Electronic conductivity of AgI using D.C. polarization and charge transfer techniques

A Study of electronic conductivity using the d.c. polarization technique has been carried out in α and β-AgI which shows the former is a hole and the latter an electron conductor. Activation energies of undoped and Cu-doped single crystals and polycrystalline β-AgI were found to be 0.46 eV, 0.34 eV and 0.44 eV respectively and can be related to electron trap depths. The electron transference number ($\text{σ}{}_{\mathrm{\theta }}\text{σ}{}_{\mathrm{t}}$) for polycrystalline β-AgI was found to be 0.008 at 306 K. The activation energy for hole conduction in α-AgI was determined to be 0.97 eV in agreement with previous XPS studies.Transient measurements have also been conducted using the charge transfer technique in double cells of polycrystalline β-AgI. The carrier concentration C_θ and electron mobility μ_θ, have thus been estimated to be 1.8 × $\text{10}{}^{15}\text{cm}{}^3$ and 5.14 × 10^?5$\text{cm}{}^2\text{V}$?sec. respectively at 306 K, while the double layer capacitance was 0.496 $\text{μF}\text{cm}{}^2$.     

Trapping probabilities and desorption energies of alkali atoms on a clean and an oxygen covered tungsten (110) surface

Alkali atoms were scattered with hyperthermal energies from a clean and an oxygen covered (θ ≈ 0.5 ML) W(110) surface. The trapping probability of K and Na atoms on oxygen covered W(110) has been measured as a function of incoming energy (0–30 eV) and incident angle. A considerable enhancement of trapping on the oxygen covered surface compared to a clean surface was observed. At energies above 25 eV there are still K and Na atoms being trapped by the oxygen covered surface. From the temperature dependence of the mean residence time τ of the initially trapped atoms the pre-exponential factor τ₀ and the desorption energy Q were derived using the relation: $\text{τ = τ}{}_0\text{exp}\text{(}\text{Q}\text{kT}{}_{\mathrm{<mtext>s</mtext>}}\text{)}$. On clean W(110) we obtained for Li: $\text{τ}{}_0\text{= (8 ±}\text{8}\text{4}\text{) × 10}{}^{\mathrm{?14}}\text{sec}$, Q = (2.78 ± 0.09) eV; for Na: τ₀ = (9 ± 3) × 10^?14 sec, Q = (2.55 ± 0.04) eV; and for K: τ₀ = (4 ± 1) × 10^?13 sec, Q = (2.05 ± 0.02) eV. Oxygen covered W(110) gave for Na: τ₀ = (7 ±3) × 10^?15 sec, Q = (2.88 ± 0.05) eV; and for K: $\text{τ}{}_0\text{= (1.3 ±}\text{0.9}\text{0.6}\text{) × 10}{}^{\mathrm{?14}}\text{sec}$, Q = (2.48 ±0.05) eV. The adsorption on clean W(110) has the features of a supermobile two-dimentional gas; on the oxygen covered W(110) adsorbed atoms have the partition function of a one-dimen-sional gas. The binding of the adatoms to the surface has a highly ionic character in the systems of the present experiment. An estimate is given for the screening length of the non-perfect conductor W(110):k_s^?1≈ 0.5 Å.     

The influence of excess oxygen on the elastic properties of non-stoichiometric SrO crystals

Measurements have been carried out of the elastic constants of SrO in the virgin undoped state and of the changes produced in them by equilibrium doping with oxygen at ? 1200°C and oxygen partial pressure of 0.95 atm. The method used was Papadakis' pulse-echo overlap technique in conjunction with thermogravimetric analysis (T.G.A.) to determine mass and density changes due to oxygen doping.The values obtained for C₁₁, C₁₂ and C₄₄ of the virgin crystal at 23°C are

$\text{C}{}_{11}\text{= 17.60 ± 0.03 × 10}{}^{11}\text{dynes/cm}{}^2$

;

$\text{C}{}_{12}\text{= 4.808 ± 0.007 × 10}{}^{11}\text{dynes/cm}{}^2$

;

$\text{C}{}_{44}\text{= 5.577 ± 0.008 × 10}{}^{11}\text{dynes/cm}{}^2$

.(These values are in very good agreement with those of Son and Bartels [2].)Values for $\text{δC}{}_{11}\text{C}{}_{11}$ and $\text{δC}{}_{44}\text{C}{}_{44}$ were found to be ?1.74% and ?0.86% respectively. Accurate valu $\text{δC}{}_{12}\text{C}{}_{12}$ could not be obtained because of sample size limitations after quenching. However, C₁₂ was shown to definitely increase due to doping.Analysis of the results indicate that the elastic modulus changes can only be attributed to the formation of cation vacancies during doping. Analysis of the T.G.A. behavior indicates that this cation vacancy formation is probably associated with the presence of various tripositive cation and uninegative anion species depending upon the impurity concentrations of the sample. This implied impurity-controlled cation vacancy concentration is consistent with the earlier observed extrinsic nature of cation diffusion in SrO at 1200°C.     

Mössbauer-effect studies of excited states of 155Gd, 156Gd and 157Gd

Mössbauer-effect studies yield the following nuclear parameters: In ¹⁵⁵Gd, Q(86)/Q(0) = 0.087 ± 0.006, Q(105)/Q(0) = 1.00 ± 0.03. In ${}^{156}\text{Gd}\text{, g(89) = 0.386 ± 0.004,}{}^{156}\text{Q(89)/}{}^{155}\text{Q(0) = ?1.51 ± 0.02.}\text{In}{}^{157}\text{Gd}\text{, Q(64)/Q(0) = 1.80 ± 0.03}\text{and}\text{g(64) = ?0.185 ± 0.005}$. The value of g(89) is in very good agreement with the theoretical value.     

Centrifugal distortion effects in the hyperfine spectrum of KCl

The hyperfine spectrum of KCl has been examined at near-zero electric field and zero magnetic field using a molecular beam electric resonance spectrometer. Rotational as well as vibrational shifts have been observed in both nuclear quadrupole interactions. With $\text{eqQ = Q}{}_{00}\text{+ Q}{}_{10}\text{(v +}\text{1}\text{2}\text{) + Q}{}_{20}\text{(v +}\text{1}\text{2}\text{)}{}^2\text{+ Q}{}_{01}\text{J(J + 1)}$, we find (all in units of kHz) for K in ³⁹K³⁵Cl: Q₀₀ = ?5691.47 ± 0.04, Q₁₀ = 51.32 ± 0.06, Q₂₀ = ?0.205 ± 0.020, Q₀₁ = 0.014 ± 0.007, Q₀₀(K³⁷Cl) ? Q₀₀(K³⁵Cl) = ?0.03 ± 0.07; for Cl in ³⁹K³⁵Cl: Q₀₀ = 137.0 ± 0.3, Q₁₀ = ?163.2 ± 0.5, Q₂₀ = 1.57 ± 0.15, Q₀₁ = 0.07 ± 0.03, $\text{[}\text{Q(}{}^{35}\text{Cl}\text{)}\text{Q(}{}^{37}\text{Cl}\text{)}\text{]Q}{}_{00}\text{(}\text{K}{}^{37}\text{Cl}\text{) ? Q}{}_{00}\text{(}\text{K}{}^{35}\text{Cl}\text{) = ?0.5 ± 0.6}$; and magnetic constants c_K = 0.154 ± 0.007, c_Cl = 0.435 ± 0.010, c₃ = 0.035 ± 0.012, and c₄ = 0.009 ± 0.006. These have been used to provide a mapping of the field gradients at both nuclear sites to fourth order in $\text{ξ =}\text{(r ? r}{}_{\mathrm{e}}\text{)}\text{r}{}_{\mathrm{e}}$. We find eQq_K(ξ) = (?5692.5 ± 2.5) + (1.7 ± 0.8) × 10⁴ξ + (?2. ± 4.) × 10⁴ξ² + (?8. ± 18.) × 10⁵ξ³ + (8. ± 15.) × 10⁶ξ⁴ and eQq_Cl(ξ) = (120. ± 22.) + (8. ± 4.) × 10⁴ξ + (?5.8 ± 2.0) × 10⁵ξ² + (?1.1 ± 1.6) × 10⁷ξ³ + (1.1 ± 1.3) × 10⁸ξ⁴.     

Relativistic many-body calculation of parity-violating E1-amplitude for the 6S → 7S transition in atomic cesium

The parity violating E1-amplitude for the 6S–7S transition in cesium has been calculated from first principles: $\text{〈7S|D}{}_{\mathrm{z}}\text{|6S〉 = (0.88 ± 0.03) × 10}{}^{\mathrm{?11}}\text{(}\text{?Q}{}_{\mathrm{W}}\text{N}\text{)(?iea}{}_{\mathrm{B}}\text{)}$, where Q_W is the weak nuclear charge, N is the number of neutrons, and a_B is The Bohr radius. The experimental data from Bouchiat et al. make it possible to find Q_W = ?73.4 ± 8.1 ± 6 and the Weinberg angle sin²θ_W = 0.237 ± 0.036 ± 0.03. To control the accuracy, the energy levels, the fine and hyperfine structure intervals and the oscillator strenghts in the S-P transitions in Cs have been calculated.     

Vacancy diffusion in magnetite

The chemical diffusion coefficient in a single crystal of magnetite was measured by observing the relaxation of deviations from stoichiometry responding to a stepwise change in oxygen partial pressure between 1300 and 1450°C. The chemical diffusion coefficient was proportional to $\text{(?}\text{In}\text{δ}\text{?}\text{In}\text{p}{}_{\mathrm{o2}}\text{)}{}^{\mathrm{?1}}$. The vacancy diffusion coefficient was calculated with the help of nonstoichiometric data and was found to be independent of the vacancy composition. The value of D_v was

$\text{D}{}_{\mathrm{v}}\text{= (0.14 ± 0.08)}\text{exp}\text{(?}\text{(32,500 ± 1800)}\text{RT)}\text{cm}{}^2\text{s}{}^{\mathrm{?1}}$

.     

A thermo-chemical study of the defect structure of barium oxide

A study of BaO has been made by use of thermogravimetric analysis, oxygen concentration analysis, and X-ray lattice parameter measurements in the temperature range 850°C ? T ? 1420°C and oxygen pressure range 7 × 10^-6 atm ? p_O2 ? 0·820 atm. Both the weight gain by the BaO samples and subsequently determined excess oxygen concentration were found to be directly proportional to . The enthalpy of incorporation oxygen in the lattice

$\text{1}\text{2}\text{O}{}_2\text{(g)=O(excess)}$

was determined to be ?0·395 ± 0·034 eV. Creation of vacancies on cation sites or of oxygen interstitials are consistent with the experimental results. As an alternative, the formation of O₂^2? ions, (as in BaO₂) as a result of incorporation of excess oxygen in the lattice, has been suggested.     

Effect of the deviation from stoichiometry on cation self-diffusion and isotope effect in wüstite,Fe1−xO

Diffusion of ⁵⁹Fe in Fe_1xO crystals has been measured by a serial-sectioning technique as a function of temperature and deviation from stoichiometry. The results indicate that the diffusivity increases slightly at 1200°C, decreases at 802°C with an increase in x, and is insensitive to change in x at 1003°C. The temperature dependence of the cation diffusivity in Fe_0.94O is given by the expression, $\text{D=(0.6±0.5)×10}{}^{\mathrm{?3}}\text{exp(?29350 ±}\text{300}\text{RT}\text{)cm}{}^2\text{/se}$ the temperature range 700–1340°C. The isotope effect for cation self-diffusion was measured by simultaneous diffusion of ⁵²Fe and ⁵⁹Fe in Fe_1?xO at various temperatures and values of x. Although the measured values of fΔK are independent of temperature within the limits of experimental error, they decrease with an increase in the deviation from stoichiometry. The experimental results appeared to be consistent with the diffusion of Fe ions via “free mobile vacancies” that coexist with defect clusters. As a consequence of a “site-blocking” effect, the mobility of “free mobile vacancies” and the apparent correlation factor for cation tracer diffusion decrease with an increase in deviation from stoichiometry.     

A new N = Z isotope: Krypton 72

Beta-delayed γ-rays have been observed from the decay of ${}^{72}\text{Kr}\text{(τ}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{= 16.7 ± 0.6}\text{s}\text{)}$. A decay scheme is proposed based on γ-γ and β⁺-γ coincidence measurements. The total decay energy was measured to be Q_EC = 5057 ± 135 keV. The value is compared with mass predictions.     

Electromigration in tin single crystals

Atom transport in high-purity tin single crystals due to the influence of large direct currents has been measured by the “vacancy flux” technique. Cylindrical specimens were selected with c-axis oriented with 9° perpendicular or parallel to the direction of current flow. Rates of both longitudinal and transverse dimensional changes were used to calculate the anode-directed atom drift velocity. The results gave $\text{Z}{}^1{}_6\text{?}{}_6\text{= ?18±2}$ and $\text{z}{}^1{}_{\mathrm{\perp }}\text{?}{}_{\mathrm{\perp }}\text{= ?18 ±2}$, where Z¹ is the effective charge number and ?₆ = 0.89 and ?_⊥ = 0.54 are the estimated correlation factors in the parallel and perpendicular directions. These values for Z¹ are appreciably smaller than the results reported earlier for polycrystalline tin by Kuz'memko. The activation energies for $\text{Z}{}^1\text{?}$ agree within experimental error with those of self-diffusion.     

Electrical and structural properties of iron-doped β-alumina

β-alumina containing 50 w/o Fe exhibits high electronic conductivity when sintered in air but Mössbauer studies have shown the presence of Fe₃O₄. Single-phase β-alumina containing 50 w/o Fe could be prepared by sintering at 1400°C for 4–4.5 h followed by annealing at 1300°C for 96 h encapsulated with coarse β-alumina powder enriched with Na₂CO₃. Mössbauer spectroscopy indicated that all iron was present as Fe(III). Complex-plane impedance data showed a maximum bulk $\text{σ}{}_{\mathrm{25°C}}\text{= 5.56 × 10}{}^{-4}\text{(Ω cm)}{}^{-1}$ with little electronic conductivity. Reduction treatments on Fe-doped β-alumina utilizing H₂:N₂ gas were successful in producing a mixed conductor containing Fe(II) and Fe(III) but also produced a distorted β-alumina lattice. This material exhibited an electronic conductivity $\text{σ}{}_{\mathrm{e,25°C}}\text{= 2 × 10}{}^{-4}\text{(Ω cm)}{}^{-1}$ and a bulk ionic conductivity $\text{σ}{}_{\mathrm{b,25°C}}\text{= 1.35 × 10}{}^{-4}\text{(Ω cm)}{}^{-1}$.     

The 238U(n, α)235Th reaction with thermal neutrons

The thermal neutron induced (n, α) reaction cross section of ²³⁸U was measured using the highly pure thermal neutron beam from the 87 m curved neutron guide at the High Flux Reactor of the ILL (Grenoble). The energy spectrum showed an α-particle line with E_α = 9.05±0.06 MeV and σ(n, α) = 1.3±0.6 μb. The α-particle energy was used to calculate the ²³⁵Th mass of 235.04700±0.00008 amu, the Q_α value of 9.20±0.06 MeV for the ${}^{238}\text{U(n}\text{, α)}{}^{235}\text{Th}$ reaction and the Q_β value of 1.44±0.08 MeV for the β-decay of ²³⁵Th. The cross-section data are compared with the results obtained with the statistical model calculation.     

Nuclear matrix elements from L/K electron capture ratios in 59Ni decay

Using a recent theoretical method, the ratio of nuclear matrix elements $\text{R = (}{}^{\mathrm{v}}\text{F}{}^0{}_{220}\text{?√}\text{3}\text{2}{}^{\mathrm{A}}\text{F}{}^0{}_{221}\text{/}{}^{\mathrm{v}}\text{F}{}^0{}_{211}\text{)}$ was determined to be either 20.50^+0.35_?0.55 or 25.22^+0.28_?0.17 in the second-forbidden nonunique decay of 8 × 10⁴ y ⁵⁹Ni. These values of R were obtained from a value of L₃/K = 0.008 ± 0.002 found by subtracting the theoretical ratio $\text{(L}{}_1\text{+ L}{}_2\text{)}\text{K}$ = 0.113 (based on Q_PEC = 1070 ± 8 keV) from the total ratio L/K = 0.121 ± 0.002, which was measured with a reactor-produced, doubly-mass-separated ⁵⁹Ni source introduced as gaseous nickel-ocene, (C₅H₅)₂, into a wall-less, anticoincidence, multiwire proportional counter. The 854–1008 eV L and the 8.33 keV K peaks were measured simultaneously.     

Microwave spectrum and structure of cyanamide: Semirigid bender treatment

An extensive study of the microwave spectrum of cyanamide has been undertaken, the analysis being based in part on semirigidbender calculations by the methods of Bunker and Szalay. Inversion lines of NH₂CN, $\text{K}{}_{\mathrm{?1}}\text{= 2}{}^{\mathrm{a}}\text{Q}$ branches and a number of vibrational satellites of the J = 2?1 transition were observed. A two-vibrational-state Hamiltonian was used to fit simultaneously the 0⁺ and 0^? microwave data and yielded rotational constants X, Y, Z, D_J, D_JK, d₁, H_JK as well as the inversion splitting and the μ_yz-connecting matrix element. Vibrational satellite data of seven isotopic species and infrared frequencies of NH₂CN were included in the semirigid bender calculations: The NCN spine is nonlinear by ca. 5° in the equilibrium structure of the molecule. Also, $\text{r}{}_{\mathrm{<mtext>NH</mtext>}}\text{A}\text{?}\text{= 0.9994 + 0.0144?}{}^2$; <HNH/2 = 60.39° ? 0.1134?²; $\text{r}{}_{\mathrm{<mtext>NC</mtext>}}\text{A}\text{?}\text{= 1.3301 + 0.0327?}{}^2$ (? is the inversion angle in rad); $\text{r}{}_{\mathrm{<mtext>CN</mtext>}}\text{= 1.1645}\text{A}\text{?}$ fixed. The inclusion of the NC bond flexing was necessary in order to reproduce the observed vibrational satellite patterns of NH₂CN, NHDCN, and ND₂CN. The barrier to inversion of the amino group is 510 ± 6 cm^?1 with minima at ±45.0 ±0.2°. The inversion dipole moment is 0.91 ± 0.02 Debye.     

Coriolis intensity perturbations in the SO2 molecule: Experimental determination of the relative signs of (∂μ∂Qi)

The Coriolis interactions between ν₁ and ν₃, and between ν₂ and ν₃ in SO₂ have been analyzed to obtain the signs of the products $\text{ζ}{}_{3.1}{}^{\mathrm{c}}\text{(}\text{?μ}{}^{\mathrm{a}}\text{?Q}{}_3\text{)(}\text{?μ}{}^{\mathrm{b}}\text{?Q}{}_1\text{)}$ and $\text{ζ}{}_{3.2}{}^{\mathrm{c}}\text{(}\text{?μ}{}^{\mathrm{a}}\text{?Q}{}_3\text{)(}\text{?μ}{}^{\mathrm{b}}\text{?Q}{}_2\text{)}$. It has been found that both of the signs of these products are positive. Then, relative signs of ($\text{?μ}\text{?Q}{}_1$) have been determined using the calculated values of the Coriolis zeta constants for the present definition of the normal coordinates. The obtained sign combination of ($\text{?μ}\text{?Q}{}_{\mathrm{i}}$) is ±(+?+), which agrees with the one predicted by the molecular orbital calculations. Using the sign combination (+?+), the polar tensors of S and O atoms were also calculated.     

Hydrogen burning of 20Ne and 22Ne in stars

The ²⁰Ne(p, γ)²¹Na capture reaction has been studied in the energy range E_p = 0.37–2.10 MeV. Direct-capture transitions to the $\text{332 (}\text{5}\text{2}{}^{\mathrm{+}}\text{)}\text{and}\text{2425}\text{keV}\text{(}\text{1}\text{2}{}^{\mathrm{+}}\text{)}$ states have been found with spectroscopic factors of C²S(1d) = 0.77±0.13 and C²S(2s) = 0.90±0.12, respectively. The high-energy tail of the 2425 keV state, bound by 7 keV against proton decay, has also been observed in the above energy range as a subthreshold resonance. The excitation function for this tail is consistent with a single-level Breit-Wigner shape for a γ-width of Γ_γ = 0.31±0.07 eV at E_x = 2425 keV. The extrapolation of these data to stellar energies gives an astrophysical S-factor of S(0) = 3500 keV · b. Two new resonances at E_p = 384±5 and 417± 5 keV have been observed with strengths of ωγ = 0.11±0.02 and 0.06±0.01 meV, corresponding to the known states at and 2829 keV (presumably $\text{9}\text{2}{}^{\mathrm{+}}$), respectively. For the known E_p = 1830 keV resonance, a strength of ωγ = 1.0± 0.3 eV and a total width of Γ = 180± 15 keV were found. Branching ratios as well as transition strengths have been obtained for these three states. The Q-value for the ²⁰Ne(p, γ)²¹Na reaction (Q = 2432.3 ± 0.5 keV) as well as excitation energies for many low-lying states in ²¹Na have been measured. No evidence was found for the existence of the state reported at E_x = 4308±4 keV.In the case of ²²Ne(p, γ)²³Na, direct-capture transitions to six final bound states have been observed revealing sizeable spectroscopic factors for these states. The astrophysical S-factor extrapolated from these data to stellar energies, is S(0) = 67 ± 12 keV · b.The astrophysical as well as the nuclear structure aspects of the present results are discussed.     

Uniaxial stress effects on the 3.4 eV optical structure of silicon by schottky-barrier electroreflectance

The electroreflectance of Si under uniaxial stress has been measured in the 3.0–4.0 eV region at 77 K. The results indicate that the dominant structure in this energy region is attributed to Λ^v₃ → Λ^c₁ (or L^v_3′ → L^c₁ transition. The deformation potentials of these bands are determined to be $\text{D}{}^1{}_1\text{= -7 ± 3 eV,}\text{D}{}^3{}_3\text{= 4 ± 1 eV}\text{and}\text{D}{}^5{}_1\text{= 5 ± 2 eV}$.     

Elastic leed intensity-energy studies of clean (001), (110) and (111) nickel surfaces

Elastic low energy electron diffraction (LEED) intensity-energy (I-E) measurements for clean (001), (110), and (111) nickel surfaces were obtained at room temperature. Surface composition was monitored by Auger spectroscopy. I-E data from 15 to 220 eV were obtained at normal incidence for the non specular beams and for the specular beams at incidence angles from 4° to 20° on the 0° and 45° azimuths of (001), on the 0° and 90° azimuths of (110), and on the 0° azimuth of (111) nickel. Normalization of the data was performed electronically during data acquisition. Intensities were calibrated with the use of a shielded, biased Faraday collector. The effects of instrumental and experimental uncertainties were examined and minimized to obtain intensities accurate to ± 15 %, energy scales accurate to ± 0.35 eV, and incident and azimuthal angles accurate to ± 0.25° and ± 1.0° respectively.All nickel surfaces have I-E spectra which are characteristic of strong multiple scattering. Angular evolution features for (001) and (110) spectra may be correlated with intraplanar resonances associated with the onset of propagating beams. Only the (001) surfaces were found to have pronounced, sharp resonance features associated with surface barrier resonances and inelastic loss processes. Kinematic analysis of the Lorenzian-shaped I-E peaks on all surfaces in consistent with surface expansion using either an energy-dependent or a constant inner potential of 10.75 ± 0.5 eV. The widths of these same peaks on all surfaces were found to vary as $\text{E}{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ above 40 eV and $\text{E}{}^{\mathrm{<mtext>1</mtext><mtext>3</mtext>}}$ below.