Ion irradiation of H2O ice on top of sulfurous solid residues and its relevance to the Galilean satellites

In this paper we present the results of new experiments of ion irradiation of water ice deposited on top of a solid sulfurous residue to study the potential formation of SO₂ at the interface ice/refractory material and discuss the possibility that this mechanism accounts for the sulfur dioxide ice detected on the surfaces of the Galilean satellites. In situ infrared spectroscopy was the used experimental technique. We have irradiated a thin film of H₂O frost on a sulfurous layer with 200 keV of He⁺ at 80 K. The used sulfurous residue was obtained by irradiation of frozen SO₂ at 16 K and it is used as a template of sulfur bearing solid materials. We have not found evidences of the efficient formation of SO₂ after irradiation of H₂O ice on top of the sulfurous residue. An upper limit to the production yield of SO₂, of interface area for each 100 eV of energy absorbed in 1 cm³ of ice-covered residue, has been estimated. These results have relevance in the context of the surfaces of the icy Galilean satellites in which SO₂ was detected. Our results show that radiolysis of mixtures of water ice and refractory sulfurous materials is not the primary formation mechanism responsible for the SO₂ present on the surfaces of the Galilean satellites.     

Studies of proton-irradiated SO2 at low temperatures: Implications for lo

The infrared absorption spectrum from 3.3 to 27 μm (3030-370 cm^?) of SO₂ ice films has been measured at 20 and 88°K before and after 1-MeV proton irradiation. The radiation flux was chosen to simulate the estimated flux of Jovian magnetospheric 1-MeV protons incident on Io. After irradiation, SO₃ is identified as the dominant molecule synthesized in the SO₂ ice. This is also the case after irradiation of composite samples of SO₂ with sulfur, or disulfites. Darkening was observed in irradiated SO₂ ice and in irradiated S₈ pellets. Photometric and spectral measurements of the thermoluminescence of irradiated SO₂ have been made during warming. The spectrum appears as a broad band with a maximum at 4450 Å. Analysis of the luminescence data suggests that, at Ionian temperatures, irradiated SO₂ ice would not be a dominant contributor to posteclipse brightening phenomena. After warming to room temperature, a form of SO₃ remains along with a sulfate and S₈. Based on these experiments, it is reasonable to propose that small amounts of SO₃ may exist on the surface of Io as a result of irradiation synthesis in SO₂ frosts.     

Geology and activity around volcanoes on Io from the analysis of NIMS spectral images

The last two successful flybys of Io by Galileo in 2001 (orbits I31, I32) allowed the Near Infrared Mapping Spectrometer to enrich its collection of IR spectral image cubes of the satellite. These data cover hemispheric portions of Io, several volcanic centers as well as their surroundings with a spatial resolution ranging from 2 to 93 km pixel⁻¹. They map thermal emission from the hot-spots and the distribution of solid SO₂ in the 1.0-4.7 μm spectral range. We obtain maps of SO₂ abundance and granularity from the NIMS data using the method of Douté et al. (2002, Icarus 158, 460-482). The maps are correlated to distinguish four different physical units that indicate zones of SO₂ condensation, metamorphism and sublimation. We relate these information with visible images from Galileo's Solid State Imaging System and with detailed mapping of the thermal emission produced by Io's surface. Our principal goal is to understand the mechanisms controlling how lava, pyroclastics and gas are emitted by different types of volcanoes and how these products evolve. The 800 km diameter white ring of fallout created by a violent “Pillanian” eruption during summer of 2001 is at least partly composed of solid SO₂ and has enriched preexisting regional deposits. Orange materials have been recently or are currently emplaced 240 km south from the main eruption site, possibly as sulfur flows. A similar event may have taken place in the past at Ababinili Patera (12.5° N, 142° W). Carefull study of SO₂ maps covering the Emakong region also suggests that sulfur forms the bright channel-fed flow emerging from the south eastern side of the caldera. Within the main caldera of Tvashtar Catena completely cooled patches of crust exist. Elsewhere, the caldera is still cooling from previous episodes of flooding. We confirm that Amirani emits constantly large amount of SO₂ gas by interaction of fresh lava with the volatiles of the underlying plains. Nevertheless SO₂ frost is not the major component of the bright white ring seen in the SSI images. Over the whole Gish Bar region, SO₂ frost seems barely stable and is constantly regenerated. The stability increases along gray filamentary structures which could be faults filled with materials having peculiar thermal properties. Northwest of Gish Bar Patera, a localized bright deposit shows an unusual spectral signature potentially indicative of H₂O molecules forming ice crystals or being trapped in a nonidentified matrix. The Chaac region may present a thickened old crust reducing the geothermal flux to levels lower than 0.5 W m⁻² and thus creating a cold trap for SO₂. Looking at the abundance and degree of metamorphose of SO₂, we establish the relative age of different flows and ejecta for the Sobo Fluctus. Finally the assumption that the white patches in visible images indicate SO₂ rich deposits is once again challenged. In the Camaxtli region we identify a topographically controlled compact white deposit showing only moderate SO₂ abundance. In contrast, we detect two spots of quite pure SO₂ ice on the gray flanks of Emakong. Furthermore, the close association of fumarolic SO₂ and red S₂ already noted for several volcanic centers is observed at Tupan.     

The radiolysis of SO2 and H2S in water ice: Implications for the icy jovian satellites

Spectra of Europa, Ganymede, and Callisto reveal surfaces dominated by frozen water, hydrated materials, and minor amounts of SO₂, CO₂, and H₂O₂. These icy moons undergo significant bombardment by jovian magnetospheric radiation (protons, electrons, and sulfur and oxygen ions) which alters their surface compositions. In order to understand radiation-induced changes on icy moons, we have measured the mid-infrared spectra of 0.8 MeV proton-irradiated SO₂, H₂S, and H₂O-ice mixtures containing either SO₂ or H₂S. Samples with H₂O/SO₂ or H₂O/H₂S ratios in the 3-30 range have been irradiated at 86, 110, and 132 K, and the radiation half-lives of SO₂ and H₂S have been determined. New radiation products include the H₂S₂ molecule and HSO⁻₃, HSO⁻₄, and SO²⁻₄ ions, all with spectral features that make them candidates for future laboratory work and, perhaps, astronomical observations. Spectra of both unirradiated and irradiated ices have been recorded as a function of temperature, to examine thermal stability and phase changes. The formation of hydrated sulfuric acid in irradiated ice mixtures has been observed, along with the thermal evolution of hydrates to form pure sulfuric acid. These laboratory studies provide fundamental information on likely processes affecting the outer icy shells of Europa, Ganymede, and Callisto.     

Simultaneous mapping of SO2, SO, NaCl in Io’s atmosphere with the Submillimeter Array

Many of the key properties of Io’s atmosphere, such as its spatial distribution, temperature, column density and composition, are still not fully assessed despite decades of extensive observations. The contribution of the possible gas sources to the atmospheric replenishment are then still unclear.This paper presents disk-resolved observations performed with the Submillimeter Array (SMA) at 345 GHz of atmospheric rotational lines of the main atmospheric species SO₂, and, for the first time, of the minor species SO and NaCl. All these species appear concentrated on the anti-jovian hemisphere, but do not share the same spatial distribution. The obtained maps and line-averaged fluxes are compared to realistic models simulating gas sources including volcanic plume outgassing, SO₂ frost sublimation and photolysis. Arguments in favor of each sources are examined and compared to observations, putting constraints on their relative roles for each species.While sublimation clearly appears as the favored major source for SO₂, SO₂ photolysis may account for most of the production of SO. Using constraints on the volcanic plumes distribution from Galileo results, we find that direct volcanic input can only contribute for a minor fraction of atmospheric SO₂, but represent a more significant source for SO atmosphere, and is likely to be the only source for NaCl. Temperature and column densities findings are also presented for SO₂, and compare well to previously published observations and atmospheric models.     

Io's 4-μm band and the role of adsorbed SO2

The role of adsorbed SO₂ on Io's surface particles in producing the observed spectral absorption band near 4 μm in Io's reflectance spectrum is explored. Calculations show that a modest 50% monolayer coating of adsorbed SO₂ molecules on submicron grains of sulfur of alkali sulfide, assumed to make up Io's uppermost optical surface (“radialith”), will result in a ν₁ + ν₃ absorption band near 4 μm with depth ～30% below the adjacent continuum, consistent with the observed strength of the Io band. The precise wavelength position of the ν₁ + ν₃ band of SO₂ in different phase states such as frost, ice, adsorbate, and gas are summarized from the experimental literature and compared with the available telescopic measurements of the Io band position. The results suggest that the 4-μm band in Io's full disk spectrum can best be explained by the presence on Io's surface of widespread SO₂ in the form of adsorbate rather than ice or frost.     

Microwave Remote Sensing of the Temperature and Distribution of Sulfur Compounds in the Lower Atmosphere of Venus

A multi-wavelength radio frequency observation of Venus was performed on April 5, 1996, with the Very Large Array to investigate potential variations in the vertical and horizontal distribution of temperature and the sulfur compounds sulfur dioxide (SO₂) and sulfuric acid vapor (H₂SO₄(g)) in the atmosphere of the planet. Brightness temperature maps were produced which feature significantly darkened polar regions compared to the brighter low-latitude regions at both observed frequencies. This is the first time such polar features have been seen unambiguously in radio wavelength observations of Venus. The limb-darkening displayed in the maps helps to constrain the vertical profile of H₂SO₄(g), temperature, and to some degree SO₂. The maps were interpreted by applying a retrieval algorithm to produce vertical profiles of temperature and abundance of H₂SO₄(g) given an assumed sub-cloud abundance of SO₂. The results indicate a substantially higher abundance of H₂SO₄(g) at high latitudes (above 45°) than in the low-latitude regions. The retrieved temperature profiles are up to 25 K warmer than the profile obtained by the Pioneer Venus sounder probe at altitudes below 40 km (depending on location and assumed SO₂ abundance). For 150 ppm of SO₂, it is more consistent with the temperature profile obtained by Mariner 5, extrapolated to the surface via a dry adiabat. The profiles obtained for H₂SO₄(g) at high latitudes are consistent with those derived from the Magellan radio occultation experiments, peaking at around 8 ppm at an altitude of 46 km and decaying rapidly away from that altitude. At low latitudes, no significant H₂SO₄(g) is observed, regardless of the assumed SO₂ content. This is well below that measured by Mariner 10 (Lipa and Tyler 1979, Icarus39, 192-208), which peaked at ∼14 ppm near 47 km. Our results favor ≤100 ppm of SO₂ at low latitudes and ≤50 ppm in polar regions. The low-latitude value is statistically consistent with the results of Bézard et al. (1983, Geophs. Res. Lett.20, 1587-1590), who found that a sub-cloud SO₂ abundance of 130±40 ppm best matched their observations in the near-IR. The retrieved temperature profile and higher abundance of H₂SO₄(g) in polar regions are consistent with a strong equatorial-to-polar, cloud-level flow due to a Hadley cell in the atmosphere of Venus.     

Sulfur chemistry in the Venus mesosphere from SO2 and SO microwave spectra

First measurements of SO₂ and SO in the Venus mesosphere (70-100 km) are reported. This altitude range is distinctly above the ∼60-70 km range to which nadir-sounding IR and UV investigations are sensitive. Since July 2004, use of ground-based sub-mm spectroscopy has yielded multiple discoveries. Abundance of each molecule varies strongly on many timescales over the entire sub-Earth Venus hemisphere. Diurnal behavior is evident, with more SO₂, and less SO, at night than during the day. Non-diurnal variability is also present, with measured SO₂ and SO abundances each changing by up to 2× or more between observations conducted on different dates, but at fixed phase, hence identical sub-Earth Venus local times. Change as large and rapid as a 5σ doubling of SO on a one-week timescale is seen. The sum of SO₂ and SO abundances varies by an order of magnitude or more, indicating at least one additional sulfur reservoir must be present, and that it must function as both a sink and source for these molecules. The ratio SO₂/SO varies by nearly two orders of magnitude, with both diurnal and non-diurnal components. In contrast to the strong time dependence of molecular abundances, their altitude distributions are temporally invariant, with far more SO₂ and SO at 85-100 km than at 70-85 km. The observed increase of SO₂ mixing ratio with altitude requires that the primary SO₂ source be upper mesospheric photochemistry, contrary to atmospheric models which assert upward transport as the only source of above-cloud SO₂. Abundance of upper mesospheric aerosol, with assumption that it is composed primarily of sulfuric acid, is at least sufficient to provide the maximum gas phase (SO + SO₂) sulfur reported in this study. Sulfate aerosol is thus a plausible source of upper mesospheric SO₂.     

A sensitive search for SO2 in the martian atmosphere: Implications for seepage and origin of methane

Mars was observed near the peak of the strongest SO₂ band at 1364-1373 cm⁻¹ with resolving power of 77,000 using the Texas Echelon Cross Echelle Spectrograph on the NASA Infrared Telescope Facility. The observation covered the Tharsis volcano region which may be preferable to search for SO₂. The spectrum shows absorption lines of three CO₂ isotopomers and three H₂O isotopomers. The water vapor abundance derived from the HDO lines assuming D/H = 5.5 times the terrestrial value is 12±1.0 pr. μm, in agreement with the simultaneous MGS/TES observations of 14 pr. μm at the latitudes (50° S to 10° N) of our observation. Summing of spectral intervals at the expected positions of sixteen SO₂ lines puts a 2σ upper limit on SO₂ of 1 ppb. SO₂ may be emitted into the martian atmosphere by seepage and is removed by three-body reactions with OH and O. The SO₂ lifetime, 2 years, is longer than the global mixing time 0.5 year, so SO₂ should be rather uniformly distributed across Mars. Seepage of SO₂ is less than 15,000 tons per year on Mars which is smaller than the volcanic production of SO₂ on the Earth by a factor of 700. Because CH₄/SO₂ is typically 10⁻⁴-10⁻³ in volcanic gases on the Earth, our results show seepage is unlikely to be the source of the recently discovered methane on Mars and therefore strengthen its biogenic origin.     

Enhanced CO2 trapping in water ice via atmospheric deposition with relevance to Mars

It has been suggested that inclusions of CO₂ or CO₂ clathrate hydrates may comprise a portion of the polar deposits on Mars. Here we present results from an experimental study in which CO₂ molecules were trapped in water ice deposited from CO₂/H₂O atmospheres at temperatures relevant for the polar regions of Mars. Fourier-Transform Infrared spectroscopy was used to monitor the phase of the condensed ice, and temperature programmed desorption was used to quantify the ratio of species in the generated ice films. Our results show that when H₂O ice is deposited at 140-165 K, CO₂ is trapped in large quantities, greater than expected based on lower temperature studies in amorphous ice. The trapping occurs at pressures well below the condensation point for pure CO₂ ice, and therefore this mechanism may allow for CO₂ deposition at the poles during warmer periods. The amount of trapped CO₂ varied from 3% to 16% by mass at 160 K, depending on the substrate studied. Substrates studied were a tetrahydrofuran (C₄H₈O) base clathrate and Fe-montmorillonite clay, an analog for Mars soil. Experimental evidence indicates that the ice structures are likely CO₂ clathrate hydrates. These results have implications for the CO₂ content, overall composition, and density of the polar deposits on Mars.     

Cratering of icy targets by different impactors: Laboratory experiments and implications for cratering in the Solar System

Studies of impacts (impactor velocity about 5 km s⁻¹) on icy targets were performed. The prime goal was to study the response of solid CO₂ targets to impacts and to find the differences between the results of impacts on CO₂ targets with those on H₂O ice targets. The crater dimensions in CO₂ ice were found to scale with impact energy, with little dependence on projectile density (which ranged from nylon to copper, i.e., 1150-8930 kg m⁻³). At equal temperatures, craters in CO₂ ice were the same diameter as those in water ice, but were shallower and smaller in volume. In addition, the shape of the radial profiles of the craters was found to depend strongly on the type of ice and to change with impact energy. The impact speed of the data is comparable to that for impacts on many types of icy bodies in the outer Solar System (e.g., the satellites of the giant planets, the cometary nuclei and the Kuiper Belt objects), but the size and thus energy of the impactors is lower. Scaling with impact energy is demonstrated for the impacts on CO₂ ice. The issue of impact disruption (rather than cratering) is discussed by analogy with that on water ice. Expressions for the critical energy density for the onset of disruption rather than cratering are established for water ice as a function of porosity and silicate content. Although the critical energy density for disruption of CO₂ ice is not established, it is argued that the critical energy to disrupt a CO₂ ice body will be greater than that for a (non-porous) water ice body of the similar mass.     

Carbon dioxide segregation in 1:4 and 1:9 CO2:H2O ices

The mid-infrared spectra of mixed vapor deposited ices of CO₂ and H₂O were studied as a function of both deposition temperature and warming from 15 to 100 K. The spectra of ices deposited at 15 K show marked changes on warming beginning at 60 K. These changes are consistent with CO₂ segregating within the ice matrix into pure CO₂ domains. Ices deposited at 60 and 70 K show a greater degree of segregation, as high as 90% for 1:4 CO₂:H₂O ice mixtures deposited at 70 K. As the ice is warmed above 80 K, preferential sublimation of the segregated CO₂ is observed. The kinetics of the segregation process is also examined. The segregation of the CO₂ as the ice is warmed corresponds to temperatures at which the structure of the water ice matrix changes from the high density amorphous phase to the low density amorphous phase. We show how these microstructural changes in the ice have a profound effect on the photochemistry induced by ultraviolet irradiation. These experimental results provide a framework in which observations of CO₂ on the icy bodies of the outer Solar System can be considered.     

The global distribution of sulfur dioxide ice on Io, observed with OSIRIS on the W.M. Keck telescope

We present ground based observations of Io taken with a high spatial resolution imaging spectrometer on 1 and 2 June 2006. We mapped the 1.98 and 2.12 μm absorptions of SO₂ frost, across Io's surface. We analyze these data with surface reflectance modeling using the Hapke method to determine the general frost distribution. This analysis also determined a lower limit of 700 μm on the grain size for the areas of strongest absorption. We incorporate our findings of a predominantly equatorial distribution of SO₂ frost, with the maps of Carlson et al. [Carlson, R.W., Smythe, W.D., Lopes-Gautier, R.M.C., Davies, A.G., Kamp, L.W., Mosher, J.A., Soderblom, L.A., Leader, F.E., Mehlman, R., Clark, R.N., Fanale, F.P., 1997. Geophys. Res. Lett. 24, 2479-2482], McEwen [McEwen, A.S., 1988. Icarus 73, 385-426] and Douté et al. [Douté, S., Schmitt, B., Lopes-Gautier, R., Carlson, R., Soderblom, L., Shirley, J., and The Galileo NIMS Team, 2001. Icarus 149, 107-132] to produce a self consistent explanation of the global distribution of SO₂. We propose that the differences between the above maps is attributable, in part, to the different bands that were studied by the investigators.     

Residual south polar cap of Mars: Stratigraphy, history, and implications of recent changes

The residual south polar cap (RSPC) of Mars includes a group of different depositional units of CO₂ ice undergoing a variety of erosional processes. Complete summer coverage of the RSPC by ∼6-m/pixel data of the Context Imager (CTX) on Mars Reconnaissance Orbiter (MRO) has allowed mapping and inventory of the units in the RSPC. Unit maps and estimated thicknesses indicate the total volume of the RSPC is currently <380 km³, and represents less than 3% of the total mass of the current Mars atmosphere. Scarp retreat rates in the CO₂ ice derived from comparison of High Resolution Imaging Science Experiment (HiRISE) data with earlier images are comparable to those obtained for periods up to 3 Mars years earlier. These rates, combined with sizes of depressions suggest that the oldest materials were deposited more than 125 Mars years ago. Most current erosion is by backwasting of scarps 1-12 m in height. This backwasting is initiated by a series of scarp-parallel fractures. In the older, thicker unit these fractures form about every Mars year; in thinner, younger materials they form less frequently. Some areas of the older, thicker unit are lost by downwasting rather than by the scarp retreat. A surprising finding from the HiRISE data is the scarcity of visible layering of RSPC materials, a result quite distinct from previous interpretations of layers in lower resolution images. Layers ∼0.1 m thick are exposed on the upper surfaces of some areas, but their timescale of deposition is not known. Late summer albedo changes mapped by the CTX images indicate local recycling of ice, although the amounts may be morphologically insignificant. Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) data show that the primary material of all the different forms of the RSPC is CO₂ ice with only small admixtures of water ice and dust.     

Mars CO2 cycle: Effects of airborne dust and polar cap ice emissivity

Mars General Circulation Model (GCM) simulations are presented to illustrate the importance of the ice emissivity of the seasonal CO₂ polar caps in regulating the effects of airborne dust on the martian CO₂ cycle. Simulated results show that atmospheric dust suppresses CO₂ condensation when the CO₂ ice emissivity is high but enhances it when the CO₂ ice emissivity is low. This raises the possibility that the reason for the repeatable nature of the CO₂ cycle in the presence of a highly variable dust cycle is that the CO₂ ice emissivity is “neutral” - the value that leads to no change in CO₂ condensation with changing atmospheric dust. For this GCM, the “neutral” emissivity is approximately 0.55, which is low compared to observed cap emissivities. This inconsistency poses a problem for this hypothesis. However, it is clear that the CO₂ ice emissivity is a critical physical parameter in determining how atmospheric dust affects the CO₂ cycle on Mars.     

Sulfurous acid (H2SO3) on Io?

Sulfurous acid (H₂SO₃) has never been characterized or isolated on Earth. This is caused by the unfavorable conditions for H₂SO₃ within Earth's atmosphere due to the high temperatures, the high water content and the oxidizing environment. Kinetic investigations by means of transition state theory showed that the half-life of H₂SO₃ at 300 K is 1 day but at 100 K it is increased to 2.7 billion years. Natural conditions to form H₂SO₃ presumably require cryogenic SO₂ or SO₂/H₂O mixtures and high energy proton irradiation at temperatures around 100 K. Such conditions can be found on the Jupiter moons Io and Europa. Therefore, we calculated IR-spectra of H₂SO₃ which we compared with Galileo's spectra of Io and Europa. From the available data we surmise that H₂SO₃ is present on Io and probably but to a smaller extent on Europa.     

Vertical profile of H2SO4 vapor at 70-110 km on Venus and some related problems

The vertical profile of H₂SO₄ vapor is calculated using current atmospheric and thermodynamic data. The atmospheric data include the H₂O profiles observed at 70-112 km by the SOIR solar occultations, the SPICAV-UV profiles of the haze extinction at 220 nm, the VeRa temperature profiles, and a typical profile of eddy diffusion. The thermodynamic data are the saturated vapor pressures of H₂O and H₂SO₄ and chemical potentials of these species in sulfuric acid solutions. The calculated concentration of sulfuric acid in the cloud droplets varies from 85% at 70 km to a minimum of 70% at 90 km and then gradually increasing to 90-100% at 110 km. The H₂SO₄ vapor mixing ratio is ∼10⁻¹² at 70 and 110 km with a deep minimum of 3 × 10⁻¹⁸ at 88 km. The H₂O-H₂SO₄ system matches the local thermodynamic equilibrium conditions up to 87 km. The column photolysis rate of H₂SO₄ is 1.6 × 10⁵ cm⁻² s⁻¹ at 70 km and 23 cm⁻² s⁻¹ at 90 km. The calculated abundance of H₂SO₄ vapor at 90-110 km and its photolysis rate are smaller than those presented in the recent model by Zhang et al. (Zhang, X., Liang, M.C., Montmessin, F., Bertaux, J.L., Parkinson, C., Yung, Y.L. [2010]. Nat. Geosci. 3, 834-837) by factors of 10⁶ and 10⁹, respectively. Assumptions of 100% sulfuric acid, local thermodynamic equilibrium, too warm atmosphere, supersaturation of H₂SO₄ (impossible for a source of SO_X), and cross sections for H₂SO₄·H₂O (impossible above the pure H₂SO₄) are the main reasons of this huge difference. Significant differences and contradictions between the SPICAV-UV, SOIR, and ground-based submillimeter observations of SO_X at 70-110 km are briefly discussed and some weaknesses are outlined. The possible source of high altitude SO_X on Venus remains unclear and probably does not exist.     

Distributions of H2O and CO2 ices on Ariel, Umbriel, Titania, and Oberon from IRTF/SpeX observations

We present 0.8-2.4 μm spectral observations of uranian satellites, obtained at IRTF/SpeX on 17 nights during 2001-2005. The spectra reveal for the first time the presence of CO₂ ice on the surfaces of Umbriel and Titania, by means of 3 narrow absorption bands near 2 μm. Several additional, weaker CO₂ ice absorptions have also been detected. No CO₂ absorption is seen in Oberon spectra, and the strengths of the CO₂ ice bands decline with planetocentric distance from Ariel through Titania. We use the CO₂ absorptions to map the longitudinal distribution of CO₂ ice on Ariel, Umbriel, and Titania, showing that it is most abundant on their trailing hemispheres. We also examine H₂O ice absorptions in the spectra, finding deeper H₂O bands on the leading hemispheres of Ariel, Umbriel, and Titania, but the opposite pattern on Oberon. Potential mechanisms to produce the observed longitudinal and planetocentric distributions of the two ices are considered.     

Europa’s disk-resolved ultraviolet spectra: Relationships with plasma flux and surface terrains

The full set of high-resolution observations from the Galileo Ultraviolet Spectrometer (UVS) is analyzed to look for spectral trends across the surface of Europa. We provide the first disk-resolved map of the 280 nm SO₂ absorption feature and investigate its relationship with sulfur and electron flux distributions as well as with surface features and relative surface ages. Our results have implications for exogenic and endogenic sources. The large-scale pattern in SO₂ absorption band depth is again shown to be similar to the pattern of sulfur ion implantation, but with strong variations in band depth based on terrain. In particular, the young chaos units show stronger SO₂ absorption bands than expected from the average pattern of sulfur ion flux, suggesting a local source of SO₂ in those regions, or diapiric heating that leads to a sulfur-rich lag deposit.While the SO₂ absorption feature is confined to the trailing hemisphere, the near UV albedo (300-310 nm) has a global pattern with a minimum at the center of the trailing hemisphere and a maximum at the center of the leading hemisphere. The global nature of the albedo pattern is suggestive of an exogenic source, and several possibilities are discussed. Like the SO₂ absorption, the near UV albedo also has local variations that depend on terrain type and age.     

Radiolysis of sulfuric acid, sulfuric acid monohydrate, and sulfuric acid tetrahydrate and its relevance to Europa

We report laboratory studies on the 0.8 MeV proton irradiation of ices composed of sulfuric acid (H₂SO₄), sulfuric acid monohydrate (H₂SO₄·H₂O), and sulfuric acid tetrahydrate (H₂SO₄·4H₂O) between 10 and 180 K. Using infrared spectroscopy, we identify the main radiation products as H₂O, SO₂, (S₂O₃)_x, H₃O⁺, , and . At high radiation doses, we find that H₂SO₄ molecules are destroyed completely and that H₂SO₄·H₂O is formed on subsequent warming. This hydrate is significantly more stable to radiolytic destruction than pure H₂SO₄, falling to an equilibrium relative abundance of 50% of its original value on prolonged irradiation. Unlike either pure H₂SO₄ or H₂SO₄·H₂O, the loss of H₂SO₄·4H₂O exhibits a strong temperature dependence, as the tetrahydrate is essentially unchanged at the highest irradiation temperatures and completely destroyed at the lowest ones, which we speculate is due to a combination of radiolytic destruction and amorphization. Furthermore, at the lower temperatures it is clear that irradiation causes the tetrahydrate spectrum to transition to one that closely resembles the monohydrate spectrum. Extrapolating our results to Europa’s surface, we speculate that the variations in SO₂ concentrations observed in the chaotic terrains are a result of radiation processing of lower hydration states of sulfuric acid and that the monohydrate will remain stable on the surface over geological times, while the tetrahydrate will remain stable in the warmer regions but be destroyed in the colder regions, unless it can be reformed by other processes, such as thermal reactions induced by diurnal cycling.