共查询到20条相似文献,搜索用时 203 毫秒
1.
采用典型偶氮染料酸性大红GR为模板污染物,以制得的谷壳源胺基修饰的石墨烯纳米纤维(aGRNF)为吸附脱除材料,深入研究了水样中模板污染物酸性大红GR的脱除效果。分别研究了脱除时间、水样pH、aGRNF添加量及染料起始浓度等不同因素对酸性大红GR染料的脱除效果的影响。研究结果表明,制得的aGRNF与酸性大红GR间极易通过氢键、π-π键等形成弱相互作用,使得吸附脱除效果更为显著,常温下,小剂量aGRNF纳米材料即可有效脱除0.2~4.0mg/mL较宽浓度范围的水样中酸性大红GR污染物,在酸性大红GR初始浓度为1.0mg/mL,aGRNF用量为1.5mg,脱除时间为120min条件下,aGRNF对酸性大红GR的脱除效果最好,脱除率最高达到97.1%,充分展现了该纳米材料在水质净化领域的应用潜力。 相似文献
2.
3.
用配位调控法在室温下制备了配位聚合物材料Cu_3(BTC)_2。通过粉末XRD、SEM、N_2吸附、TGA等手段对样品的物相、形貌和比表面积及热稳定性进行了表征。结果表明,制备的配位聚合物材料Cu_3(BTC)_2为球形纳米颗粒,BET比表面积为1 183m~2/g。考察了Cu_3(BTC)_2对活性大红染料废水的处理效果,探讨了吸附剂加入量、pH值、活性大红初始浓度及反应时间对吸附过程的影响。结果表明,吸附剂Cu_3(BTC)_2对活性大红染料具有较高的吸附性能,平衡吸附量可达83.33mg/g。吸附等温线拟合结果较好的符合Langmuir模型,动力学研究结果表明吸附过程符合准二级动力学模型。 相似文献
4.
利用半导体二氧化钛粉体光催化氧化法,对影响分散大红和活性艳兰两种染料的光降解率的因素--染料初始浓度、光照时间、催化剂TiO2用量、溶液初始pH值进行了研究,找出了最佳的反应条件,使处理后的水达到较高的标准.并对羟基和H+离子在光催化氧化法中对染料发色基团作用机理进行了初步分析. 相似文献
5.
6.
《化工新型材料》2016,(11)
制备葫芦脲[6]接枝壳聚糖(CB[6]-CS)吸附剂,分别获得3种不同接枝率的CB[6]-CS,并对其结构进行表征。将合成的3种吸附剂CB[6]-CS用于对酸性铬兰K染料进行吸附研究,分别考察了温度、pH值、染料浓度、吸附时间及CB[6]含量对吸附性能的影响。结果表明:CB[6]含量较高时,CB[6]-CS对酸性铬兰K有较高的去除率,并且,CB[6]-CS对酸性铬兰K的吸附作用受溶液的温度和pH影响较大,适宜的吸附条件为25℃,pH大于6.5。通过吸附等温线研究,可知,CB[6]-CS对酸性铬兰K的吸附规律更符合Freundlich吸附等温式;吸附动力学采用了准一级速率方程和准二级速率方程来描述,结果表明吸附动力学符合准二级速率方程。 相似文献
7.
《化工新型材料》2016,(3)
采用B、N和Ce共掺杂TiO_2降解酸性蓝BRL、活性金黄K-2RA、弱酸性黑RB和酸性大红GR 4种染料废水,考察了催化剂用量、染料初始浓度、光照时间和pH值等对其降解率的影响。结果表明:B、N和Ce共掺杂TiO_2除了能使染料快速褪色外,还能将其完全矿化为CO_2,SO_4~(2-)和NH~+_4等离子。酸性大红GR染料和酸性蓝BRL在pH=5、催化剂用量50mg、初始浓度50mg/L、光照180min时降解率分别为98%和94.2%。pH=1、催化剂用量50mg、初始浓度40mg/L、光照时间180min时,活性金黄K-2RA的降解率达94.5%。弱酸性黑RB在pH=2、催化剂用量60mg、初始浓度20mg/L、光照时间210min时,降解率达到最大,为92.6%。 相似文献
8.
9.
以KOH为活化剂进行两段式活化程序,将废弃生物质材料转化为活性炭,并评估此活性炭吸对液相中农药(呋喃丹)的去除能力。结果表明,此活性炭具有大比表面积与高吸附能力可快速有效地去除液相中的呋喃丹。吸附前后的活性炭用扫描电子显微镜、元素分析仪与傅里叶变换红外光谱仪进行特征分析。活性炭的比表面积与平均孔径分别为1304.8 m2/g与2.39 nm。同时对不同的吸附参数进行批次分析,包括呋喃丹初始浓度,吸附时间、温度与酸碱度。最大吸附量(296.52mg/g)的吸附参数为90min、30℃、吸附剂剂量100mg/L、180 r/min、呋喃丹初始浓度200mg/L。根据三种平衡吸附等温线(Langmuir,Freundlich and Temkin)与动力学分析,Langmuir模式最符合此活性炭的吸附结果,伪二级动力学方程可预测此活性炭的吸附动力学。 相似文献
10.
11.
12.
Abstract The purpose of this study is the investigation of the adsorption of heavy metals from wastewater with waste activated sludge (WAS) so as to increase the operational flexibility of activated sludge processes for the shock loading problems of heavy metals. By contacting the raw wastewater with WAS, before it entered the activated sludge process unit, some heavy metals in the wastewater were removed, and the pH value of the acidic wastewater rose. Five metals, Cu, Zn, Ni, Cd and Pb, were studied, some factors which affected this biosorption phenomena were investigated, and expressions of the adsorption isotherms were discussed. A semi‐empirical mass transfer‐adsorption model was developed to describe the kinetic experimental data. 相似文献
13.
文章从静态和动态研究了剩余活性污泥的超声脱水及污泥的破解。静态下,污泥的脱水应在低功率(以50W为例)短时间(7min)内进行,最高的脱水率(相对于未超声而言)可增加近16%;污泥破解应在高功率长时间下进行,本实验在250W的功率下连续处理20min,COD的增加值达到近1600mg/L;污泥的破解满足一级反应动力学。动态下,以低功率(50W)为例,脱水及破解曲线都比较平坦,污泥的总脱水率相对于未超声而言增加可达近23%;COD的增加值近似达1800mg/L。通过比较低功率下实验,动态实验效果明显优于静态实验。 相似文献
14.
15.
Abstract The study investigated the effect of compartmentalization of anaerobic zone on sludge settling property in an enhanced biological phosphorus removal (EBPR) system. Continuous‐flow pilot‐plant experiments with synthetic influent were performed at varied anaerobic‐oxic volume ratios (Van : Vo , 1 : 9 and 2 : 8), involving 5, 10 and 15 days of sludge retention times (SRTs). Experimental results indicated that, regardless of Van : Vo and SRT, satisfactory removal of COD and phosphate were achieved during all test runs. However, extremely high sludge volume index (SVI) values were observed when there were 5 days of SRT. Further experiments with compartmentalization of anaerobic zone were therefore conducted to confirm the necessity of incorporating the kinetic selection mechanism of bulking control into an EBPR process operated at a low SRT. These results revealed that the two factors, Van : Vo and anaerobic compartmentalization, had interaction with respect to sludge settling property in terms of SVI. When anaerobic retention time increased from 0.72hr to 1.36hr, compartmentalizing anaerobic zone significantly decreased the SVI value because of generating high COD concentration gradient and phosphate release in the anaerobic zone. This result implies that supplementing kinetic selection pressure of bulking control exhibits a critical influence on sludge settling when the EBPR process operates at a lower SRT. 相似文献
16.
污泥制备活性炭对 Pb(Ⅱ)和Ni(Ⅱ)的吸附和回收利用 总被引:3,自引:0,他引:3
在静态条件下研究了用污泥制备的活性炭吸附剂去除水溶液中Pb(Ⅱ)、Ni(Ⅱ)的效果,考察了溶液pH值、吸附时间、吸附剂用量和Pb(Ⅱ)、Ni(Ⅱ)的初始浓度对去除率的影响.结果表明,污泥制备的活性炭吸附剂对Pb(Ⅱ)、Ni(Ⅱ)具有较强的吸附性能,pH值是影响吸附的主要因素;吸附过程符合Langmuir吸附等温式;在试验条件下,其对Pb(Ⅱ)具有更高的去除能力.还探讨了吸附Pb(Ⅱ)、Ni(Ⅱ)后回收铅和镍的可行性. 相似文献
17.
Wang G Sui J Shen H Liang S He X Zhang M Xie Y Li L Hu Y 《Journal of hazardous materials》2011,192(1):93-98
In this study, chlorine dioxide (ClO2) instead of chlorine (Cl2) was proposed to minimize the formation of chlorine-based by-products and was incorporated into a sequencing batch reactor (SBR) for excess sludge reduction. The results showed that the sludge disintegrability of ClO2 was excellent. The waste activated sludge at an initial concentration of 15 g MLSS/L was rapidly reduced by 36% using ClO2 doses of 10 mg ClO2/g dry sludge which was much lower than that obtained using Cl2 based on similar sludge reduction efficiency. Maximum sludge disintegration was achieved at 10 mg ClO2/g dry sludge for 40 min. ClO2 oxidation can be successfully incorporated into a SBR for excess sludge reduction without significantly harming the bioreactor performance. The incorporation of ClO2 oxidation resulted in a 58% reduction in excess sludge production, and the quality of the effluent was not significantly affected. 相似文献
18.
The combined carbon-activated sludge process has been proposed as an alternative to protect the biomass against toxic substances in wastewaters; however, the information about the effect of powdered-activated carbon (PAC) addition in activated sludge reactors for the treatment of wastewaters containing Cr(VI) is limited. The objectives of the present study were: (a) to evaluate the removal of hexavalent chromium by (i) activated sludge microorganisms in aerobic batch reactors, (ii) powdered-activated carbon, and (iii) the combined action of powdered-activated carbon and biomass; (b) to propose mathematical models that interpret the experimental results. Different Cr(VI) removal systems were tested: (S1) biomass (activated sludge), (S2) PAC, and (S3) the combined activated carbon-biomass system. A Monod-based mathematical model was used to describe the kinetics of Cr(VI) removal in the system S1. A first-order kinetics with respect to Cr(VI) and PAC respectively, was proposed to model the removal of Cr(VI) in the system S2. Cr(VI) removal in the combined carbon-biomass system (S3) was faster than both Cr(VI) removal using PAC or activated sludge individually. Results showed that the removal of Cr(VI) using the activated carbon-biomass system (S3) was adequately described by combining the kinetic equations proposed for the systems S1 and S2. 相似文献
19.
准确测定活性污泥中化学需氧量(Chemical Oxygen Demand, CODCr)含量,是实现污泥资源化利用的重要条件。文章提出一种超声破解联合湿法测定活性污泥中CODCr含量的检测方法。基于单因素实验结果,以CODCr浓度作为响应值,采用响应曲面法考察了污泥混合液的稀释倍数、超声功率和超声时间3个因素间单独及交互作用,并对影响因素进行了评估。结果表明,取样量为10 mL,稀释倍数为225倍,超声时间为18 min,超声功率为720 W时,样品平行测定的相对标准偏差小于等于2.00 %,加标回收率为96.51 %~105.32 %,测定结果的准确度、精密度较高。光学显微镜照片和激光粒度仪分析表明,超声破解能够有效破碎微生物细胞的絮体结构,显著降低污泥颗粒粒径,减少污泥取样过程中的误差。对不同f的污泥样品,CODCr测定值与理论值相关性拟合曲线的拟合值R2≥0.9961。研究结果证明超声破解联合湿法测定活性污泥中CODCr具有良好的可靠性和经济性。 相似文献
20.
Effect of chemical composition on the flocculation dynamics of latex-based synthetic activated sludge 总被引:1,自引:0,他引:1
This study investigates the effect of calcium, alginate, fibrous cellulose, and pH on the flocculation dynamics and final properties of synthetic activated sludges. A laboratory-scale batch reactor, fed with standard synthetic sludges was used. The effects of varying calcium concentration (5-25 mM), alginate concentration (25-125 mg/L), fibrous cellulose concentration (0.2-0.8 g/L) and pH (3-9) on the sludge characteristics were studied by varying one parameter whilst keeping the others constant. The results from experiments indicated that the calcium, alginate, fibrous cellulose, and pH had the critical effect on the aggregation rate, flocs size, and made the improvement of the final properties of sludge. Dynamic measurements have established the optimum conditions for floc formation and can accurately reflect the state of formation of the synthetic activated sludge flocs. These correlate well with measurements of settleability and turbidity of the synthetic activated sludge. The results of this study support the bonding theory and indicate that formation of cations-polymer complexes and polymer gelation are important means of flocculation. The development of synthetic activated sludges is suggested also to be a possible surrogate for studying the final properties of activated sludge. 相似文献