Untersuchungen zur immissions‐ und geruchsreduzierenden Eigenschaft von zeolithehaltigen Gipsbaustoffen

Examination of the exposure‐ and odour‐reducing characteristics of gypsum‐based building materials containing zeolite. Emissions of volatile organic materials (VOC) from building products are increasingly regarded as harmful. In Germany the AgBB scheme was developed, which describes the health assessment procedure for emissions of volatile organic compounds from building products and today offers the main basis for requirements relating to room air hygiene‐related properties of building products. This article describes studies on plasterboard containing zeolite.     

A review of the emission of VOCs from polymeric materials used in buildings

Building and furnishing materials and consumers products are important sources of formaldehyde and other volatile organic compounds (VOCs) in the indoor environment. The emission from materials is usually continuous and may last for many years in a building. The available evidence indicates that VOCs can cause adverse health effects to the building occupants and may contribute to symptoms of ‘Sick Building Syndrome’.

Control of VOC emission should increasingly become an important consideration for the design and manufacture of polymeric materials used in buildings. The EC Construction Products Directive ‘Essential Requirements’ set a framework for limiting the use of materials that could pose a health risk to building occupants. Furthermore, the on-going development of voluntary labelling schemes and data bases of material emissions that could be used by building designers, should further strengthen the demand for ‘low VOC emitting’ products.

This paper reviews available information about the emission of VOCs from polymeric building materials, the level of emissions in the indoor environment and the requirements for testing of the materials.     

Europäische Dämmstoffnormen der 2. Generation: Prüfmethoden zur Ermittlung flüchtiger organischer Komponenten (VOC)

2nd generation European Standards for insulating materials and products: test methods for the determination of emissions of volatile organic compounds (VOC) In October 2001 ten “first generation” standards (EN 13162 through EN 13171) were introduced in Europe dealing with insulating materials and products. The new standards now in effect had to be based on the European Construction Products Directive (CPD) and conceptual details had been mandated by the European Commission to the standardization body CEN. Among other properties like thermal conductivity and fire performance the mandate requested to standardize a so called “initial type test (ITT)” for the release of dangerous substances (also called “regulated substances”) to be performed by an independent testing laboratory on behalf of the manufacturer before placing the product onto the market. However, due to the lack of experience and due to a non‐existing European harmonized common method for testing and classification, this property could not be included in the standards in due time and reference was only made to national regulations. Because of this shortcoming, a research project, started in 2003, developed a cost effective and very practical test method based on the emission cell device with a subunit that proved suitable for an initial type test (ITT) for the determination of emissions from thermal insulation materials and products – in particular volatile organic compounds (VOC).     

Harmonisierte europäische Normen für Dämmstoffe für betriebstechnische Anlagen in der Industrie und in der technischen Gebäudeausrüstung

Harmonised European standards for insulation in industrial and building services installations. European standards (EN) for building materials prepared by CEN according to the Construction Products Directive supersede national standards as reference documents in specification documents and standards, building codes and regional building regulations, based on Germany's obligation to implement EU Directives and DIN 's obligations vis‐à‐vis the European Committee for Standardization (CEN). The substitution of national standards by European standards does not apply to working papers prepared by the industrial construction association (Arbeitsgemeinschaft Industriebau e. V. – AGI). These papers continue to apply as the basis for the “generally recognised state of the art“. In the event of deviations between AGI working papers and European standards or DIN EN standards, any decision on which statement should be regarded as “generally recognised state of the art” may have to be referred to a court of law.     

Do time‐averaged,whole‐building,effective volatile organic compound (VOC) emissions depend on the air exchange rate? A statistical analysis of trends for 46 VOCs in U.S. offices

We used existing data to develop distributions of time‐averaged air exchange rates (AER), whole‐building ‘effective’ emission rates of volatile organic compounds (VOC), and other variables for use in Monte Carlo analyses of U.S. offices. With these, we explored whether long‐term VOC emission rates were related to the AER over the sector, as has been observed in the short term for some VOCs in single buildings. We fit and compared two statistical models to the data. In the independent emissions model (IEM), emissions were unaffected by other variables, while in the dependent emissions model (DEM), emissions responded to the AER via coupling through a conceptual boundary layer between the air and a lumped emission source. For 20 of 46 VOCs, the DEM was preferable to the IEM and emission rates, though variable, were higher in buildings with higher AERs. Most oxygenated VOCs and some alkanes were well fit by the DEM, while nearly all aromatics and halocarbons were independent. Trends by vapor pressure suggested multiple mechanisms could be involved. The factors of temperature, relative humidity, and building age were almost never associated with effective emission rates. Our findings suggest that effective emissions in real commercial buildings will be difficult to predict from deterministic experiments or models.     

Sources and dynamics of semivolatile organic compounds in a single‐family residence in northern California

Semivolatile organic compounds (SVOCs) emitted from building materials, consumer products, and occupant activities alter the composition of air in residences where people spend most of their time. Exposures to specific SVOCs potentially pose risks to human health. However, little is known about the chemical complexity, total burden, and dynamic behavior of SVOCs in residential environments. Furthermore, little is known about the influence of human occupancy on the emissions and fates of SVOCs in residential air. Here, we present the first‐ever hourly measurements of airborne SVOCs in a residence during normal occupancy. We employ state‐of‐the‐art semivolatile thermal‐desorption aerosol gas chromatography (SV‐TAG). Indoor air is shown consistently to contain much higher levels of SVOCs than outdoors, in terms of both abundance and chemical complexity. Time‐series data are characterized by temperature‐dependent elevated background levels for a broad suite of chemicals, underlining the importance of continuous emissions from static indoor sources. Substantial increases in SVOC concentrations were associated with episodic occupant activities, especially cooking and cleaning. The number of occupants within the residence showed little influence on the total airborne SVOC concentration. Enhanced ventilation was effective in reducing SVOCs in indoor air, but only temporarily; SVOCs recovered to previous levels within hours.     

Volatile and semi-volatile organochlorine compounds in tap and riverine waters in the area of influence of a chlorinated organic solvent factory

The study of volatile and semi-volatile organochlorinated compounds, VOC and SVOC, respectively, in the river and tap water of an area under the influence of a chlorinated organic solvent factory has shown that the industrial activities are reflected in the composition of the river waters, namely by the presence of chloroform, carbon tetrachloride, trichloroethylene, tetrachloroethylene, penta and hexachlorobenzene and octachlorostyrene as major pollutants, but that the tap waters are free from products which can be related to this origin. However, the potable water contains significant concentrations of species derived from chlorination, namely chloroform, bromodichloromethane, dibromochloromethane and bromoform, as well as pesticides of wide use in agriculture, α- and γ-hexachlorocyclohexane. The VOC and SVOC compositions in these tap waters are very similar to that found in the waters of Barcelona, a reference urban area which is not under the influence of large organochlorine solvent factories.     

Characterizing sources and emissions of volatile organic compounds in a northern California residence using space‐ and time‐resolved measurements

We investigate source characteristics and emission dynamics of volatile organic compounds (VOCs) in a single‐family house in California utilizing time‐ and space‐resolved measurements. About 200 VOC signals, corresponding to more than 200 species, were measured during 8 weeks in summer and five in winter. Spatially resolved measurements, along with tracer data, reveal that VOCs in the living space were mainly emitted directly into that space, with minor contributions from the crawlspace, attic, or outdoors. Time‐resolved measurements in the living space exhibited baseline levels far above outdoor levels for most VOCs; many compounds also displayed patterns of intermittent short‐term enhancements (spikes) well above the indoor baseline. Compounds were categorized as “high‐baseline” or “spike‐dominated” based on indoor‐to‐outdoor concentration ratio and indoor mean‐to‐median ratio. Short‐term spikes were associated with occupants and their activities, especially cooking. High‐baseline compounds indicate continuous indoor emissions from building materials and furnishings. Indoor emission rates for high‐baseline species, quantified with 2‐hour resolution, exhibited strong temperature dependence and were affected by air‐change rates. Decomposition of wooden building materials is suggested as a major source for acetic acid, formic acid, and methanol, which together accounted for ~75% of the total continuous indoor emissions of high‐baseline species.     

Untersuchungen zur Dauerhaftigkeit von Verbindungen und Anschlüssen bei Luftdichtheitsschichten mittels Klebemassen und Klebebändern

Durability tests for airtight connections and joints based on adhesive compounds and adhesive tapes. To meet the basic requirements of structural stability, energy conservation and hygiene specified in the Construction Products Directive, components must be shown to be airtight, including proof of functionality at component, slabs or web joints, connections and terminations. Buildings are generally assumed to have a service life of around 50 years, construction elements, such as pitched roofs, for example, around 20 to 30 years. It is therefore necessary to demonstrate the suitability of the design and individual elements over the whole period. A task group of the German Association for Air‐tightness in Buildings (FLIB) prepared draft testing and labelling guidelines for adhesive tapes for internal application. A research project on testing adhesive compounds compared three artificial ageing techniques. As part of this project a new test procedure based on realistic loads was developed.     

挥发性有机化合物对室内空气品质影响研究进展

系统回顾了近年来一些国家对室内空气环境中挥发性有机化合物（VOC）研究的各个方面,包括VOC研究在室内空气品质研究中的地位,建筑物内VOC对人体健康的影响,VOC研究的实验方法、理论方法及主要研究结论,各国政府、学术团体采取的行动等。得出结论：与建筑科学、环境科学及人体健康相关的工作人员,如居住者、建筑业主、建筑科学家、环境科学家、心理学家和生理学家、建筑师与暖通空调设计人员、建筑和装饰材料生产商、供应商,都应重视VOC问题。     

Semi‐volatile organic compounds in heating,ventilation, and air‐conditioning filter dust in retail stores

Retail stores contain a wide range of products that can emit a variety of indoor pollutants. Among these chemicals, phthalate esters and polybrominated diphenyl ethers (PBDEs) are two important categories of semi‐volatile organic compounds (SVOCs). Filters in heating, ventilation, and air‐conditioning (HVAC) system collect particles from large volumes of air and thus potentially provide spatially and temporally integrated SVOC concentrations. This study measured six phthalate and 14 PBDE compounds in HVAC filter dust in 14 retail stores in Texas and Pennsylvania, United States. Phthalates and PBDEs were widely found in the HVAC filter dust in retail environment, indicating that they are ubiquitous indoor pollutants. The potential co‐occurrence of phthalates and PBDEs was not strong, suggesting that their indoor sources are diverse. The levels of phthalates and PBDEs measured in HVAC filter dust are comparable to concentrations found in previous investigations of settled dust in residential buildings. Significant correlations between indoor air and filter dust concentrations were found for diethyl phthalate, di‐n‐butyl phthalate, and benzyl butyl phthalate. Reasonable agreement between measurements and an equilibrium model to describe SVOC partitioning between dust and gas‐phase is achieved.     

Sonderlösungen bei der brandschutztechnischen Bewertung von Konstruktionsdetails

Special‐purpose solutions in the fire‐protective evaluation of construction details Very often components or construction details in existing buildings but also in new buildings cannot be evaluated with regard to its fire resistance ability considering established technical building regulations. There are no regulations for the evaluation of such components or construction details as these specific construction details have not been evaluated by a certified test authority. However, these components and construction details very often can be classified in fire resistance classes e. g. by evaluating fire tests, with regard to DIN 4102‐4, on the basis of similar proof of usability or only by pragmatic considerations. Since introducing the technical approval of the fire protection Eurocodes more often engineering methods of fire protection are used based on these Eurocodes by using temperature assessment in order to secure the evaluation results. Within this essay we show methods and ways of fire‐protective evaluation for components and construction details. The approach of proof including dimensions of possible upgrade measurements if necessary are being illustrated by examples of use out of practical experience. At the same time different materials such as steel, concrete and wood will be treated with different fire‐proof products. The essay is to explain ways of evaluation of components and construction details involving fire‐proof requirements including upgrade measurements also especially for existing buildings.     

Emissions of VOCs,SVOCs, and mold during the construction process: Contribution to indoor air quality and future occupants’ exposure

Building materials and human activities are important sources of contamination indoors, but little information is available regarding contamination during construction process which could persist during the whole life of buildings. In this study, six construction stages on two construction sites were investigated regarding the emissions of 43 volatile organic compounds (VOCs), 46 semi-volatile organic compounds (SVOCs), and the presence of 4 genera of mold. Results show that the future indoor air quality does not only depend on the emissions of each building product but that it is also closely related to the whole implementation process. Mold spore measurements can reach 1400 CFU/m³, which is particularly high compared with the concentrations usually measured in indoor environments. Relatively low concentrations of VOCs were observed, in relation to the use of low emissive materials. Among SVOCs analyzed, some phthalates, permethrin, and hydrocarbons were found in significant concentrations upon the delivery of building as well as triclosan, suspected to be endocrine disruptor, and yet prohibited in the treatment of materials and construction since 2014. As some regulations exist for VOC emissions, it is necessary to implement them for SVOCs due to their toxicity.     

Simulation of VOC emissions from building materials by using the state-space method

There are many mass-transfer models for predicting VOC emissions from building materials described in the literature. In these models, the volatile organic compound (VOC) emission rate and its concentration in a chamber or a room are usually obtained by analytical method or numerical method. Although these methods demonstrate some salient features, they also have some flaws, e.g., for analytical method the solutions of both room or chamber VOC concentration and building material VOC emission rate are constituted of the sum of an infinite series, in which additional computation for finding roots to a transcendental function is necessary, but sometimes quite complicated. Besides, when it is applied in complex cases such as multilayer emission with internal reaction, the solution is very difficult to get; for conventional numerical methods such as finite difference method, discrete treatment of both time and space may cause calculation errors. Considering that, the state-space method widely used in modern automation control field and the heat transfer field is applied to simulate VOC emissions from building materials. It assumes that a slab of building material is composed of a number of finite layers, in each of which the instantaneous VOC concentration is homogenous during the entire process of emission, while the time is kept continuous. Based on this assumption we can predict both the VOC emissions rate and the concentrations of VOCs in the air of a chamber or room. The method is generally applied to simulate VOC emissions from arbitrary layers of building materials, and the solution is explicit and simple. What's more, the method can be applied to the cases where a reaction producing/removing VOC in building materials exists. For some specific cases the method is validated using the experimental data and the analytical solutions in the literature. The method provides a simple but powerful tool for simulating VOC emissions from building materials, which is especially useful in developing indoor air quality (IAQ) simulation software.     

Die Novelle der Energieeinsparverordnung EnEV 2007 – Chancen für die bessere Bewertung von Nichtwohngebäuden und Einführung von Energieausweisen

Amendment of the German Building Energy Conservation Ordinance (Energieeinsparverordnung – EnEV 2007) Opportunities for better assessment of non‐domestic buildings and introduction of Energy Passports. EU member states were required to implement the Energy Performance of Buildings Directive (2002/91/EC) in their respective national law by January 2006 [1]. In this context the German Government proposed comprehensive amendments of the existing energy saving legislation (‘Energieeinspargesetz’ or Energy Conservation Law, ‘Energieeinsparverordnung’ or Building Energy Conservation Ordinance). This article describes the current status of the considerations, in particular with regard to technical assessment options for non‐domestic buildings. The second amendment to the German Energy Conservation Law [7] came into force on 8 September 2005. The draft amendment of the Building Energy Conservation Ordinance (EnEV 2007) was presented by the German Government on 16 November 2006 [2]. However, due to the time required for consideration by the Federal Cabinet and the upper house of the German parliament it is not expected to come into force before mid 2007. This article provides an overview of the proposed new requirements for energy saving in buildings.     

Determination of radon exhalation from construction materials using VOC emission test chambers

The inhalation of ²²²Rn (radon) decay products is one of the most important reasons for lung cancer after smoking. Stony building materials are an important source of indoor radon. This article describes the determination of the exhalation rate of stony construction materials by the use of commercially available measuring devices in combination with VOC emission test chambers. Five materials – two types of clay brick, clinker brick, light‐weight concrete brick, and honeycomb brick – generally used for wall constructions were used for the experiments. Their contribution to real room concentrations was estimated by applying room model parameters given in ISO 16000‐9, RP 112, and AgBB. This knowledge can be relevant, if for instance indoor radon concentration is limited by law. The test set‐up used here is well suited for application in test laboratories dealing with VOC emission testing.     

State-of-the-Art in the Measurement of Volatile Organic Compounds Emitted from Building Products: Results of European Interlaboratory Comparison

Abstract Eighteen laboratories from 10 European countries participated in a comparison organized as part of the VOCEM project, a 2.5-year research collaboration among 4 research institutes and 4 industrial companies. The scope of the project was to improve the procedure used to measure volatile organic compounds (VOC) emitted from building materials and products in small test chambers. The interlaboratory comparison included the GC-MS determination of 5 target compounds from carpet, 8 from polyvinyl chloride (PVC) cushion vinyl and 2 from paint; for the first time, chamber recovery (sinks), homogeneity of solid materials and possible contamination during transport were tested. The results show that the intralaboratory variance (random errors) is much smaller than the interlaboratory variance (systematic errors). Causes of the largest interlaboratory discrepancies were: (i) analytical errors; (ii) losses of the heaviest compounds due to sorption on the chamber walls; and (iii) non homogeneity of the materials. The output of this work concerns both the objective of labelling materials with regard to their VOC emissions and the pre-standard drafted by the European Commitee for Standardization (CEN) for this type of determination.     

Estimation of biogenic volatile organic compounds emissions in subtropical island--Taiwan

Elevated tropospheric ozone is harmful to human health and plants. It is formed through the photochemical reactions involving volatile organic compounds (VOCs) and nitrogen oxides (NO(x)). The elevated ozone episodes occur mainly in summer months in the United States, while the high-ozone episodes frequently occur during the fall in Taiwan. The unique landscape of Taiwan produces tremendous amounts of biogenic VOCs in the mountain regions that are adjacent to concentrated urban areas. The urban areas, in turn, generate prodigious amounts of anthropogenic emissions. Biogenic VOC emissions have direct influence on tropospheric ozone formation. To explore the air quality problems in Taiwan, this study attempts to develop a biogenic VOC emission model suitable for air quality applications in Taiwan. The emission model is based on the Biogenic Emissions Inventory System Version 2 and coupled with a detailed Taiwan land use database. The 1999 total Taiwan biogenic VOC emissions were estimated at 214,000 metric tons. The emissions of isoprene, monoterpenes, and other VOCs were about 37.2%, 30.4%, and 32.4% of total biogenic VOC emissions, respectively. The annual total biogenic VOC emission per unit area was more than two times the value of that in any European country, implying that detailed emissions estimates in any size of region will benefit the global biogenic emission inventories.     

Volatile organic pollutants in new and established buildings in Melbourne, Australia

Volatile organic compounds (VOCs) within new and established buildings have been determined and factors significant to their presence have been identified. In established dwellings, total volatile organic compound (TVOC) concentrations were low, but were approximately four times higher than in outdoor air, showing a dominant effect of indoor sources. The presence of attached garages, site contamination and 'faulty' wool carpet were associated with higher indoor pollution. In three dwellings, unidentified sources of benzene were indicated. Much higher VOC concentrations were observed in new or renovated buildings, persisting above "baseline" levels for several weeks, concentration decay rate correlating with VOC molecular volume, indicating emissions were limited by material diffusion processes. VOC and formaldehyde emission decays in a new dwelling occurred by a double-exponential source model. This shows that persistent low levels of volatile organic pollutants in established dwellings can occur due to long-term emissions from building materials.