共查询到19条相似文献,搜索用时 78 毫秒
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分别以活性炭(AC)和色氨酸(L-Trp)作为两种不同类型载体,通过溶胶-凝胶法制得TiO2/AC和TiO2/L-Trp光催化剂,比较了两种载体对亚甲基蓝(MB)吸附和光降解反应的性能影响,分析了其反应机理,并对光催化剂进行了表征分析。实验结果表明,TiO2/AC和TiO2/L-Trp的最优煅烧温度均为550℃,最优用量均为1 g/L。表征结果表明,TiO2/AC和TiO2/L-Trp均负载了以锐钛矿型存在的TiO2,TiO2/AC比表面积大于TiO2/L-Trp。动力学拟合结果表明TiO2/AC和TiO2/L-Trp光催化剂光降解MB受其扩散步骤控制。 相似文献
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《浙江化工》2019,(6)
以硝酸锌、二甲基咪唑(制备沸石咪唑酯骨架结构材料(ZIF)的主要原料)、以及硝酸铈等制备了Ce掺杂的Zn O光催化剂(即Ce-ZnO),对催化剂进行了XRD,SEM,EDS等表征分析,考察了Ce掺杂量、废水初始pH等对亚甲基蓝降解影响,用UV-Vis(可见-紫外光谱)对亚甲基蓝降解液进行了分析。研究表明,与ZIF为前驱体的Zn O的形貌和晶体结构类似,Ce掺杂的Zn O催化剂仍为方形颗粒微纳米材料(颗粒尺寸约100 nm)、Zn O为六方晶系纤锌矿结构,但颗粒尺寸减小。掺杂1%的Ce可使Zn O的光催化剂活性提高(光催化剂降解亚甲基蓝的反应速率提高了31%),且具有较好的重复利用性能。Ce-ZnO光催化剂催化降解亚甲基蓝的反应符合一级反应动力学,弱碱性(pH≈10)环境有利于亚甲基蓝光催化剂降解,亚甲基蓝在光催化反应中其显色基团、芳香基团被分解并产生了酸性物质,亚甲基蓝被有效降解。 相似文献
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选取亚甲基蓝染料为降解目标物,研究了ZnO掺杂TiO2为催化剂的可见光催化反应,重点考察了ZnO的掺杂量、催化剂的添加量、溶液初始浓度、光照时间、溶液pH值对降解效率的影响。实验结果表明,在ZnO掺杂比为0.5%、ZnO掺杂TiO2的催化剂用量为10g/L、pH为8、浓度为2mg/L的亚甲基蓝100mL,白炽灯光照降解... 相似文献
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摘要:选用掺杂锌的纳米TiO2作为光催化剂对亚甲基蓝进行降解研究。制备工艺参数对样品光催化降解亚甲基蓝的活性具有很大影响,焙烧温度为500oC,Zn2+掺入量为0.5%,催化剂的加入量为1g/L时光催化剂对亚甲基蓝的降解效果最好;亚甲基蓝的初始浓度为5mg/L降解速率较快。 相似文献
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掺锌纳米TiO_2光催化降解亚甲基蓝研究 总被引:1,自引:0,他引:1
选用掺杂锌的纳米TiO2作为光催化剂对亚甲基蓝进行降解研究。制备工艺参数对样品光催化降解亚甲基蓝的活性具有很大影响,焙烧温度为500℃,Zn2+掺入量为0.5%,催化剂的加入量为1 g/L时光催化剂对亚甲基蓝的降解效果最好;亚甲基蓝的初始浓度为5 mg/L降解速率较快。 相似文献
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采用三种不同方法对TiO2粉末进行改性,制得蒙脱土/TiO2、Ag/TiO2和SO42-/TiO2催化剂。以亚甲基水蓝溶液的脱色率为指标,采用XRD、SEM和XPS等手段分析考察了3种改性催化剂的活性及抗无机离子的干扰能力。结果显示,三种改性光催化剂在溶液中的活性顺序为:蒙脱土/TiO2>SO42-/TiO2>Ag/TiO2>TiO2。其中,蒙脱土/TiO2活性提高最大,在温度30 ℃和催化剂用量1.0 g·L-1条件下,1 h内使 5.0 mg·L-1的亚甲基蓝溶液的脱色率达90%以上,Ag/TiO2的抗无机离子干扰能力最强。 相似文献
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《Catalysis communications》2010,11(15):1957-1961
The photocatalytic removal of sodium pentachlorophenate (PCP-Na) over BiOI nanosheets under simulated solar light irradiation has been studied. BiOI nanosheets exhibited an excellent photocatalytic activity to remove PCP-Na from aqueous solution driven by simulated light. The photocatalytic reaction over BiOI nanosheets followed the pseudo first-order reaction, owning to its weak adsorption behavior to PCP-Na molecules and low initial PCP-Na concentration. Finally, the photocatalytic mechanism was investigated initially on the basis of the experimental result and band edge potential analysis. 相似文献
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《Applied catalysis. B, Environmental》2003,40(2):131-140
Photocatalytic degradation of cationic blue X-GRL (CBX), a strongly adsorbing substrate on TiO2/SiO2, has been investigated by diffuse reflection UV–VIS spectra (UV–visible/DRS) and FT-IR methods. The heterogeneous photocatalysis processes include: adsorption of dye, surface reaction and desorption of final products. The adsorption of CBX onto the surface of TiO2/SiO2 was characterized, and the effect of initial pH of solution on the adsorption was determined. The results demonstrated that CBX was strongly adsorbed at the TiO− site of the catalyst by a penta-heterocyclic-N group. The adsorbed CBX was monitored directly by the UV–VIS/DRS technique during the photodegradation. The results confirmed that the surface photodegradation reaction of CBX was predominantly procedure with the mechanism of direct charge transfer from the semiconductor to the dye adsorbed at TiO center, and its reaction followed the pseudo-first-order kinetics. This mechanism resulted in the formation of more aliphatic amines and/or amide byproducts, which were further transformed to NH4+. 相似文献
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In this paper, the synthesis of AgBr/TiO2 catalyst and the photocatalytic activity in water under simulated sunlight irradiation were studied. The influence of AgBr content in catalyst and the incident light intensity on the degradation of methyl orange (MO) was investigated. It was found that the initial reaction rate constant was dependent on the relative levels of AgBr content and incident light intensity, ranging between 0.008 min−1 and 0.023 min−1. At higher levels of AgBr content (>9 wt%), MO degradation was exclusively dependent on the incident light intensity, which implied that the excessive AgBr in catalyst had negligible effect on catalyst activity. However, at lower AgBr contents, the reaction rate increased with the increase of incident light intensity, and eventually reached a plateau level, indicating that the degradation of MO was limited by AgBr content. The results from powder X-ray diffraction (XRD) analysis showed that more than 80% of AgBr remained intact after 14 h of irradiation, although metallic silver was also detected. 相似文献
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Photodegradation of methylene blue with a titanium dioxide/polyacrylamide photocatalyst under sunlight 下载免费PDF全文
Hydrogels containing TiO2 nanoparticles (NPs) have photocatalytic properties and degrade pollutants under light. In this study, a polyacrylamide (PAAm) hydrogel was synthesized with TiO2 P25 NPs as the initiator, acrylamide as a monomer, and N,N′‐methylene bisacrylamide as a crosslinker in aqueous media under sunlight. Fourier transform infrared spectroscopy, thermogravimetric analysis, scanning electron microscopy, and transmission electron microscopy were applied to characterize the TiO2/PAAm hydrogel. The effects of different synthetic conditions, such as the initiator concentration, crosslinker, and dilution, on swelling were investigated. The maximum swelling of the TiO2/PAAm hydrogel was 45 g/g in the hydrogel synthesized with optimum conditions by 0.2% TiO2. The photocatalytic degradability of the hydrogel was investigated with methylene blue (MB) as the pollutant target. Also, the effects of the pH and MB concentration were studied. Under optimum conditions, 95.00% of the MB was degraded by the TiO2/PAAm photocatalyst after 5 h of irradiation under sunlight. The comparison of the results with those of the TiO2 P25 powder showed that the TiO2 NPs had better activity than the hydrogel, but unlike the hydrogel, the activity of these NPs decreased in each recycling time because of the aggregation of NPs. Finally, the hydrogel was recycled seven times without a considerable reduction in the degradation efficiency. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43386. 相似文献
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Aubrey Makofane David E. Motaung Nomso C. Hintsho-Mbita 《Ceramics International》2021,47(16):22615-22626
The extensive occurrence of textile and pharmaceutical contaminants and their metabolites in water systems has posed significant concerns regarding their possible threat to human health and the environmental system. As a result, herein ZnFe2O4 nanoparticles were synthesized through the use of Monsonia burkeana plant extract. The synthesized nanoparticles were characterized using XRD, FTIR, UV–vis, SEM, EDS, TGA, BET, PL, EPR and VSM. XRD showed that the crystalline structure of ZnFe2O4 nanoparticles with a calculated crystal size of 25.03 nm was formed. FT-IR confirmed the characteristic functional groups contained within the M. burkeana plant were deposited on the formed ferrite nanoparticles. BET analysis confirmed the mesoporous nature of ZnFe2O4 with an average pore diameter of 31.6 nm. Morphological studies demonstrated that the formed nanoparticles had spherical as well as rod-like shapes. ZnFe2O4 photocatalyst illustrated that it may be effortlessly detached by an external magnetic field. The optimum conditions for the 99.8% removal of Methylene Blue was obtained at pH12, within 45min and at the optimum dosage of 25 mg of the catalyst. The as-prepared ZnFe2O4 nanoparticles proved to be easily separated and recycled, and remained efficient even after 5 reuses, proving that the material is highly stable. The ROS studies also demonstrated that electrons are the main factors contributing to the degradation of MB. Upon testing the photocatalytic performance of the sulfonamide antibiotic, sulfisoxazole in water showed a degradation of 67%. This study has shown that these materials can be used in targeting textile and pharmaceutically polluted water. 相似文献