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酸对合成二氧化钛介孔材料的影响 总被引:3,自引:0,他引:3
以硫酸和乙酸为酸度调节试剂,采用Sol-Gel过程和水热处理结合,在没有添加任何表面活性剂作模板剂的条件下,通过钛酸丁酯(TBOT)在酸性体系中的控制水解和自组装制备TiO2介孔材料.产物采用XRD、N2吸附-脱附等温线、TG-DSC进行分析表征.通过选择酸的种类和控制酸的浓度,添加配位抑制剂TEA减缓Ti的水解速率,可合成介孔纯TiO2材料.使用硫酸(H2SO4∶TBOT=1∶1,摩尔比)和TEA制备出比表面积为176m2/g,孔容为0.222cm3/g,平均孔径约5nm,孔径分布窄,热稳定性较好的TiO2介孔材料. 相似文献
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以廉价的工业水玻璃为凝胶前躯体,柠檬酸为凝胶促进剂,使用溶胶-凝胶与CO2超临界干燥工艺制备了块状的SiO2气凝胶,并探讨了酸性和碱性条件对所制备SiO2气凝胶结构与性能的影响.实验结果表明:水玻璃在酸性条件(pH≈4)和碱性条件(pH≈10)下均可以制备出完整、无开裂的二氧化硅气凝胶块体样品,酸性和碱性环境对水凝胶和最终SiO2气凝胶结构和性能的影响较大.酸性条件下获得的水凝胶呈透明块体,而碱性条件下所得水凝胶为白色不透明体.与碱性条件下制备的SiO2气凝胶相比,酸性条件下所得气凝胶具有更高的比表面积、较大的密度以及尺寸较小的胶体粒子. 相似文献
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为了提高铜基复合材料的强度和电导率,采用具有良好机械性能和热物理性能的ZrO2(3%(摩尔分数)Y2O3)作为增强相,原位化学法制备了ZrO2纳米颗粒增强铜基复合材料,其主要制备工艺包括前驱复合粉体CuO、ZrO2的制备,经氢气还原得到ZrO2/Cu复合粉,再经过压制,真空烧结,复压等工序制得最后的样品.研究了制备工艺包括初压压力,烧结温度、时间对材料性能的影响;结果表明,在初压压力为550MPa,975℃烧结1.5h时,可得到最佳性能复合材料.透射电镜观察表明,在ZrO2/Cu纳米复合粉中,氧化锆纳米颗粒形状为圆形和四方形,平均尺寸约为20nm左右.纳米ZrO2在基体中分布均匀,细化了晶粒,提高材料硬度,使复合材料具有良好的综合性能.随着ZrO2含量的提高,密度、电导率降低,硬度升高. 相似文献
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纳米TiO2/SiO2复合催化剂的制备与表征 总被引:2,自引:0,他引:2
以钛酸四丁酯、正硅酸乙酯作为前驱体,冰醋酸作为水解抑制剂,用溶胶-凝胶法制备了纳米TiO2/SiO2复合物.讨论了加水量、稳定剂、催化剂、乙醇用量、反应温度等工艺因素对制备过程的影响.用X射线衍射、红外光谱、比表面积仪等测试手段对纳米TiO2/SiO2复合粒子进行了表征.结果表明,用溶胶-凝胶法制备TiO2/SO2复合光催化粒子,整个反应采用滴加方式;各反应组分用量为n(TEOS+TBOT) :n(EtOH) :n(HCl) :n(H2O)=1 :16 :0.06 :4,n(TBOT) :n(HAc)=1 :0.6;反应温度为室温.制备得到的纳米TiO2/SiO2复合粒子主要以锐钛矿型存在;SiO进入TiO2晶体结构中,两者以化学键相结合;TiO2/SiO2复合粒子的比表面积要比纯TiO2粒子的比表面积大得多,当xTi :xsi=3时,TiO2/SiO2复合粒子比表面积达389.11 m2/g. 相似文献
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F. N. Dresvyannikov 《Journal of Engineering Physics and Thermophysics》1968,14(6):563-565
Experimental data on the thermal conductivity of dissociating nitrogen tetroxide have been obtained by the hot-wire method in the temperature range from 290 to 870° K at pressures up to 105 N/m2. 相似文献
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C. Bersier E. P. Stoll P. F. Meier T. A. Claxton 《Journal of Superconductivity and Novel Magnetism》2002,15(5):399-402
First-principles cluster calculations are reported of the local electronic structure of the three compounds: La2CuO4, Sr2CuO2Cl2, and Sr2CuO2F2. The copper ${\text{3d}}_{x^2 - y^2 } $ and the planar oxygen 2p σ atomic orbitals exhibit a similar degree of covalency. The out-of-plane orbitals, however, are quite different with the ${\text{3}}d_{3z^2 - r^2 } $ atomic orbital lowered significantly in energy for chlorine and fluorine apical positions. 相似文献
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The growth of crystalline mica in K2O-SiO2-MgO-MgF2 glass has been studied and characterised through various techniques, viz. differential thermal analysis (DTA), X-ray diffraction
(XRD), microscopy (SEM), and microhardness tests. It is observed that the addition of titania has a stronger influence on
the growth of mica crystallites as compared to variation in heat treatment schedules. 相似文献
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5Na2O·95(SiO2 + TiO2 + ZrO2) gels together with Na2O-MO2 gels (MO2 = SiO2, TiO2, ZrO2) were synthesized and effect of Na2O addition to the gel formation and crystallization behavior were studied. From Si(OC2H5)4, Ti(iso-OC3H7)4, Zr(n-OC3H7)4 and NaOCH3 solutions in EtOH without H2O, transparent, opaque and heterogeneous gels were obtained. By SEM observation, it was found that the opague bulk gels, rich in TiO2 or ZrO2 component, contain agglomerated spherical particles of less than 10 m diameter. Crystallization temperature (Tc) measured by DTA decreased sharply from 1258°C (SiO2) to 613°C (30Na2O·70SiO2) due to the increasing non-bridging oxygens in the Na2O-SiO2 system. But in the Na2O-TiO2 and Na2O-ZrO2 systems, Tc increased as Na2O content was increased up to 10 mol%. The thermal stability, defined by Tc/TL ratio, decreased from Tc/TL = 0.77 (SiO2) to 0.57 (5Na2O·95SiO2) or increased from Tc/TL = 0.30 (TiO2) to 0.67 (30Na2O·70TiO2) with Na2O addition. In the 5Na2O·95(SiO2 + TiO2 + ZrO2) system maximum Tc was 891°C at 5Na2O·76SiO2·19ZrO2 composition and decreased as TiO2 or ZrO2 contents increased. Compared with the SiO2-TiO2-ZrO2 gels, Tc of the 5 mol%Na2O containing gels (Na2O-SiO2-TiO2-ZrO2) was lower in SiO2 rich composition and higher in TiO2 or ZrO2 rich compositions. It is assumed that addition of Na2O changed the structure of amorphous TiO2 and ZrO2 someway to increase their thermal stability or amorphous forming ability. After DTA run up to 1000°C, cystalline phases precipitated in the 5Na2O·95(SiO2 + TiO2 + ZrO2) gels were determined by XRD analysis. 相似文献
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The concept of an optimal electron–phonon interaction spectral density as an Einstein spectrum which allows to describe all physical properties of a superconductor in an optimal way is developed from Carbotte's original definition of an optimum spectrum. It is shown, using the borocarbides YNi2B2C and LuNi2B2C as examples, that such a concept is meaning ful even for anisotropic systems. An Einstein spectrum is sufficient for clean-limit systems, a 2-peak spectrum is better suited for anisotropic systems with impurities. 相似文献