共查询到20条相似文献,搜索用时 140 毫秒
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利用太阳能驱动光催化反应制备氢气成为了目前的研究热点。综述了近年来在可见光下光催化分解水制氢的研究进展,着重介绍了固溶体光催化剂、非金属化合物型光催化剂、Z型光催化系统及新型助催化剂的最新研究成果,并展望了光催化制氢的发展。 相似文献
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据有关媒体报导,在利用具有可见光反应的半导体光催化剂,直接通过太阳能分解水生产氢气的研究方面,南京大学居世界领先地位。据悉,该校这方面的研究工作,是由著名的中青年专家、“长江学者”邹志刚教授领导的科研团队完成的。该校在世界上首次开发成功可见光响应型水全分解光催化剂;在世界上首次实现了在实际太阳光下光催化分解水制氢。现已开发成功具有可视光反应的半导体光催化剂,直接由太阳能分解有毒有害气体和物质,净化已被污染的环境;该校在世界上首次开发成功了室内用可见光响应型高效光催化剂; 相似文献
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用光还原方法制备了负载Cu的光催化剂Cu-TiO2,用染料Rose bengal敏化Cu-TiO2制备了具有可见光活性的Rose bengal-Cu-TiO2光催化剂,通过可见光(λ≥420nm)下分解水制氢考察了催化剂的活性,利用XRD、UV-vis吸收光谱对样品进行了表征.结果表明:载Cu增强了TiO2对可见光的吸收,Cu负载量对催化剂活性有一定的影响,Cu的最佳负载量为5%(质量分数).Cu的负载也增加了TiO2对染料的吸附,从而提高了TiO2对可见光的吸收和光催化活性. 相似文献
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Chengxiao Zhao Zupeng Chen Run Shi Xiaofei Yang Tierui Zhang 《Advanced materials (Deerfield Beach, Fla.)》2020,32(28):1907296
With the ambition of solving the challenges of the shortage of fossil fuels and their associated environmental pollution, visible-light-driven splitting of water into hydrogen and oxygen using semiconductor photocatalysts has emerged as a promising technology to provide environmentally friendly energy vectors. Among the current library of developed photocatalysts, organic conjugated polymers present unique advantages of sufficient light-absorption efficiency, excellent stability, tunable electronic properties, and economic applicability. As a class of rising photocatalysts, organic conjugated polymers offer high flexibility in tuning the framework of the backbone and porosity to fulfill the requirements for photocatalytic applications. In the past decade, significant progress has been made in visible-light-driven water splitting employing organic conjugated polymers. The recent development of the structural design principles of organic conjugated polymers (including linear, crosslinked, and supramolecular self-assembled polymers) toward efficient photocatalytic hydrogen evolution, oxygen evolution, and overall water splitting is described, thus providing a comprehensive reference for the field. Finally, current challenges and perspectives are also discussed. 相似文献
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We demonstrate plasmonic enhancement of photocatalytic water splitting under visible illumination by integrating strongly plasmonic Au nanoparticles with strongly catalytic TiO2. Under visible illumination, we observe enhancements of up to 66× in the photocatalytic splitting of water in TiO2 with the addition of Au nanoparticles. Above the plasmon resonance, under ultraviolet radiation we observe a 4-fold reduction in the photocatalytic activity. Electromagnetic simulations indicate that the improvement of photocatalytic activity in the visible range is caused by the local electric field enhancement near the TiO2 surface, rather than by the direct transfer of charge between the two materials. Here, the near-field optical enhancement increases the electron-hole pair generation rate at the surface of the TiO2, thus increasing the amount of photogenerated charge contributing to catalysis. This mechanism of enhancement is particularly effective because of the relatively short exciton diffusion length (or minority carrier diffusion length), which otherwise limits the photocatalytic performance. Our results suggest that enhancement factors many times larger than this are possible if this mechanism can be optimized. 相似文献
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Xu Guo Xing Liu Menglong Wang Junqing Yan Yubin Chen Shengzhong Liu 《Small (Weinheim an der Bergstrasse, Germany)》2023,19(19):2206695
Spinel cobalt oxide displays excellent photocatalytic performance, especially in solar driven water oxidation. However, the process of water reduction to hydrogen is considered as the Achilles’ heel of solar water splitting over Co3O4 owing to its low conduction band. Enhancement of the water splitting efficiency using Co3O4 requires deeper insights of the carrier dynamics during water splitting process. Herein, the carrier dynamic kinetics of colloidal Co3O4 quantum dots-Pt hetero-junctions is studied, which mimics the hydrogen reduction process during water splitting. It is showed that the quantum confinement effect induced by the small QD size raised the conduction band edge position of Co3O4 QDs, so that the ligand-to-metal charge transfer from 2p state of oxygen to 3d state of Co2+ occurs, which is necessary for overall water splitting and cannot be achieved in Co3O4 bulk crystals. The findings in this work provide insights of the photocatalytic mechanism of Co3O4 catalysts and benefit rational design of Co3O4-based photocatalytic systems. 相似文献
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光催化制取太阳能燃料主要包括光催化分解H2O制取H2及光催化还原CO2制取碳氢化合物, 是应对能源危机最具前景的方法之一。目前, 太阳能燃料的最高转化效率为5%, 无法满足商业化要求(≥10%)。纳米异质结由于能展现出单组分纳米材料或体相异质结所不具备的独特性质, 更能促进光生电子和空穴快速转移, 提供更多的光生电子或使光生电子具有更强的还原性, 因而能显著提高光催化活性。本文主要综述了几种纳米异质结(I-型、II-型、p-n型及Z-型)的光催化原理及其在制取太阳能燃料方面的研究进展, 并展望了研究发展方向。 相似文献
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利用太阳能制氢的方法及发展现状 总被引:1,自引:0,他引:1
发展清洁可再生能源是人类面临的巨大技术挑战,氢气作为一种理想的清洁能源,其制取及储运技术近年来都取得了很大进展。综述了利用太阳能分解水制氢的基本途径及发展现状,主要包括电解水制氢及人工模拟光合作用制氢、半导体光解水及其催化剂以及最有希望实现的高温热化学循环分解水制氢技术。 相似文献
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Photocatalytic water splitting into hydrogen and oxygen is a method to directly convert light energy into storable chemical energy, and has received considerable attention for use in large-scale solar energy utilization. Particulate semiconductors are generally used as photocatalysts, and semiconductor properties such as bandgap, band positions, and photocarrier mobility can heavily impact photocatalytic performance. The design of active photocatalysts has been performed with the consideration of such semiconductor properties. Photocatalysts have a catalytic aspect in addition to a semiconductor one. The ability to control surface redox reactions in order to efficiently produce targeted reactants is also important for photocatalysts. Over the past few decades, various photocatalysts for water splitting have been developed, and a recent main concern has been the development of visible-light sensitive photocatalysts for water splitting. This review introduces the study of water-splitting photocatalysts, with a focus on recent progress in visible-light induced overall water splitting on oxynitride photocatalysts. Various strategies for designing efficient photocatalysts for water splitting are also discussed herein. 相似文献
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Ali M. Huerta-Flores J. M. Mora-Hernández Leticia M. Torres-Martínez Edgar Moctezuma D. Sánchez-Martínez María E. Zarazúa-Morín Björn Wickman 《Journal of Materials Science: Materials in Electronics》2018,29(22):18957-18970
Limited visible light absorption, slow charge transference, and high recombination are some of the main problems associated with low efficiency in photocatalytic processes. For these reasons, in the present work, we develope novel zirconate–FeS2 heterostructured photocatalysts with improved visible light harvesting, effective charge separation and high photocatalytic water splitting performance. Herein, alkali and alkaline earth metal zirconates are prepared by a solid state reaction and coupled to FeS2 through a simple wet impregnation method. The incorporation of FeS2 particles induces visible light absorption and electron injection in zirconates, while the appropriate coupling of the semiconductors in the heterostructure allows an enhanced charge separation and suppression of the recombination. The obtained heterostructures exhibit high and stable photocatalytic activity for water splitting under visible light, showing competitive efficiencies among other reported materials. The highest hydrogen evolution rate (4490 µmol g?1 h?1) is shown for BaZrO3–FeS2 and corresponds to more than 20 times the activity of the bare BaZrO3. In summary, this work proposes novel visible light active heterostructures for efficient visible light photocatalytic water splitting. 相似文献
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Photocatalytic water splitting is a cost-effective way to convert sustainable solar energy into chemical energy. Among various photocatalytic systems, coupling the H2- and O2- evolving photocatalysts has been widely used in photocatalytic water splitting. However, due to the close spatial distance between surface electrons and surface holes, this heterogeneous material easily catalyzes the unwanted reverse reaction, limiting the solar energy conversion efficiency. Here we present a carbon nitride nanosheet (CNN) homojunction which possesses electrons-enriched region and holes-enriched region induced by the interfacial internal electric field. The reverse reactions are significantly suppressed by benefiting from the spatial separation of the oxidation (+2.21 V) and reduction (-1.19 V) regions. The homojunction exhibits efficient photocatalytic activity for H2 and O2 evolution (1270.5 and 36.0 μmol h−1) with the scavenger. Meanwhile, the solar-to-hydrogen efficiency of overall water splitting was improved to 0.14%. This research provides a new way for semiconductor design in solar energy conversion applications. 相似文献