Polycyclic aromatic hydrocarbons and their molecular diagnostic ratios in urban atmospheric respirable particulate matter

Atmospheric concentrations of polycyclic aromatic hydrocarbons (PAHs) in Santiago de Chile city were evaluated to study particulate PAHs profiles during cold and spring weather periods. Urban atmospheric particulate matter PM10 was collected using High Volume PM10 samplers. Fifteen samples of 24 h during austral winter and 20 samples of 24 h during spring, 2000 were collected at two sampling sites (North–East and Central areas of the city) whose characteristics were representative of the prevailing conditions. Seventeen PAHs were quantified and total PAHs concentration ranged from 1.39 to 59.98 ng m⁻³, with a seasonal variation (winter vs. spring ratio) from 0.5 to 12.6 ng m⁻³. Molecular diagnostic ratios were used to characterize and identify PAHs emission sources such as combustion and biogenic emissions. Results showed that the major sources of respirable organic aerosol PM10 in Santiago are mobile and stationary ones.     

Seasonal variation of PM10-bound PAHs in the atmosphere of Xiamen, China

PM₁₀ samples from a garden site (site A), an industrial-traffic intersection (site B), a residential site (site C) and an island site (site D) were collected at December 21–29, 2004; March 18–22, 2005; July 4–13, 2005 and October 24–28, 2005 in Xiamen. 15 priority PAHs compounds were analyzed by using a gas chromatograph/mass spectrometer (GC/MS). The abundance and origin of PAHs are discussed to reveal seasonal variations in Xiamen air quality. Average concentrations of Σ15PAHs were 17.5 ng/m³, 3.7 ng/m³, 32.6 ng/m³ and 10.5 ng/m³ from spring to winter with the highest value in autumn. The dominant PAHs components in every season were low and middle molecular weight PAHs including phenanthrene, pyrene, fluoranthene and chrysene. Diagnostic ratios and PCA analysis identified the main sources of particle bound PAHs: mainly from both gasoline and diesel vehicles exhaust, with some contribution from coal combustion, industry emission and cooking sources.     

Formation of spring warm water southwest of the Philippine Islands: Winter monsoon wake effects

From satellite observations and the reanalysis data, the late spring formation of warm water with temperature higher than 30 °C to the southwest of the Philippine Islands (8–18°N, 115–120°E) is investigated. Our analysis suggests that the blockage of the winter monsoon by the Philippine Islands results in this “Luzon warm water” (LWW) to the southwest of the Luzon Island and the “Vietnam cold tongue” (VCT) to the southeast of the Vietnam coast during winter and early spring in the South China Sea (SCS). The VCT is formed by the southward cold advection by the western boundary current and surface heat loss in the SCS. During the winter monsoon, the LWW first forms due to weak winds southwest of the Philippine Islands and the countering effect of warm Ekman advection against cold geostrophic advection. In spring its temperature exceeds 30 °C (LWW30), helped by strong solar radiation and the winter monsoon wake effect lee of the Philippine Islands. With the winter monsoon weakening, LWW30 extends southwestward in late spring but disappears quickly after the summer monsoon onset. Reduced latent heat flux in the winter monsoon wake is the dominant factor for the spring fast warming southwest of the Philippine Islands.Both VCT and LWW persist from winter to early spring as the Philippine Islands block the winter monsoon. Their interannual variations are correlated with the variation of the LWW30 since the blockage of the winter monsoon by the Philippine Islands modifies surface latent heat flux and ocean advection from winter to early spring. These results strongly suggest that the LWW30 is a result of land–sea–winter monsoon interaction.     

Roadside, Urban, and Rural comparison of size distribution characteristics of PAHs and carbonaceous components of Beijing, China

Size-segregated aerosol samples were collected with a low-pressure impactor (LPI) at urban, roadside and rural sites in winter in Beijing. The size distribution of Polycyclic Aromatic Hydrocarbons (PAHs), organic carbon (OC) and elemental carbon (EC) were measured and this study focused on their size distributions and relationships of PAH to OC/EC. All PAHs show uni-modal at the accumulation mode (0.1–1.8 μm) and almost all PAHs are associated with fine particles. The absence of PAHs in the nucleus mode contributes to the coagulation under the condition of high concentration of the accumulation mode particles. The absence of PAHs in the coarse mode was probably attributed to the low temperature that restrained the redistribution of PAHs from the accumulation mode to the coarse mode. Flu(fluoranthene) and Pyr(pyrene, 4-ring) were the most abundant particulate PAHs ; however, IcdP(indeno[1,2,3-cd]pyrene) and BghiP(benzo[ghi]perylene, 6-ring) were rather low. Diagnostic ratios show vehicle and coal burning were the major sources of PAHs in winter. Ratios at rural site are obviously different from those found at roadside and urban sites. Lower value of OC/EC in the rural area than that in the urban area was probably resulted from coal burning prevailed in the rural area. OC1 and OC2 exhibit uni-mode distribution similar to their particle surface area distribution indicating their existence on particles by adsorption. OC3 and OC4 show bi-mode distribution. Grinding of biomass debris can be a probable source of OC3 and OC4 in the coarse mode. EC1 is mostly from the pyrolysis of OC; however, both the natural and anthropogenic emissions contribute to EC2. The correlation between size-segregated PAHs and carbonaceous component is also discussed to identify their sources.     

Particulate PAHs levels at Mt. Halla site in Jeju Island, Korea: Regional background levels in northeast Asia

The levels of PM.25 PAHs at Mt. Halla site, Jeju Island, a background site in Korea were observed between March 1999 and March 2002. A seasonal variation was observed for the particulate PAHs concentrations with high levels during cold season similar to Gosan, a nearby coastal background site, due to the seasonal variations of fossil fuel usage in Asia. The total average concentration of ambient particulate PAHs was 404 ± 579 pg m^− 3, about one order lower than the ambient level at Gosan. However, the ratios of the anthropogenic inorganic ion concentrations between Mt. Halla and Gosan were smaller, 1.5 for non sea-salt (nss) sulfate and 2.7 for nitrate. Two possible explanations for these characteristics are (1) two sites measured different air parcels and/or (2) the effect of local emissions were different at two sites. Based on the Bep/BaP ratio result, upper air wind direction data, backward trajectory analysis, and LIDAR measurement data at Gosan, it was found that the degree of the effects of local emissions to the sampling sites be the major reason for the different PAHs levels at two sites though, in some cases, the air parcels arriving at Mt. Halla were different from those arriving at Gosan. For secondary aerosol such as nss sulfate, the lower concentration difference indicates both site are affected by regional transport. It points that the measurement result for directly emitted species such as PAHs at Gosan might be significantly influenced by local emissions.     

Cloud condensation nuclei measurements at Mace Head, Ireland, over the period 1994–2002

Analyses of cloud condensation nuclei (CCN) number concentrations (cm^− 3) measured at the Mace Head Atmospheric Research Station, near Carna, County Galway, Ireland, using a DH Associates Model M1 static thermal diffusion cloud chamber over the period from March 1994 to September 2002 are presented in this work. Air masses are defined as being ‘marine’ if they originate from a wind direction of 180–300° and ‘continental’ air masses are defined as originating from a wind direction of 45–135°. Air masses without such filtering were classified as ‘undefined’ air masses. Air masses were found to be dominated by marine sector air, re-affirming Mace Head as a baseline atmospheric research station. CCN levels for specific air masses at Mace Head were found to be comparable with earlier studies both at Mace Head and elsewhere. Monthly averaged clean marine (wind direction of 180–300° and black carbon absorption coefficient < 1.425 Mm^− 1) CCN and marine CCN varied between 15–247 cm^− 3 and 54–670 cm^− 3, respectively. As expected, significant increases in number concentration were found in continentally sourced CCN over that of marine CCN and were found to follow a log-normal distribution significantly tighter than that of clean marine air masses. No significant trend was found for CCN over the 9-year period. While polluted continental air masses showed a slight increase in CCN concentrations over the winter months, most likely due to increased fuel usage and a lower mixed boundary layer, the dominance of marine sector air arriving at Mace Head, which generally consists of background CCN concentrations, reduced seasonal differences for polluted air. Marine air showed a distinct seasonal pattern, with elevated values occurring over the spring and summer seasons. This is thought to be due to enhanced biogenic aerosol production as a result of phytoplankton bloom activity in the North Atlantic.     

Aliphatic alkanes and polycyclic aromatic hydrocarbons in atmospheric PM10 aerosols from Baoji, China: Implications for coal burning

Normal alkanes and PAHs in atmospheric PM₁₀ aerosols collected during 2008 winter and spring in Baoji, a mid-scale inland city of China, were determined on a molecular level. Concentrations of n-alkanes ranged from 232 to 3583 ng/m³ with an average of 1733 ng/m³ in winter and from 124 to 1160 ng/m³ with an average of 449 ng/m³ in spring, while PAHs in the PM₁₀ samples were 594 ± 405 and 128 ± 82 ng/m³ in the two seasons. Molecular compositions showed that CPI (odd/even) values of n-alkanes were close to unity for all the samples especially in winter, and diagnostic ratios of PAHs (e.g., Phe/(Phe + Ant), CPAH/ΣPAHs and IcdP/(IcdP + BghiP)) were found similar to those in coal burning smoke with a strong linear relationship (R² ≥ 0.85) between PAHs and fossil fuel derived n-alkanes, demonstrating that coal burning is the main source of n-alkanes and PAHs in the city, especially in winter due to house heating. Concentrations of the determined compounds in Baoji are much higher than those in Chinese mega-cities, suggesting that air pollution in small cities in the country is more serious and need more attention.     

Organic composition of atmospheric urban aerosol: Variations and sources of aliphatic and polycyclic aromatic hydrocarbons

The non-polar organic composition of airborne particulate matter was analysed over a two year period in an urban area under oceanic climate conditions (Errenteria, Basque Country, Spain). In addition, the distribution of polycyclic aromatic hydrocarbons (PAH) among different aerosol particle sizes was determined. Clues as to the origin of various particle types were gained by using scanning electron microscopy to view the morphology of the particulates in each size fraction. Samples were collected on glass fibre filters and analysed by means of soxhlet extraction and gas chromatography (either with a flame ionization detector or coupled to a mass spectrometry). In general, total PAH levels were moderate (0.96–50 ng m^− 3) as compared to other studies conducted in Europe, and showed clear seasonal variation with maxima in winter and minima in summer. Vehicular traffic was identified as a major source of PAHs in the study area. Regarding particle size, a bimodal distribution was observed. The large sized particles exhibited an apparent seasonal variation with higher concentrations in winter than in summer. The dependences between particle size, PAH distribution and meteorological variables were studied with multivariate statistics. Three main sources of organic compounds were identified: combustion, vegetation, and atmospheric oxidation.     

Chemical characteristics of haze during summer and winter in Guangzhou

Airborne particles were collected with a 10-stage MOUDI and a PM₁₀ sampler in Guangzhou, China, during both haze and normal days in the summer of 2002 and 2003, and winter 2002. The characteristics of PAHs, organic carbon, elemental carbon and water-soluble inorganic ions were studied under four periods (summer normal, summer haze, winter normal and winter haze). In this study, secondary pollutants (OC, SO₄²⁻, NO₃⁻ and NH₄⁺) were the major chemical components and appeared to show a remarkably rapid increase from normal to haze days. The particle mass size distributions were bimodal and dominated by fine particles in haze days. A significantly higher OC/EC ratio was found in haze days (3.2–4.7) compared to normal days (1.8–2.8), indicating secondary organic aerosol formation might be significant during haze days. Correlation analysis between visibility and chemical species showed that the major scattering species were TC (total carbon) and sulfate in normal days and nitrate and TC in haze days, respectively. Simultaneously, correlation analysis between visibility and meteorological factors demonstrated that visibility increased with both temperature and wind speed, while it decreased with relative humidity. Furthermore, the relatively higher value of IcdP/(BghiP + IcdP) and the low value of Cmax, CPI, and BghiP/BeP in winter haze could be due to the growth of motor vehicle usage and energy consumption in winter.     

Optical observations of transient luminous events associated with winter thunderstorms near the coast of Israel

We report the results of two observation campaigns conducted during the Northern Hemisphere winters of 2005–6 and 2006–7 aiming to detect transient luminous events (TLEs) above winter thunderstorms in the vicinity of Israel and the eastern coastline of the Mediterranean Sea. In 10 out of 31 different observation nights we detected 66 events: 56 sprites and 10 Elves. The detection ranges varied from 250 to 450 km. Sprites were found to be produced by active cells with a vertical dimension of 5–9 km and cloud top temperature ~ − 40 °C, embedded in a much larger matrix of stratiform precipitating cloudiness. This configuration closely resembles the conditions for winter sprites in the Hokuriku region of Japan. Synchronized with the optical observations, ELF data were recorded at two observation stations in Israel and Hungary in order to qualify and quantify parameters of the parent lightning discharge associated with the TLEs. These stations are located 500 km and 2100 km respectively from the Eastern Mediterranean Sea, where most TLEs occur. Among the optically observed TLE events, we found that all the ELF signals were produced solely by positive cloud-to-ground flashes (+ CGs), most of which were recorded in Israel (88%) and Hungary (77%). Calculation of the Charge Moment Change showed average values of 1400 ± 600 C km, with some extreme events exceeding 3500 C km. The average time delay between the ELF transient of the parent + CG and the observed sprites was 55 ms, with shorter delays for column sprites (42 ± 34 ms) compared to carrot sprites (68 ± 34). Furthermore, based on the ELF data, there were no early identifiable precursors to TLE occurrence in the regional lightning activity. From the spatial formation of the observed columniform sprites, we propose that columniform sprites are sometimes arranged in a 3-dimensional circular pattern, thus mapping the instantaneous electric field in the mesosphere.     

Polycyclic aromatic hydrocarbons (PAHs) associated with atmospheric particles in Higashi Hiroshima, Japan: Influence of meteorological conditions and seasonal variations

This work studied the influence of meteorological conditions on particulate polycyclic aromatic hydrocarbons (PAHs) in the atmosphere of Higashi Hiroshima, Japan. The seasonal variation of particulate PAHs was also covered. It was found that ambient temperature, solar intensity and weekly rainfall had significant influence on the particulate PAH concentration based on correlation studies. Correlation of particulate PAHs with ambient temperature, solar intensity, weekly rainfall, wind speed and humidity was studied by using Pearson correlation analysis. Particulate PAHs had a strong negative correlation with ambient temperature and solar intensity. A moderate negative correlation with weekly rainfall was also observed. There was no significant correlation between particulate PAHs with wind speed as well as humidity. Besides, particulate PAHs were found to have significant positive correlation with sulfur dioxide and nitrogen dioxide while having a moderate negative correlation with ozone. The particulate PAHs in Higashi Hiroshima exerted distinct seasonal variation with a higher concentration in winter and lower concentration in summer. When compared among PAHs with different numbers of aromatic rings; 5-ring PAHs was found to exert the most distinct seasonal variation. The contribution of carcinogenic PAHs to total particulate PAH concentration was fairly constant at about 50% throughout the year.     

Seasonal variations of spectra of wind speed and air temperature in the mesoscale frequency range

Seasonal variations of the spectra of wind speed and air temperature in the mesoscale frequency range from 1.3 × 10^-4 to 1.5 × 10^-3 Hz (10 min to 2 h periods) have been studied through observations over land for one year. Spectrographs [time series of isopleths of spectral densities, f · S(f) vs f] of wind speed and air temperature contain occasional peaks that are attributed to short-lived mesoscale atmospheric activity with narrow frequency bands. Significant spectral peaks of wind speed were found in 19% of the total observations in winter, and in 15–16% in the other seasons; for air temperature, they occured in 12% of observations in autumn, and in 16–19% in the other seasons. The peaks most often occurred in the period range from 30 min to 1 h; most had durations less than 24 h. Mesoscale fluctuations of wind speed and air temperature were highly correlated, and in most cases, phase differences were 90–180 ° with air temperature leading wind speed. Significant spectral peaks of wind speed often occurred during northerly seasonal cold winds in winter, and accompanied tropical and/or mid-latitude cyclones in the other seasons. When the peaks occurred, wind speed was usually relatively high and the atmospheric surface layer was unstable.     

Seasonal surface ocean circulation and dynamics in the Philippine Archipelago region during 2004–2008

The dynamics of the seasonal surface circulation in the Philippine Archipelago (117°E–128°E, 0°N–14°N) are investigated using a high-resolution configuration of the Regional Ocean Modeling System (ROMS) for the period of January 2004–March 2008. Three experiments were performed to estimate the relative importance of local, remote and tidal forcing. On the annual mean, the circulation in the Sulu Sea shows inflow from the South China Sea at the Mindoro and Balabac Straits, outflow into the Sulawesi Sea at the Sibutu Passage, and cyclonic circulation in the southern basin. A strong jet with a maximum speed exceeding 100 cm s⁻¹ forms in the northeast Sulu Sea where currents from the Mindoro and Tablas Straits converge. Within the Archipelago, strong westward currents in the Bohol Sea carry the surface water of the western Pacific (WP) from the Surigao Strait into the Sulu Sea via the Dipolog Strait. In the Sibuyan Sea, currents flow westward, which carry the surface water from the WP near the San Bernardino Strait into the Sulu Sea via the Tablas Strait.These surface currents exhibit strong variations or reversals from winter to summer. The cyclonic (anticyclonic) circulation during winter (summer) in the Sulu Sea and seasonally reversing currents within the Archipelago region during the peak of the winter (summer) monsoon result mainly from local wind forcing, while remote forcing dominates the current variations at the Mindoro Strait, western Sulu Sea and Sibutu passage before the monsoons reach their peaks. The temporal variations (with the mean removed), also referred to as anomalies, of volume transports in the upper 40 m at eight major Straits are caused predominantly by remote forcing, although local forcing can be large during sometime of a year. For example, at the Mindoro Strait, the correlation between the time series of transport anomalies due to total forcing (local, remote and tides) and that due only to the remote forcing is 0.81 above 95% significance, comparing to the correlation of 0.64 between the total and local forcing. Similarly, at the Sibutu Passage, the correlation is 0.96 for total versus remote effects, comparing to 0.53 for total versus local forcing. The standard deviations of transports from the total, remote and local effects are 0.59 Sv, 0.50 Sv, and 0.36 Sv, respectively, at the Mindoro Strait; and 1.21 Sv, 1.13 Sv, and 0.59 Sv at the Sibutu Passage. Nonlinear rectification of tides reduces the mean westward transports at the Surigao, San Bernardino and Dipolog Straits, and it also has non-negligible influence on the seasonal circulation in the Sulu Sea.     

Parameterisation of surface radiation flux at an Antarctic site

During the Antarctic summer 1994/95 the values of downward and upward flux densities of both solar and terrestrial radiation were recorded at 1200 m for a period of 1 month on the Reeves Nevè Glacier (lat 74°39′S, long 161°35′E), near the Italian base of Terra Nova Bay. The relations proposed by Swinbank [Swinbank, W.C., 1963. Long-wave radiation from clear skies. Q. J. R. Meteorol. Soc. 89, 339–348], Idso and Jackson [Idso, S.B., Jackson, R.D., 1969. Thermal radiation from the atmosphere. J. Geophys. Res. 74, 5397–5403] and Deacon [Deacon, E.L., 1970. The derivation of Swinbank's long-wave radiation formula. Q. J. R. Meteorol. Soc. 96, 313–319] associating the long-wave atmospheric radiation flux only to the air temperature at screen level were tested in extreme Antarctic climatological condition. A relation between the long-wave radiation flux and both screen air temperature and cloud cover fraction in accordance to the height of the cloud base was defined using the Kasten and Czeplak relationship that relates the solar radiation flux and the cloud cover index. The study of the incoming short-wave radiation flux from the clear sky and that reflected by the surrounding snow cover allowed for highlighting the role of surface geometry on the albedo measurements.     

Lidar depolarization measurements for aerosol source and property studies over Chungli (24.58° N, 121.1° E)

Aerosol depolarization ratio and aerosol optical depth (AOD) were measured at Chungli (24.58° N, 121.1° E), Taiwan during the period from 2002–2004. The depolarization ratios of background aerosol have values mostly less than 0.06. The maximum AOD in the altitude range of 0.7 to 2km occurs in the summer (June–August) while between 2 and 5km, the spring (March–May) shows the maximum. The former is mainly related to strong convection and humidity; however the latter is due to anthropogenic aerosols transported from East China and Southeast Asia based on calculations of backward trajectories. This seasonal variation of AOD inferred from different transport mechanisms and aerosol compositions which are supported by the height distributions of aerosol extinction and origins.     

Geochemistry of regional background aerosols in the Western Mediterranean

The chemical composition of regional background aerosols, and the time variability and sources in the Western Mediterranean are interpreted in this study. To this end 2002–2007 PM speciation data from an European Supersite for Atmospheric Aerosol Research (Montseny, MSY, located 40 km NNE of Barcelona in NE Spain) were evaluated, with these data being considered representative of regional background aerosols in the Western Mediterranean Basin. The mean PM₁₀, PM_2.5 and PM₁ levels at MSY during 2002–2007 were 16, 14 and 11 µg/m³, respectively. After compiling data on regional background PM speciation from Europe to compare our data, it is evidenced that the Western Mediterranean aerosol is characterised by higher concentrations of crustal material but lower levels of OM + EC and ammonium nitrate than at central European sites. Relatively high PM_2.5 concentrations due to the transport of anthropogenic aerosols (mostly carbonaceous and sulphate) from populated coastal areas were recorded, especially during winter anticyclonic episodes and summer midday PM highs (the latter associated with the transport of the breeze and the expansion of the mixing layer). Source apportionment analyses indicated that the major contributors to PM_2.5 and PM₁₀ were secondary sulphate, secondary nitrate and crustal material, whereas the higher load of the anthropogenic component in PM_2.5 reflects the influence of regional (traffic and industrial) emissions. Levels of mineral, sulphate, sea spray and carbonaceous aerosols were higher in summer, whereas nitrate levels and Cl/Na were higher in winter. A considerably high OC/EC ratio (14 in summer, 10 in winter) was detected, which could be due to a combination of high biogenic emissions of secondary organic aerosol, SOA precursors, ozone levels and insolation, and intensive recirculation of aged air masses. Compared with more locally derived crustal geological dusts, African dust intrusions introduce relatively quartz-poor but clay mineral-rich silicate PM, with more kaolinitic clays from central North Africa in summer, and more smectitic clays from NW Africa in spring.     

Composition and sources of organic matter in atmospheric PM10 over a two year period in Beijing, China

The solvent-extractable organic compounds of atmospheric PM₁₀ samples, collected over two years beginning in 2003 at urban and suburban sites of Beijing, were characterized using gas chromatography–mass spectrometry (GC–MS). The elemental carbon (EC) contents were determined and ranged from 4.3 to 42 μg m^− 3. Organic compounds in total extracts were identified and included unresolved complex mixture (UCM) and series of n-alkanes, n-alkanols, n-alkanoic acids, polycyclic aromatic hydrocarbons (PAHs); saccharides, alkanedioic acids, steroids, and other biomarkers and source tracers. The seasonal variations of their relative abundances are discussed. The abundance order for the major molecular classes in the particulate organic matter (POM) was the following: UCM > saccharides > n-alkanoic acids >n-alkanes > n-alkanols > PAHs > hydroxy-PAHs > other biomarker tracers. Based on the genetic significance of the molecular tracers, the dominant sources of POM are proposed for the two sampling sites. The emissions from fossil fuel use (both coal and petroleum products), biomass combustion, other pyrolysis sources, higher plant wax, and secondary products contribute > 98.0% of the POM mass. The fossil fuel use (average = 65% of POM) is the largest contributor and derives mainly from vehicular traffic.     

Exposure of global mountain systems to climate warming during the 21st Century

We provide an assessment of surface temperature changes in mountainous areas of the world using a set of climate projections at a 0.5° resolution for two 30-year periods (2040–2069 and 2070–2099), using four Intergovernmental Panel for Climate Change (IPCC) emission scenarios and five AOGCM. Projected average temperature changes varied between +3.2 °C (+0.4 °C/per decade) and +2.1 °C (+0.26 °C/per decade) for 2055 and +5.3 °C (+0.48 °C/per decade) and +2.8 °C for 2085 (+0.25 °C/per decade). The temperature is expected to rise by a greater amount in higher northern latitude mountains than in mountains located in temperate and tropical zones. The rate of warming in mountain systems is projected to be two to three times higher than that recorded during the 20th century. The tendency for a greater projected warming in northern latitude mountain systems is consistent across scenarios and is in agreement with observed trends. In light of these projections, warming is considered likely to affect biodiversity (e.g., species extinctions, changes in the composition of assemblages), water resources (e.g., a reduction in the extent of glaciated areas and snow pack), and natural hazards (e.g., floods). Accurate estimate of the effects of climate change in mountain systems is difficult because of uncertainties associated with the climate scenarios and the existence of non-linear feedbacks between impacts.     

Trend analysis of air temperature time series in Greece and their relationship with circulation using surface and satellite data: 1955–2001

Summary In this study, trends of annual and seasonal surface air temperature time series were examined for 20 stations in Greece for the period 1955–2001, and satellite data for the period 1980–2001. Two statistical tests based on the least square method and one based on the Mann-Kendall test, which is also capable of detecting the starting year of possible climatic discontinuities or changes, were used for the analysis. Greece, in general, shows a cooling trend in winter for the period 1955–2001, whereas, summer shows an overall warming trend, however, neither is statistically significant. As a result, the overall trend of the annual values is nearly zero. Comparison with corresponding trends in the Northern Hemisphere (NH) shows that temperatures in Greece do not follow the intense warming trends. Satellite data indicate a remarkable warming trend in mean annual, winter and summer in Greece for the period 1980–2001, and a slight warming trend in annual, spring and autumn for the NH. Comparison with the respective trends detected in the surface air temperature for the same period (1980–2001) shows they match each other quite well in both Greece and the NH. The relationship between temperature variability in Greece and atmospheric circulation was also examined using correlation analysis with three circulation indices: the well-known North Atlantic Oscillation Index (NAOI), a Mediterranean Oscillation Index (MOI) and a new Mediterranean Circulation Index (MCI). The MOI and MCI indices show the most interesting correlation with winter temperatures in Greece. The behaviour of pressure and the height of the 500hPa surface over the Mediterranean region supports these results.     

A diagnostic calculation of the circulation in the upper and middle layers of the Luzon Strait and the northern South China Sea during March 1992

Wind data from NCEP and hydrographic data obtained during 8–27 March 1992 have been used to compute circulation in the Luzon Strait and the northern South China Sea using three-dimensional diagnostic models with a modified inverse method. Numerical results are as follows: the main Kuroshio is located above 800 m levels. It has two intrusive branches of the Kuroshio in the areas above 400 m. One part intrudes anti-cyclonically northwestward, then flows through the area above 200 m southwest of Taiwan and into the Taiwan Strait. The other part intrudes westward and flows cyclonically in the areas north of the cyclonic eddies, then flows southward through the southern boundary of the region. The net westward volume transport (VT) through Section at 120°15′E between Luzon Island and Taiwan Island is about 3.0 Sv, net northward VT through northern boundaries into the Taiwan Strait is about 1.4 Sv and net southward VT through southern boundaries is about 1.6 Sv, which finally flows into the Karimata and Mindoro Straits. In the areas above 400 m east of 117°15′E, the circulation is mainly dominated by the basin-scale cyclonic gyre, which consists of two cyclonic eddies. However, in the areas below 400 m east of 119°00′E, the circulation is mainly dominated by basin-scale anti-cyclonic gyre. The joint effect of baroclinity and relief and interaction between wind stress and relief are important in different area respectively for the pattern of the depth-averaged flow across contours of fH⁻¹.