共查询到20条相似文献,搜索用时 411 毫秒
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采用化学修饰方法,以二氧化硅为内层修饰材料,r-氨丙基三甲氧硅烷(APS)偶联剂为外层修饰材料,对磁性ZnFe2O4纳米粒子进行了双层修饰。并采用XRD、IR、Zeta电位对未包裹粒子,二氧化硅包裹的磁纳米粒子,APS和二氧化硅双层包修饰的纳米磁粒进行表征。同时也比较了三种粒子的耐酸性能。结果显示硅包裹的纳米磁粒Zeta电位明显向酸性方向移动,而双层的纳米磁粒Zeta电位向碱性方向移动。包裹的纳米磁粒在pH2.0的酸中具有很好的耐酸性能,而未处理的纳米粒子在酸溶液中发生了溶解。 相似文献
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ZnFe2O4高温煤气脱硫剂的再生 总被引:1,自引:0,他引:1
在热天平上对自制的ZnFe2O4脱硫剂进行了再生工艺研究,考察了再生温度、O2浓度对ZnFe2O4脱硫剂再生性能的影响;进行了多次硫化、再生循环实验,并与加入玻璃粉的样品进行了比较。结果表明,700℃下氧含量2.0%(vol)时再生可以获得良好的再生率和二次硫化反应活性;玻璃粉的少量加入,会改善脱硫剂长期使用的稳定性,但反应活性有所下降。 相似文献
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以Zn(Ac)2×4H2O和FeCl3×6H2O为主要原料,采用一步水热法合成了中空结构的ZnFe2O4微球,对其物相、形貌和组成进行了分析. 结果表明,中空ZnFe2O4粒径微球约300 nm,壳厚约25 nm. 以其为锂离子电池负极材料,100 mA/g电流密度下,首次放电容量为1524 mA×h/g, 50次充放电循环后容量约为826 mA×h/g,呈现出优异的循环性能. 相似文献
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采用基于密度泛函理论的第一性原理平面波超软赝势法,计算了尖晶石型Zn1-xMnxFe2O4(x=0,0.5,1)铁氧体的电子结构和磁性,计算结果表明:ZnFe2O4铁氧体为绝缘体,MnFe2O4和Zn0.5Mn0.5Fe2O4铁氧体为半金属,ZnFe2O4铁氧体的能隙为0.89eV,小于实验值。此外,计算研究了Zn1-xMnxFe2O4(x=0,0.5,1)铁氧体中Zn的含量对其磁性的影响。结果表明,随着Zn含量的增加Zn1-xMnxFe2O4(x=0,0.5,1)铁氧体的磁矩先增大后减小,这与实验结果一致。 相似文献
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聚合物配位法合成尖晶石型铁酸锌 总被引:6,自引:0,他引:6
采用聚合物配位法,在较低温度下合成高均匀性的铁酸锌粉体材料,Zn2+、Fe3+、柠檬酸和乙二醇以1:2:6:30的摩尔比混合后,在130℃时发生酯化反应得到前驱体,所得前驱体400℃下在空气中热处理2h,可得到尖晶石结构的铁酸锌,并采用TG-DTA、XRD、FT-IR等测试手段进行表征,所合成产物粒径由Scherrer公式计算得到。 相似文献
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ZnFe2O4高温煤气脱硫剂的还原与硫化 总被引:1,自引:0,他引:1
采用共沉淀法制备了ZnFe2O4高温煤气脱硫剂,并在动态热天平上对其还原和硫化行为进行了研究,分别考察了温度、反应气氛对脱硫性能的影响。低于300℃,还原反应基本不发生:在450℃出现ZnFe2O4脱硫剂的最大还原速率:CO还原能力远不及ZnFe2O4脱硫剂硫化反应速率与浊度、H2S浓度成正比,300℃左右出现ZnFe2O4脱硫剂的最大硫化速率。还原与硫化反应可用等效应粒子模型描述,ZnFe2O4脱硫剂的还原与硫化反应存在控制段的转移。 相似文献
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Zhang Ruike Chen Tian Wang Gongshu Guan Yuqiu Yan Guiyang Chen Zhangpei Hu Jianshe 《Catalysis Letters》2022,152(11):3506-3516
Catalysis Letters - A magnetic recyclable Cu/ZnFe2O4 composite material was successfully prepared with easy-to-obtain raw materials. This obtained copper composite material could be employed as... 相似文献
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锌尖晶石ZnM2O4(M=Cr,Mn,Fe)纳米晶的制备及其在可见光下对染料的光催化降解 总被引:3,自引:0,他引:3
采用无机盐溶胶-凝胶法,以硝酸锌、硝酸铁、硝酸铬、硝酸锰为原料,柠檬酸为络合剂,在空气气氛中,制得干凝胶经600 ℃热处理制备了系列锌尖晶石ZnM2O4(M=Cr,Mn,Fe)纳米粉体.用X射线衍射仪和透射电子显微镜分别对粉体的结构、形貌进行了分析和表征.结果表明:制备的ZnCr2O4,ZnMn2O4和ZnFe2O4粉体均为单一尖晶石晶体结构,呈不规则颗粒状,粒径为10~35 nm.通过紫外-可见漫反射吸收光谱,得到吸收极限波长分别红移至400,600,680 nm,具有较好的可见光响应.在高压汞灯(λ>400 nm)和太阳光照射下,纳米ZnM2O4(M=Cr,Mn,Fe)粉体对甲基橙、酸性红B、活性艳红K-2G等有机模拟降解液的2h脱色降解率分别达到80%,57%和39%以上,表明锌尖晶石ZnM2O4(M=Cr,Mn,Fe)光催化剂具有良好的可见光催化活性,并随禁带宽度Eg的减小,催化活性增加.根据无机固体化学能带理论和晶体场理论,依据M-O电负性和d电子数量讨论了它们光催化活性的差别. 相似文献
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Xu Wang Jianli Zhang Jingyu Chen Qingxiang Ma Subing Fan Tiansheng Zhao 《中国化学工程学报》2018,26(4):761-767
Potassium promoted iron–zinc catalysts prepared by co-precipitation method(C–Fe–Zn/K),solvothermal method(S–Fe–Zn/K)and hydrothermal method(H–Fe–Zn/K)could selectively convert CO_2to light olefins,respectively.The physicochemical properties of the obtained catalysts were determined by SEM,N_2physisorption,XRD,H_2-TPR,CO_2-TPD and XPS measurements.The results demonstrated that preparation methods had great influences on the morphology,phase structures,reduction and adsorption behavior,and hence the catalytic performance of the catalysts.The samples prepared by hydrothermal and co-precipitation method generated small uniform particles and led to lower specific surface area.In contrast,microspheres with larger specific surface area were formed by self-assembly of nanosheets using solvothermal method.ZnFe_2O_4was the only detectable phase in the fresh C–2Fe–1Zn/K,S–3Fe–1Zn/K and S–2Fe–1Zn/K samples.ZnFe_2O_4and ZnO co-existed with increasing Zncontent in S–1Fe–1Zn/K sample,while ZnO and Fe_2O_3could be observed over H–2Fe–1Zn/K sample.All the used samples contained Fe_3O_4,ZnO and Fe_5C_2.The peak intensity of ZnO was strong in the AR-H–2Fe–1Zn/K sample while it was the lowest in the AR-C–2Fe–1Zn/K sample after reaction.The formation of ZnFe_2O_4increased the interaction between iron and zinc for C–2Fe–1Zn/K and S–Fe–Zn/K samples,causing easier reduction of Fe_2O_3to Fe_3O_4.The surface basicity of the sample prepared by co-precipitation method was much more than that of the other two methods.During CO_2hydrogenation,all the catalysts showed good activity and olefin selectivity.The CO selectivity was increased with increasing Zncontent over S–Fe–Zn/K samples.H–2Fe–1Zn/K catalyst preferred to the production of C_5~+hydrocarbons.CO_2conversion of 54.76%and C_2~=–C_4~=contents of 57.38%were obtained on C–2Fe–1Zn/K sample,respectively. 相似文献
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