Performance improvement of absorption refrigeration system using triple-pressure-level

In the absorption refrigeration system (ARS) working with aqua–ammonia, the ejector is commonly located at the condenser inlet. In this study, the ejector was located at the absorber inlet. Therefore, the absorber pressure becomes higher than the evaporator pressure and the system works with triple-pressure-level. The ejector has two main functions: (i) aiding pressure recovery from the evaporator, (ii) upgrading the mixing process and the pre-absorption by the weak solution of the ammonia coming from the evaporator. In addition to these functions, it can also act to lower the refrigeration and heat-source temperatures. Energy analyses show that the system’s coefficient of performance (COP) and exergetic coefficient of performance (ECOP) were improved by 49% and 56%, respectively and the circulation ratio (f) was reduced by 57% when ARS is initiated at lower generator temperatures. Due to the reduced circulation ratio, the system dimensions can be reduced; consequently, this decreases overall cost. The heat source and refrigeration temperatures decreased in the range of 5–15 °C and 1–3 °C, respectively. Exergy analyses show that the exergy loss of the absorber of ARS with ejector had a higher exergy loss than those of the other components. Therefore, a multiple compartment absorber can be proposed to reduce the exergy loss of the absorber of ARS with ejector.     

Thermodynamic properties and performance evaluation of [EMIM] [DMP]-H2O working pair for absorption cooling cycle

The combination of ionic liquid-refrigerant based [EMIM][DMP]-H₂O as an alternative working pair for single effect vapor absorption cycles (VACs) is assessed and optimized by using energy and exergy based performances. Thermodynamics properties of binary mixture of [EMIM] [DMP]-H₂O like Dühring's (P-T-x1) and h-T-X1 plots are computed from the activity coefficient based non-random two-liquid model (NRTL) model. Further modeling and simulation of VACs are accomplished in open source Scilab as mathematical programing software and used to ascertain the optimal generator temperature established on energetic and exergetic COP. Optimal results include an extensive range of temperatures like T_e from 2.5 to 15°C and T_a and T_c from 30 to 45°C. Simulation of the single effect VAC with SHE by using [EMIM][DMP]-H₂O mixture at T_e = 10°C, T_g = 100°C, T_a = 30°C, and T_c = 40°C were evaluated and compared with the 5 working fluids. Simulation outcomes depicted greater COP of 0.82 for [EMIM][DMP]-H₂O in comparison with NH₃-H₂O, EMISE-H₂O, [EMIM][BF4]-H₂O and nearly equal to LiBr-H₂O (COP = 0.83). In addition, the effect of T_g on the COP, ECOP f _, and composition are compared and optimized for the evaporation temperature range from 2.5 to 15°C, T_a/T_c from 30 to 45°C and cooling water (CW) flow in series and parallel. Additionally, the optimal T_g exhibited distinction based on energy and exergy analysis. Thus, it resulted in optimized performances of [EMIM] [DMP]-H₂O that can be suitable to replace corrosive aqueous LiBr in VACs.     

A methodology for the performance evaluation of an experimental desiccant cooling system

An experimental investigation was conducted in an open cycle desiccant cooling system (DCS) operating on the ventilation mode in the laboratory site [M. Yıldırım, An experimental investigation on heat and mass transfer in a desiccant cooling system, PhD thesis, Gaziantep University, Turkey (2002). [1]]. Although the operation of DCS is presumably affected by the design of primary components of rotary regenerator (RR) and desiccant wheel (DW) the methodology used in the analysis of experimental data is presented in this paper to set a different approach for the performance evaluation of similar systems.

The rotational speeds of RR and DW (N_RR and N_DW), air mass flow rate (m_a) in process and regeneration lines, and the regeneration temperature (T_R) were defined as operation parameters. Meanwhile coefficient of performance (COP) and cooling capacity (CC) of the system were called as the performance parameters. The system operation with a variety of experimental conditions resulted in an extensive data set covering the ranges of N_RR, N_DW, m_a and T_R as 5 rpm ≤ N_RR ≤ 20 rpm, 0.1 rpm ≤ N_DW ≤ 0.4 rpm, 0.05 kg/s ≤ m_a ≤ 0.139 kg/s and 60 °C ≤ T_R ≤ 90 °C, respectively. The interactive influence of the operation parameters was determined through the realization of the psychrometric cycle in deviation from an ideal cycle. A dimensional analysis based on a trial and error procedure was followed to determine the functional relationship of COP and CC.

The proposed correlations between COP and CC and the introduced system performance parameter (PP) were determined to be a sole function of m_a independent of N_RR, N_DW and T_R in their covered ranges.     

Performance characteristics of two combined ejector–absorption cycles

The paper describes the performance of an ammonia–water combined ejector–absorption cycle as refrigerator using two simple models. In the first an ejector draws vapour from an evaporator and discharges to a condenser. In the second, an ejector draws vapour from an evaporator and discharges to an absorber. The thermodynamics cycles and ejector operation on the temperature–entropy charts are shown. The thermodynamics of the combined ejector–absorption cycle are simulated by a suitable method and a corresponding computer code, based on analytic functions, describes the behaviour of the binary mixture NH₃–H₂O. It was found from the first model that the refrigerator (theoretical) coefficient of performance (COP) varied from 1.099 to 1.355 when the operation conditions were: generation temperature (237°C), condenser temperature (25.9–30.6°C), absorber temperature (48.6–59.1°C) and evaporator temperature (−1.1–7.7°C). In the second the theoretical COP vary from 0.274 to 0.382 when the operation conditions were: generation temperature (237°C), condenser temperature (91°C), absorber temperature (76.7–81°C) and evaporator temperature (−1.1–7.7°C).     

Energy and exergy analysis of a double absorption heat transformer operating with water/lithium bromide

In the present study, the first and second law of thermodynamics have been used to analyze in detail the performance of a double absorption (lift) heat transformer operating with the water–lithium bromide mixture. A mathematical model was developed to estimate the coefficient of performance (COP), the exergy coefficient of performance (ECOP), the total exergy destruction in the system (Ψ_TD) and the exergy destruction (Ψ_D) in each one of the main components, as a function of the system temperatures, the efficiency of the economizer (EF_EC), the gross temperature lift and flow ratio (FR). The results showed that the generator is the component with the highest irreversibilities or exergy destruction contributing to about 40% of the total exergy destruction in the whole system, reason why this component should be carefully designed and optimized. The results also showed that the COP and ECOP increase with increase in the generator, the evaporator and the absorber–evaporator temperatures and decrease with the absorber and condenser temperatures. Finally, it was observed that the COP and ECOP are very dependent of the FR and the economizer efficiency (EF_EC) values. Also the optimum operating region of the analyzed system is shown in the present study. Copyright © 2009 John Wiley & Sons, Ltd.     

Screening of novel water/ionic liquid working fluids for absorption thermal energy storage in cooling systems

Absorption thermal energy storage (ATES) is significant for renewable/waste energy utilization in buildings. The ATES systems using ionic liquids (ILs) are explored to avoid crystallization and enhance the performance. Property model and cycle model have been established with verified accuracies. Based on the preliminary screening, seven ILs are found feasible to be ATES working fluids, while four ILs ([DMIM][DMP], [EMIM][Ac], [EMIM][DEP], and [EMIM][EtSO₄]) have been selected for detailed comparisons. The coefficient of performance (COP) and energy storage density (ESD) of the ATES using different H₂O/ILs are compared with H₂O/LiBr. Results show that the operating temperatures of LiBr are constrained by crystallization, limiting the COPs and ESDs under higher generation temperatures and lower condensation temperatures. With varying T_g, [DMIM][DMP] yields higher COPs with T_g above 100°C and [EMIM][Ac] yields comparable ESDs (67.7 vs 67.1 kWh/m³) with T_g around 120°C, as compared with LiBr. The maximum COP is 0.745 for [DMIM][DMP]. With varying T_c, [DMIM][DMP] yields higher COPs with T_c below 38°C and [EMIM][Ac] yields higher ESDs with T_c below 33°C, as compared with LiBr. The maximum ESD is 87.5 kWh/m³ for [EMIM][Ac]. With varying T_e, [DMIM][DMP] yields higher COPs with T_e above 8°C, as compared with LiBr. The maximum ESD of ILs is 104.0 kWh/m³ for [EMIM][EtSO₄]. Comparing with the volume-based ESDs, the differences between ILs and LiBr are smaller for the mass-based ESDs. This work can provide suggestions for the selection of novel working fluids for ATES for performance and reliability enhancement.     

Thermodynamic study of a two-stage vapour absorption refrigeration system using NH3 refrigerant with liquid/solid absorbents

A systematic investigation is made of the two-stage vapour absorption refrigeration system employing the refrigerant absorbent combinations of NH₃---H₂O and NH₃---LiNO₃. The system consists of coupling two conventional absorption cycles so that the first-stage evaporator produces cooling water to circulate in the absorber of the second stage. The effect of operating variables such as generator temperature, evaporator temperature, absorber temperature and condenser temperature on the coefficient of performance (COP), heat transfer rates and relative circulation have been studied for both single-stage and two-stage absorption refrigeration systems. It is found that the COP is higher for NH₃---LiNO₃ than for NH₃---H₂O, in both single-stage and two-stage absorption systems, especially at higher generator temperatures. Furthermore, the minimum evaporator temperature achieved is lower for NH₃---LiNO₃, and the system can be operated at lower generator temperatures.     

Exergy analysis of double effect vapor absorption refrigeration system

Energy and exergy analyses previously performed by the authors for a single effect absorption refrigeration system have been extended to double effect vapor absorption refrigeration system with the expectation of reducing energy supply as well as an interest in the diversification of the motive power employed by HVAC technologies. The total exergy destruction in the system as a percentage of the exergy input from a generator heating water over a range of operating temperatures is examined for a system operating on LiBr–H₂O solution. The exergy destruction in each component, the coefficient of performance (COP) and the exergetic COP of the system are determined. It is shown that exergy destructions occur significantly in generators, absorbers, evaporator2 and heat exchangers while the exergy destructions in condenser1, evaporator1, throttling valves, and expansion valves are relatively smaller within the range of 1–5%. The results further indicate that with an increase in the generator1 temperature the COP and ECOP increase, but there is a significant reduction in total exergy destruction of the system for the same. On the other hand, the COP and ECOP decrease with an increase in the absorber1 temperature while the total exergy destruction of the system increases significantly with a small increase in the absorber1 temperature. The results show that the exergy method can be used as an effective criterion in designing an irreversible double effect absorption refrigeration system and may be a good tool for the determination of the optimum working conditions of such systems. Copyright © 2007 John Wiley & Sons, Ltd.     

Ionic liquid based absorption chillers for usage of low grade waste heat in industry

The standard working pairs for absorption chillers, ammonia/water and water/lithium bromide show problematic behaviours like crystallisation and corrosiveness. Because of their convenient solving properties and their low vapour pressure, ionic liquids are a new promising class of sorbents for absorption cooling purposes. In this study, the working pairs water/1,3‐dimethylimidazolium dimethylphosphate ([MMIM][DMP]) and water/1‐ethyl‐3‐methylimidazolium dimethylphosphate ([EMIM][DMP]) are implemented in AspenPlus. The performance of a single effect cycle with these pairs is simulated and compared to results of a cycle with water/LiBr. For [EMIM][DMP] a coefficient of performance (COP) comparable to that of LiBr or even higher (up to 0.85) is found. [MMIM][DMP] shows a smaller maximum COP but a largely wider operating temperature range than LiBr. Results are compared with those of other groups, discrepancies discussed and improvements suggested. Copyright © 2013 John Wiley & Sons, Ltd.     

A comprehensive study of hydrogen production from ammonia borane via PdCoAg/AC nanoparticles and anodic current in alkaline medium: experimental design with response surface methodology

In this paper, the optimization of hydrogen (H₂) production by ammonia borane (NH₃BH₃) over PdCoAg/AC was investigated using the response surface methodology. Besides, the electro-oxidation of NH₃BH₃ was determined and optimized using the same method to measure its potential use in the direct ammonium boran fuel cells. Moreover, the ternary alloyed catalyst was synthesized using the chemical reduction method. The synergistic effect between Pd, Co and Ag plays an important role in enhancement of NH₃BH₃ hydrolysis. In addition, the support effect could also efficiently improve the catalytic performance. Furthermore, the effects of NH₃BH₃ concentration (0.1–50 mmol/5 mL), catalyst amount (1–30 mg) and temperature (20°C–50°C) on the rate of H₂ production and the effects of temperature (20°C–50°C), NH₃BH₃ concentration (0.05–1 mol/L) and catalyst amount (0.5–5 µL) on the electro-oxidation reaction of NH₃BH₃ were investigated using the central composite design experimental design. The implementation of the response surface methodology resulted in the formulation of four models out of which the quadratic model was adjudged to efficiently appropriate the experimental data. A further statistical analysis of the quadratic model demonstrated the significance of the model with a p-value far less than 0.05 for each model and coefficient of determination (R²) of 0.85 and 0.95 for H₂ production rate and NH₃BH₃ electrroxidation peak current, respectively.     

Energy and exergy analysis of an experimental single‐stage heat transformer operating with the water/lithium bromide mixture

The first and second law of thermodynamics have been used to analyze the performance of an experimental single‐stage heat transformer operating with the water/lithium bromide mixture. Enthalpy coefficients of performance (COP), external coefficients of performance (COP_EXT), exergy coefficient of performance (ECOP), exergy destruction or irreversibility in the system and components (I) and the improvement potential (Pot) have been calculated against the gross temperature lift and the main operating temperatures of the system. The results showed that the highest COP, COP_EXT and ECOP values are obtained at the highest solution concentrations meanwhile the Pot and the I of the cycle remain almost constant against these parameters. Also it was shown that the COP, COP_EXT and ECOP decrease with an increase with the absorber temperature, meanwhile the Pot and the I increase. Moreover, it was observed that in all the cases independently of the operating temperatures of the system, the absorber accounts with most of the half of the total irreversibility in the system. Finally, it was shown that the improvement potential is considerable for the system. Copyright © 2009 John Wiley & Sons, Ltd.     

Performance Evaluation of R134a/DMF-Based Vapor Absorption Refrigeration System

This article describes an experimental investigation to measure performances of a vapor absorption refrigeration system of 1 ton of refrigeration capacity employing tetrafluoro ethane (R134a)/dimethyl formamide (DMF). Plate heat exchangers are used as system components for evaporator, condenser, absorber, generator, and solution heat exchanger. The bubble absorption principle is employed in the absorber. Hot water is used as a heat source to supply heat to the generator. Effects of operating parameters such as generator, condenser, and evaporator temperatures on system performance are investigated. System performance was compared with theoretically simulated performance. It was found that circulation ratio is lower at high generator and evaporator temperatures, whereas it is higher at higher condenser temperatures. The coefficient of performance is higher at high generator and evaporator temperatures, whereas it is lower at higher condenser temperatures. Experimental results indicate that with addition of a rectifier as well as improvement of vapor separation in the generator storage tank, the R134a/DMF-based vapor absorption refrigeration system with plate heat exchangers could be very competitive for applications ranging from –10°C to 10°C, with heat source temperature in the range of 80°C to 90°C and with cooling water as coolant for the absorber and condenser in a temperature range of 20°C to 35°C.     

Application of absorption heat transformer to recover waste heat from a synthetic rubber plant

This paper reports the test results of the first industrial-scale absorption heat transformer (AHT) equipment in China, to recover the waste heat released from mixture of steam and organic vapor at 98 °C in coacervation section, synthetic rubber plant of Yanshan Petrochemical Corporation, Beijing, China. The recovered heat is used to heat hot water from 95 to 110 °C, feeding back to the coagulator as the supplementary heating source. The AHT system is operating with H₂O/LiBr solution with heat flow of 5000 kW. The coefficient of performance (COP), the thermal efficiency and the temperature lift of the AHT system are presented. The heat transfer characteristics of the AHT components, i.e. absorber, generator, evaporator, condenser and the liquid–liquid solution heat exchanger, are also illustrated by comparison of experimental data and the model calculated results. The results show that the mean COP is 0.47, the gross temperature lift of 25 °C can be realized and the payback period is ≈2 years.     

NOx and H2S formation in the reductive zone of air-staged combustion of pulverized blended coals

Low NO_x combustion of blended coals is widely used in coal-fired boilers in China to control NO_x emission; thus, it is necessary to understand the formation mechanism of NO_x and H₂S during the combustion of blended coals. This paper focused on the investigation of reductive gases in the formation of NO_x and H₂S in the reductive zone of blended coals during combustion. Experiments with Zhundong (ZD) and Commercial (GE) coal and their blends with different mixing ratios were conducted in a drop tube furnace at 1200°C–1400°C with an excessive air ratio of 0.6–1.2. The coal conversion and formation characteristics of CO, H₂S, and NO_x in the fuel-rich zone were carefully studied under different experimental conditions for different blend ratios. Blending ZD into GE was found to increase not only the coal conversion but also the concentrations of CO and H₂S as NO reduction accelerated. Both the CO and H₂S concentrations inblended coal combustion increase with an increase in the combustion temperature and a decrease in the excessive air ratio. Based on accumulated experimental data, one interesting finding was that NO and H₂S from blended coal combustion were almost directly dependent on the CO concentration, and the CO concentration of the blended coal combustion depended on the single char gasification conversion.Thus, CO, NO_x, and H₂S formation characteristics from blended coal combustion can be well predicted by single char gasification kinetics.     

Theoretical analysis of LiBr/H2O absorption refrigeration systems

A computational model is developed for the parametric investigation of single‐effect and series flow double‐effect LiBr/H₂O absorption refrigeration systems. The effects of generator, absorber, condenser, evaporator and dead state temperatures are examined on the performance of these systems. The parameters computed are coefficient of performance (COP), exergy destruction rates, thermal exergy loss rates, irreversibility and exergetic efficiency. The results indicate that COP and exergetic efficiency of both the systems increase with increase in the generator temperature. There exist different optimum values of generator temperature for maximum COP and maximum exergetic efficiency. The optimum generator temperature is lower corresponding to maximum exergetic efficiency as compared to optimum generator temperature corresponding to maximum COP. The effect of increase in absorber, condenser and evaporator temperatures is to decrease the exergetic efficiency of both the systems. The irreversibility is highest in absorber in both systems. Copyright © 2009 John Wiley & Sons, Ltd.     

New refrigeration system using CO vapor-solid as refrigerant

A refrigerant must be in the vapor-liquid phase in a vapor-compression refrigeration system, therefore, CO₂ cannot be used as a refrigerant for temperatures lower than -56°C because solid CO₂ will form under the triple point temperature of -56°C. A refrigeration system with CO₂ vapor-solid particles as refrigerant is put forward, by which a temperature lower than the triple point is achieved. An adjustable nozzle, a sublimator, a high-pressure regulating valve and a low-pressure regulating valve are used to replace the conventional evaporator. Theoretical cycle analysis of the refrigeration system shows that its COP can be 50% higher than that of the conventional one.     

Effect of temperature on the morphological and photovoltaic stability of bulk heterojunction polymer:fullerene solar cells

In high performance polymer:fullerene bulk heterojunction solar cells the nanoscale morphology of interpenetrating acceptor:donor materials is optimized through appropriate preparation conditions such as annealing and choice of solvent, but this initial state-of-the-art morphology will not remain stable during long-term operation. We report the effects of prolonged storage at elevated temperatures on both the morphology and the photovoltaic performance for the model systems MDMO-PPV:PCBM and P3HT:PCBM as compared to ‘High T_g PPV’:PCBM based solar cells, where the ‘High T_g PPV’ is characterized by its high glass transition temperature (138 °C). In situ monitoring of the photocurrent–voltage characteristics at elevated temperatures, in combination with a systematic transmission electron microscopy (TEM) study and complementary optical spectroscopy, reveals distinct degradation kinetics and morphological changes that indicate the occurrence of different underlying physico-chemical mechanisms.     

Thermochemical hydrogen production from a two-step solar-driven water-splitting cycle based on cerium oxides

A new thermochemical cycle for H₂ production based on CeO₂/Ce₂O₃ oxides has been successfully demonstrated. It consists of two chemical steps: (1) reduction, 2CeO₂ → Ce₂O₃ + 0.5O₂; (2) hydrolysis, Ce₂O₃ + H₂O → 2CeO₂ + H₂. The thermal reduction of Ce(IV) to Ce(III) (endothermic step) is performed in a solar reactor featuring a controlled inert atmosphere. The feasibility of this first step has been demonstrated and the operating conditions have been defined (T = 2000 °C, P = 100–200 mbar). The hydrogen generation step (water-splitting with Ce(III) oxide) is studied in a fixed bed reactor and the reaction is complete with a fast kinetic in the studied temperature range 400–600 °C. The recovered Ce(IV) oxide is then recycled in first step. In this process, water is the only material input and heat is the only energy input. The only outputs are hydrogen and oxygen, and these two gases are obtained in different steps avoiding a high temperature energy consuming gas-phase separation. Furthermore, pure hydrogen is produced (it is not contaminated by carbon products like CO, CO₂), thus it can be used directly in fuel cells. The results have shown that the cerium oxide two-step thermochemical cycle is a promising process for hydrogen production.     

Thermodynamic assessment of hydrogen production via solar thermochemical cycle based on MoO2/Mo by methane reduction

Inspired by the promising hydrogen production in the solar thermochemical (STC) cycle based on non-stoichiometric oxides and the operation temperature decreasing effect of methane reduction, a high-fuel-selectivity and CH₄-introduced solar thermochemical cycle based on MoO₂/Mo is studied. By performing HSC simulations, the energy upgradation and energy conversion potential under isothermal and non-isothermal operating conditions are compared. In the reduction step, MoO₂: CH₄ = 2 and 1020 K<T_red<1600 K are found to be most favorable for syngas selectivity and methane conversion. Compared to the STC cycle without CH₄, the introduction of methane yields a much higher hydrogen production, especially at the lower temperature range and atmospheric pressure. In the oxidation step, a moderately excessive water is beneficial for energy conversion whether in isothermal or non-isothermal operations, especially at H₂O: Mo= 4. In the whole STC cycle, the maximum non-isothermal and isothermal efficiency can reach 0.417 and 0.391 respectively. In addition, the predicted efficiency of the second cycle is also as high as 0.454 at T_red = 1200 K and T_oxi = 400 K, indicating that MoO₂ could be a new and potential candidate for obtaining solar fuel by methane reduction.