共查询到18条相似文献,搜索用时 296 毫秒
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以3撑硫化剂、双酚AF/BPP、DCP/TAIC三种硫化体系硫化的氟橡胶26为实验材料,采用美国Cortest公司生产的高压釜测试系统,依照NACE标准对其进行不同温度下硫化氢老化试验,研究了三种硫化体系对氟橡胶26硫化特性、物理性能和耐硫化氢老化性能的影响。结果表明:采用3#硫化剂硫化体系的氟橡胶硫化特性、物理性能相对较好;不同温度下氟橡胶在气相中含硫化氢气体、试样置于液相的腐蚀环境腐蚀后,3#硫化剂硫化体系氟橡胶硬度较高,拉伸性能较好,耐硫化氢性能相对较好,但其体积变化率在不同的温度下均超过20%,很难满足硫化胶条件下的使用。 相似文献
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以普光油气田现场所用快开盲板密封橡胶为研究对象,进行了室内模拟H2S/CO2环境的腐蚀实验,分析了其腐蚀前后的外观、力学性能、微观结构及红外光谱的变化,推断了快开盲板橡胶密封材料的腐蚀机理。结果表明,腐蚀后密封橡胶材料的力学性能损失严重,主要是由三种原因造成的,一是加压时溶解在密封材料基体内部的气体在减压的过程中膨胀而形成裂纹;二是在腐蚀过程中基体内部的填料与氟橡胶基体之间脱粘;三是在腐蚀过程中硫化氢与主链共轭双键反应,使密封材料的交联点被破坏。 相似文献
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Elastomers are widely used in drilling and logging applications as static seals such as casing packers and dynamic seals such as o-rings for drill bits. Static seals often fail in service because of thermochemical degradation due to the combined effects of steam and sour gas at elevated temperatures that are characteristic of deep wells. Dynamic seals frequently fail because of abrasive wear that occurs even at the low temperatures that prevail in shallow wells. We have shown that improved steam–sour gas resistance of a fully formulated ethylene–propylene rubber at elevated temperatures can be achieved by coating the rubber with a thin film of plasma polymerized tetrafluoroethylene. Thus, no change in the mechanical properties of the coated rubber was observed after exposure to steam and sour gas at 275°C for 48 h. In contrast, the shear modulus of the uncoated rubber increased by 96% after the same exposure. While the effectiveness of the fluorocarbon coating decreased at longer exposure times, short-term protection of elastomers could be beneficial in certain logging operations. It was also found that the coefficient of friction of a nitrile rubber (Buna N) was reduced by 20% after treatment with a carbon tetrafluoride plasma. This enhanced lubricity could lead to better wear characteristics in conventional drill bits where the seal is in contact with a moving metal surface. The surfaces of the plasma treated elastomers were characterized by water contact angle, scanning electron microscopy, and electron spectroscopy for chemical analysis. 相似文献
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Ni-ZrO2纳米复合电铸层耐蚀性的研究 总被引:5,自引:0,他引:5
用静态浸泡实验法研究了镍镀层和Ni-ZrO2纳米复合电铸层在质量分数分别为10% HCl溶液和10% H2SO4溶液中的耐蚀性.用SEM观察了各种样品腐蚀后的表面形貌,分析了纳米ZrO2微粒复合量对复合电铸层耐蚀性的影响,同时对纳米复合电铸层的腐蚀机理进行了初步探讨.结果表明,脉冲纳米复合电铸层的耐蚀性明显优于相同条件下制备的镍镀层,镀液中纳米ZrO2悬浮量对提高纳米复合电铸层耐蚀性有一定程度的影响. 相似文献
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