土壤剖面中粉煤灰垂向迁移的磁响应

对浙江省安吉县梅溪发电厂粉煤灰贮灰场附近的土壤短剖面进行环境磁学、元素含量及粒度研究.借助模糊聚类分析,分辨出粉煤灰原位堆积、富集、迁移深度及未受污染土壤特征.剖面上部0～14cm为粉煤灰的原位反映,多畴磁铁矿主导了该段样品磁性.其中11～14cm处磁性矿物和金属元素有所富集.14～21cm为粉煤灰在土壤中的迁移深度.迁移段土壤中亚铁磁性矿物及Pb、Zn等金属含量介于底部未污染土壤与上部粉煤灰原位堆积层之间.单畴斜交反铁磁性矿物及来源于上部粉煤灰的多畴磁铁矿共同主导了该段土壤的磁性特征.21cm以下土壤基本未受粉煤灰污染,单畴斜交反铁磁性矿物是其主要磁性矿物.指标聚类分析表明,亚铁磁性矿物主要赋存在粗粉砂中,单畴磁晶粒主要存在于细粉砂中.χ、ARM、SIRM与Cu、Mn、Pb、Zn呈显著相关.结合多元统计分析,磁参数可用于追踪、识别粉煤灰在土壤剖面中的垂向迁移.     

南京某钢铁公司周边耕作土壤的磁学性质与重金属污染的相关性研究

对取自于南京西南郊某钢铁公司附近水稻田土壤NJ008样芯进行了磁性测量和重金属含量分析,探讨了利用农业耕作土壤的磁参数指示工业区周围重金属污染的可行性。环境磁学测试结果表明：磁化率（χ）、非磁滞剩磁（ARM）及饱和等温剩磁（SIRM）在土壤剖面上部20cm显著增强,磁化率平均值达到112.5×10^-8m^3·kg^-1;20cm以下呈现为较低磁背景特征,磁化率平均值为27.8×10^-8m^3·kg^-1。进一步的磁学实验证明低矫顽力的亚铁磁矿物主导了NJ008样芯的磁性特征,不完整反铁磁性矿物在20cm以下土壤中含量相对较高。Ni,Cu,Fe,Pb,V和Zn等重金属与磁化率呈现相同的变化特征。主成分分析表明亚铁磁性矿物和重金属受同一主成分控制,且磁指标（χ,ARM和SIRM）与重金属（Ni,Cu,Fe,Pb,V和Zn）呈显著相关关系（0.69≤R≤0.98）。对远离钢铁公司的同种耕作土壤剖面NJ013测试表明：其磁化率随深度变化不大,绝对值与NJ008在20cm以下磁背景值基本一致。表明耕作过程中的化肥和农药对土壤磁化率影响不大,钢铁公司释放的工业污染是NJ008土壤剖面中磁化率显著增强的主要原因。耕作土壤由于反复翻种,虽然不能用于污染历史及污染物迁移过程研究,但基于磁指标与部分重金属之间的显著相关性,耕作土壤仍然可以用于重金属污染分布范围的圈定和相对污染程度评价。     

首钢工业区土壤剖面重金属含量及其结合态的磁指示作用的研究

对取自首都钢铁厂附近的土壤样芯进行了重金属含量、形态分析和的磁学测量.探讨了利用磁参数追踪和指示重金属污染和有机结合态和铁锰氧化结合态重金属的可行性.结果表明:土壤样芯中Cu、Pb、Zn、Fe和Mn的含量与χ、SIRM和ARM存在着十分相似的垂向变化特征,且相关关系显著(0.98>R>0.86).进一步对磁化率和Cu、Pb、Zn、Fe和Mn各结合态进行相关分析表明:五种元素的有机结合态与铁锰结合态和磁化率呈显著相关关系(0.98>R>0.56),而交换态和残渣态重金属与磁化率基本不存在相关关系.反映了磁性矿物和和重金属在赋存状态的本质联系.表明了磁性测量可作为工业区土壤重金属污染及有机结合态与铁锰结合态重金属记录信息提取的辅助手段.     

临汾市树叶磁性的时空变化特征及其对大气重金属污染的指示

粉煤灰经工厂废气排放进入大气,对人类健康和生态系统都造成了无法弥补的破坏.本文选取具有高空间分辨率优势的树叶作为收集粉煤灰的载体,对临汾市大气中可吸入颗粒物进行磁学参数和重金属含量监测.结果表明,磁化率最大值出现在工厂污染源附近,磁化率空间分布呈现随污染源距离增加而降低的趋势.工业区收集到的磁性颗粒以低矫顽力、粗粒度的磁铁矿为主.夏季磁性矿物来源单一,主要为人为影响.冬季大气中悬浮的磁性颗粒有部分来自于西北风/北风的自然尘降.同一采样点磁化率随时间变化特征表明,树叶的磁学性质可以灵敏和有效地反映较短时期内大气污染的现状.统计分析表明磁化率和重金属元素(铁,铬,镍,铜,铅,钴)之间存在显著相关性.污染负荷指数用于评估研究区域内重金属各元素综合污染的程度.结果显示,在废弃的旧工业区附近无大气污染指示,但在运营中的工厂集中的地区,大气均受到严重污染.污染负荷指数与表征磁性矿物含量的磁化率呈相关性(r2=0.66),因此树叶的磁性参数可以作为大气重金属污染的替代指标.     

典型沙漠绿洲城市表土磁性特征及环境指示意义

选取典型沙漠绿洲城市（乌海、石嘴山、银川）表土为研究对象,对其环境磁学性质、土壤质地与重金属含量分布进行系统研究.结果表明,乌海市和石嘴山市表土为典型砂土,银川市为砂壤土.三个城市表土样品均以较粗的MD-PSD颗粒的亚铁磁性矿物（磁铁矿）为主导,磁化率均值分别为152×10^-8、104×10^-8和117×10^-8 m³·kg^-1.乌海市表土磁性矿物含量和磁性颗粒大小都显著高于石嘴山和银川市.重金属（Cr、Cu、Pb、Zn、Fe）的污染负荷指数（PLI）均显示,三个城市表土均存在轻度污染特征.同时磁化率和污染负荷指数在非工业区表现出点状高值分布,在工业区表现为面状高值分布特征.乌海市表土磁参数与重金属的相关系数显著高于石嘴山和银川,表明磁参数对于污染来源单一地区的污染程度评估更具优势.尽管三个城市表土磁学性质存在较大差异,但其磁化率均随污染负荷指数的增加呈现相同程度的递增.磁化率可以作为宁夏平原地区表土重金属污染程度评估的统一有效的代用指标.     

澳大利亚悉尼Long Reef Beach中新世古土壤岩石磁学特征及环境意义

本文对发育在澳大利亚悉尼附近的Long Reef Beach中新世古土壤剖面进行了系统的岩石磁学研究,测量了磁化率、饱和磁化强度、饱和等温剩磁、非磁滞剩磁等常温磁学参数和磁滞回线,并对所有样品进行了热磁分析.实验结果表明:全新世软土层主要磁性矿物为MD颗粒磁铁矿,磁性矿物含量与黄土高原黄土层相当.中新世老成土层随地层深度增加主要磁性矿物由磁铁矿转变为磁赤铁矿,随着磁铁矿向磁赤铁矿的转化,开始出现赤铁矿;磁性矿物粒径分布较广,以PSD颗粒为主,其次为SD颗粒,同时含有少量MD颗粒;磁性矿物含量高于黄土高原强发育古土壤层.中新世红土矿层主要磁性矿物为赤铁矿,同时含有少量磁赤铁矿和针铁矿,属于铁的富集层,赤铁矿以SD颗粒为主,含少量PSD和MD颗粒.Long Reef Beach中新世古土壤形成时期,对应着一种全球性高温多雨气候,地表化学风化作用十分强烈.丰富的降水,导致中新世老成土层发生淋溶作用,磁铁矿在向下淋溶迁移过程中逐渐氧化为磁赤铁矿和赤铁矿,铁氧化物最终在红土矿层淀积,磁赤铁矿经高温压实作用再结晶转化为赤铁矿.磁性矿物转化过程可概括为磁铁矿—磁赤铁矿化的磁铁矿—磁赤铁矿—赤铁矿,其中部分磁赤铁矿具有热稳定性,在空气(氩气)环境中加热到700℃未发生转化.     

钢铁厂周围不同污染介质的磁学性质及环境意义

为了通过钢铁厂周围不同污染介质的磁学性质研究,实现对环境污染的有效监测,本文系统地采集了河北兴隆和湖南娄底两个钢铁厂周围的树皮和草表面的飞灰、土壤及不同树种的年轮样品.其中前三者用来反映现今污染源,而树木年轮用来追踪长时间尺度的污染历史.通过综合岩石磁学实验分析（包括热磁曲线、磁滞性质和低温实验等）、电子扫描电镜(SEM)和能谱(EDX)以及X射线衍射(XRD)分析,发现钢铁厂周围现今污染源中的主要粗颗粒磁性矿物为磁铁矿、赤铁矿和纯铁.其中8~50 μm的球形磁铁矿颗粒和呈棱角状的铁颗粒是钢铁厂污染物的特征磁性矿物.对不同树种来说,其中香樟树和枫树树木年轮中的磁性矿物以顺磁性物质为主, 不适合用于环境磁学的污染监测.而柳树中的磁性矿物（主要为磁铁矿）与现今污染源的磁性矿物相符.以上研究表明多参数岩石磁学测量并辅以微观分析等手段,可以精确地提取磁性矿物的种类及粒度特征, 判别重工业区污染源,为应用磁学方法来监测环境污染提供依据.     

福建三明地区被污染土壤的磁学性质及其环境意义

对福建三明某钢铁厂和火电厂附近的污染表土样品进行了多参数的岩石磁学测试分析,包括χ T曲线、磁滞回线、等温剩磁获得曲线等. 三明地区污染表土中的磁性矿物有磁铁矿、赤铁矿和磁黄铁矿. 样品中磁性矿物的平均粒度较粗,为较大的准单畴,甚至多畴,粒度明显大于成土作用所产生的磁性颗粒. 粗粒的磁铁矿颗粒是污染物的主要磁性组分. 虽然磁化率测量可以作为一种简单、快速而且廉价的检测污染土壤的方法,但同时辅以必要的岩石磁学测量将有利于提取更多的污染信息. 对于低磁化率的污染土壤,亚铁磁性硫化物的存在可以作为土壤可能被污染的证据之一.     

甘肃西山坪遗址岩石磁学性质及其研究意义探讨

对甘肃西山坪遗址剖面样品进行磁化率、频率磁化率、热磁分析、非磁滞剩磁和等温剩磁等一系列岩石磁学实验测试,分析环境磁学参数特征变化,试图探讨西山坪遗址研究意义,为今后深入研究该沉积序列蕴含的古环境记录提供了岩石磁学基础.结果表明：西山坪遗址剖面沉积物中磁性矿物主要以低矫顽力的磁铁矿和磁赤铁矿为主,高矫顽力磁性矿物赤铁矿含量极其有限,越向剖面表层,强磁性矿物含量逐渐增加.磁性矿物颗粒表现出黄土的典型特征,以单畴、准单畴为主,含有一定量的超顺磁颗粒,颗粒度越向剖面表层越细.从物源上看,遗址沉积物主要来自近源的黄土风尘堆积,主要是风成堆积,并混合大量人类活动信息,给今后综合研究岩石磁学与人类活动特征的关系有一定借鉴意义.     

黄土高原西北缘末次冰期晚期以来黄土沉积物的岩石磁学性质

以黄土高原西北缘的靖远和古浪剖面(包含黄土层L1上部和占土壤层SO)作为研究对象,选取代表性样品进行磁化率、频率磁化率、热磁曲线、等温剩磁获得曲线和磁滞回线等测定.结果表明,靖远和古浪L1黄土和SO古土壤具有相似的岩石磁学特征.磁性矿物含量相对较低,载磁矿物均以磁铁矿为主,同时含有磁赤铁矿和赤铁矿,且SO占土壤中的磁赤...     

强震观测网、高灵敏度地震观测网、地中强震观测网、宽频带地震观测网

阪神·淡路大震灾后 ,日本着手对原有的地震观测体制作彻底改革 ,多项全国性配置地震计的计划同时开始启动。地震引起的地面晃动的程度不尽相同 ,无感微小地震引发的晃动仅有 0 .0 0 1 μm,频率为1 0 Hz;巨大地震引起的地面晃动的幅度高达 2～ 3 m,周期也有几十秒。虽说都称之为地震计 ,但由于地震动的振幅和频率涉及的范围太大 ,所以应针对观测对象选用不同类型的地震计。下面介绍不同类型的观测网。1　强震观测网 ( K- NET)无论大地有多大的晃动都能将其准确记录下来的地震计称之为强震计。它构造坚实 ,信号明确 ,通常设置在地表 ,对了…     

Sun, climate, hunger, and mass migration

Paleoclimatic studies indicate four epochs of global cooling during the last 4 000 years, i. e. during the few centuries before and after 2000 BC, 800 BC, 400 AD, and 1 600 AD; the quasiperiodicity corresponds to cyclic variation of solar activity. Global temperature changes influenced regional precipitation patterns: Northern Europe was wetter while the middle- and low-latitude lands were more arid during colder epochs. Both sets of cold climatical conditions were unfavorable for agricultural production. Historical records show that large demographic movements in history took place because of crop failures and mass starvation, rather than escaping from war zones. The “wandering” of the Germanic tribes during the first two or three centuries of the Christian Era is one example. Whereas the accelerated release of carbon dioxide from the burning of fossil fuels is ultimately to cause global warming, historical evidence indicates, however, that global warming has been on the whole a blessing to mankind. Global cooling, on the other hand, has curtailed agricultural production and has led to famines and mass migrations of people. Perhaps the most important task at the present is not so much computer-modelling of greenhouse effect on global climate, but water-management and agricultural researches to insure food-supply for an everincreasing world population.     

山西高平地震

阐述了发生在山西高平的地震和对高平有影响的地震，分析了高平市的地震灾害，通过分析得出高平地震与晋获断裂带活动有关的结论。     

Spatial distribution,source apportionment,and associated risks of trace metals (As,Pb, Cr,Cd, and Hg) from a subtropical river,Gomti, Bangladesh

Sediment samples from the Gomti River basin were investigated to determine and evaluate trace metal concentrations,their biological effect,and potential ecological and human health risks for adults and children.The mean concentrations of trace metals were organized in the descending order of mercury(Hg)(0.08 mg/kg)>chromium(Cr)(0.06 mg/kg)>lead(Pb)(0.05 mg/kg)>arsenic(As)(0.02 mg/kg)>cadmium(Cd)(0.01 mg/kg).The current study illustrated that metals were attributed to the area from natural sources and different anthropogenic sources especially from industries.However,the concentration levels were lower than the sediment quality guidelines(SQGs)based on the effect-range classifications of threshold effect concentration(TEC)and probable effect concentration(PEC).Therefore,the concentration of the elements showed no adverse biological effects on aquatic organisms.The evaluated potential ecological risk index also revealed the low toxicity to the aquatic environment.Moreover,the applied sediment quality indices,geo-accumulation index(Igeo),contamination factor(CF),and contamination severity index(CSI)suggested that the contamination levels of the elements were in the acceptable range,and the contamination had not notably impacted on the sediment quality.The risk index(HI)concerning age groups was significantly less than the threshold limit of 1 indicating that the contamination had no non-carcinogenic risk effect.The total carcinogenic risk(TCR)was less than a risk value of 1×10⁴.Hence,the current study suggests that immediate remediation is not required due to an absence of alarming conditions in the study area.Proper monitoring of the attribution of the metal elements should be done for the betterment of human and environmental health。     

Age, geology, geophysics, and geochemistry of Mahukona Volcano, Hawai`i

The size, shape, and magmatic history of the most recently discovered shield volcano in the Hawaiian Islands, Mahukona, have been controversial. Mahukona corresponds to what was thought to be a gap in the paired sequence (Loa and Kea trends) of younger Hawaiian volcanoes (<4?Ma). Here, we present the results of marine expeditions to Mahukona where new bathymetry, sidescan sonar, gravity data, and lava samples were collected to address these controversies. Modeling of bathymetric and gravity data indicate that Mahukona is one of the smallest Hawaiian volcanoes (～6,000?km³) and that its magmatic system was not focused in a long-lived central reservoir like most other Hawaiian volcanoes. This lack of a long-lived magmatic reservoir is reflected by the absence of a central residual gravity high and the random distribution of cones on Mahukona Volcano. Our reconstructed subsidence history for Mahukona suggests it grew to at least ～270?m below sea level but probably did not form an island. New ⁴⁰Ar–³⁹Ar plateau ages range from 350 to 654?ka providing temporal constraints for Mahukona’s post-shield and shield stages of volcanism, which ended prematurely. Mahukona post-shield lavas have high ³He/⁴He ratios (16–21?Ra), which have not been observed in post-shield lavas from other Hawaiian volcanoes. Lava compositions range widely at Mahukona, including Pb isotopic values that straddle the boundary between Kea and Loa sequences of volcanoes. The compositional diversity of Mahukona lavas may be related to its relatively small size (less extensive melting) and the absence of a central magma reservoir where magmas would have been homogenized.     

Dynamics of dissolved major (Na,K, Ca,Mg, and Si) and trace (Al,Fe, Mn,Zn, Cu,and Cr) elements along the lower Orinoco River

This study addresses the changes in dissolved major and trace element concentrations along the Orinoco River, including the mixing zone between the Orinoco and Apure Rivers. Water samples from the Apure and Orinoco Rivers were collected monthly in four sectors over a period of 15 months. Auxiliary parameters (pH, dissolved oxygen, conductivity, and temperature), total suspended sediments, dissolved organic carbon (DOC), and major (Na, K, Ca, Mg, and Si) and trace (Al, Fe, Mn, Zn, Cu, and Cr) element concentrations were measured in all sectors. The relative contribution of both rivers after the Apure–Orinoco confluence was determined using Ca as a tracer. Moreover, a mixing model was developed to determine whether dissolved species exhibit a conservative behavior during mixing. The results indicate that DOC is removed from waters during the Apure–Orinoco mixing, probably due to absorption of DOC on mineral phases supplied by the Apure River. Dissolved Na, Ca, and Mg behave conservatively during the mixing processes, and their concentrations are controlled by a dilution process. The anomaly in the temporal pattern of K in the Orinoco is caused by the input of biogenic K originating from the Apure River during the high‐water stage. The loss of dissolved Si during the low‐water stage can be explained by the uptake of Si by diatoms. Dissolved Mn, Zn, Al, and Fe showed a non‐conservative behavior during the Apure–Orinoco mixing. The removal of Mn and Zn from the dissolved phase can be explained by the formation of Mn‐oxyhydroxides and the scavenging of Zn onto Mn oxides. Dissolved Fe is controlled by redox processes, although the removals of Fe and Al due to the preferential adsorption of large organometallic complexes by mineral surfaces after the Apure–Orinoco confluence can affect the mobility of both elements during transport. The conservative behavior shown by Cu and Cr can be related to the tendency of both elements to be complexed with small organic colloids, which are not preferentially adsorbed by clays.     

The Yecheng,Xinjiang, China,earthquake of February 14, 1980

In this study, we have checked the location and focal depth of the Yecheng earthquake (m _b = 6.0, maximum intensity VII) of February 14, 1980. The result shows that this is an intermediate event with a focal depth of 90 km. The microepicenter is located at 36. 4°N, 76, 9°E, while the macroepicenter is at 37.3°N, 76.9°E, 90 km to the north of the microepicenter. This is the first destructive intermediate event in China which led to a damage as severe as of intensity VII. The focal mechanism of the event is determined to be of thrust type. Combined with the analysis of seismological and geological data in surrounding area, the possible relation between the event and plate movement has been discussed. The result in this paper indicates that in some particular place, the destructive effect of intermediate event should be considered in seismic hazard assessment.     

Transitional, entraining, cloudy, and coastal boundary layers

Atmospheric boundary layers are marvelously varied and complex. Recent research has examined some of that variety. Boundary layers over land undergo drastic changes throughout the day as the sun rises and sets, and as clouds form and dissipate. Air is entrained at the top of the boundary layer at varying rates. As air moves over the coast, the boundary layer reacts to changes in surface forcing. All of these changes affect pollutant transport and weather formation. In this paper, research attempting to understand transitional, cloud-topped, and coastal boundary layers, and boundary-layer top entrainment, is reviewed.