Evaluation of laboratory crude oil threshold fouling data for application to refinery pre-heat trains

`Threshold' models for crude oil fouling present a logical framework for analysing chronic fouling problems in refinery pre-heat trains. Few complete data sets of fouling thresholds in crude oil exist: this paper presents a modelling (correlation) study of the data set obtained by Knudsen et al. [Understanding Heat Exchanger Fouling and its Mitigation, Begell House, New York, 1999, p. 265] for threshold fouling experiments performed in a pilot plant. The threshold fouling equation proposed previously by Ebert and Panchal, and extended by Panchal et al. [Understanding Heat Exchanger Fouling and its Mitigation, Begell House, New York, 1999, p. 273] has been modified following a critique of some of its underlying assumptions. These previous efforts in developing threshold fouling equations were based on observed fouling rates, extrapolated to yield operating conditions that presumably exhibit zero fouling. This study represents an attempt to model measured physical parameters that actually resulted in no observable fouling. The validity of such a model to describe threshold fouling conditions in refinery pre-heat exchangers is discussed.     

Design of shell-and-tube heat exchangers when the fouling depends on local temperature and velocity

Shell-and-tube heat exchangers are normally designed on the basis of a uniform and constant fouling resistance that is specified in advance by the exchanger user. The design process is then one of determining the best exchanger that will achieve the thermal duty within the specified pressure drop constraints. It has been shown in previous papers [Designing shell-and-tube heat exchangers with velocity-dependant fouling, 34th US National Heat Transfer Conference, 20–22 August 2000, Pittsburg, PA; Designing shell-and-tube heat exchangers with velocity-dependant fouling, 2nd Int. Conf. on Petroleum and Gas Phase Behavior and Fouling, 27–31 August 2000, Copenhagen] that this approach can be extended to the design of exchangers where the design fouling resistance depends on velocity. The current paper briefly reviews the main findings of the previous papers and goes on to treat the case where the fouling depends also on the local temperatures. The Ebert–Panchal [Analysis of Exxon crude-oil, slip-stream coking data, Engineering Foundation Conference on Fouling Mitigation of Heat Exchangers, 18–23 June 1995, California] form of fouling rate equation is used to evaluate this fouling dependence. When allowing for temperature effects, it becomes difficult to divorce the design from the way the exchanger will be operated up to the point when the design fouling is achieved. However, rational ways of separating the design from the operation are proposed.     

Influence of Scaling on the Performance of Shell-and-Tube Heat Exchangers

Fouling in shell-and-tube heat exchangers was modeled by combining Hasson's ionic diffusion model for scaling from CaCO₃ solutions with a model for predicting the temperature distribution developed by Gaddis and Schlünder. Using the computed results, clean heat exchanger design rules were tested for fouling conditions. The effects of fouling on the efficiency of heat exchanger configurations were determined.     

Fouling and Uncertainty Margins in Tubular Heat Exchanger Design: An Alternative

Fouling is a costly problem in heat exchanger design and operation. Over the past 20–30 years, design capabilities have advanced such that most fouling can be mitigated through effective design techniques. A design margin is added to the initial clean design in order to handle uncertainties in design and any deterioration in performance due to the reduced fouling that occurs in spite of good design practice. This article explains the advantages and disadvantages of three common methods for adding design margin to heat exchangers. It then introduces a new design margin method that combines the strengths of the previous three while avoiding their weaknesses.     

Experimental Analysis of the Effects of Particulate Fouling on Heat Exchanger Heat Transfer and Air-Side Pressure Drop for a Hybrid Dry Cooler

It is well known that significant fouling by particulate matter can have a deleterious effect on the performance of enhanced surface heat exchangers, and the same is true for hybrid heat exchangers. Hybrid heat exchangers are heat exchangers that are typically run in dry mode to reject heat. When the ambient conditions require more heat rejection than can be provided by sensible heat transfer, a water pump is turned on and water flows over the fins, and the evaporation of water provides a further cooling effect. Fouling in dry-mode operation is physically similar to that of air-cooled heat exchangers, but in evaporative mode the flow of the water over the coil eliminates the impact of fouling. A hybrid dry cooler heat exchanger of 60 cm × 60 cm frontal area has been installed in a well-instrumented wind tunnel to measure the heat exchanger's performance. Hot water flows through the coil to provide the load, and air flows over the coil to provide cooling. During evaporative mode operation another stream of water flows over the outside face of the coil, adhering mainly to the louvered fins. The louvered fins are specially designed for optimized water flow during wetting mode. The fins are made of aluminum, the tubes are copper, and protection against corrosion is realized by a special E-coating. This coil has been tested clean and fouled with ASHRAE standard dust, for both dry and wet operation. Results are presented for the air-side pressure drop and overall heat transfer conductance of the coil under all conditions for which 50% increases in air-side pressure drop are found under heavy fouling. The influence of fouling on heat transfer is small. Also, using the wetting water to wash the fouling off the coil is investigated and is found to be of some limited utility.     

Design of Shell-and-Tube Heat Exchangers to Achieve a Specified Operating Period in Refinery Preheat Trains

Fouling dominates the design of heat exchangers used in crude oil preheat trains. It also dominates the lifetime cost of the trains, where the most important cost factor is lost profit through reduced production. Thus, the design objective should be the identification of geometries that provide acceptable performance throughout a desired operating period. This paper suggests a new design approach for shell-and-tube heat exchangers in refinery preheat trains that uses dynamic crude oil fouling models rather than conventional fouling factors to yield designs that are capable of achieving a specified operating period between cleaning operations.     

Mitigation of ice crystallization fouling in stationary and circulating liquid–solid fluidized bed heat exchangers

Liquid–solid fluidized bed heat exchangers are attractive ice crystallizers since they are able to mitigate ice crystallization fouling and exhibit high heat transfer coefficients. Experiments show that the fouling removal ability of stationary fluidized beds increases with decreasing bed voidage (95–80%) and increasing particle size (2–4 mm). The removal of ice crystallization fouling appears to be more effective in circulating fluidized beds, especially at high circulation rates. Fouling removal is realized by both particle–wall collisions and pressure fronts induced by particle–particle collisions. A comparison between ice crystallization experiments and impact characteristics shows that the removal rate is proportional to the impulse exerted on the wall. A model based on these phenomena is discussed and predicts the transition temperature difference for ice crystallization fouling in both stationary and circulating fluidized beds with an average absolute error of 9.2%.     

Effect of Geometry and Flow Conditions on Particulate Fouling in Plate Heat Exchangers

This article describes particulate fouling experiments performed on small-scale and full-scale plate heat exchangers for three different corrugation angles (30 deg, 45 deg and 60 deg). The velocity effect has been studied as well as the particle type and concentration effects. The test duration ranges between 20 and 1,500 h in order to reach asymptotic behavior. The results clearly indicate that the corrugation angle has a major influence on the asymptotic fouling resistance. Increasing the corrugation angle leads to lower values for the fouling resistance. Furthermore, for a given corrugation angle, the asymptotic fouling resistance is inversely proportional to the velocity squared. Finally, the asymptotic fouling resistance is proportional to the particle concentration. Fouling mitigation can be obtained by taking into account at the design stage the heat exchanger geometry and fluid velocity.     

Fouling Management of Thermal Cracking Units

ABSTRACT

Visbreakers and other thermal cracking units are thermal process units in crude oil refineries that upgrade heavy petroleum, usually residual oils produced from atmospheric or vacuum distillation of crude oil. The associated process streams of these units consist of heavy hydrocarbons with very high viscosities and impurities, resulting in fouling of the heat exchangers used to cool or heat these streams. This paper presents a practical fouling analysis for thermal cracking units in a refinery in Germany. Fouling management at this refinery was initiated as part of the refinery energy-saving program. Following similar analysis of the refinery's crude preheat trains, heat exchanger networks associated in the thermal cracking units were modeled by entering the plant monitoring data, network topology, and heat exchanger geometries into a commercial heat exchanger network simulator, SmartPM. Fouling behaviors of vacuum residue streams and thermal cracker residue streams were identified and quantified. Both chemical reaction fouling and particulate fouling mechanisms were identified to be responsible for the fouling in these streams. Dynamic fouling models were fitted and used to predict fouling of these heavy petroleum streams, which fouled on both the shell and tube sides of the shell-and-tube heat exchangers.     

Modeling and Prediction of Shell-Side Fouling in Shell-and-Tube Heat Exchangers

Fouling is a challenging, longstanding, and costly problem affecting a variety of heat transfer applications in industry. Mathematical models that aim at capturing and predicting fouling trends in shell-and-tube heat exchangers typically focus on fouling inside the tubes, while fouling on the shell side has generally been neglected. However, fouling deposition on the shell side may be significant in practice, impairing heat transfer, increasing pressure drops, and modifying flow paths. In this paper, a new model formulation is presented that enables capturing fouling on the shell side of shell-and-tube heat exchangers including the effect of occlusion of the shell-side clearances. It is demonstrated by means of an industrial case study in a crude oil refinery application. The model, implemented in an advanced simulation environment, is fitted to plant data. It is shown to capture the complex thermal and hydraulic interactions between fouling growth inside and outside of the tubes, the effect of fouling on the occlusion of the shell-side construction clearances, and to unveil the impact on shell-side flow patterns, heat transfer coefficient, pressure drops, and overall exchanger performance. The model is shown to predict the fouling behavior in a seamless dynamic simulation of both deposition and cleaning operations, with excellent results.     

Fluid temperature and velocity effect on fouling

A wide variety of industrial processes involve the transfer of heat energy between fluids in process equipment. As a result of this energy exchange unwanted deposits accumulate on the process surfaces causing a resistance to energy transfer. These deposits reduce the heat recovery and can restrict fluid flow in the exchanger by narrowing the flow area. Prevention and control of fouling is costly and time consuming. In many situations, fouling can be reduced but not necessarily eliminated. Fouling is a major unresolved problem in heat transfer.In general, the heat exchangers evaluated in this study were exposed to untreated lake water for typical conditions. After the prescribed time period the exchangers were taken off line and evaluated. Conclusions and observations regarding fouling of brazed heat exchangers, exposed to once-through lake water, are presented here. Transient observations and photographs of the exchanger surfaces are given. Results are presented that compare these heat exchangers to test plates, also exposed to lake water. The progressive change of surface appearance with increasing immersion times is presented.     

Analysis of Fouling in Six-Start Spirally Corrugated Tubes

Abstract

Fouling on heat exchanger surfaces can weaken the heat-transfer capability, increase the energy consumption, and even cause the failure of the whole system. In coaxial heat exchangers, spirally corrugated tubes perform better than smooth ones concerning heat transfer and antifouling. In this article, a parametric study on the antifouling performance of a six-start spirally corrugated tube is carried out with a solid–liquid two-phase model. First, comparisons between a smooth tube and a specific sample six-start spirally corrugated tube on the solid particle volume fraction distributions are carried out. Then, the effects of solid particle diameter, the main geometric parameters, including pitch and the corrugation depth, are investigated. Analyzing the solid particle volume fraction with different geometries, solid particle diameters and Reynolds number, the roles played by the centrifugal force, drag force, and gravity of solid particles on fouling performance in six-start spirally corrugated tubes are obtained. In addition, the corrugation depth affects the volume fraction range more while the pitch affects more on the steady range of particle volume fraction. This work is of significance for further design of spirally corrugated tubes and analysis of fouling problems in heat exchangers.     

Scheduling cleaning in a crude oil preheat train subject to fouling: Incorporating desalter control

Fouling is a serious operating problem in oil refinery distillation preheat trains (PHTs) as the reduction in heat transfer effectiveness not only reduces the overall rate of heat transfer but also causes difficulty in maintaining key temperatures in the network within their defined operating envelopes. This work considers the problem of controlling the desalter inlet temperature by using hot stream bypassing, within a PHT fouling mitigation strategy based on heat exchanger cleaning. The formulation of the problem is incorporated in the PHT simulator described by Ishiyama et al. (2009) [1]. The methodology is illustrated using a case study based on an industrial network subject to fouling, where the fouling rates of heat exchangers were extracted through a data reconciliation exercise. The case study scenarios suggest that our simulation-based tool should be effective in controlling desalter inlet temperature within a fouling management strategy.     

A probabilistic fouling and cost model for plate‐and‐frame heat exchangers

Fouling in plate‐and‐frame heat exchangers (PHEs) may be defined as the deposition of unwanted material on the heat transfer surface that reduces heat‐transfer and increases the resistance to fluid flow. Once the thermal–hydraulic performance decreases to a minimum acceptable level, cleaning of the equipment has to be done to restore the performance. The decision regarding periodic off‐line maintenance of the heat exchangers is generally based on a thermal–economic performance of the process. In this paper, we discuss a probabilistic maintenance model for PHE by incorporating the risk level and scatter parameter of the four random fouling growth models, namely linear, power law, falling rate and asymptotic models, which are integrated in the dimensionless cost model for a heat exchanger used in a steel plant. All the results are presented in terms of non‐dimensional plots. The results show that there is a strong relationship between t_down and the uptime, particularly in the region where the costs of operation and maintenance are minimum. Copyright © 2005 John Wiley & Sons, Ltd.     

影响换热面结垢诱导期的表面特性研究

换热面结垢是一个普遍存在的问题,而结垢诱导期的长短对污垢形成过程具有重要的影响,即使在相同实验条件下,不同材料换热面的结垢诱导期仍相差较大.因此本文通过对附着在换热面上的半球形污垢晶核进行受力分析,发现污垢晶核与换热面之间的附着力对其结垢诱导期长短起决定性作用,然后根据颗粒与平板间附着力模型,计算了污垢晶核与具有不同表面能的换热面间附着力,并与相应的结垢诱导期进行对比.结果表明:结垢诱导期的长短与换热面的表面能、污垢晶核与换热面间的附着力及表面粗糙度尺度有关.     

Mitigation of Crude Oil Preheat Train Fouling by Design

Fouling in crude oil preheat trains is a significant industrial problem which has restricted the application of process integration techniques such as "pinch technology" in this sector. A semiempirical fouling model for crude oil fouling developed by Panchal and co-workers allows the effects of fouling to be considered at the design stage for such networks. Application of this model at three levels--(1) design of new networks; (2) retrofitting of existing systems; and (3) identification of robust specifications for individual heat exchanger units--is discussed. The design issues are discussed using case studies illustrated by a graphical construction, the temperature field plot. Rigorous optimization of the final designs is not reported. The specification discussion describes how the crude fouling model can be incorporated into existing heat exchanger design software to identify exchanger configurations which are less likely to experience significant fouling over a range of operating conditions. This article concentrates on shell-and-tube designs, but the concepts will be applicable to other exchanger types once a suitable fouling model becomes available.     

Supervision of the thermal performance of heat exchanger trains

In oil refining, heat exchanger networks are employed to recover heat and therefore save energy of the plant. However, many heat exchangers in crude oil pre-heat trains are under high risk of fouling. Under fouling conditions, the thermal performance of heat exchangers is continuously reduced and its supervision becomes an important task. The large number of heat exchangers in pre-heat trains and the change of operation conditions and feedstock charges make the daily supervision a difficult task. This work applies an approach to follow the performance of heat exchangers [M.A.S. Jerónimo, L.F. Melo, A.S. Braga, P.J.B.F. Ferreira, C. Martins, Monitoring the thermal efficiency of fouled heat exchangers – A simplified method, Experimental Thermal and Fluid Science 14 (1997) 455–463] and extends it to monitor the whole train. The approach is based on the comparison of measured and predicted heat exchanger effectiveness. The measured value is computed from the four inlet and outlet temperatures of a heat exchanger unit. The predicted clean and dirty values of effectiveness are calculated from classical literature relations as a function of NTU and of heat capacity ratio (R). NTU and R are continuously adjusted according to mass flow rate changes. An index of fouling is defined for the whole network and the results show the performance degradation of the network with time. The work also suggests that Jerónimo’s index of fouling can be used to estimate the fouling thermal resistance of heat exchangers.     

Influence of the Apex Angle of Cone-Shaped Tubes on Particulate Fouling of Heat Exchangers

A two-dimensional (2D) cone shape has been added to the normal circular tubes of heat exchangers to minimize the area of stagnation and to streamline the air flow around the heat exchanger tubes. An experimental setup has been developed to study the influence of the apex angle of the cone-shaped tubes on particulate fouling of heat exchangers. Fouling experiments have been performed in which calcium carbonate particles are injected during the experiments and the deposition of particles on the tubes of the heat exchanger is monitored. Four sets of experiments have been performed, in which normal cylindrical tubes and coned tubes with an apex angle of 60°, 90°, and 120° are examined. It was found that particulate fouling ceased if the apex angle of the cone-shaped tubes is smaller than 90°. The attached cones enhance the flow around the tubes of the heat exchanger, by minimizing the stagnation area and keeping the flow attached to the tubes starting from the tip of the attached cone until separation, such that particles that deposit on the top of the tubes of the heat exchanger can be removed by the air flow.     

The impact of fouling on performance evaluation of evaporative coolers and condensers

Fouling of evaporative cooler and condenser tubes is one of the most important factors affecting their thermal performance, which reduces effectiveness and heat transfer capability with time. In this paper, the experimental data on fouling reported in the literature are used to develop a fouling model for this class of heat exchangers. The model predicts the decrease in heat transfer rate with the growth of fouling. A detailed model of evaporative coolers and condensers, in conjunction with the fouling model, is used to study the effect of fouling on the thermal performance of these heat exchangers at different air inlet wet bulb temperatures. The results demonstrate that fouling of tubes reduces gains in performance resulting from decreasing values of air inlet wet bulb temperature. It is found that the maximum decrease in effectiveness due to fouling is about 55 and 78% for the evaporative coolers and condensers, respectively, investigated in this study. For the evaporative cooler, the value of process fluid outlet temperature T_p,out varies by 0.66% only at the clean condition for the ambient wet bulb temperatures considered. Copyright © 2005 John Wiley & Sons, Ltd.