratio and ignition delay decreased. These behaviors affected the combustion phenomena of biodiesel which caused to reduction 57% in carbon monoxide (CO) emission, about 40% in unburned hydrocarbon (HC) emission and about 23% in smoke opacity when compared with PBDF. However, NO_x and CO₂ emissions of the biodiesel have showed different behaviors in terms of the engine speed.     

Effect of ignition timing and hydrogen fraction on combustion and emission characteristics of natural gas direct-injection engine

An experimental study on the combustion and emission characteristics of a direct-injection spark-ignited engine fueled with natural gas/hydrogen blends under various ignition timings was conducted. The results show that ignition timing has a significant influence on engine performance, combustion and emissions. The interval between the end of fuel injection and ignition timing is a very important parameter for direct-injection natural gas engines. The turbulent flow in the combustion chamber generated by the fuel jet remains high and relative strong mixture stratification is introduced when decreasing the angle interval between the end of fuel injection and ignition timing giving fast burning rates and high thermal efficiencies. The maximum cylinder gas pressure, maximum mean gas temperature, maximum rate of pressure rise and maximum heat release rate increase with the advancing of ignition timing. However, these parameters do not vary much with hydrogen addition under specific ignition timing indicating that a small hydrogen fraction addition of less than 20% in the present experiment has little influence on combustion parameters under specific ignition timing. The exhaust HC emission decreases while the exhaust CO₂ concentration increases with the advancing of ignition timing. In the lean combustion condition, the exhaust CO does not vary much with ignition timing. At the same ignition timing, the exhaust HC decreases with hydrogen addition while the exhaust CO and CO₂ do not vary much with hydrogen addition. The exhaust NO_x increases with the advancing of ignition timing and the behavior tends to be more obvious at large ignition advance angle. The brake mean effective pressure and the effective thermal efficiency of natural gas/hydrogen mixture combustion increase compared with those of natural gas combustion when the hydrogen fraction is over 10%.     

Study of methane enrichment in a biogas fuelled HCCI engine

Biogas has been a promising alternative fuel for IC engines. However, its CO₂ content reduces calorific value and ignitability. The CO₂ fraction of raw biogas can be separated out by various techniques, which are collectively called methane enrichment. The present study explores the effect of methane enrichment on the output parameters of a Homogeneous Charge Compression Ignition (HCCI) engine. A single cylinder CI engine is altered for this purpose. Biogas (CH₄ + CO₂) is supplied along with air. Diethyl Ether (DEE) is used as the secondary fuel to initiate auto-ignition. The effects of injecting DEE at the inlet port and upstream in the intake manifold are also compared. Performance, emission and combustion characteristics such as brake thermal efficiency, equivalence ratio, HC, CO, CO₂, NO_x and smoke emissions, start and duration of combustion, in-cylinder pressure and maximum heat release rate are compared for operation with raw biogas (50% methane) and methane enriched biogas (100% methane) for various biogas flow rates and engine torques. Results show that methane enrichment enhances brake thermal efficiency by up to 2% compared to raw biogas. Methane enrichment advances and speeds up combustion. HC, CO and CO₂ emissions, maximum cylinder pressure and maximum heat release rate are also improved with methane enrichment. Ultra-low NO_x and smoke emissions can be obtained using raw biogas as well as methane enriched biogas. Low biogas flow rates provide better brake thermal efficiency and HC emissions. Manifold injection of DEE enhances brake thermal efficiency by up to 2% compared to port injection by virtue of greater mixture homogeneity.     

Performance and emission analysis of compression ignition engine using biodiesels from Acid oil,Mahua oil,and Castor oil

Research on and use of biodiesels for engines is growing continuously in the present era. Compression ignition (CI) engine performance for biodiesels of blends B20 from Acid oil, Mahua oil, and Castor oil is experimentally investigated. The engine performance analysis in the form of brake‐specific fuel consumption, brake‐specific energy consumption, brake thermal efficiency (BTE), exhaust gas temperature (EGT), and air fuel ratio are compared with diesel as base fuel. Emission characteristics like CO, CO₂, NOx, and opacity are comparatively studied in detail for the considered biodiesels. The entire study is compared with the performance of engine when pure diesel is chosen as fuel. From the complete analysis it was observed that the BTE was higher for Acid oil and Mahua oil among the biodiesels used. And regarding CO emissions, Mahua oil showed lower effect than other biodiesels. Upto 6% increase in EGT of Mahua oil was obtained at no load and for other loads the percent reduced. For all the biodiesels the % enhancement in Co, CO₂, and NOx was more than 60% at highest load compared with diesel.     

Hydrogen enriched waste oil biodiesel usage in compression ignition engine

In the present study, hydrogen enrichment for biodiesel-diesel blends was evaluated to investigate the performance and emission characteristics of a compression ignition engine. Biodiesel was obtained from waste oil and blended to pure diesel fuel by volume fraction of 0%, 10% and 20%. After that, pure hydrogen was introduced through the intake air at different flow rates. Effects of pure hydrogen on performance and emission characteristics were investigated by evaluating power, torque, specific fuel consumption, CO, CO₂ and NO_x emissions. Experimental study revealed that waste oil biodiesel usage deteriorated performance and emission parameters except CO emissions. However, the enrichment test fuels with hydrogen fuel can improve performance characteristics and emission parameters, whereas it increased NO_x emissions. Brake thermal efficiency and specific fuel consumption were improved when the test fuels enriched with hydrogen gas. Because of absence of carbon atoms in the chemical structure of the hydrogen fuel, hydrogen addition dropped CO and CO₂ emissions but increment in cylinder temperature caused rising in NO_x emissions.     

Experimental and numerical investigation of effects of CNG and gasoline fuels on engine performance and emissions in a dual sequential spark ignition engine

Compared to widening usage of CNG in commercial gasoline engines, insufficient but increasing number of studies have appeared in open literature during last decades while engine characteristics need to be quantified in exact numbers for each specific fuel converted engine. In this study, a dual sequential spark ignition engine (Honda L13A4 i-DSI) is tested separately either with gasoline or CNG at wide open throttle. This specific engine has unique features of dual sequential ignition with variable timing, asymmetrical combustion chamber, and diagonally positioned dual spark-plug. Thus, the engine led some important engine technologies of VTEC and VVT. Tests are performed by varying the engine speed from 1500 rpm to 4000 rpm with an increment of 500 rpm. The engine’s maximum torque speed of 2800 rpm is also tested. For gasoline and CNG fuels, engine performance (brake torque, brake power, brake specific fuel consumption, brake mean effective pressure), emissions (O₂, CO₂, CO, HC, NO_x, and lambda), and the exhaust gas temperature are evaluated. In addition, numerical engine analyses are performed by constructing a 1-D model for the entire test rig and the engine by using Ricardo-Wave software. In the 1-D engine model, same test parameters are analyzed, and same test outputs are calculated. Thus, the test and the 1-D engine model are employed to quantify the effects of gasoline and CNG fuels on the engine performance and emissions for a unique engine. In general, all test and model results show similar and close trends. Results for the tested commercial engine show that CNG operation decreases the brake torque (12.7%), the brake power (12.4%), the brake mean effective pressure (12.8%), the brake specific fuel consumption (16.5%), the CO₂ emission (12.1%), the CO emission (89.7%). The HC emission for CNG is much lower than gasoline. The O₂ emission for CNG is approximately 55.4% higher than gasoline. The NO_x emission for CNG at high speeds is higher than gasoline. The variation percentages are the averages of the considered speed range from 1500 rpm to 4000 rpm.     

不同点火时刻下天然气掺氢缸内直喷发动机燃烧与排放特性

在缸内直喷火花点火发动机上开展了天然气掺混0％-18％氢气的混合燃料不同点火时刻下的试验研究。结果表明：对于给定的喷射时刻和喷射持续期，点火时刻对发动机性能、燃烧和排放有较大影响，喷射结束时刻与点火时刻的间隔对直喷天然气发动机极为重要，喷射结束时刻与点火时刻的间隔缩短时，混合气分层程度高，燃烧速率快，热效率高。最大放热率等燃烧特征参数随点火时刻的提前而增加。HC排放随点火时刻的提前而下降，CO2和NOx排放随点火时刻的提前而增加，NOx排放的增加在大点火提前角下更明显。掺氢可降低HC排放，对CO和CO2排放影响不大。掺氢量大于10％时可提高天然气发动机热效率。     

Effect of exhaust gas recirculation on diesel engine nitrogen oxide reduction operating with jojoba methyl ester

Jojoba methyl ester (JME) has been used as a renewable fuel in numerous studies evaluating its potential use in diesel engines. These studies showed that this fuel is good gas oil substitute but an increase in the nitrogenous oxides emissions was observed at all operating conditions. The aim of this study mainly was to quantify the efficiency of exhaust gas recirculation (EGR) when using JME fuel in a fully instrumented, two-cylinder, naturally aspirated, four-stroke direct injection diesel engine. The tests were carried out in three sections. Firstly, the measured performance and exhaust emissions of the diesel engine operating with diesel fuel and JME at various speeds under full load are determined and compared. Secondly, tests were performed at constant speed with two loads to investigate the EGR effect on engine performance and exhaust emissions including nitrogenous oxides (NO_x), carbon monoxide (CO), unburned hydrocarbons (HC) and exhaust gas temperatures. Thirdly, the effect of cooled EGR with high ratio at full load on engine performance and emissions was examined. The results showed that EGR is an effective technique for reducing NO_x emissions with JME fuel especially in light-duty diesel engines. With the application of the EGR method, the CO and HC concentration in the engine-out emissions increased. For all operating conditions, a better trade-off between HC, CO and NO_x emissions can be attained within a limited EGR rate of 5–15% with very little economy penalty.     

Effect of hydroxy (HHO) gas addition on performance and exhaust emissions in compression ignition engines

In this study, hydroxy gas (HHO) was produced by the electrolysis process of different electrolytes (KOH_(aq), NaOH_(aq), NaCl_(aq)) with various electrode designs in a leak proof plexiglass reactor (hydrogen generator). Hydroxy gas was used as a supplementary fuel in a four cylinder, four stroke, compression ignition (CI) engine without any modification and without need for storage tanks. Its effects on exhaust emissions and engine performance characteristics were investigated. Experiments showed that constant HHO flow rate at low engine speeds (under the critical speed of 1750 rpm for this experimental study), turned advantages of HHO system into disadvantages for engine torque, carbon monoxide (CO), hydrocarbon (HC) emissions and specific fuel consumption (SFC). Investigations demonstrated that HHO flow rate had to be diminished in relation to engine speed below 1750 rpm due to the long opening time of intake manifolds at low speeds. This caused excessive volume occupation of hydroxy in cylinders which prevented correct air to be taken into the combustion chambers and consequently, decreased volumetric efficiency was inevitable. Decreased volumetric efficiency influenced combustion efficiency which had negative effects on engine torque and exhaust emissions. Therefore, a hydroxy electronic control unit (HECU) was designed and manufactured to decrease HHO flow rate by decreasing voltage and current automatically by programming the data logger to compensate disadvantages of HHO gas on SFC, engine torque and exhaust emissions under engine speed of 1750 rpm. The flow rate of HHO gas was measured by using various amounts of KOH, NaOH, NaCl (catalysts). These catalysts were added into the water to diminish hydrogen and oxygen bonds and NaOH was specified as the most appropriate catalyst. It was observed that if the molality of NaOH in solution exceeded 1% by mass, electrical current supplied from the battery increased dramatically due to the too much reduction of electrical resistance. HHO system addition to the engine without any modification resulted in increasing engine torque output by an average of 19.1%, reducing CO emissions by an average of 13.5%, HC emissions by an average of 5% and SFC by an average of 14%.     

Comparison between direct and indirect (prechamber) spark ignition in the case of a cogeneration natural gas engine,: part II: engine operating parameters and turbocharger characteristics

In the first paper (part I), prechamber ignition in cogeneration natural gas engines has been shown to significantly intensify and accelerate the combustion process, offering a further potential to reduce the exhaust gas emissions while keeping efficiency at a high level. This second part discusses the influence of the engine operating parameters (spark timing and load) and the turbocharger characteristics with the objective of evaluating the potential to reduce the exhaust gas emissions, particularly the CO emissions, below the Swiss limits (NO_X and CO emissions: 250 and 650 mg/m_N³, 5% O₂, respectively), without exhaust gas after treatment. The advantage of using an unscavenged prechamber is conditioned by a significant delay of the spark timing in order to generate substantial gas jets. This results in a large decrease in peak cylinder pressure and in an important reduction of NO_X, CO and THC emissions. Minimum emissions are achieved at a spark timing of about 8° CA_BTDC. In comparison with the direct ignition, the prechamber ignition yields approximately 40% and 55% less CO and THC emissions, respectively. However, this also leads to about 2%-point lower fuel conversion efficiency. The optimisation of the turbocharger results in a recovery of about 1%-point in fuel conversion efficiency, but a consequent change in the exhaust manifold gas dynamics attenuates the reduction in THC emissions. At the rated power output (150 kW), the prechamber ignition operation fulfils the Swiss requirements for exhaust gas emissions and still achieves a fuel conversion efficiency higher than 36.5%.     

Experimental investigation on biogas enrichment with hydrogen for improving the combustion in diesel engine operating under dual fuel mode

Biogas valorization as fuel for internal combustion engines is one of the alternative fuels, which could be an interesting way to cope the fossil fuel depletion and the current environmental degradation. In this circumstance, an experimental investigation is achieved on a single cylinder DI diesel engine running under dual fuel mode with a focus on the improvement of biogas/diesel fuel combustion by hydrogen enrichment. In the present investigation, the mixture of biogas, containing 70% CH₄ and 30% CO₂, is blended with the desired amount of H₂ (up to 10, 15 and 20% by volume) by using MTI 200 analytical instrument gas chromatograph, which flow thereafter towards the engine intake manifold and mix with the intake air. Depending on engine load conditions, the volumetric composition of the inducted gaseous fraction is 20–50% biogas, 2–10% H₂ and 45–78% air. Near the end of the compression stroke, a small amount of diesel pilot fuel is injected to initiate the combustion of the gas–air mixture. Firstly, the engine was tested on conventional diesel mode (baseline case) and then under dual fuel mode using the biogas. Consequently, hydrogen has partially enriched the biogas. Combustion characteristics, performance parameters and pollutant emissions were investigated in-depth and compared. The results have shown that biogas enriched with 20% H₂ leads to 20% decrease of methane content in the overall exhaust emissions, associated with an improvement in engine performance. The emission levels of unburned hydrocarbon (UHC) and carbon monoxide (CO) are decreased up to 25% and 30% respectively. When the equivalence ratio is increased, a supplement decrease in UHC and CO emissions is achieved up to 28% and 30% respectively when loading the engine at 60%.     

Effect of hydrogen on compression-ignition (CI) engine fueled with vegetable oil/biodiesel from various feedstocks: A review

Compression ignition (CI) engines used in the transportation sector operates on fossil diesel and is one of the biggest causes of air pollution. Numerous studies were carried out over last two decades to substitute the fossil diesel with biofuels so that the net carbon dioxide (CO₂) emission can be minimized. However, the engine performance with these fuel was sub-standard and there were many long-term issues. Therefore, many researchers inducted hydrogen along with the biofuels. The present study gives an outlook on the effect of hydrogen addition with biodiesel/vegetable oil from various sources in CI engine. Engine parameters (brake thermal efficiency, brake specific fuel consumption), combustion parameters (in-cylinder pressure and heat release rate) and emission parameters (unburned hydrocarbon (HC), carbon monoxide (CO), oxides of nitrogen (NOx) and smoke emissions) were evaluated in detail. The results show that hydrogen induction in general improves the engine performance as compared to biodiesel/vegetable oil but it is similar/lower than diesel. Except NOx emissions all other emissions showed a decreasing trend with hydrogen addition. To counter this effect numerous after-treatment systems like selective catalytic reduction (SCR), exhaust gas recirculation (EGR), selective non-catalytic reduction system (SNCR) and non-selective catalytic reduction system (NSCR) were proposed by researchers which were also studied in this review.     

Effect of addition of hydrogen and TiO2 in gasoline engine in various exhaust gas recirculation ratio

The effects of hydrogen ratios on combustion and emission characteristics of gasoline engine were studied under different exhaust gas recirculation (EGR), ignition timing and ignition pressure. The test performed in a modified gasoline direct ignition engine at different hydrogen ratios of 0%, 5%, 10% and 25%. In addition, the EGR rate set to 0%, 5%, 10% and 20% to study the combustion and emission characteristics. Addition to the different hydrogen fractions, 5% of TiO₂ is added to increase the combustion characteristics with reduced emission. Regarding the results of the current study, the engine torque increases by 15% due to the addition of hydrogen in gasoline, while mechanical efficiency is improved by achieving a large throttle opening. At the same time, NOx emission decreased by 62% compared to the unmodified engine due to the influence of EGR, hydrogen ratio and high oxygen concentration TiO₂. Moreover, the emission of CO and HC also reduced due to the influence of hydrogen fuel. Additionally, few more tests are taken to monitor the effect of the injection pressure for the hydrogen fuel. Higher injection reports higher effective thermal efficiency at 4 MPa and lower NOx. Reasonable injection pressure results in shorten flame development period.