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Ti/IrO2-Ta2O5阳极电催化氧化法处理含酚废水 总被引:1,自引:0,他引:1
采用新型的钛基金属氧化物涂层电极(Ti/IrO2–Ta2O5)作为阳极,石墨作为阴极对含酚模拟废水进行电催化氧化降解实验。当电解条件为电压U=9.0V;电流I=2.5A;板间距d=3.0cm;电解质NaCl浓度20.0g·L-1,初始pH=7.0时,初始浓度为1000mg·L-1苯酚模拟废水电解90min后,处理效果较理想,其中电流和电解质浓度为主要影响因子。Ti/IrO2–Ta2O5阳极电催化氧化降解苯酚的过程符合一级反应动力学。 相似文献
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新型钛基体PbO2电极的制备及降解性能研究 总被引:1,自引:0,他引:1
采用电沉积法制备钛基体PbO2电极并对其表面形貌进行了表征,所制备的电极具有较高的析氧电位和良好的电催化活性。以制备的钛基PbO2为阳极,抛光钛电极为阴极,分别进行电流密度、反应时间、pH、电解质质量浓度等单因素试验,确定PbO2电极对亚甲基蓝的最优降解条件为:pH=6,电解质质量浓度为5.0 g.L-1,电流密度为5×10-2A.cm-2,该条件下亚甲基蓝1 h的降解率可以达到99%;且电流密度为0.25×10-2A.cm-2时能耗最低。 相似文献
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掺硼金刚石薄膜电极电催化降解染料废水的研究 总被引:10,自引:0,他引:10
通过测试新型掺硼金刚石薄膜电极的电化学性质,发现掺硼金刚石薄膜电极具有较高的析氢析氧过电位,有效地抑制了析氧副反应,具有较高的催化氧化效率。在研究活性艳红模拟染料废水在该电极上的催化降解过程中,考察了不同工艺条件:活性炭投加、电解质、电流密度、pH值和染料废水的初始浓度对染料降解脱除的影响。实验结果表明:在酸性介质中,投加一定量的活性炭和2gL-1硫酸钠电解质,选用电流密度为0.08Acm-2,来处理高浓度染料废水色度去除率可达到99%。由染料废水处理前后的紫外可见光谱表明电解不仅破坏了染料分子中的偶氮共轭发色基团,达到去色的目的,还可以断裂其他难降解小分子基团。 相似文献
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采用三电极体系探究了Ti/RuO2-IrO2、Ti/SnO2-Sb2O3、Ti/Pt、石墨4类电极的电化学性能,考察了不同电极材料、初始pH、初始Cl-质量浓度、电流密度对生成活性氯浓度的影响。在选取较优的操作条件下电解模拟氨氮废水,结果表明,以Ti/RuO2-IrO2电极为阳极,在初始pH为7、初始Cl-质量浓度为12 500 mg/L、电流密度为100 A/m2的条件下电解120 min氨氮,总氮去除率分别达96.71%、90.44%;活性炭吸附150 min,总氯、余氯去除率分别达到98.43%、98.81%,减小了废水对后续生物处理系统的影响。 相似文献
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Electrochemical oxidation of phenol using a Ti/TiO2‐RuO2‐IrO2 anode in the presence of chloride as the supporting electrolyte was investigated. The experiments were performed in an undivided batch reactor. Preliminary investigations showed that only a small fraction of phenol was oxidized by direct electrolysis, while complete degradation of phenol was achieved by indirect electrochemical oxidation using chloride as a supporting electrolyte. The effect of operating parameters such as initial pH, supporting electrolyte concentration, phenol concentration, and charge input was studied using Box‐Behnken second order composite experimental design. The effect of current density on COD removal was studied separately. TOC removal and AOX formation were studied for selected conditions. It was found that the formation of chlorinated organic compounds was pronounced at the beginning of electrolysis, but it was reduced to lower levels by extended electrolysis. 相似文献
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以盐酸四环素(TC·HCl)为研究对象,钛基钌铱涂层(IrO2-RuO2/Ti)为阳极,钛板为阴极,电催化氧化降解TC·HCl模拟废水,探讨了初始质量浓度、电流密度、pH、电解质硫酸钠浓度对电催化降解TC·HCl效率的影响。结果表明,电催化氧化可有效降解水中的TC·HCl。提高电流密度,降低TC·HCl初始质量浓度、电解质硫酸钠浓度,可增大TC·HCl去除率。反应的前90 min,pH对去除率无影响,反应90 min后降解效果出现明显差别,pH为3、7和12时,反应300 min去除率分别为92%、100%和72%。降解过程遵循一级反应动力学模型。通过综合各工艺参数下的去除率、能量消耗和电流效率,得出最佳工艺参数为:TC·HCl初始质量浓度300 mg/L、电流密度10 mA/cm2、硫酸钠浓度0.05 mol/L、pH=7,在该条件下反应180 min后TC·HCl去除率达94%。该实验结果为电化学处理制药工业废水提供了基础数据和科学参考。 相似文献
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对以空气扩散电极为阴极,铁板为阳极的电化学体系降解苯酚模拟废水进行了研究。采用分光光度法测定苯酚浓度,研究了pH值、电解时间和电流密度对苯酚去除率的影响。结果表明,电芬顿体系对含酚废水有很强的降解能力,初始浓度为300 mg/L的苯酚溶液,在电流密度20 mA/cm2条件下电解180 min,苯酚去除率99.5%,COD(Chemical Oxygen Demand)去除率85.1%。 相似文献
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The electrochemical oxidation of phenol for waste water treatment applications was investigated on lead dioxide packedbed anodes. Cells were operated in both batch and continuous modes with feed streams up to 1100 mg/l phenol dissolved in aqueous solutions of Na2SO4 and H2SO4 or NaOH. All the phenol in solution could be readily oxidized but complete total organic carbon (T.O.C.) removal was more difficult. The percent phenol oxidized increased with increasing current density, and decreased as initial phenol concentration, electrolyte flow rate, pH and anode particle size were increased. Results are compared to simple mathematical models. 相似文献
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利用单槽无隔膜电化学反应器,研究了硫化氢恶臭气体碱性吸收液在圆形平板钌钛DSA电极上的电化学氧化处理过程,考察了电流密度、初始料液浓度、辅助电解质以及pH值对S2?电解去除效果的影响。结果表明:在电流密度25 mA/cm2、S2?初始浓度23 mmol/L时,S2?去除率可达95%以上;S2?的氧化产物主要为SO42?,约占总反应产物的95%,而硫单质占2%~3%,同时生成少量SO32?、S2O32?;S2?去除速率受到S2?浓度的较大影响,电流密度越高去除速率越快;pH值影响Sx2?的形成,强碱条件可避免阳极钝化;与NaCl等辅助电解质相比,NaOH最有利于提高电解氧化的速度和深度,S2?去除率达90%时,可缩短处理时间近40%。 相似文献
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The electrochemical oxidation of phenol for waste water treatment applications was investigated on lead dioxide packed-bed anodes. Cells were operated in both batch and continuous modes with feed streams up to 1100 nig/1 phenol dissolved in aqueous solutions of Na2SO4 and H2SO4 or NaOH. All the phenol in solution could be readily oxidized but complete total organic carbon (T.O.C.) removal was more difficult. The percent phenol oxidized increased with increasing current density, and decreased as initial phenol concentration, electrolyte flow rate, pH and anode particle size were increased. Results are compared to simple mathematical models. 相似文献