共查询到20条相似文献,搜索用时 437 毫秒
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为了提高聚酰亚胺(PI)胶粘剂的耐热性能,将碳硼烷引入PI分子链中,首次合成出一种新型含碳硼烷的PI单体,并采用红外光谱(FT-IR)法对其结构进行了表征。结果表明:含碳硼烷的PI单体在400~500℃升温过程中可交联固化;以此作为PI胶粘剂的基体,可赋予PI胶粘剂极佳的热稳定性能(500~1 300℃时热失重变化不大),从而为制备耐高温胶粘剂提供了新的途径和新的方法。 相似文献
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为了提高乐器胶粘剂的耐湿热稳定性和粘接性能,采用桉树皮灰(A)和偶联桉树皮灰(CA)对涂料胶粘剂进行了改性处理,研究了其占胶粘剂占比,以及添加面粉后对酚醛胶粘剂的改性效果。结果表明,相同改性剂添加量时,CA改性胶粘剂的干胶合强度和湿胶合强度都高于A改性胶粘剂;在相同占比下,偶联桉树皮灰+面粉(CAF)改性胶粘剂的干胶合强度和湿胶合强度都高于桉树皮灰+面粉(AF)改性胶粘剂。A改性胶粘剂的固化起始点、峰值、终止点和热焓值的变化趋势与CA改性胶粘剂较为相似,CA改性胶粘剂的固化峰值温度低于A改性胶粘剂。CAF占比为25%时胶粘剂具有较好的干胶合强度和湿胶合强度。 相似文献
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本文通过聚乙烯本性改性、表面改性以及粘合剂的选择,探讨了聚乙烯与铝材的粘结,发现通过表面改性或/和使用热交、可以使铝材和聚乙烯达到优良的粘结,在实际上可获得应用。 相似文献
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J. Li 《Polymer-Plastics Technology and Engineering》2013,52(4):337-340
Silane coupling agent SG-Si900 (SGS) modification and air-oxidation methods were used to improve the interfacial adhesion of the carbon fiber-reinforced polyimide (CF/PI) composite. The interfacial characteristics of the composites reinforced by the carbon fibers treated with different surface modification methods were comparatively investigated. Results showed that both SGS modification and air-oxidation method improved the adhesion between the reinforcement and matrix and SGS modification method was superior to air-oxidation method. For CF/PI composite the optimum interfacial adhesion was obtained at 0.3 wt% SGS concentration. The fracture surfaces of samples were investigated by scanning electronic microscopy (SEM) to analyze the effects of different surface treatment methods. 相似文献
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探讨了用废聚苯乙烯泡沫塑料(WPS)制备胶粘剂的原理,介绍了化学改性和共混改性的方法;改性剂,助剂,溶剂的选择以及几种改性实例。 相似文献
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《Journal of Adhesion Science and Technology》2013,27(5):573-592
The influence of the surface modification of pressure-sensitive adhesive tapes on their adhesion behavior has been investigated. PBA [poly(butyl acrylate)] and PIB [poly(isobutylene)] adhesives were chosen as pressure-sensitive adhesives and nitrogen plasma was used for the surface modification of the adhesives. The peel force of PBA or PIB adhesive/stainless steel joints was evaluated. The nitrogen plasma treatment showed large effects on the adhesion behavior of both the PBA and the PIB adhesives. The peel force for the PBA adhesive/stainless steel joint decreased by 57 times as a result of the nitrogen plasma treatment and that for the PIB adhesive/stainless steel joint increased by 2.2 times. There are essential differences in the modification reactions caused by the nitrogen plasma between the PBA and PIB adhesives. For the PBA adhesive, cross-linking reactions occurred among the PBA polymer chains and the surface was hardened. For the PIB adhesive, degradation reactions occurred and products with a low molecular weight were formed on the surface. These differences are due to the different responses of the PBA and PIB adhesives towards the nitrogen plasma. The mechanism of the changes in adhesion behavior caused by the nitrogen plasma is discussed. 相似文献
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综述了水性聚氨酯的改性方法,包括环氧树脂改性、丙烯酸酯改性、有机硅改性、有机氟改性、纳米材料改性、复合改性。比较了各种改性方法的优缺点,指出了水性聚氨酯胶粘剂所存在的问题,展望了水性聚氨酯胶粘剂改性发展趋势。 相似文献
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采用硅烷偶联剂KH-550、高温氧化和超声波+偶联剂复合方法(简称超声复合方法)分别对碳纤维(CF)进行表面处理,制备不同表面处理的CF改性热塑性聚酰亚胺(PI)复合材料,研究表面处理CF对CF/PI复合材料力学和摩擦磨损性能的影响,利用扫描电子显微镜对PI复合材料磨损表面进行观察。结果表明:与纯PI相比,CF的加入提高了PI复合材料的机械性能,经超声复合处理的CF的增强效果较好;磨损表面表明:超声复合处理CF改性PI复合材料磨损表面的犁沟和磨屑较少,且平整。 相似文献
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Doroteja Vnučec Andreja Kutnar Andreja Goršek 《Journal of Adhesion Science and Technology》2013,27(8):910-931
Over recent years, the interest in bio-adhesives, including soy-based adhesives, has increased rapidly. Among natural renewable resources suitable for industrial use, soy is a reasonable choice due to its high production volume and the small use of soy meal-based products for human food consumption. Soy flour can be an ideal raw material for the manufacturing of wood adhesives due to its low cost, high protein content and easy processing. There are also more concentrated forms of soy proteins, i.e. concentrates and isolates, which are also suitable raw materials for adhesive production except that their prices are higher. Extensive research has been carried out on improving the cohesive properties, especially water resistance, of soy-based adhesives. However, there is insufficient experimental data available for understanding the influences of modification methods on the structure of soy proteins and therefore for understanding the influences of structural changes on the adhesion. In this paper, some experimental techniques are proposed to be used for analysing soy-based adhesives to enable better understanding of those factors and improve future development. This review of soy-based adhesives is made with the focus on soy proteins’ chemical composition, soy protein product types (raw materials for adhesive production), modification methods for improving the adhesive properties of soy-based adhesives, and commercial soy-based adhesives. 相似文献
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综述了国内外聚四氟乙烯(PTFE)表面亲水改性的研究进展,主要介绍了湿化学处理、低温等离子、辐射接枝、激光处理等方法在PTFE表面改性方面的应用情况,简要叙述了各改性方法的优缺点,并对PTFE表面改性的发展前景进行了展望. 相似文献